Crumb Rubber Research Articles

Experimental and modelling analysis of waste material-based geopolymer concrete incorporated with crumb rubber particles

Rubberized geopolymer concrete (RuGPC) emerges as an eco-friendly alternative to conventional concrete, significantly reducing greenhouse gas emissions. This study investigates the use of steel slag (SS) in varying proportions (30 %, 35 %, and 40 %) as a replacement for ground granulated blast furnace slag (GGBS) in geopolymer concrete, with crumb rubber (CR) replacing crusher dust (CD) as fine aggregate due to its increasing demand. The research focuses on understanding the impact of aluminosilicate materials on the mechanical, thermal, and microstructural properties of geopolymer concrete cured at 60°C. Advanced characterization techniques, including Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDX), X-ray Diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR), were employed. SEM and EDX analyses revealed that the microstructural properties of GGBS and SS materials, mainly Na/Si, Si/Al, H₂O/Na₂O, and Na/Al ratios, significantly influence RuGPC performance through gel formation. FTIR analysis indicates a shift in the stretching vibrations of GGBS and SS to lower wavenumbers due to geopolymerization changes. XRD results show the formation of C-S-H gel at around 27–30° 2theta, attributed to increased GGBS and SS content. Despite efforts to incorporate CR into geopolymer matrices, challenges in mitigating strength degradation persist. To address this, a predictive model was developed to understand the key factors affecting RuGPC performance. Six machine learning techniques—M5P (pruned and unpruned), random forest, random tree, linear regression, and support vector machine with various kernels (PUK, RBF, PK, and NPK), and artificial neural network (ANN)—were employed to predict the physical and thermal behavior of RuGPC. The analysis identified ANN-based models as the most effective. Sensitivity analysis highlighted the grade of rubber and the CR replacement percentage by volume of CD as the most influential parameters determining RuGPC compressive strength, density, and thermal conductivity. Moreover, The economic analysis revealed that RuGPC mixtures were 1.2–11.61 % more cost-effective than OPC concrete. These findings underscore the importance of predictive model development in optimizing RuGPC properties for practical applications, offering valuable insights for decision-making processes.

Constitutive behaviour of a granular matrix containing coal mine waste intermixed with rubber crumbs

AbstractTraditional railway substructure materials (i.e., natural crushed rock aggregates used for ballast and capping layers) degrade under service loads, incurring higher periodic maintenance costs compared to recycled materials. Using recycled waste materials such as coal wash and rubber crumbs for infrastructure upgrades not only reduces construction and maintenance costs but also supports environmental sustainability. By exploring unconventional avenues, earlier studies have delved into the viability of blending rubber crumbs (RC) and coal wash (CW) as an innovative substitute for traditional railway substructure materials, with a specific focus on the capping layer. This study introduces a semi-empirical constitutive model to simulate the response of mixtures of coal wash and rubber crumbs (CWRC) using the bounding surface plasticity framework. The novelty of this study is that a modified volumetric strain expression is introduced to capture the compressibility of rubber, thus enabling a more accurate representation of the internal deformation of rubber within the granular matrix. The variation of rubber content in the mixture is captured by the corresponding critical state void ratio surface and the hardening modulus. The theoretical model is then calibrated and validated using static drained triaxial test data for CWRC mixtures as well as mixtures of steel furnace slag, coal wash, and rubber crumbs (SFS + CW + RC).

Diffusion Mechanism of Waste Crumb Rubber Composite Modified Asphalt Based on Molecular Dynamics Simulation

