Rydberg States Of Atoms Research Articles

Publisher Correction: Rydberg states of alkali atoms in atomic vapour as SI-traceable field probes and communications receivers

Publisher Correction: Rydberg states of alkali atoms in atomic vapour as SI-traceable field probes and communications receivers

Error-robust hybrid atom-photon entangling gate via Gaussian soft control

Hybrid atom-photon gates play an important role for the realization of a quantum interface capable of mapping atomic states to photons for communication across quantum networks. Here, we propose a feasible theoretical scheme for implementing a hybrid atom-photon controlled-Z gate between an atom and a microwave photon in a superconducting coplanar waveguide resonator based on the Gaussian soft control technique. The gate protocol employs a classical auxiliary field that induces an atomic transition between one state of the atomic qubit and Rydberg states for obtaining strong coupling of the atom and microwave resonator. By tailoring the amplitude of this field with Gaussian temporal modulation, the gate performances are improved in various aspects. Numerical simulations demonstrate that the controlled-Z gate based on Gaussian soft control is resilient to the variation of the atom-photon coupling strength and deviation in the gate time, and it is less sensitive to the Rydberg level shifts caused by stray electric fields.

Rydberg states of alkali atoms in atomic vapour as SI-traceable field probes and communications receivers

Rydberg states of alkali atoms in atomic vapour as SI-traceable field probes and communications receivers

Subcycle dynamics of excitons under strong laser fields.

Excitons play a key role in the linear optical response of two-dimensional (2D) materials. However, their role in the nonlinear response to intense, nonresonant, low-frequency light is often overlooked as strong fields are expected to tear the electron-hole pair apart. Using high-harmonic generation as a spectroscopic tool, we theoretically study their formation and role in the nonlinear optical response. We show that the excitonic contribution is prominent and that excitons remain stable even when the driving laser field surpasses the strength of the Coulomb field binding the electron-hole pair. We demonstrate a parallel between the behavior of strongly laser-driven excitons in 2D solids and strongly driven Rydberg states in atoms, including the mechanisms of their formation and stability. Last, we show how the excitonic contribution can be singled out by encapsulating the 2D material in a dielectric, tuning the excitonic energy and its contribution to the high-harmonic spectrum.

Floquet geometric entangling gates in ground-state manifolds of Rydberg atoms

We propose new applications of Floquet theory in Rydberg atoms for constructing quantum entangling gates in atomic ground-state manifolds. By dynamically periodically modulating the Rabi frequencies of transitions between ground and Rydberg states of atoms, error-resilient two-qubit entangling gates can be implemented in the regime of Rydberg blockade. According to different degrees of Floquet theory utilization, the fidelity of the resulting controlled gates surpasses that of the original reference, and it exhibits high robustness against Rabi error in two qubits and detuning error in the control qubit. Our method only uses encoding in the ground states, and compared to the original scheme using Rydberg state for encoding, it is less susceptible to environmental interference, making it more practical to implement. Therefore, our approach may have broader applications or potential for further expansion of geometric quantum computation with neutral atoms.

Long-Lived Circular Rydberg Qubits of Alkaline-Earth Atoms in Optical Tweezers

Coherence time and gate fidelities in Rydberg atom quantum simulators and computers are fundamentally limited by the Rydberg state lifetime. Circular Rydberg states are highly promising candidates to overcome this limitation by orders of magnitude, as they can be effectively protected from decay due to their maximum angular momentum. We report the first realization of alkaline-earth circular Rydberg atoms trapped in optical tweezers, which provide unique and novel control possibilities due to the optically active ionic core. Specifically, we demonstrate creation of very high-n (n=79) circular states of Sr88. We measure lifetimes as long as 2.55 ms at room temperature, which are achieved via cavity-assisted suppression of black-body radiation. We show coherent control of a microwave qubit encoded in circular states of nearby manifolds, and characterize the qubit coherence time via Ramsey and spin-echo spectroscopy. Finally, circular-state tweezer trapping exploiting the Sr+ core polarizability is quantified via measurements of the trap-induced light shift on the qubit. Our work opens routes for quantum simulations with circular Rydberg states of divalent atoms, exploiting the emergent toolbox associated with the optically active core ion. Published by the American Physical Society 2024

Sensitivity of radio-frequency electric field sensor based on Rydberg Stark effect

