A deep understanding of the particle–wall collision (PWC) behaviors of non-spherical particles is important for managing gas–solid flows in industrial applications. It is important to identify the dominant parameters and to develop the common PWC prediction models for typical non-spherical particles. In this paper, different types of non-spherical particles were used to conduct the fundamental experiments. The effects of key parameters such as particle size, non-sphericity, wall roughness, and impact angle were analyzed. The results show that the trends of the collision coefficients with the impact angle for all non-spherical particles are similar. The dominant factors of particle–wall collisions are particle sphericity and wall roughness. A model with four parameters was fitted from the experimental data. The model can predict the collisions of non-spherical particles on rough steel walls with sizes ranging from 50 to 550 microns.