Salt Accumulation Research Articles

Using a Graph Convolutional Neural Network Model to Identify Bile Salt Export Pump Inhibitors.

The bile salt export pump (BSEP) is a key transporter involved in the efflux of bile salts from hepatocytes to bile canaliculi. Inhibition of BSEP leads to the accumulation of bile salts within the hepatocytes, leading to possible cholestasis and drug-induced liver injury. Screening for and identification of chemicals that inhibit this transporter aid in understanding the safety liabilities of these chemicals. Moreover, computational approaches to identify BSEP inhibitors provide an alternative to the more resource-intensive, gold standard experimental approaches. Here, we used publicly available data to develop predictive machine learning models for the identification of potential BSEP inhibitors. Specifically, we analyzed the utility of a graph convolutional neural network (GCNN)-based approach in combination with multitask learning to identify BSEP inhibitors. Our analyses showed that the developed GCNN model performed better than the variable-nearest neighbor and Bayesian machine learning approaches, with a cross-validation receiver operating characteristic area under the curve of 0.86. In addition, we compared GCNN-based single-task and multitask models and evaluated their utility in addressing data limitation challenges commonly observed in bioactivity modeling. We found that multitask models performed better than single-task models and can be utilized to identify active molecules for targets with limited data availability. Overall, our developed multitask GCNN-based BSEP model provides a useful tool for prioritizing hits during early drug discovery and in risk assessment of chemicals.

A simulation-based multi-objective two-level optimization decision-making approach for supporting balanced irrigation water management

In this study, a simulation-based multi-objective two-level optimization decision-making approach is developed for optimal irrigation water allocation, improving irrigation water productivity and controlling regional accumulated salts. Techniques of multi-objective programming, two-level programming and simulation model of water and salt physical movement process are incorporated into the modeling framework. The simulated processes are parameterized and calibrated with field experimental data while the optimization model is used to generate optimal solutions though predefined objectives and the associated constraints. This model is applied to a case study on irrigation water allocation in the Jiefangzha Irrigation Subarea in Hetao Irrigation District, Northwest China. Firstly, the study area is delineated into several homogeneous irrigation decision-making units (IDMUs) for better characterizing their spatial variability because it’s spatially heterogeneous. Afterwards, decomposition-coordination algorithm is introduced to solve such an integrated simulation-based multi-objective two-level optimization model. Finally, optimal solutions of irrigation water allocation for different crops during crop growth periods in different IDMUs can be obtained for supporting sustainable strategies of irrigation. The results can achieve balanced tradeoffs between different stakeholders (i.e., the upper-level decision-makers and the lower-level farmers) and between conflicting economic objectives and environmental objectives. Moreover, optimal solutions have a slight increase in economic returns over the baseline scenario (i.e., status quo), but the irrigation water productivity is increased by nearly 60% due to less irrigation water used. Regional accumulated salts can be controlled because the soil salinity is constrained within the predetermined salt accumulation constraint. Therefore, these findings can provide evidence for efficient use of irrigation water resources and further support of sustainable irrigated agriculture.

Three-Dimensional Mirror-Assisted and Concave Pyramid-Shaped Solar-Thermal Steam Generator for Highly Efficient and Stable Water Evaporation and Brine Desalination.

Although significant advances have been achieved in developing solar-driven water evaporators for seawater desalination, there is still room for simultaneously enhancing water evaporation efficiency, salt resistance, and utilization of solar energy. Herein, for the first time, we demonstrate a highly efficient three-dimensional (3D) mirror-assisted and concave pyramid-shaped solar-thermal water evaporation system for high-yield and long-term desalination of seawater and brine water, which consists of a 3D concave pyramid-shaped solar-thermal architecture on the basis of polypyrrole-coated nonwoven fabrics (PCNFs), a 3D mirror array, a self-floating polystyrene foam layer, and a tail-like PCNF for upward transport of water. The 3D concave pyramid-shaped solar-thermal architecture enables multiple solar light reflections to absorb more solar energy, while the 3D mirror-assisted solar light enhancement design can activate the solar-thermal energy conversion of the back side of the concave pyramid-shaped PCNF architecture to improve the solar-thermal energy conversion efficiency. Crucially, selective accumulation of the precipitated salts on the back side of the concave pyramid-shaped architecture is realized, ensuring a favorable salt-resistant feature. The 3D mirror-assisted and concave pyramid-shaped solar-driven water evaporation system achieves a record high water evaporation rate of 4.75 kg m-2 h-1 under 1-sun irradiation only and exhibits long-term desalination stability even when evaporating high-salinity brine waters, demonstrating its great applicability and reliability for high-yield solar-driven desalination of seawater and high-salinity brine water.

