Room Temperature Research Articles

Time-resolved EPR observation of blue-light-induced radical ion pairs in a flavin-Trp dyad.

A dyad of flavin and Trp bridged by a p-phenylamide linker was synthesized as an artificial model system to investigate molecular-based magnetic-field sensors relevant to blue-light photoreceptor proteins. The results demonstrated that intramolecular electron transfer generates a radical pair, only the triplet-born one of which has a microsecond lifetime at room temperature.

Lattice Engineering via Transition Metal Ions for Boosting Photoluminescence Quantum Yields of Lead-Free Layered Double Perovskite Nanocrystals.

Lead-free layered double perovskite nanocrystals (NCs), i.e., Cs4M(II)M(III)2Cl12, have recently attracted increasing attention for potential optoelectronic applications due to their low toxicity, direct bandgap nature, and high structural stability. However, the low photoluminescence quantum yield (PLQY, <1%) or even no observed emissions at room temperature have severely blocked the further development of this type of lead-free halide perovskites. Herein, two new layered perovskites, Cs4CoIn2Cl12 (CCoI) and Cs4ZnIn2Cl12 (CZnI), are successfully synthesized at the nanoscale based on previously reported Cs4CuIn2Cl12 (CCuI) NCs, by tuning the M(II) site with different transition metal ions for lattice tailoring. Benefiting from the formation of more self-trapped excitons (STEs) in the distorted lattices, CCoI and CZnI NCs exhibit significantly strengthened STE emissions toward white light compared to the case of almost non-emissive CCuI NCs, by achieving PLQYs of 4.3% and 11.4% respectively. The theoretical and experimental results hint that CCoI and CZnI NCs possess much lower lattice deformation energies than that of reference CCuI NCs, which are favorable for the recombination of as-formed STEs in a radiative way. This work proposes an effective strategy of lattice engineering to boost the photoluminescent properties of lead-free layered double perovskites for their future warm white light-emitting applications.

Transcriptome: New perspective for the rational planting of Dendrobium nobile and the improvement of medicinal quality through cold stimulation

Temperature affects the growth and accumulation of carbohydrate in plants. To study the response of Dendrobium nobile to cold stimulation, by using room temperature as the control, four low-temperature gradients (8 °C, 4 °C, 0 °C, −4 °C) were set to investigate the physiological changes and polysaccharide content of D. nobile. The results showed that under −4 °C treatment, the plant suffered severe damage and normal physiological activities were inhibited, resulting in inability to grow normally. Meanwhile, treatment at 0 °C for 4 d significantly increased the accumulation of polysaccharides in D. nobile (an increase of 56.18 % compared to CK), and the plant can grow normally after relieving cold stimulation. To explore the mechanism of its promoting polysaccharide accumulation, we conducted transcriptome analysis of D. nobile in this treatment. The results showed that TPP6, DPE1, PGMP, BAM3 genes in the starch and subcrosse metropolis; The pel gene in pentose and glucose conversions and transcription factors such as bHLH, MYB, and WRKY were significantly upregulated, thereby promoting the accumulation of polysaccharides in D. nobile. This study provides new perspective into the low-temperature adaptability of D. nobile and lays the foundation for further research on the biosynthetic pathways of D. nobile polysaccharides.

Structural formation yield of GeV centers from implanted Ge in diamond

In order to study the structural formation yield of germanium-vacancy (GeV) centers from implanted Ge in diamond, we have investigated its lattice location by using the β − emission channeling technique from the radioactive isotope 75Ge (t 1/2 = 83 min) produced at the ISOLDE/CERN facility. 75Ge was introduced via recoil implantation following 30 keV ion implantation of the precursor isotope 75Ga (126 s) with fluences around 2 × 1012–5 × 1013 cm−2. While for room temperature implantation fractions around 20% were observed in split-vacancy configuration and 45% substitutional Ge, following implantation or annealing up to 900 °C, the split-vacancy fraction dropped to 6%–9% and the substitutional fraction reached 85%–96%. GeV complexes thus show a lower structural formation yield than other impurities, with substitutional Ge being the dominant configuration. Moreover, annealing or high-temperature implantation seem to favor the formation of substitutional Ge over GeV. Our results strongly suggest that GeV complexes are thermally unstable and transformed to substitutional Ge by capture of mobile carbon interstitials, which is likely to contribute to the difficulties in achieving high formation yields of these optically active centers.