Waste crumb rubber composite modified asphalt (CRCMA), composed of base asphalt, waste rubber powder, and several additives (softener, activator, and cross-linking agent), has been shown to effectively improve asphalt properties. The interactions between the components in CRCMA are complex, involving molecular diffusion that significantly impacts its performance. The diffusion behavior in asphalt molecules will affect various properties of asphalt and the reasons for the different properties of asphalt can be explained by studying its diffusion mechanism. Therefore, understanding the diffusion mechanism of CRCMA is essential. The molecular dynamics simulation was employed to analyze the factors influencing the diffusion mechanism, using the diffusion coefficient as a key indicator of molecular mobility. The findings showed that the diffusion coefficient of the asphalt system decreased over time but increased with temperature. The rubber composition type also had a significant impact on diffusion, with butadiene rubber (BR) showing the highest coefficient, followed by natural rubber (NR), crumb rubber (CR), and styrene-butadiene rubber (SBR). The diffusion coefficient was the lowest and the diffusion rate was slowest after adding softeners. The diffusion coefficient increased slightly with the addition of CR, and the diffusion rate was slightly accelerated but not significantly. The diffusion coefficient increased rapidly with adding activator and the diffusion rate increased significantly. With the addition of cross-linking agent, the diffusion coefficient began to decrease and the diffusion rate became slower. The CRCMA microscopic performance tests indicated that the swelling effect of CR limits diffusion, while activators promote degradation and desulfurization of CR due to the large molecule structure getting smaller, enhancing diffusion. The S=O bond in the asphalt system was regenerated and re-crosslinked to create a mesh after adding the cross-linking agent. The small molecule structure was transformed into large one. The molecular diffusion was restricted partly and thus the diffusion rate was slowed down.

Mechanical Property Prediction in Silica Fume and Crumb Rubber–Modified Concrete: Soft Computing and Experimental Approach

Mechanical Property Prediction in Silica Fume and Crumb Rubber–Modified Concrete: Soft Computing and Experimental Approach

Chemical and Rheological Evaluation of the Ageing Behaviour of High-Content Crumb Rubber Asphalt Binder

High-Content Crumb Rubber Asphalt (HCRA) binder improves road performance and address waste tyre pollution, yet its ageing behaviour is not fully understood. In this study, 70# neat asphalt binder and HCRA with rubber contents of 35% and 50% were selected and aged through the Thin Film Oven Test (TFOT) and Pressure Ageing Vessel (PAV) tests. FTIR (Fourier Transform Infrared Spectroscopy) and DSR (Dynamic Shear Rheometer) were employed to investigate their chemical composition and rheological properties. The FTIR results show that HCRA’s chemical test results are similar to those of 70#, but HCRA is more susceptible to ageing. I(C=C) strength decreases with age. The DSR results show that HCRA outperforms 70# neat asphalt binder in terms of viscoelasticity, high temperature performance and fatigue resistance, and exhibits greater resistance to ageing. The ageing index (AI) was obtained through a calculation using the formula, and overall, 70# neat asphalt binder is more sensitive to ageing behaviour and less resistant to ageing, and HCRA is particularly outstanding for fatigue resistance. A strong correlation is observed between chemical composition and some rheological property indicators. Therefore, we are able to predict the rheological properties using chemical composition indicators. This study provides insight into the ageing behaviour of a neat asphalt binder and an HCRA binder and demonstrates that the HCRA binder outperforms conventional asphalt in several performance areas. It also provides theoretical support for the consumption of waste tyres to prepare high content crumb rubber asphalt.

Mechanical and Durability Properties of Rubberized Sulfur Concrete Using Waste Tire Crumb Rubber

The use of rubber crumbs provides a viable solution for alleviating the disposal problem of waste tires. In this study, rubberized sulfur concrete (RSC) was researched to investigate the optimal mixture proportion and to improve the mixing process in terms of compressive strength and durability performance. For the mixture of the RSC, sand, rubber particles, and micro-filler were adopted as aggregates and sulfur was used for the binding material. Moreover, two mixing processes were applied: the dry mixing process and the wet mixing process. Based on the test results, the increment of rubber particles in the mixture led to a decrease in the compressive strength for both the dry and wet mixing processes. To minimize the voids between the sand and rubber particles, the micro-filler was used at 5% of the total volume. The amount of sulfur varied slightly depending on the mixing process: 30% sulfur for the dry mixing process and 34% sulfur for the wet mixing process, respectively. Consequently, compared to the dry mixing process, the wet mixing process increased the bonding force between sulfur and rubber powder due to the simultaneous heating and combining. In toughness, the wet mixing process demonstrates a 40% higher energy absorption capability compared to the dry mixing process. For the durability performance of the RSC, the mixture with 20% rubber particles produced using the wet mixing process exhibited better corrosion and freeze–thaw resistance.