Soil Nutrient, Salinity, and Alkalinity Responses of Dendrocalamopsis oldhami in High-Latitude Greenhouses Depending on Planting Year and Nitrogen Application

This study explored the viability of greenhouse cultivation of Dendrocalamopsis oldhami under the “South Bamboo North Transplanting” initiative. In this study, the effects of planting year and nitrogen application on changes in soil nutrient levels, salinity, and alkalinity over the plant growth period were explored. After the introduction and planting of bamboo in 2017, a soil layer with a thickness of 0–40 cm was sampled at the end of the shooting stage in the greenhouse between 2017 and 2019 (late August), and the bamboo shoot yield and standing culm density were measured. Following the application of nitrogen to the bamboo groves in 2019, three nitrogen levels were established: no nitrogen (N1:0 g grove−1), medium nitrogen (N2:540 g grove−1), and high nitrogen (N3:1080 g grove−1). Soil layers at depths of 0–20 and 20–40 cm were sampled during the shoot elongation stage (late May) and at the end of the shooting stage (late August). The yield and nutrient content of bamboo shoots under different nitrogen treatments were also investigated. The results showed that Ca2+ and HCO3− were the main salt ions in greenhouse soil. With later planting years, the total number of cations (Ca2+, Na+, Mg2+, and K+) decreased, whereas the total number of anions (HCO3−, SO42−, NO3−, and Cl−) increased, resulting in a decrease in the percentage of exchangeable sodium (ESP), pH, and electrical conductivity (EC). The diameter at breast height, individual weight, and quantity of bamboo shoots increased annually, and the standing culm density increased by 1.4 times. Each year, the total nitrogen content decreased, whereas the alkali-hydrolyzed nitrogen, available phosphorus, and available potassium contents increased. Nitrogen application resulted in a significant decrease in ESP and pH and an increase in the total anion, cation, and EC values. It also reduced soil organic carbon, total nitrogen, total phosphorus, total potassium, available phosphorus, and available potassium. Nitrogen application increased the number of bamboo shoots, total yield, and accumulation of N and P; however, there was no significant difference between N2 and N3. In conclusion, the salinization of calcareous soil was alleviated, and the available nutrients were activated following the introduction of D. oldhami from south to north. The mineralization rates of organic matter and soil fertility increased. Soil acidification and EC decreased at the end of the shoot stage. Nitrogen application acidified the soil, and the yield and soil salt accumulation increased with increasing nitrogen levels. The nutrient uptake efficiencies of nutrients at high nitrogen levels were lower than those at medium nitrogen levels. Therefore, soil salt concentrations with values 0.26 < EC < 0.42 hindered the nutrient uptake of D. oldhami.

Role of mitochondria in the myopathy of juvenile dermatomyositis and implications for skeletal muscle calcinosis