Efficient and Durable Oxidation Removal of Formaldehyde over Layered Double Hydroxide Catalysts at Room Temperature.

Room temperature catalytic oxidation (RTCO) using non-noble metals has emerged as a highly promising technique for removal of formaldehyde (HCHO) under ambient conditions; however, non-noble catalysts still face the challenges related to poor water resistance and low stability under harsh conditions. In this study, we synthesized a series of layered double hydroxides (LDHs) incorporating various dual metals (MgAl, ZnAl, NiAl, NiFe, and NiTi) for formaldehyde oxidation at ambient temperature. Among the synthesized catalysts, the NiTi-LDH catalyst showed an HCHO removal efficiency and CO2 yield close to 100.0%, and exceptional water resistance and chemical stability on running 1300 min. The abundant hydroxyl groups in LDHs directly bonded with HCHO, leading to the production of CO2 and H2O, thus inhibiting the formation of CO, even in the absence of O2 and H2O. The coexistence of O2 effectively reduced the reaction barrier for H2O molecule dissociation, facilitating the formation of hydroxyl groups and their subsequent backfill on the catalyst surface. The mechanisms underlying the involvement and regeneration of hydroxyl groups in room temperature oxidation of formaldehyde were elucidated with the combined in situ DRIFTS, HCHO-TPD-MS, and DFT calculations. This work not only demonstrates the potential of LDH catalysts in environmental applications but also advances the understanding of the fundamental processes involved in room temperature oxidation of formaldehyde.

ZnIn2S4 Nanosheets for Efficient NO2 Detection at Room Temperature: Insights into the Role of Sulfur Vacancies.

Engineering atomic vacancies in metal sulfide semiconductors allows for the efficient tuning of their electronic and chemical properties. In this work, we synthesized hollow tubular structures constructed by bimetallic ZnIn2S4 using a metal-organic framework (MOF) as the template. We found that the sulfur vacancies in ZnIn2S4 enabled extremely fast NO2 detection with high response at room temperature (RT), and the material with high sulfur vacancy content delivers a 2 times higher response to 10 ppm NO2 than the device with low sulfur vacancy content. To unveil the crucial role played by sulfur vacancies, DFT calculations were conducted to reveal that sulfur vacancies greatly enhance the interaction and electron transfer between ZnIn2S4 and NO2. This study will provide hints for the engineering of bimetallic sulfide materials for low-power gas sensors at RT.

EXPERIMENTAL CONDITIONS FOR ROOM TEMPERATURE FERROMAGNETISM IN Fe-DOPED SnO2 VIA MECHANOCHEMICAL MILLING AND THERMAL TREATMENT

