Carbon fibre reinforced polymer rolls are an interesting alternative to steel or aluminium rolls for the paper, textile and foil industries on account of their great stiffness and very low inertia. However, their application is inpeded by insufficient wear resistance. In cooperation with a roll manufacturer, a technology was developed to apply a coating system of superior wear resistance to these rolls. The process consists of several steps: (1) microroughening of the substrate surface, (2) deposition of nucleation sites, (3) electroless deposition of an NiP coating, (4) chrome plating. The most critical area of this coating system is the interface polymer-NiP layer. Because the van der Waals bonds are too weak to give sufficient adhesive strength, the substrate surface has to be prepared very carefully for optimum mechanical interlocking by grit blasting. In this way an adhesive strength up to 20 MPa could be achieved, as measured by pull-off tests. This often exceeds the cohesive strength of the carbon fibre/epoxy composite. Apart from the process technology, the paper also adresses the characterization of the coatings with respect to microstructure, surface quality and wear resistance.