Rubbercrete as a sustainable solution for recycling waste tires in concrete: An overview

Due to the rapid growth of the automotive industry, the number of waste tires has been rising dramatically each year. This increase is causing a strain on landfills, as the bulky nature of waste tires, with about 75% of their volume being void, quickly depletes available space of landfills. Furthermore, waste tires are non-biodegradable and, due to their concave shape, provide an ideal breeding ground for insects and harmful rodents, posing a public health risk. Given the limited range of products that can be produced from recycled tires, it is crucial to find economically viable solutions to recycle these tires and use them in mass production of useful materials, such as concrete. Concrete has been chosen by researchers as it is the second most consumed material per capita, after water. Researchers have produced crumb rubber from recycled tires and used it to partially replace fine aggregates in concrete, creating a material known as rubbercrete. Compared to conventional concrete, rubbercrete has better thermal and acoustic properties, is lighter in weight, and more ductile. However, it also shows a reduction in mechanical strengths. This paper provides an overview of rubbercrete, highlighting its key challenges, advantages, and properties.

Experimental Study on the Influence of Crumb Rubber on Temperature Susceptibility of Asphalt for Railway Application in the Tropics

The granular sub-ballast in conventional ballasted trackbed structure, though cheap and easy to construct, requires frequent maintenance, and cannot protect the subgrade against water infiltration. However, asphaltic sub-ballast in asphalt-ballast trackbed can reduce stress on the subgrade and provide a waterproofing layer against water infiltration. Asphalt binder is however, susceptible to temperature fluctuations. The aim of this study therefore is to investigate whether the addition of crumb rubber to asphalt binder could reduce the susceptibility of asphalt to temperature, and thus, improve its performance. The main objective of this research is the addition of four different ratios of crumb rubber; 1, 2, 3, and 4%, of size 0.3 mm to bitumen or asphalt 60/70 grade. The results showed that penetration of the asphalt binder reduced from 66.70 to 59.20 mm at 4% rubber content, implying that the modified asphalt became harder with addition of crumb rubber and thus, can withstand temperatures variations in asphaltic pavements. Softening point, used to test temperature susceptibility of bitumen, increased from 49.10°C to 52.80°C at 4% crumb rubber content, implying that crumb rubber modified asphalt can withstand elevated temperatures in asphaltic pavements, in the tropics. Flashpoint increased from 295.20 to 296.12°C, fire point also increased from 306.50°C to 308.28°C, Specific gravity of the unmodified and crumb rubber-modified asphalt did not change significantly because crumb rubber is not very flammable, Viscosity at 135°C increased from 338.00 to 360.00 cSt at crumb rubber content of 4%, Ductility at 25°C reduced from 122.40 cm to 79.40 cm at 4% crumb rubber content, implying that crumb rubber made asphalt stiffer. This study concludes that crumb rubber can reduce the susceptibility of asphalt to temperature changes.

Influence of Incorporating Waste Rubber Crumbs on Shear Parameters of Recycled and Natural Materials

Influence of Incorporating Waste Rubber Crumbs on Shear Parameters of Recycled and Natural Materials

Incorporating crumb rubber in slag-based geopolymer: Experimental work and predictive modelling

Crumb rubber (CR), a prevalent hazardous waste material, poses significant environmental challenges that necessitate innovative management strategies. Recent studies have focused on incorporating CR and ground granulated blast furnace slag (GGBS) into geopolymer concrete (GC) to address this challenge. This research presents a novel approach that combines experimental analysis with machine learning (ML) techniques to investigate the chemical effects of these materials on GC. Initially, compressive strength (CS) tests are conducted on rubberized geopolymer (RG) concrete, and the resulting data are further analyzed through ML algorithms to enhance the understanding of material behavior. Despite numerous attempts by researchers to integrate CR into geopolymer-based materials, the challenge of mitigating strength degradation persists. Therefore, it becomes imperative to construct a predictive model that relies on new variables influencing the strength characteristics. This research develops a predictive model to assess concrete compressive strength (CS). Key variables such as CR grade (particle size), incorporation percentage, and oxide ratio were analyzed for their impact on geopolymer strength. Employing ensemble techniques, namely Bagging (BA) and Gradient boosting (GB) with five learners (M5P, random forest (RF), random tree (RT), reduced error pruning tree (REPT), and support vector machine (SVM), the study found that M5P-GB models offered the most accurate CS predictions with the highest accuracy and lowest errors. Moreover, the dataset was checked via the k-fold cross-validation technique and confirmed the developed models' robustness, reliability, and effectiveness. Furthermore, uncertainty analysis revealed that GB-M5P-unpruned models-maintained uncertainty percentages of 14.769 % at 7 days and 11.277 % at 28 days, which was under the 35 % threshold. Additionally, the sensitivity analysis identified the CR grade and replacement percentage by volume of crusher dust (CD) as the most critical factors affecting CS. These findings underscore the importance of considering predictive model development in decision-making processes related to RG concrete properties, providing valuable insights into optimizing the model's robustness and reliability for practical applications. However, the study's reliance on specific input parameters and controlled laboratory conditions may limit the generalizability of the predictive models, necessitating further validation under diverse real-world conditions and variations in CR source and environmental factors.