Abstract Identifying optimal experimental conditions, preferably through a simple and cost-effective method, for the fabrication of oxide-diluted magnetic semiconductors, such as Fe-doped SnO2, holds great significance in the quest for spintronic materials operating at room temperature (RT). While mechanochemical milling is a well-established technique meeting these requirements, its numerous milling variables necessitate careful consideration of restricted experimental conditions. In this study, we present some experimental mechanochemical milling conditions to prepare impurity-free iron-doped tin dioxide nanoparticles exhibiting a RT ferromagnetic signal. To achieve this, we investigated the effects of milling time, the choice of the starting Sn reactant, and iron concentration on the purity of Sn1-xFexO2 (x=0, 0.03, and 0.05) nanopowders obtained through mechanochemical milling followed by thermal treatment. Characterization through XRD, XANES, and EXAFS at the Fe K-edge, RT Raman spectroscopy, 119Sn and 57Fe Mössbauer spectroscopies, and magnetic measurements was conducted. Among the experimental techniques, micro-Raman spectroscopy proved most effective in detecting the formation of hematite as an impurity phase. Our results indicate that extending the milling time to 12 h, as opposed to 3 h, employing anhydrous SnCl2, instead of SnCl2·2H2O and using the low iron concentration of x = 0.03, results in proper conditions for producing impurity-free samples with a robust RT ferromagnetic signal. The oxidation states for iron and tin ions were determined to be 3+ and 4+, respectively, with both occupying octahedral sites, suggesting iron's replacement of tin. Our findings propose that both the bound magnetic polaron and RKKY models offer potential explanations for the origin of the ferromagnetic signal observed at room temperature in Sn0.97Fe0.03O2 sample milled for 12 h.&amp;#xD;

Kanamycin‐Cu(II) Complex Catalyzed Ullmann Amine Synthesis at Room Temperature: A Tool for Mechanistic Insights into Methylene Blue Degradation

This study highlights the significance of Ullmann coupling reaction in modern organic synthesis and advances catalytic methodologies through the introduction of a kanamycin‐copper complex as a highly efficient catalyst for the synthesis of diverse N‐Aryl compounds. We demonstrate the catalyst's versatility through the synthesis of 20 Daryl‐amine instances, 21 Ar(het)‐N compounds, and 10 miscellaneous examples. NMR, IR, and UV spectroscopy offers insights into the catalyst's behaviour. Additionally, DFT studies support the catalyst's proficiency in generating SO4 radicals by stabilizing with aminosugars moieties. Ex‐situ NMR experiments confirm a ternary complex‐based mechanism at concentrations below 0.1μM. Furthermore, we showcase the degradation of methylene blue to its precursor amine under optimized conditions. Overall, this research underscores the potential of Ullmann condensation reactions in contemporary organic synthesis and contributes significantly to the advancement of catalytic methodologies.

Enhancing Performance and Longevity of Solid-State Zinc-Iodine Batteries with Fluorine-Rich Solid Electrolyte Interphase

Abstract Rechargeable zinc-iodine (ZnI2) batteries have gained popularity within the realm of aqueous batteries due to their inherent advantages, including natural abundance, intrinsic safety, and high theoretical capacity. However, challenges persist in their practical applications, notably battery swelling and vulnerability in aqueous electrolytes, primarily linked to the hydrogen evolution reaction and zinc dendrite growth. To address these challenges, this study presents an innovative approach by designing an all-solid-state ZnI2 battery featuring a solid perfluoropolyether (PFPE)-based polymer electrolyte. The results demonstrate the formation of a solid electrolyte interphase (SEI) layer on zinc, promoting horizontal zinc growth, mitigating dendrite penetration, and enhancing battery cycle life. Moreover, the solid electrolyte hinders the iodine ion shuttle effect, reducing zinc foil corrosion. Symmetric batteries employing this electrolyte demonstrate excellent cycle performance, maintaining stability for approximately 5000 hours at room temperature, while all-solid-state ZnI2 batteries exhibit over 7000 cycles with a capacity retention exceeding 72.2%. This work offers a promising pathway to achieving reliable energy storage in solid-state ZnI2 batteries and introduces innovative concepts for flexible and wearable zinc batteries.&amp;#xD;

Knowledge, attitudes, practices, and risk perception of waterborneand foodborne diseases: a study with food handlers from food services