ObjectivesTo elucidate mechanisms contributing to skeletal muscle calcinosis in patients with juvenile dermatomyositis. MethodsA well-characterized cohorts of JDM (n = 68), disease controls (polymyositis, n = 7; juvenile SLE, n = 10, and RNP + overlap syndrome, n = 12), and age-matched health controls (n = 17) were analyzed for circulating levels of mitochondrial (mt) markers including mtDNA, mt-nd6, and anti-mitochondrial antibodies (AMAs) using standard qPCR, ELISA, and novel-in-house assays, respectively. Mitochondrial calcification of affected tissue biopsies was confirmed using electron microscopy and energy dispersive X-ray analysis. A human skeletal muscle cell line, RH30, was used to generate an in vitro calcification model. Intracellular calcification is measured by flow cytometry and microscopy. Mitochondria were assessed for mtROS production and membrane potential by flow cytometry and real-time oxygen consumption rate by Seahorse bioanalyzer. Inflammation (interferon-stimulated genes) was measured by qPCR. ResultsIn the current study, patients with JDM exhibited elevated levels of mitochondrial markers associated with muscle damage and calcinosis. Of particular interest are AMAs predictive of calcinosis. Human skeletal muscle cells undergo time- and dose-dependent accumulation of calcium phosphate salts with preferential localization to mitochondria. Calcification renders skeletal muscle cells mitochondria stressed, dysfunctional, destabilized, and interferogenic. Further, we report that inflammation induced by interferon-alpha amplifies mitochondrial calcification of human skeletal muscle cells via the generation of mitochondrial reactive oxygen species (mtROS). ConclusionsOverall, our study demonstrates the mitochondrial involvement in the skeletal muscle pathology and calcinosis of JDM and mtROS as a central player in the calcification of human skeletal muscle cells. Therapeutic targeting of mtROS and/or upstream inducers, such as inflammation, may alleviate mitochondrial dysfunction, leading to calcinosis. AMAs can potentially identify patients with JDM at risk for developing calcinosis.

Bioponics—An Organic Closed-Loop Soilless Cultivation System: Yields and Characteristics Compared to Hydroponics and Soil Cultivation

Sustainable food production has become increasingly important. Soilless cultivation systems offer several advantages, such as water and nutrient use efficiency, and can be implemented where traditional agriculture is impossible. Bioponic systems use locally or regionally available nutrient sources from organic waste streams (either fluid or solid) and can thus contribute to closing nutrient cycles locally. Bioponics harnesses the metabolic processes of microorganisms which release nutrients from organic matter. This study aimed to set up a bioponic system, by using biogas digestate concentrate and biochar as nutrient sources, and promoting nutrient release from the organic sources by including a biofilter in the system. The development of water quality, plant growth, and quality was monitored extensively. In addition, the influence of either the fungal biocontrol agent Trichoderma atrobrunneum or UV-C treatment of the nutrient solution on plant health and growth was investigated. Three cultivation cycles with Lactuca sativa (“HAWKING” Salanova®) in bioponic (BP), hydroponic (HP), and soil (SO) cultivation were performed. The study showed that healthy lettuces could be produced in BP systems, using a biogas digestate concentrate and biochar as nutrient sources, despite salt accumulation in the nutrient solution. In plant sap analyses, lettuces cultivated in BP systems contained less nitrate but more ammonium and chloride. The yield of the lettuces grown in the BP systems was intermediate, compared to the HP and the SO. The fungus, T. atrobrunneum, strain, T720, survived in soil and soilless cultivation systems. Compared to the HP and the SO systems, the shoot height of lettuces grown in the BP system, with the application of Trichoderma, was significantly increased. In SO systems with Trichoderma application, a significantly higher chlorophyll and flavonoid content, but significantly lower shoot height was observed. The fresh weight of lettuce roots was significantly higher in HP systems with Trichoderma treatment. Cultivating plants by using organic waste streams requires commitment and experience from producers. In BP systems, a biofilter (either within the system or externally, to increase nutrient levels) can help to rapidly convert the ammonium-rich fertilizer to plant-available nutrients. Unlike conventional HP systems, in BP systems, nutrients are released slowly over time, requiring close monitoring and adjustments. In conclusion, healthy lettuces for human consumption can be produced in BP systems, and the application of the biocontrol agent used has some beneficial influence on plant growth.

Solar-driven evaporation device based on coal-derived nanomaterials for efficient and stable desalination

Solar-driven interfacial evaporation is considered as an effective and environmental-friendly pathway to address the issues of water shortages and pollution. Small-size evaporators with high evaporation rates based on expensive materials and complex preparation processes have been widely reported. However, attentions have rarely focused on the methods for continuous mass production of photo-thermal active materials, with which to develop a low-cost, efficient, and simple production evaporator with high performance. Herein, using low-cost materials such as coal-based carbon nanomaterial (CCN) based on wet ball milling and commercial filter paper, the CCN/filter paper evaporators are fabricated via solution impregnation method for solar-driven interface desalination. As a result, the CCN/filter paper evaporator under optimized conditions can achieve an evaporation rate of 1.40 kg m-2h−1 and conversion efficiency of 90.1%, even works in a 10% wt% NaCl solution, as well as stably working 10 h with an evaporation rate of 1.35 kg m-2h−1 without salt accumulation. Importantly, the large-scale evaporator developed for outdoor experiment can produce freshwater that meets the drinking water standard of WHO at an evaporation rate of about 6.48 kg m−2 day−1. The work demonstrates a simple and effective strategy for producing membrane evaporator with high-performance solar steam generation and superior salt rejection capability at low cost from a laboratory scale to an industrial scale, which can potentially be utilized in efficient, long-term and stable seawater desalination.