Rydberg atoms hold special attraction in electric applications due to their large transition electric dipole moments and huge polarization, which leads to a strong response of atom to electric fields. In radio-frequency (RF) fields, the Rydberg levels are AC Stark shift and splitting, which can realize the study of high-sensitivity electric field sensor of Rydberg atoms. In this work, we use the simpler Shirley’s time-independent Floquet Hamiltonian model to calculate the AC Stark energy spectrum of Cs Rydberg atoms. This model can reduce the basic Hamiltonian into such a Hamiltonian that includes only those Rydberg states that have direct dipole-allowed transitions with the target state, thereby significantly improving the speed of computation. The accuracy of the calculation is proved by fitting with the calculated frequency shift of DC Stark energy levels in the weak fields, and the polarizability of 60D<sub>5/2</sub> and 70D<sub>5/2</sub> Rydberg atomic states are obtained by fitting with the measured ion spectra of DC Stark Cs ultra-cold Rydberg atoms in magneto-optical trap. In addition, we calculate the AC Stark shift of Cs Rydberg atom <inline-formula><tex-math id="M2">\begin{document}$ \left| {60{{\text{D}}_{5/2}},{m_j} = 1/2} \right\rangle $\end{document}</tex-math><alternatives><graphic specific-use="online" xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="9-20240162_M2.jpg"/><graphic specific-use="print" xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="9-20240162_M2.png"/></alternatives></inline-formula> state in electric fields with different frequencies with <i>ε</i> = 100 mV/m. Rydberg atoms provide a structured spectrum of sensitivity to electric fields due to strong resonant interaction and off-resonant interaction with many dipole-allowed transitions to nearby Rydberg states. This kind of the frequency response structure is of significance to a broadband sensor. And we calculate the sensitivity and the scaling of the signal-to-noise ratio (SNR), <i>β</i>, varying with detuning from the <inline-formula><tex-math id="M3">\begin{document}$ \left| {60{{\text{D}}_{5/2}}} \right\rangle \to \left| {61{{\text{P}}_{3/2}}} \right\rangle $\end{document}</tex-math><alternatives><graphic specific-use="online" xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="9-20240162_M3.jpg"/><graphic specific-use="print" xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="9-20240162_M3.png"/></alternatives></inline-formula> transition. The value of <i>β</i> allows one to use the result for any Rydberg state sensor to determine the SNR for any <i>Ε</i> in a 1 s measurement. Therefrom, Rydberg sensor can preferentially detect many RF frequencies spreading across its carrier spectral range without modification while effectively rejecting large portions where the atom response is significantly weaker, and the signal depends primarily on the detuning of the RF field to the nearest resonance which does not convey the RF frequency directly.

Tune-out wavelengths of Rydberg atoms

The atomic polarizability represents the response characteristics of atoms to externally applied electro-magnetic fields. The wavelength (or frequency) at which the dynamic polarizability of an atom is equal to zero is referred to as the tune-out wavelength (or frequency). Spectroscopy technology based on the tune-out effect has potential applications in quantum precision measurement, quantum computation and quantum communication. Related research topics include the measurement of fundamental physical constants and strong interactions. The tune-out wavelengths of atoms in low-lying states primarily fall within the optical band, where the theoretical calculations and experimental measurements have significant progress. However, for Rydberg atoms in highly excited states, theoretical calculations are challenging due to their high density of atomic states. The difficulty of experimental measurement arises from small splitting of adjacent atomic energy levels. In this paper, we demonstrate the tune-out wavelengths measurement for Rydberg atoms in a cesium vapor cell at room temperature. We utilize a two-photon cascade excitation to prepare Rydberg states and employ amplitude-modulation electromagnetically-induced transparency (AM-EIT) spectroscopy to measure the tune-out wavelength. By continuously scanning the microwave frequencies, we obtain AM-EIT signals of Rydberg atoms. At near-resonant microwave transition wavelengths, strong AM-EIT signals are observed due to microwave-atom coupling. Conversely, at tune-out wavelengths, the dynamically polarization-induced destructive interference in neighboring energy states occurs which leads to the weak AM-EIT signals. The AM-EIT provides a spectral resolution of about 10 MHz. We have developed a simplified three-level model to calculate the tune-out wavelength. The results of our theoretical calculations are consistent with the experimental findings within a range of ±90 MHz.

Computing Decay Widths of Autoionizing Rydberg States with Complex-Variable Coupled-Cluster Theory.