Introduction: Foodborne diseases (FBD) occur due to inadequate food handling; therefore, studies to evaluate the hygienic-sanitary aspects of food production are important. Objective: To evaluate the knowledge, attitudes, self-reported practices (KAP), and risk perception of DTHA from the perspective of food handlers in food services. Method: Questionnaires were administered through interviews, containing questions about the sociodemographic profile, KAP, and the risk perception of DTHA. The sample consisted of 30 handlers from 20 small food service establishments in Laranjeiras do Sul-PR. All participants signed an informed consent form. Results: Only 66.7% of the participants had participated in Good Practices training. The general average of knowledge was 84.7%, which was considered sufficient. All attitudes evaluated were above 70.0% for positive attitudes. Some handlers had negative attitudes toward hand hygiene (26.7%), food thawing (10.0%), and fruits and vegetables sanitation (10.0%). The interviewees showed adequate practices for most questions and inadequate practices, mainly for thawing (53.3%), wearing a uniform (20.0%), and temperature of perishable foods (10.0%). Handlers had a low-risk perception of DTHA in the food handled by them (93.3%), as well as for thawing at room temperature (53.4%) and use of non-potable water (30.0%). Conclusions: Knowledge and attitude were not translated into practice. It is necessary to conduct training in good practices to improve the knowledgeof food handlers about the correct handling of food and, above all, to increase risk perception and motivate positive attitudes and appropriate practices to produce safe food.

Synthesis and Characterization of Multiple Stimuli-Responsive Fluorescent Polymer Hydrogels Based on Terpyridine and N-isopropylacrylamide

A series of stimuli-responsive fluorescent hydrogels were successfully synthesized via micelle radical copolymerization of hydrophilic acrylamide (AM), hydrophobic chromophore terpyridine-based monomer (TPY), and N-isopropylacrylamide (NIPAM). These hydrogels presented blue emissions (423–440 nm) under room temperature, which is caused by the π-π* transition of the conjugated structures. Once the ambient temperature was increased to 55 °C, the fluorescence color changed from blue (430 nm) to pink (575 nm) within 10 min, subsequently to yellow (535 nm), and eventually back to pink. The thermal-responsive properties are attributed to the transition of the TPY units from unimer to dimer aggregation via the intermolecular charge transfer complex at high temperatures. The hydrogels showed pH-responsive properties. The emission peak of the hydrogel exhibited a blue shift of ~54 nm from neuter conditions to acidic conditions, while a 6 nm red shift to an alkaline environment was observed. The hydrogels demonstrated an obvious change in fluorescence intensity and wavelength upon adding different metal ions, which is caused by the coordination between the terpyridine units incorporated on the backbones and the metal ions. As a consequence, the hydrogels presented a sharp quenching fluorescence interaction with Fe2+, Fe3+, Cu2+, Hg2+, Ni2+, and Co2+, while it exhibited an enhanced fluorescence intensity interaction with Sn2+, Cd2+, and Zn2+. The microstructural, mechanical, and rheological properties of these luminescent hydrogels have been systematically investigated.

Probing the Thermal and Electrical Properties of Ultrawide Bandgap Nitrogen‐Polar AlGaN Heterostructures

AbstractUltra‐wide bandgap semiconductor AlGaN is a promising candidate for high‐power and high‐frequency electronics. AlGaN‐heterostructures with nitrogen (N)‐polarity can offer added benefits of low‐leakage and large drive current. However, electro‐thermal transport in such heterostructures remains unexplored, although they are essential for electronic device functionality. Here, the thermal and electrical properties of N‐polar AlxGa1‐xN‐channel heterostructures (Al percentage, x = 15–90%) are explored and compared with their GaN counterpart. The thermal measurements uncover that the effective thermal resistance of the thin channel and barrier layers are similar in magnitudes for N‐polar‐ AlGaN and GaN heterostructures, however, the total effective thermal conductivity in N‐polar AlGaN heterostructure is ≈4× smaller. This reduction originates from the larger thermal resistance of the thick Al0.15Ga0.85N buffer layer within the AlGaN stack. N‐polar AlxGa1‐xN stack displays a thermal conductivity almost independent of temperature, measured from room temperature up to 200 °C. Hall measurements of an N‐polar Al0.30Ga0.70N‐channel heterostructure further reveal that electrical properties such as resistivity, carrier density, and mobility remain nearly unchanged with temperature, indicating the dominance of alloy‐phonon scattering in such material systems. These results offer important insights into material‐device co‐design and reliability of N‐polar AlGaN heterostructures.