Microbiota-Liver-Bile Salts Axis, a Novel Mechanism Involved in the Contrasting Effects of Sodium Selenite and Selenium-Nanoparticle Supplementation on Adipose Tissue Development in Adolescent Rats.

Adolescence is a period during which body composition changes deeply. Selenium (Se) is an excellent antioxidant trace element related to cell growth and endocrine function. In adolescent rats, low Se supplementation affects adipocyte development differently depending on its form of administration (selenite or Se nanoparticles (SeNPs). Despite this effect being related to oxidative, insulin-signaling and autophagy processes, the whole mechanism is not elucidated. The microbiota-liver-bile salts secretion axis is related to lipid homeostasis and adipose tissue development. Therefore, the colonic microbiota and total bile salts homeostasis were explored in four experimental groups of male adolescent rats: control, low-sodium selenite supplementation, low SeNP supplementation and moderate SeNPs supplementation. SeNPs were obtained by reducing Se tetrachloride in the presence of ascorbic acid. Supplementation was received orally through water intake; low-Se rats received twice more Se than control animals and moderate-Se rats tenfold more. Supplementation with low doses of Se clearly affected anaerobic colonic microbiota profile and bile salts homeostasis. However, these effects were different depending on the Se administration form. Selenite supplementation primarily affected liver by decreasing farnesoid X receptor hepatic function, leading to the accumulation of hepatic bile salts together to increase in the ratio Firmicutes/Bacteroidetes and glucagon-like peptide-1 (GLP-1) secretion. In contrast, low SeNP levels mainly affected microbiota, moving them towards a more prominent Gram-negative profile in which the relative abundance of Akkermansia and Muribaculaceae was clearly enhanced and the Firmicutes/Bacteroidetes ratio decreased. This bacterial profile is directly related to lower adipose tissue mass. Moreover, low SeNP administration did not modify bile salts pool in serum circulation. In addition, specific gut microbiota was regulated upon administration of low levels of Se in the forms of selenite or SeNPs, which are properly discussed. On its side, moderate-SeNPs administration led to great dysbiosis and enhanced the abundance of pathogenic bacteria, being considered toxic. These results strongly correlate with the deep change in adipose mass previously found in these animals, indicating that the microbiota-liver-bile salts axis is also mechanistically involved in these changes.

CsbD, a Novel Group B Streptococcal Stress Response Factor That Contributes to Bacterial Resistance against Environmental Bile Salts.

Group B Streptococcus (GBS) can cause many serious infections and result in severe symptoms depending on the infected organs. To survive and initiate infection from the gastrointestinal tract, GBS must resist physiochemical factors, such as bile salts, a potent antibacterial compound in the intestine. We found that GBS isolated from diverse sources all possess the capability to defend bile salts and permit survival. By constructing the GBS A909 transposon mutant library (A909Tn), we identified several candidate genes that might participate in the bile salt resistance of GBS. The rodA and csbD genes were validated as relevant to bile salt resistance. The rodA gene was anticipated to be related to peptidoglycan synthesis and influence the bile salt resistance of GBS by cell wall construction. Notably, we found that the csbD gene worked as a bile salt resistance response factor and influenced several ABC transporter genes, specifically at the later growth period of GBS under bile salt stress. We further detected the marked intracellular bile salt accumulation in ΔcsbD by hydrophilic interaction chromatography-liquid chromatography/mass spectrometry (HILIC-LC/MS). Collectively, we showed a novel GBS stress response factor, csbD, contributes to bacterial survival in bile salts by sensing bile salt stress and subsequently induces transcription of transporter genes to excrete bile salts. IMPORTANCE GBS, a conditional pathogenetic colonizer of the human intestinal flora, can cause severe infectious diseases in immunocompromised patients. Therefore, it is critical to understand the factors that contribute to the resistance to bile salts, which are abundant in the intestine but harmful to bacteria. We identified rodA and csbD genes involved in bile salt resistance using a transposon insertion site sequencing (TIS-seq) based screen. The rodA gene products might be involved in peptidoglycan synthesis as important contributors to stress resistance including bile salts. However, the csbD gene conferred bile salt resistance by promoting transporter genes transcription at the later growth period of GBS in response to bile salts. These findings developed a better understanding of the stress response factor csbD on the bile salt resistance of GBS.

