The ultra-thin-walled corrugated sheet is a crucial component of metal honeycomb structures. Due to the size effect, the traditional roll bend forming process often leads to significant dimensional deviations in ultra-thin-walled corrugated sheets. To address this issue, an ultrasonic vibration-assisted roll bend forming process was proposed. First, an ultrasonic vibration-assisted roll bend forming device was designed, which had a special drive roller structure that can alter the original axial direction of ultrasonic vibration to produce a radial vibration with an amplitude of 0–2 µm. Under the high-frequency impact and acoustic softening effect of ultrasonic vibration, the ultra-thin-walled corrugated sheets formed numerous plastic penetration zones. As a result, the influence of individual grain heterogeneity was weakened and the stress distribution states underwent an interchange. Therefore, the ultra-thin-walled corrugated sheets demonstrated improved edge length uniformity, increased hardness in the deformed areas, reduced surface roughness, and decreased springback angle. However, excessive ultrasonic amplitude resulted in severe thinning or even rupture. Ultimately, high-quality ultra-thin-walled corrugated sheets were successfully fabricated using pure titanium foil with a t/d of 5.4 and an ultrasonic amplitude of 1.6 μm.