In situ generation of azo dyes on silk fibroin through three-step chemical modification

To enhance the efficiency and reduce the environmental footprint of silk dyeing, this study introduces a novel method that synthesizes azo dyes directly on silk fibroin (SF) using a three-step chemical modification at room temperature. Initially, SF undergoes modification with isatoic anhydride to yield aromatic primary amino-modified silk fibroin (SF–NH2). Subsequently, SF-NH2 is treated with nitrous acid to produce diazotized silk fibroin (SF–N2+). In the final step, SF-N2+ is combined with coupling components to directly form azo chromophores on the SF, culminating in the creation of coloured silk fibroin (SF–NN-CC). The efficacy of the three-step dyeing method was validated using infrared spectroscopy and colour development analysis. The modification sites on SF-NH2 were identified as the hydroxyl and amino groups of amino acid residues, confirmed through simulated reactions. SF-N2+ demonstrated excellent storage and thermal stability under dry conditions; however, its stability decreased in wet environments. Various coupling components were then reacted with SF-N2+ to synthesize in situ yellow, red, crimson, and green azo dyes on SF. The formation of covalent bonds between the dyes and SF was verified using DMF stripping methods. The dyed SF-NN-CC fabrics underwent testing for fastness, revealing wet fastness rating above grade 4. These findings demonstrate that the three-step modification process represents an innovative, energy-efficient, and fast-reacting dyeing method for SF.

Stability of Liposomal Membrane of Hemoglobin-Vesicles (Artificial Red Cells) for Over Years of Storage Evaluated Using Liquid Chromatography-Mass Spectrometry.

Hemoglobin-Vesicles (Hb-V) are artificial oxygen carriers encapsulating a purified and concentrated Hb solution in liposomes composed of 1,2-dipalmitoyl-sn-glycero-3-phosphatidylcholine (DPPC), cholesterol, 1,5-O-dihexadecyl-N-succinyl-l-glutamate (DHSG), and 1,2-distearoyl-sn-glycero-3-phosphatidylethanolamine-N-poly(ethylene glycol) (PEG5000) (DSPE-PEG). The safety and efficacy of Hb-V have been studied extensively by both preclinical and clinical test methods. Deoxygenation of Hb-V prevents autoxidation of Hb and can extend its shelf life to 2 years at room temperature. However, the lipid components raise concerns about hydrolysis because Hb-V is dispersed in saline. For this study, we attempted to estimate the lipid degradation of long-term stored Hb-V using liquid chromatography-mass spectrometry. Analyses of lipid components extracted from the stored Hb-V showed that the degradation increased depending on the storage temperature. The calculated % remaining of intact lipids of Hb-V were 98.1% after 4 years and 90.4% after 7.2 years at 4 °C, 95.8% after 1 year and 86.7% after 2 years at 25 °C, and 85.6% after 6 months at 40 °C. The main degradation products were lyso-PC and palmitic acid which are hydrolyzed at the ester bond of DPPC. A few hydrolyzed products of DHSG and DSPE-PEG were also detected in Hb-V, but almost no degradation or oxidation products derived from cholesterol could be identified. A shear test of Hb-V at 1500 s-1 showed no significant increase in Hb leakage after storage of 2 years at 25 °C and 6 months at 40 °C. Lipid degradation products including free fatty acids would decrease the pH of the Hb-V dispersion and synergistically facilitate degradation, but it maintained pH 6.5 during 6 years at 4 °C, 2 years at 25 °C, and 3 months at 40 °C because of its high buffering capacity. These results indicate that the storage conditions for Hb-V are appropriate to minimize lipid degradation in the long term.