Bis-triazole linked organosilane based sensing platform for Cu2+ ions and insilico tyrosinase inhibitor activity

The development of a ligand for their selective and sensitive detection is required due to the widespread use of Cu2+ in many industrial processes and the potential threat to human health. Herein, we report a bis-triazole linked organosilane (5) derived from the Cu(I) catalyzed azide-alkyne cycloaddition reaction. The synthesized compound 5 was characterized by (1H and 13C) NMR spectroscopic and mass spectrometry techniques. The UV–Visible and Fluorescence experiments of the designed compound 5 were performed with various metal ions, revealing its high selectivity and sensitivity to Cu2+ ions in MeOH: H2O (8:2, v/v, pH = 7.0, PBS buffer) solution. The selective fluorescence quenching upon addition of Cu2+ to the compound 5 is due to Photo-induced electron transfer process (PET). The limit of detection of compound 5 to Cu2+ was calculated as 2.56 × 10−6 M and 4.36 × 10−7 M through UV–Visible and Fluorescence titration data, respectively. The possible mechanism of 1:1 binding of 5 with Cu2+ could be affirmed by the density functional theory (DFT). Further, it was found that compound 5 showed a reversible behavior towards Cu2+ ions by the accumulation of sodium salt of CH3COO– which can be used in the construction of molecular logic gate where Cu2+ and CH3COO– are considered as inputs and the absorbance at 260 nm as output. Moreover, the molecular docking studies provide useful information about compound 5′s interaction with the tyrosinase enzyme (PDB ID- 2Y9X).

Salt-resistant agarose-polyvinylpyrrolidone composite hydrogel with pitted-surface towards highly efficient water desalination and purification

In recent years, solar energy interfacial evaporation technology has been extensively explored for seawater desalination and wastewater treatment. However, salt accumulation and complex fabrication of evaporator largely constrains the applications of this technology in practice. Here, one type of interpenetrating polymer network hydrogel composing of agarose (AG) and polyvinylpyrrolidone (PVP) using polypyrrole (PPy) as the light absorbent was fabricated via “hot-ice” template method, which was featured with pitted-surface and microchannels structure. The evenly arranged pits on the surface of the hydrogel can absorb the sunlight as much as possible and convert it into heat energy, improving the efficiency of photothermal absorption. The water channels generated by the formation of CaCl2·6H2O crystals can transport water from the bottom to the evaporation interface elevating the transmission rate and accelerating the exchange of gradient salt concentration. As consequences, excellent salt resistance of the hydrogel can be obtained, achieving seawater evaporation rate as high as 3.2 kg m−2 h−1. In addition, the outstanding ion rejection performance, strong acid/alkali purification capability, and good treatment capacity for heavy metal ions and dye wastewater were also demonstrated.