We compute autoionization widths of various Rydberg states of neon and N2 by equation-of-motion coupled-cluster theory combined with complex scaling and complex basis functions. This represents the first time that complex-variable methods are applied to Rydberg states represented in Gaussian basis sets. A new computational protocol based on Kaufmann basis functions is designed to make these methods applicable to atomic and molecular Rydberg states. As a first step, we apply our protocol to the neon atom and compute widths of the 3s, 3p, 4p and 3d Rydberg states. We then proceed to compute the widths of the 3sσg, 3dσg, and 3dπg Rydberg states of N2, which belong to the Hopfield series. Our results demonstrate a decrease in the decay width for increasing angular momentum and principal quantum number within both Rydberg series.

Precision Spectroscopy of Radiation Transitions between Singlet Rydberg States of the Group IIb and Yb Atoms

The measurements of microwave (μw) and radio-frequency (RF) radiation quantitative parameters may be based on the quantum–optical approach to determine the spectral characteristics of radiation transitions between the Rydberg states of atoms. Frequencies and matrix elements are calculated for dipole transitions between opposite-parity Rydberg states nL 1L and n′L±1 1L±1 (where n′= n,n±1,n±2) of the singlet series in the alkaline–earth–metal-like atoms of group IIb (Zn, Cd, Hg) and Yb. The matrix elements determine the shifts of Rydberg-state energy levels in the field of resonance μw or RF radiation, splitting the resonance of electromagnetically induced transparency (EIT) for intensely absorbed probe radiation. Numerical computations based on the single-electron quantum defect method (QDM) and the Fues’ model potential (FMP) approach with the use of the most reliable data from the current literature on quantum defect values are performed for frequencies and matrix elements of transitions between singlet Rydberg states of 1S0-, 1P1-, 1D2-, and 1F3-series in Zn, Cd, Hg, and Yb atoms. The calculated data are approximated by polynomials in the powers of the principal quantum numbers. The polynomial coefficients are determined with the use of a standard curve-fitting interpolation polynomial procedure for numerically calculated functions. These approximation expressions provide new possibilities for accurately evaluating the frequencies and matrix elements of dipole transitions between Rydberg states over a wide range of quantum numbers n >> 1, accompanied by the emission and absorption of μw and RF photons.

Precision Spectroscopy of Rydberg States in Alkaline Earth Atoms for Millimeter-Wave Radiation Measurement

Precision Spectroscopy of Rydberg States in Alkaline Earth Atoms for Millimeter-Wave Radiation Measurement

Rydberg-Atom-Based Electrometry Using a Self-Heterodyne Frequency-Comb Readout and Preparation Scheme

Atom-based radio-frequency (rf) electromagnetic field sensing using atomic Rydberg states is a promising technique that has recently attracted significant interest. Its unique advantages, such as extraordinary bandwidth, self-calibration, and all-dielectric sensors, are a tangible improvement over antenna-based methods in applications such as test and measurement and development of broad-bandwidth receivers. Here, we demonstrate how an optical-frequency comb can be used to acquire data in the Autler-Townes regime of Rydberg-atom-based electrometry in a massively parallel fashion, eliminating the need for laser scanning. Two-photon electromagnetically induced transparency readout and preparation of cesium is used for the demonstration. A flat quasicontinuous optical comb is generated with the probe laser at 852 nm using an electro-optic modulator and arbitrary waveform generator. A single-frequency coupling laser at 509 nm is tuned to the Rydberg launch state. An enhanced transmission signal is obtained using self-heterodyne spectroscopy, where the comb signal is beat against a local oscillator derived from the single-frequency probe laser on a fast photodiode. The transmission of each probe-laser comb tooth is observed. We resolve electromagnetically induced transparency peaks with line widths below 5 MHz, with and without laser locking. Radio-frequency electromagnetic fields as low as $66\phantom{\rule{0.2em}{0ex}}\text{\ensuremath{\mu}}{\mathrm{Vcm}}^{\ensuremath{-}1}$ are detected, with sensitivities of $2.3\phantom{\rule{0.2em}{0ex}}\text{\ensuremath{\mu}}{\mathrm{Vcm}}^{\ensuremath{-}1}{\mathrm{Hz}}^{\ensuremath{-}1/2}$. The method offers a significant advantage for reading out electromagnetically induced transparency and Autler-Townes splitting, as neither laser needs to be scanned and slow frequency drifts can be tolerated in some applications. The method enables the detection of the amplitude of a pulsed rf electromagnetic field when the incoming pulse Autler-Townes splits the electromagnetically induced transparency peak.

