In order to determine the seismic properties of rocks representing the continental crust/upper mantle transition, a structural and petrographical study of peridotites of the Ivrea-Verbano zone (N. Italy) has been undertaken. The seismic behaviour (Vp, Vs, birefringence, orientation of the fast shear-wave polarisation plane) has been calculated from the modal composition of rock samples, together with the crystallographic preferred orientation and the single crystal elastic constants, using the methods of Mainprice (1990). It is shown that the intrinsic anisotropy of peridotites is mainly due to the lattice preferred orientation (LPO) of olivine and to the competing effects due to the LPO of orthopyroxene. If present, well-oriented hydrous phases such as phlogopite, leads to both P- and S-waves velocities becoming drastically reduced, but the anisotropy and the S-wave splitting (mainly on the foliation plane) is increased. An attempt has been made to apply this petrologic and microstructural approach to understand the seismic properties of ultramafic rocks with the aid of a mobile seismic network set up in the Ivrea-Verbano zone. Five recording units with 3-component geophones were installed on the most representative lithologies of the Ivrea-Verbano zone: kinzigites, gabbros, stronalites, and on metapelites of the adjacent outcrop of the Serie dei Laghi. During five months the seismic network recorded 49 events that were mainly regional earthquakes. The preliminary analysis of the first arrival revealed a high-velocity anomaly near the Finero ultramafic massif. Rough calculations indicated that this anomaly could be due to a shallow-depth, peridotitic body about six kilometres thick. S-wave polarisation analysis was carried out on the horizontal components of the seismograms of four regional earthquakes that showed a first arrival propagating almost vertically at the recording sites. Four earthquakes were chosen in order to reconstruct the orientation of the polarisation plane of the shear phases. The preliminary results of this analysis have shown a qualitatively good agreement between the orientation of the polarisation plane of the fast shear-wave and the strike of the foliation at the station near Finero, located on kinzigites of the Ivrea-Verbano zone, although the relationships between the local structural setting and the polarisation orientations at the other recording sites is not yet so clear.