Electrodialysis Membrane Technology applied to MEG reclamation – a case study

At Beach Energy’s Otway Gas Plant (OGP) the mono-ethylene glycol (MEG) system salt concentration increased significantly following the commissioning of new subsea horizontally completed wells. Therefore, to de-risk future developments, which are anticipated to include similar wells, a salt removal strategy was implemented. The use of MEG for gas hydrate suppression in wet-raw gas subsea or onshore production pipelines is common across the oil and gas industry, with the MEG recycled using well-proven regeneration and/or reclamation technologies. The MEG extracts water that can contain residual salt and minerals, which over time accumulate in the MEG and can lead to several operational issues, including severe fouling in the MEG regeneration plant, production line blockages and production pipeline integrity concerns, such as accelerated corrosion. MEG reclamation is used to minimise salt accumulation and to date, the dominant technologies employed have been vacuum distillation or flash vaporisation. However, since early 2022, electrodialysis (ED) membrane technology has been deployed at the OGP in an effort to find a more cost-effective solution. The technology is proving a viable alternative to a traditional vacuum distillation reclaiming–regeneration process with energy savings of 17–28% for a hybrid ED-Regeneration process with significantly lower capital cost. This paper details the technical and operational challenges overcome to implement the ED reclamation technology in an industry with more stringent regulatory requirements when compared to typical ED applications (e.g. within the water treatment, pharmaceutical, and food and beverage industries), as well as present the main system performance outcomes following 6 months of operation.

Numerical study on the spatial–temporal distribution of solute and salt accumulation in saturated sulfate saline soil during freezing–thawing processes: Mechanism and feedback

Knowledge of freezing–thawing (F–T) cycles of sulfate saline soil is crucial regarding the spatial–temporal distribution of solutes in the soil, soil salinization, and cold region engineering in sulfate saline soil areas. F–T tests of saturated sulfate saline soils with different salt contents, water supply conditions, and the number of F–T cycles were conducted. The coupling mechanism of water and salt migration, ice–water phase change, salt crystallization–dissolution, and deformation caused by salt expansion and frost heave of saturated sulfate saline soil during F–T processes were analyzed. A water–heat–salt–mechanics coupling mathematical model for saturated sulfate saline soil under F–T cycles is proposed using the modified salt crystallization–dissolution kinetics model. The results show that the calculated profiles of temperature, water content, concentration, and soil displacement are in good agreement with the experimental data, demonstrating that the proposed coupling model can describe the coupled water–heat–salt–mechanics process of sulfate saline soil during F–T processes. Additionally, the modified salt crystallization–dissolution kinetics model employing the FREZCHEM model can theoretically reveal the processes of salt crystal growth and dissolution. Also, the water and temperature potential gradients are the main driving force for water migrating toward the freezing front. Convection and diffusion are the dominant factors for the spatial–temporal distribution of solutes of sulfate saline soil subjected to F–T cycles, causing salt accumulation and precipitation and forming subflorescence in the frozen and unfrozen layers near the freezing front and efflorescence in the soil surface–layer at a certain number of F–T cycles. Due to the blocking effect of salt accumulation and precipitation on water and salt migration, salt expansion during freezing and residual deformation during thawing gradually stabilize with the increase of F-T cycles.

Spatiotemporal Variation in Saline Soil Properties in the Seasonal Frozen Area of Northeast China: A Case Study in Western Jilin Province

Due to the impact of climate change and human activities, the problem of soil salinization is increasingly prominent, posing a threat to the safety of the ecological environment and engineering construction. To understand the development tendency of soil salinization, this paper took the saline soil in Western Jilin province as the research object and carried out a long–term investigation into the basic properties of the soil at several monitoring stations. The results showed that the properties of saline soil in Western Jilin province changed regularly at the spatial and temporal scales. In the longitudinal profile, the water content, soluble salt content, and organic matter content in the soil vary greatly with the seasons at a depth range of 0–50 cm, while their changes below 50 cm are not significant. This is related to the influence depth of the external environment. Meanwhile, the content of sand is relatively stable in the depth direction, mostly between 5 and 15%, while the content of silt and clay fluctuates greatly, and there seems to be a mirror relationship between them. Along the N(W)–S(E) direction, the crystallization proportion of clay minerals gradually increases by about 28% because the relatively humid and hot climate is conducive to mineral crystallization. Over time, in the S(E) study area, the precipitation is relatively abundant, and the shallow soil is desalted due to leaching, resulting in high salt storage in the deep soil. However, in the N(W) study area, salt migrates upwards with water under the dominant effects of evaporation and freeze-thaw, leading to the accumulation of salt in shallow soil and a decrease in salt storage in deep soil. In addition, the saline soil in the study area has strong alkalinity, and the pH increases from 8.2 to 9.8 in the N(W)–S(E) direction. Overall, the soil salinization situation in Western Jilin is not optimistic.