A High-Efficiency Fiber-Coupled Rydberg-Atom Integrated Probe and Its Imaging Applications

Atomic sensing and electric field measurements based on the use of the all-optical electromagnetic induction transparency (EIT) spectrum of Rydberg atoms have attracted great interest due to the advantages of self-calibration, Le Système International d'unités traceability, and a broadband spectrum. At the same time, this methodology also promotes the development of atomic sensor technology. We present a novel high-efficiency Rydberg-atom radio-frequency (RF) electric (E) field integrated probe (Rydberg Field Probe or RFP). The high-efficiency RFP consists of a 10 mm cubic 133Cs vapor cell, a dichroic mirror, three collimating lenses, and three fibers. This system can be used to independently control two counterpropagating lasers passing through a vapor cell, easing the design effort. In addition, the overall system efficiency can reach a value of 40.4%, reducing the EIT power broadening doe conventional RFPs. Based on the designed high-efficiency RFP, near-field electric field measurement and imaging of a C-band horn antenna at 4.48 GHz are performed by using the resonant RF field of the 133Cs atomic Rydberg state at room temperature with a spatial resolution of λ/6. These results promote the development of atomic sensing technology and show great application potential for the measurement of measuring high-resolution radio frequency electric fields and arrays of RFPs.

Dimer states of Rydberg atoms on the Kagome lattice as resources for universal measurement-based quantum computation

We show that the quantum dimer state on the Kagome lattice, which was recently realized with high fidelity in a Rydberg quantum simulator [G. Semeghini et al., Science 374, 6572 (2021)], offers a sufficient resource for universal measurement-based quantum computations. In particular, we provide an efficient encoding of logical qubits in this state and give explicit measurement sequences that implement a universal set of gates on these qubits. Since the building blocks of the proposed measurements have already been experimentally implemented, our work highlights one possible path toward promoting Rydberg simulators to universal quantum computers relying on the measurement-based model of quantum computation with currently existing technology.

Microwave Field Metrology Based on Rydberg States of Alkali-Metal Atoms

The high-precision determination of microwave radiation parameters may be based on measurements of the spectral characteristics of radiation transitions between the Rydberg states of atoms. Frequencies and matrix elements are calculated for dipole transitions from even-parity nS1/2 and nD5/2 to odd-parity n′P3/2 and n′F7/2 (where n′ = n, n ± 1, n ± 2) for the Rydberg states of alkali-metal atoms. The matrix elements determine the splitting of Rydberg-state energy levels in the field of a resonance microwave (μw) radiation, which results in the splitting of the resonance in electromagnetic induced transparency (EIT). Numerical computations based on the single-electron quantum defect method (QDM) and the Fues’ model potential (FMP) approach with the use of the most reliable data of the current literature on quantum defect values were performed for the 2S, 2P, 2D and 2F series of the Rydberg states of Li, Na, K, Rb and Cs atoms. The calculated data were approximated by quadratic polynomials of the principal quantum number. The polynomial coefficients were determined with the use of a standard curve-fitting interpolation polynomial procedure for numerically presented functions. The approximation equations may be used for the accurate evaluation of the frequencies and matrix elements of μw transitions in wide ranges of the Rydberg-state quantum numbers n >> 1.

Bright and dark Autler–Townes states in the atomic Rydberg multilevel spectroscopy

We investigated the Autler–Townes (AT) splitting produced by microwave (mw) transitions between atomic Rydberg states explored by optical spectroscopy from the ground electronic state. The laser-atom Hamiltonian describing the double irradiation of such a multilevel system is analysed on the basis of the Morris–Shore transformation. The application of this transformation to the mw-dressed atomic system allows the identification of bright, dark, and spectator states associated with different configurations of atomic states and mw polarisations. We derived synthetic spectra that show the main features of Rydberg spectroscopy. Complex AT spectra are obtained in a regime of strong mw dressing, where a hybridisation of the Rydberg fine structure states is produced by the driving.