Artificial sport surfaces and adverse effects for human health. A literature review

Abstract The management of the Post-Consumer Tyres (PCTs) is still a hot topic. In 2021, the 27 EU Member States plus Norway, Switzerland, and the UK discarded 4,200 Ktons of PCTs. The main application of the rubber granules obtained from their recycling is represented by infill material in synthetic turf playgrounds. These widespread installations have become fundamental tools for the promotion of physical activity, especially among children. However, this material is in the spotlight for the presence in its composition of hazardous substances and for the small size of granules, which the European Commission classified as “microplastics”. This review aims to clarify the scientific knowledge, focusing on the assessment of the bio-accessibility/availability of hazardous chemicals and the risk assessment for users. Eligible articles reporting original data were identified in CAB Direct, Embase, PubMed, Scopus, and Web of Science. The included articles (preliminary results) variously demonstrated the presence of PAHs, metals, volatile organic compounds, and phthalates in artificial biofluids (n = 9 articles). The risk assessment for these toxicants and the potential cancer risk induction (n = 19), revealed a risk for users from absent or negligible to potential, according to the exposure scenario considered and the relative assumptions, the contaminants, the exposure route, the age of the pitch, and characteristics of the rubber granules such as origin, concentration of the different toxicants, and particle size. The assessment of the potential hazard due to the exposure to artificial sports surfaces is anything but simple. Indeed, the crumb rubber compositions may vary in different settings and over time and can be variously influenced by the climate and environmental conditions, making it difficult to quantify the possible health effects, as well as the specific mixture, the quantities, and sources responsible for them (Funded by LIFE20 GIE FR 282 - RE-PLAN CITY LIFE). Key messages • The bioccessibility of PAHs, metals, volatile organic compounds, and phthalates included in the infill material composition was variously demonstrated in literature. • The assessment of the potential risks due to the exposure to synthetic turf, revealed a risk from negligible to potential, according to the exposure scenario considered and the relative assumptions.

Incorporating geranium plant waste into ultra-high performance concrete prepared with crumb rubber as fine aggregate in the presence of polypropylene fibers

Abstract This research examines the efficiency of ultra-high-performance concrete (UHPC) when utilizing geranium plant (GP) ash, which is subjected to different curing temperatures ranging from 300 to 900°C for 3 h of burning time. The GP ash is used as a replacement for cement in varying amounts (10, 20, 30, 40, and 50 wt%). Crumb rubber powder is utilized as a substitute for fine aggregate. Polypropylene fibers have been used to improve concrete performance. The performance of UHPC is evaluated by assessing its mechanical qualities, such as flexural strength, splitting tensile strength, and compressive strength. The sorptivity test is also evaluated as a component of it. Scanning electron microscopy is used to analyze UHPC after exposure to temperatures as high as 900°C. The findings demonstrated a notable enhancement in the mechanical characteristics of all mixtures. The most favorable mixtures were achieved with proportions of 50, 40, 40, and 20% for mixtures including GP waste incinerated at temperatures ranging from 300 to 900°C. Furthermore, the optimal outcome is achieved when 40% substitution is performed at a temperature of 700°C, resulting in notable enhancements of 14% in compressive strength, 30% in flexural strength, and 17% splitting tensile strength, respectively. At a high temperature of 700°C, the decrease in strength increased to approximately 37–40% as a result of the initial removal of carbon dioxide from calcite at temperatures ranging from 600 to 900°C and reached 56% at 900°C. Great resistance to sorptivity, as well as a dense and compact microstructure with a high content of calcium and silicon, was obtained.

