We report here a high-performance catalyst ReMoSx@HSSZ-39 compounded with SAPO-34 for conversion of CO2 to C2-4 hydrocarbons, in which the ReMoSx clusters are responsible for highly efficient hydrogenation of CO2 to methanol as the intermediate and then the surrounding zeolitic acid sites for further conversion of methanol to hydrocarbons. The investigation finds that uniform ReMoSx clusters can be reliably fabricated in zeolitic cages by co-introduction of rhenium and molybdenum species into the HSSZ-39 zeolite and followed by sulfidation, which constitutes an intimate bifunction catalyst through better cooperation of ReMoSx clusters and the zeolitic acid sites. Compared with MoSx@HSSZ-39, the introduction of rhenium significantly suppresses CO generation. By mixing some SAPO-34 zeolite, with increased density of protonic acid, more than 86 % C2-4 hydrocarbons in organic products and only 21 % CO at 32.5 % of CO2 conversion are obtained and the composite catalyst shows excellent stability with more than 95 % C2-4 hydrocarbons in organic products, less than 30 % CO and above 26.6 % of CO2 conversion after 1000 h on stream.