Interaction of blackbody radiation with rubidium and caesium atoms in small-angular-momentum Rydberg states

We examine the possibilities of refining an asymptotic description and quantitative calculations of the effects induced by thermal blackbody radiation (BBR) of the environment on the Rydberg states of atoms. Numerical values are calculated and asymptotic expressions are proposed for simplified estimates of natural lifetimes and threshold photoionisation cross sections for Rydberg states of rubidium and caesium atoms with large values of the principal quantum number, n ⩾ 20, and small orbital momenta, l = 0, 1, 2, 3. Based on analytical expressions, we present numerical estimates for the contributions of photoionisation probabilities to the BBR-induced broadening of the Rydberg energy level, as well as the contributions of continuum integrals to thermally induced shifts in the Rydberg-state energy levels.

Controlling Rydberg Excitations Using Ion-Core Transitions in Alkaline-Earth Atom-Tweezer Arrays

Scalable local control over gate operations is an outstanding challenge in the field of quantum computing and programmable quantum simulation with Rydberg-atom arrays. One approach is to use a global field to excite atoms to the Rydberg state and tune individual atoms in and out of resonance via local light shifts. In this work, we point out that photon-scattering errors from light shifts can be significantly reduced if the light shift is applied to the Rydberg state instead of the ground state, which can be realized in Rydberg states of alkaline-earth atoms using optical transitions in the ion core. As a proof of concept, we experimentally demonstrate global control of Rydberg excitations in an Yb optical-tweezer array via light shifts induced by a laser tuned near the Yb+6s→6p1/2 transition. We also perform detailed spectroscopy of the induced light shift and scattering rates of the 6sns3S1 Rydberg states and reveal the existence of satellite lines where losses from autoionization are strongly suppressed. This work can be readily extended to implement local gate operations in Rydberg-atom arrays.Received 18 October 2021Revised 27 January 2022Accepted 24 March 2022DOI:https://doi.org/10.1103/PRXQuantum.3.020326Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.Published by the American Physical SocietyPhysics Subject Headings (PhySH)Research AreasQuantum information architectures & platformsPhysical SystemsRydberg atoms & moleculesTechniquesAtom & ion coolingOptical tweezersAtomic, Molecular & OpticalQuantum Information

Terahertz electrometry via infrared spectroscopy of atomic vapor

In recent years, the characterization of radiation falling within the so-called “terahertz (THz) gap” has become an ever more prominent issue due to the increasing use of THz systems in applications such as nondestructive testing, security screening, telecommunications, and medical diagnostics. THz detection technologies have advanced rapidly, yet traceable calibration of THz radiation remains challenging. In this paper, we demonstrate a system of electrometry in which a THz signal can be characterized using laser spectroscopy of highly excited (Rydberg) atomic states. We report on proof-of-principle measurements that reveal a minimum detectable THz electric field amplitude of 1.07 ± 0.06 V / m at 1.06 THz (3 ms detection), corresponding to a THz power at the atomic cell of approximately 3.4 nW. Due to the relative simplicity and cryogen-free nature of this system, it has the potential to provide a route to a SI traceable “atomic candle” for THz calibration across the THz frequency range, and provide an alternative to calorimetric methods.

Angle-Dependent Magic Optical Trap for the 6S1/2↔nP3/2 Rydberg Transition of Cesium Atoms

The existence of an anisotropic tensor part of atomic states with an angular momentum greater than 1/2 causes their dynamic polarizabilities to be very sensitive to the polarization direction of the laser field. Therefore, the magic wavelength of the transition between two atomic states also depends on the polarization angle between the quantized axis and the polarization vector. We perform a calculation of the magic conditions of the 6S1/2↔nP3/2 (n = 50–90) Rydberg transition of cesium atoms by introducing an auxiliary electric diople transition connected to the target Rydberg state and a low-excited state. The magic condition is determined by the intersection of dynamic polarizabilities of the 6S1/2 ground state and the nP3/2 Rydberg state. The dynamic polarizability is calculated by using the sum-over-states method. Furthermore, we analyze the dependence of magic detuning on the polarization angle for a linearly polarized trapping laser and establish the relationship between magic detuning and a principal quantum number of the Rydberg state at the magic angle. The magic optical dipole trap can confine the ground-state and Rydberg-state atoms simultaneously, and the differential light shift in the 6S1/2↔nP3/2 transition can be canceled under the magic condition. It is of great significance for the application of long-lifetime high-repetition-rate accurate manipulation of Rydberg atoms on high-fidelity entanglement and quantum logic gate operation.