Development of iodine based sustained release antimicrobial coatings for polyurethane voice prostheses.

Voice prostheses are known to fail in few weeks to several months of implantation due to the clogging mainly caused by microbial biofilm formation, which is a cause of concern. Iodine is a known broad-spectrum biocide and is reported to easily form complexes with various polymers. For long term device disinfection, strong iodine complexation that offers sustained iodine release for a prolonged period is essential. The present research work deals with the synthesis of a poly(methyl methacrylate-n-butyl acrylate-N-vinyl-2-pyrrolidone) (poly[MMA-BA-NVP]) tercopolymer through free radical polymerization for surface coating thermoplastic polyurethane (TPU) based voice prostheses. The NVP content in the tercopolymer was varied from 20% to 50% to optimise iodine loading and subsequent release. Base TPU coated with the tercopolymer was treated with 4% aqueous iodine solution at room temperature (28 ± 3 °C) for two hours. It was observed that the tercopolymer containing 35% N-vinyl-2-pyrrolidone (NVP), 32.5% methyl methacrylate (MMA) and 32.5% butyl acrylate (nBA) gave a stable coating on TPUs together with sustained iodine release for a prolonged period. Furthermore, the tercopolymer coated and iodine loaded TPUs exhibited excellent antimicrobial activity against Candida albicans, Staphylococcus aureus and Escherichia coli.

Solvent-Induced Structural Rearrangement in Ultrasound-Assisted Synthesis of Metal-Organic Frameworks.

Metal-organic frameworks (MOFs) are crystalline extended structures featuring permanent porosity, assembled from metal ions and organic ligands, often synthesized by the solvothermal method (50-260°C, 12-72h). Here, an alternative synthetic approach-solvent-induced structural rearrangement in ultrasound-assisted synthesis is presented. Six representative Zn-based MOFs, each composed of distinct secondary building units, are synthesized within 2-180min consuming less solvent (>0.03m) at room temperature. It is observed that ultrasonication induces the construction of a coordination network, and subsequent solvent exchange triggers structural rearrangement to yield MOFs of high crystallinity and porosity. Furthermore, the scalability of this method is demonstrated through the bulk synthesis of MOF-5, MOF-74, ZIF-8, and MFU-4l within 90min. The initiation of nucleation through ultrasound and the subsequent transformation induced by solvent exchange offer an alternative method for efficiently synthesizing MOFs in bulk, potentially broadening their range of applications.

Unraveling Electronic and Vibrational Coherences Following a Charge Transfer Process in a Photosystem II Reaction Center

A reaction center is a unique biological system that performs the initial charge separation within a Photosystem II (PSII) multiunit enzyme, which eventually drives the catalytic water-splitting in plants and algae. The possible role of quantum coherences coinciding with the energy and charge transfer processes in PSII reaction center is one of the active areas of research. Here, we study these quantum coherences by using a numerically exact method on an excitonic dimer model, including linear vibronic coupling and employing optimal parameters from experimental two-dimensional coherent spectroscopic measurements. This enables us to precisely capture the excitonic interaction between pigments and the dissipation of the energy from electronic and charge-transfer (CT) states to the protein environment. We employ the time nonlocal (TNL) quantum master equation to calculate the population dynamics, which yields numerically reliable results. The calculated results show that, due to the strong dissipation, the lifetime of electronic coherence is too short to have direct participation in the charge transfer processes. However, there are long-lived vibrational coherences present in the system at frequencies close to the excitionic energy gap. These are strongly coupled with the electronic coherences, which makes the detection of the electronic coherences with conventional techniques very challenging. Additionally, we unravel the strong excitonic interaction of radical pair (PD1 and PD2) in the reaction center, which results in a long-lived electronic coherence of &gt;100 fs, even at room temperature. Our work provide important physical insight to the charge separation process in PSII reaction center, which may be helpful for better understanding of photophysical processes in other natural and artificial light-harvesting systems.