Thinking Green on 3D Printing: Sustainable Polymer Compositions of Post-Consumer Polypropylene and Tire Rubber Crumbs Intended for Industrial Applications

Year by year, more and more plastic is used worldwide. A large part of post-consumer waste is still stored in landfills instead of being reused. The solution to this problem may be recycled materials (recyclates) or biodegradable materials. The method of 3D printing, regarded as a clean processing technology, can significantly contribute to addressing global plastic pollution by utilizing post-consumer recycled polymers to create new components and parts. Therefore, this study focuses on the assessment of various properties and characteristics of 3D-printed compositions based on post-consumer polypropylene (PP) and rubber crumbs, recycled from packages foils and car tires, respectively. Moreover, within this study, we compared the mechanical performance of the injection molding material with the one obtained from 3D printing. A characterization was made considering the thermal and mechanical properties as well as the “print quality” through the microscopic and tomographic analysis of subsequent print passes, the number of free spaces, and imperfections in the polymer melt. Samples obtained using the FDM and injection methods exhibited comparable melting temperatures, while the samples obtained by injection molding exhibited slightly better mechanical performance, higher hardness, and impact strength.

Mechanical and economical feasibility of LDPE Waste-modified asphalt mixtures: pathway to sustainable road construction

This research study evaluates the impact of low-density polyethylene (LDPE) modified asphalt binder on the mechanical performance and economical feasibility of asphalt concrete (AC) mixtures. LDPE-modified mixtures were compared with conventional mixes prepared with various binders commonly used in India, i.e., VG 30, VG 40, Polymer-Modified Binder (PMB), and Crumb Rubber Modified Binder (CRMB). LDPE-modified mixtures exhibit superior mechanical performance, increasing the stiffness of AC mixtures by 171% and 125% at 25 °C and 35 °C, respectively, compared to VG 30 base binder. Additionally, the indirect tensile strength (ITS) improved by 51% over VG 30. LDPE-modified mixtures also showed improved resistance to permanent deformation, with RTIndex values up to 133.46% higher than VG 30, and higher fatigue resistance, as indicated by increased CTIndex values compared to VG 30 and CRMB. However, the CTIndex values for LDPE-modified mixtures were 26.32% and 56% lower than those for VG 40 and PMB, respectively. Pavement analysis using 3D-Move showed lesser deflections at pavement layer interfaces, resulting in higher rutting and fatigue life for LDPE-modified pavements. Furthermore, LDPE-modified pavements showed up to 57% higher fatigue life (Nf) and up to 42.33% higher rutting life (Nr) than other pavements. The economic analysis showed that the cost of LDPE-modified pavements is comparable to VG 40 and around 10% more economical than pavements containing PMB. Using LDPE also offers environmental benefits by repurposing up to 750 kg for every kilometer of single-lane pavement section having 50mm thick surface course. Overall, LDPE-modified asphalt mixtures present a sustainable and high-performance solution for asphalt pavement construction.

Rheological simulation of bituminous mixes with crumb rubber by the dry process

Rheological simulation of bituminous mixes with crumb rubber by the dry process

Thermal conductivity of fiber-reinforced foam concrete filled with crumb rubber powders

Thermal conductivity of fiber-reinforced foam concrete filled with crumb rubber powders

Impacts of Waste Rubber Products on the Structure and Properties of Modified Asphalt Binder: Part II-Rubber Reclaim.

