Portland cement porous concrete (PCPC) has received immense interest recently due to its environmental aids. Its porous structure helps to reduce the water runoff amount while improving the recharge of groundwater. Earlier studies have concentrated on illustrating and knowing the functional as well as structural properties of PCPC. However, very few studies are available on PCPC in combination with natural silica sources as supplementary cementitious materials (SCMs). Most SCMs are by-products of industrial manufacturing processes and cause some environmental concerns, but with their pozzolanic effect, they could be utilized as partial substitute materials for ordinary Portland cement (OPC) to enhance the strength as well as durability performance. The aim of this study is to evaluate the effects of diatomaceous earth (DE) as a supplementary cementitious material for partial substitution of OPC for Portland cement porous concrete application. Compression strength, split tensile strength, and flexural strength tests were performed to determine the effect of partial replacement. To investigate the impact of test variables, basic tests, including void content and water permeability, were also performed. Compared to the control concrete, the results show that a 15% replacement of cement with DE significantly increased the compressive strength (by 53%) while also providing adequate porosity and better water permeability. Statistical analysis (ANOVA) and regression analysis showed that there is a significant (p < 0.05) growth within the physical characteristics of concrete upon the replacement of cement by 15% DE. Collectively, the replacement of cement with DE could not only improve the concrete strength but also reduce the consumption of cement, thereby lessening the cost of construction as well as indirectly reducing the carbon footprint.