Novel PEO-based Solid Polymer Electrolyte with High Elasticity and High Ionic Conductivity for Room Temperature Lithium Metal Batteries

Abstract The development and application of polyethylene oxide (PEO) based solid polymer electrolyte (SPE) is severely constrained by its low ionic conductivity and poor tensile resistance. To improve the electrochemical performance of SPE without losing its mechanical properties, a benzene sulfonate-based additive is adopted into crosslinking system composed of -CH2-CH2-O- segments to obtain a membrane with a high ionic conductivity of 1.47×10-4 S cm-1 and an ionic transference number of 0.70 at room temperature. The activation energy value of 0.128 eV gives evidence for a favorable migration mechanism of PTH-SPE. Anti-dendrite growth and contact optimization can be realized by molecular structure design with a tensile elongation of 490%. The reversible overpotential of Li||Li symmetric cell within 1000 h demonstrates that the compact PTH-SPE can inhibit the growth of lithium dendrite. This work provides a new strategy for designing high-performance solid electrolytes for room temperature via a green solvent-free method.

Design, Fabrication and Testing of A Novel Thermally-Actuated Tesla Valve (TATV): A Hybrid Microvalve

Abstract A novel thermally-actuated hybrid microvalve (similar to a Tesla Valve configuration) was designed, fabricated, assembled, and tested using soft lithography-based approaches. The modified design integrates the "normally open and closed" hybrid configurations of Tesla Valves with a thermo-pneumatic (or thermal-hydraulic) actuator microfabricated in-situ that modulates the diodicity of the microvalve apparatus in the microfluidic chip. Diodicity (Di) is defined as the ratio of flow rate in the forward direction to that of the reverse direction (for a constant value of pressure drop that is imposed on a microvalve device). The results from the study successfully demonstrated the operation of an array of Tesla Valves that are normally open in forward direction and marginally closed in reverse direction at room temperature (i.e., with Di &amp;gt; 1, the flow resistance values were different when the inlet and outlet ports were swapped). When the microfluidic chip was heated (at steady-state conditions with a nominal temperature of ~30°C), the diodicity virtually vanished (i.e., Di ≈ 1) resulting in both reverse and forward directions being normally open (or having the same flow resistance - irrespective of the flow direction).

Applicability Evaluation of Modified Epoxy Resin in the Repair and Reinforcement of Ancient Building Timber Members

To investigate the potential of modified epoxy resin for repairing and strengthening historical wooden structures, this study utilized polyurethane and silicone-modified epoxy resin as the base, alongside a polyamine curing agent. The resin mixture was cured at ambient temperature, resulting in the creation of ten unique epoxy resin systems. Investigation into the chemical structure and alterations to the glass transition temperature were conducted. The study conducted tests and characterization of viscosity, curing rate, mechanical properties, stress failure mode, hygrothermal aging resistance, and bonding properties. The results reveal that the curing degree of the two modified epoxy resins is high after being cured at room temperature, and the chemical structure and curing rate show insignificant changes. The range of the glass transition temperature for the modified epoxy resin is between 61.31 °C and 70.51 °C. The incorporation of polyurethane and silicone molecular chains into the epoxy resin cross-linking curing system enhances the toughness of the epoxy resin. The modified resin achieves a maximum elongation at break that is 5.18 times greater than that of the unmodified resin, along with a maximum tensile strength and a compressive strength that are 7.94 and 1.74 times, respectively, higher than those in the Chinese technical specifications for the maintenance and reinforcement of ancient wooden structures. The increase in toughness changes the failure mode of the cured epoxy resin. The modified epoxy resin exhibits great bonding ability to aged wood, with a shear strength of up to 9.6 MPa along the grain. As a result, the modified epoxy resin meets the requirements for the reinforcement and repair of the timber members of ancient buildings.