The issue of forming a reliable and stable structure of a crumb-rubber-modified binder is an important scientific and technical task. The authors supplemented existing concepts of the mechanism of effective interaction with rubber crumb by introducing a preliminary first stage: controlled partial physical destruction of rubber crumb-producing rubber reclaim. Proposed physical methods of rubber crumb destruction include high shear force (roll mills), high temperature, and a plasticizing medium. The controllability and degree of devulcanization of rubber were determined by acetone-chloroform extraction in different time intervals. The degree of devulcanization of rubber in the rubber reclaim was found to be 22 ± 0.24%, with stability over 14 days. It was found that the size of the particles of the rubber reclaim in the bitumen is less than 2 µm. The properties of the structure of the binder modified with rubber reclaim, characterizing the stability and sustainability, have been studied and established. The developed modified binders are stable in storage. Rheological parameters of the structure characterizing intermolecular interaction, such as shear stability for original and RTFOT-aged, modified bitumen, meet requirements of the state standard at test temperature 64 °C. The elastic structural component of the crumb-rubber-modified binder, as indicated by the relative irreversible deformation parameter J3,2, does not exceed 2.6 kPa (<4.5 kPa) at 64 °C. Additionally, it was determined that the rheological structural parameter for fatigue resistance, which characterizes the durability of road pavement under intensive operational conditions, does not exceed 4699 kPa (<5000 kPa) at 16 °C. The use of 10% rubber reclaim combined with waste frying oil provided the opportunity to obtain a modified binder with a stable and sustainable structure without the introduction of additional stabilizers and agents. Test results showed that the overall performance characteristics of the modified binder meet the 64(S)-40 grade standards.

Study on high-temperature emission behaviors of crumb rubber modified asphalt: Experimental analysis and molecular simulation approach

The harmful emissions produced during the manufacturing and construction processes of crumb rubber modified asphalt (CRMA) significantly hinder its widespread application. Addressing this issue hinges on a thorough investigation into the mechanism governing its high-temperature emissions. This study employed microscale testing methods to analyze the microstructure and chemical property disparities between CRMA and base asphalt (BA). Subsequently, the impacts of varying crumb rubber (CR) content, experimental temperature, and sulfur stabilizer dosage on the high-temperature emissions of CRMA were investigated. Furthermore, comparative analyses of the molecular weight distribution, emission species, and CR crosslink density in asphalt after the fume experiment were conducted to further elucidate the high-temperature emission mechanisms. Finally, molecular simulation techniques were employed to analyze the interactions between CR and the four fraction molecules of asphalt at the microscale. The results indicated that the fume release volume of CRMA initially decreased and then increased with the addition of CR, while both the experimental temperature and sulfur stabilizer content exhibited a positive correlation with emission volume. CR reduced the volatilization of some small molecular hydrocarbons in the BA by absorbing light fractions. Meanwhile, excessive swelling caused the crosslinking density of CR to decrease by 77 %, which led to the release of toxic substances. At 20% CR content, the overall emissions of CRMA achieve their lowest level; however, the emission of toxic gases does not diminish. Molecular simulations have also confirmed the above results, showing that there is a strong interaction between CR and the light fractions. Compared with asphaltene molecules, rubber molecules had higher molecular polarity and stronger adsorption behavior for light fraction molecules.

Experimental investigation of the effect of polyphosphoric acid on bitumen containing crumb rubber and waste engine oil

Experimental investigation of the effect of polyphosphoric acid on bitumen containing crumb rubber and waste engine oil

Emission Risk and Inhibition Technology of Asphalt Fume from Crumb Rubber Modified Asphalt

Crumb rubber-modified asphalt mixtures have been proven to have extensive utilization value in road engineering. However, the rubber releases more fumes during the construction period, which causes severe harm to human health and the environment. This research focused on the emission risk of asphalt fume from crumb rubber-modified asphalt, and then the inhibition technology was also optimized. Firstly, the emission behavior and the hazardous evaluation of the asphalt fume from crumb rubber-modified asphalt were investigated. Then, the characteristics of the inhibition materials were evaluated. Finally, the reduction in the emission of inhibited crumb rubber-modified asphalt fume was identified, and the optimized formula was determined based on the inhibition effect, rheological properties, and cost. The results indicate that crumb rubber-modified asphalts release more fume components with an increment in the temperature and crumb rubber content. Desulfurized rubber reduces the release of H2S and NO. Benzene compounds, including paraxylene, toluene, and benzene, are the most released pollutants that harm human health, especially DS CRA 20% and CRA 50%. Kaolin powder and expanded graphite have a sufficient pore structure and volume, the addition of which reduces the release of pollutants while possibly promoting the release of NO and H2S. Their addition also has a significant control effect on the release of particulate matter at 170 °C and 185 °C. With the consideration of emissions, rheological properties, and cost, CRA 40%-EG2%-KL2% was determined as the optimization formula. This research is helpful to the application of crumb rubber-modified asphalt in road construction and maintenance.