Analysis of the pore structure characteristics of saline soil in the profile within the frozen depth

Soil pores play a critical role in the complex physical coupling process and are closely associated with the mechanism of soil salinization. This research used mercury intrusion porosimetry (MIP), scanning electron microscopy (SEM), and laser particle size analysis on a soil profile about 230 cm deep in Qian'an, where soda saline–alkali soil is distributed and the deepest underground freezing depth is 180 cm. The material composition of the soil in active layer was identified, and the soil pores were classified as micropores (<0.04 μm), small pores (0.04–0.4 μm), mesopores (0.4–4 μm), and macropores (>4 μm). The soil deposited at a depth of 0 to 80 cm was affected by freeze–thaw cycles and dry–wet cycles, developing longitudinal cracks. During the rainy season, clay particles and salt were carried downward by rainfall, whereas at a depth of 30 to 80 cm, the exchangeable sodium ions and clay particles in the soil created a thick diffused layer and hindered rainfall infiltration, resulting in salt accumulation. The small pore diameter and low porosity of the soil in this depth range caused pores degradation, further exacerbating the salinization process. The soil deposited at a depth of 80 to 120 cm had low clay content, resulting in limited upward migration of unfrozen water during freezing periods. Upon thawing, the salt and fine clay particles moved upward with capillary water, leading to a lower salt content than the upper soil. Additionally, this depth range had a high content of macropores with a large average pore diameter. The soil deposited at a depth of 120 to 180 cm had high clay content, and during short freezing periods, salt migrated upwards with unfrozen water along poorly connected longitudinal cracks with limited clay particle migration. The macropore content was low, and the average pore diameter was small due to clay particles filling the pores. The salt content in this depth range was lower than in the upper soil. The pore structure characteristics of the saline soil in the active layer provide insights into salt deposition mechanisms, and this research offers data support from a pore-scale perspective for preventing the salinization process.

Superhydrophobic/Superhydrophilic Janus Evaporator for Extreme High Salt-Resistance Solar Desalination by an Integrated 3D Printing Method

The emerging solar desalination technology has incomparable advantages for providing a clean water solution. However, the issue of salt accumulation on the solar evaporator tops during the steam generation leads to a considerable decrease in the evaporation rate. Herein, we demonstrate a superhydrophobic/superhydrophilic Janus evaporator that enables a stable solar evaporation even in saturated brine. Our Janus solar evaporator with a superhydrophobic top and a superhydrophilic bottom has been manufactured integrally, allowing for a fast steam evaporation without the impediment of the accumulated salt residues. The superhydrophobic top changes the water passageway from the center toward the edges while it allows for the vertical transport of both solar thermo and evaporated steams. Salt residues would only be deposited at the edges of the superhydrophilic bottom, allowing for a long-term stability of the evaporator for a continuous (>50 h) solar evaporation in saturated brine, which is record-breaking for salt-resistant solar evaporators. With stable and efficient evaporation performance out of high-salinity brine, this work provides a fascinating avenue for the desalination of seawater in a salt-resistant and efficient manner.

A Renewable and Antibacterial Solar Evaporator for Efficient Seawater Desalination: Performance Analysis and Empirical Formula

AbstractInterfacial solar evaporation has been considered as a compromising way to alleviate water shortage. However, when applied in real sea water environment, the undissolved salt accumulation and bacteria adhesion will cause blockage and fouling problem of the evaporator, and deteriorate its evaporation performance. Herein, a solar evaporator based on hollow cylinder‐shaped photocatalytic modified ceramic with renewability and antibacterial activity is fabricated for efficient seawater desalination. This evaporator can reach an evaporation rate of 3.43 kg m−2 h−1 in the normal environment (1 sun irradiation, 50% ambient relative humidity and 0 m s−1 convective airflow) and also can reach a rate of 28.9 kg m−2 h−1 in the controlled environment (1 sun irradiation, 10% ambient relative humidity and 5 m s−1 convective airflow) due to the sufficient effective evaporation area and timely vapor diffusion. Meanwhile, after long‐term desalination of real seawater, the blocked evaporators can be regenerated by acid treatment. The evaporator also shows 91.7% antibacterial ratio due to photocatalytic modification. In the field environment, the array evaporator shows a good evaporation performance of 54.5 kg m−2 for continuous 10 h. Finally, the empirical formula is obtained to quantitatively analyze the environmental factors and predict the evaporation rate in practical application.

Strontium-Cobaltite-Based Perovskite (SrCoO3) for Solar-Driven Interfacial Evaporation Systems for Clean Water Generation.

Solar-driven evaporation technology is often used in areas with limited access to clean water, as it provides a low-cost and sustainable method of water purification. Avoiding salt accumulation is still a substantial challenge for continuous desalination. Here, an efficient solar-driven water harvester that consists of strontium-cobaltite-based perovskite (SrCoO3) anchored on nickel foam (SrCoO3@NF) is reported. Synced waterways and thermal insulation are provided by a superhydrophilic polyurethane substrate combined with a photothermal layer. The structural photothermal properties of SrCoO3 perovskite have been extensively investigated through state-of-the-art experimental investigations. Multiple incident rays are induced inside the diffuse surface, permitting wideband solar absorption (91%) and heat localization (42.01 °C @ 1 sun). Under 1 kW m-2 solar intensity, the integrated SrCoO3@NF solar evaporator has an outstanding evaporation rate (1.45 kg/m2 h) and solar-to-vapor conversion efficiency (86.45% excluding heat losses). In addition, long-term evaporation measurements demonstrate small variance under sea water, illustrating the system's working capacity for salt rejection (1.3 g NaCl/210 min), which is excellent for an efficient solar-driven evaporation application compared to other carbon-based solar evaporators. According to the findings of this research, this system offers significant potential for producing fresh water devoid of salt accumulation for use in industrial applications.

Efficient solar water evaporation enabled by Ti3O5/Ti4O7-based melamine-urea–formaldehyde aerogel evaporators

In emerging solar water evaporation technology, inorganic semiconductors have been brought into focus for their outstanding photo-thermal conversion (PTC) capabilities. Among them, only limited studies focused on the application of Magnéli phase titanium oxides as PTC materials, while fatal salt accumulation problems remained to be solved. Herein, evaporators containing Ti3O5/Ti4O7 as the PTC material and melamine-urea–formaldehyde (MUF) aerogel as the matrix were fabricated. The highest evaporation rates achieved under 1.0 sun illumination were 2.45 and 2.24 kg m-2h−1 in pure water and real seawater, respectively. Benefiting from the extensive number of channels constructed from ice-templated and cured aerogel matrix, our MUF-based evaporators eliminated the fouling problem caused by salt accumulation during desalination. Our work provides an integrated design for the fabrication of Magnéli phase titanium oxides into evaporators to ensure stable and efficient solar water evaporation.

Spatiotemporal variability of soil physical properties and water, salt, nitrogen, and phosphorus contents for farm level

Soil water, salt, and nutrient variability are essential factors that impact crop productivity in agriculture systems. However, effective management of small farms requires access to fine-scale data on soil water, salt, and nutrients. Large-scale assessments of spatial variability using classical statistics and geostatistical methods can help identify nutrient-deficient zones. In Xinjiang, China, inadequate water and nutrient management has resulted in low crop productivity in agriculture systems. To address this issue, this study evaluated the mechanical composition, bulk density, and contents of water, salt, ammonium nitrogen ([Formula: see text]), nitrate nitrogen ([Formula: see text]), and available phosphorus (A-P) in soil at the farm level in the Xinjiang region. Results showed low variability in soil bulk density, medium variability in soil water content, mechanical composition, [Formula: see text], and A-P, and high variability in soil salt content and [Formula: see text]. Mechanical composition and A-P showed a small range of variation across different soil depths, while soil water content and [Formula: see text] in the surface layer varied significantly more than in other soil layers. [Formula: see text] variability increased with soil depth. Soil properties showed minimal differences over time. Multi-factor deficiencies, particularly in nitrogen, were observed throughout the study area. The generated maps offer a useful tool for farm managers and policymakers. In summary, this study highlights the significance of evaluating the spatial variability of soil properties for identifying zones deficient in water and nutrients, as well as those with salt accumulation. This information can be utilized to develop effective strategies for site-specific nutrient management.