Amphibolite Facies Rocks Research Articles

Recognition of late Paleoproterozoic gold mineralization in the North China craton: Evidence from multi-mineral U-Pb geochronology and stable isotopes of the Shanggong deposit

Abstract The North China craton was stabilized in the late Paleoproterozoic but experienced significant removal of ancient lithospheric keel in the late Mesozoic that resulted in the formation of numerous world-class gold deposits with combined reserves of more than 7000 t of gold. However, it remains uncertain whether the North China craton contains older gold deposits formed during generation and final stabilization of the craton. Here, we show that the Shanggong gold deposit (105 t Au at 5.31 g/t) on the southern margin of the North China craton formed in the late Paleoproterozoic during the collision between the Eastern and Western blocks that led to formation of the Trans–North China orogen and final stabilization of the craton. The Shanggong deposit is hosted in amphibolite-facies rocks of the Neoarchean to early Paleoproterozoic Taihua Group and overlying volcanic rocks of the late Paleoproterozoic Xiong’er Group. Gold mineralization is structurally controlled by NE-striking faults and occurs in four segments: the Liuxiugou, Hugou, Shanggong, and Qiliping segments. The ores consist mainly of quartz-ankeritesulfide stockworks and sulfide disseminations in hydrothermally altered wall rocks. Gold is mostly contained in arsenian pyrite that is variably associated with minor sphalerite, galena, and chalcopyrite. Ore-related alteration assemblages comprise mainly quartz, ankerite, K-feldspar, sericite, and tourmaline. Both the stockworks and mineralized alteration assemblages contain hydrothermal accessory minerals, including monazite, apatite, and rutile. Paragenetic relations and textural data show that these accessory phases precipitated synchronously with gold-bearing sulfides. Laser ablation–inductively coupled plasma–mass spectrometry spot analyses of monazite and apatite from the Shanggong segment yielded reproducible U-Pb dates of 1747 ± 20 Ma (2σ, mean square of weighted deviates [MSWD] 0.46) and 1788 ± 200 Ma (2σ, MSWD = 11.3), respectively. These dates are indistinguishable within errors from an apatite U-Pb date of 1743 ± 79 Ma (2σ, MSWD = 1.6) at the Liuxiugou segment and a rutile U-Pb date of 1804 ± 52 Ma (2σ, MSWD = 0.77) at the Hugou segment. These new dates suggest that the Shanggong deposit formed at ca. 1.80–1.74 Ga, coeval with or immediately after formation of the Trans–North China orogen and final stabilization of the North China craton. Sulfides from the Shanggong gold deposit have δ34S values ranging from −18.5‰ to −6.9‰, whereas the coexisting ankerite has δ13CPDB of −6.81‰ to −1.61‰ and δ18OSMOW of 15.70‰–17.62‰. The stable isotope data are distinctively different from values of the Early Cretaceous gold deposits in the southern North China craton, indicating contrasting hydrothermal systems responsible for these two categories of gold deposits. The results presented here, combined with independent geologic evidence, allow Shanggong to be the first confirmed Paleoproterozoic orogenic gold deposit in the North China craton. Recognition of Paleoproterozoic orogenic gold mineralization provides significant new insights into the gold metallogeny of the well-endowed North China craton and has implications for future gold exploration along the three Paleoproterozoic orogenic belts in this craton.

Zircon as a Recorder of Trace Element Changes during High-Grade Metamorphism of Neoarchean Lower Crust, Shevaroy Block, Eastern Dharwar Craton, India

AbstractSystematic changes in whole-rock chemistry, mineralogy, mineral textures, and mineral chemistry are seen along a ca. 95-km traverse of late Archean granitoid orthogneisses in the Shevaroy Block, Eastern Dharwar Craton, southern India. The traverse passes from amphibolite-grade gneisses in the north to granulite-grade rocks (charnockite) in the south. Changes include whole-rock depletion of Rb, Cs, Th, and U in the granulite grade rocks as relative to the amphibolite grade gneisses, and oxidation trends regionally from highly oxidised granulite-facies rocks near the magnetite–haematite buffer to relatively reduced amphibolite-facies rocks below the fayalite-magnetite-quartz. Rare earth elements show limited mobility and are hosted a variety of minerals whose presence is dependent on the metamorphic grade ranging from titanite and allanite in the amphibolite-facies rocks to monazite in the vicinity of the orthopyroxene-in isograd to apatite in the granulite-grade charnockite. Cathodoluminescence and back-scattered electron sub-grain imaging and sensitive high-resolution ion microprobe analysis of zircon from 29 samples of dioritic, tonalitic, and granitic orthogneiss from the traverse reveals magmatic zircon cores that record the emplacement of the granitoid protoliths mostly about 2580 to 2550 Ma, along with a few older mid to late Archean tonalites. Protolith zircon was modified during metamorphism by overgrowth and/or replacement. Relative to igneous cores, U-enriched metamorphic zircon, dominant in the amphibolite-grade gneisses, formed at ca. 2530 Ma, predating retrograde titanite growth at ca. 2500 Ma. Uranium-depleted mantles grew on zircon between 2530 and 2500 Ma in granulite-grade samples south of the orthopyroxene-in isograd. In some of these samples, the U-depleted metamorphic zircon is preceded by mantles of U-undepleted zircon, indicating a progression of metamorphic zircon growth with increasingly depleted compositions between 2530 and 2500 Ma. With increasing metamorphic grade (from amphibolite to granulite) and oxidation state, allanite and monazite disappear from the assemblage and zircon became depleted in U and Th. Whole-rock U-Th compositions became decoupled from relict magmatic zircon compositions, reflecting the development of U-depleted metamorphic zircon and indicating that whole-rock chemical differences along the traverse were produced during metamorphism, rather than just reflecting differences in dioritic vs granitic protoliths. Although in situ anatexis and melt extraction may have played a role, whole-rock and zircon depletion of trace elements can be explained by the action of externally derived, oxidising, low-H2O activity hypersaline fluids migrating up through the mid to lower crust. Fluids and element migration during metamorphism may be the end result of subduction related processes that cumulated in the collision and concatenation of island arcs and continental blocks. These tectonic processes assembled the Dharwar Craton at the end of the Archean.

High pressure granulite facies metamorphism at the interface of the Archean Bastar craton and the Proterozoic Eastern Ghats Belt, India

Nd model ages show that the suture between the Archean Bastar craton and Proterozoic Eastern Ghats Province (a part of the Eastern Ghats Belt), India is marked by a broad shear zone that contains a mixture of rocks from both the blocks. In this suture zone, amphibolite facies rocks of the Bastar craton were subjected to high pressure granulite facies metamorphism possibly at ~500 Ma (published isotopic data). New petrological, geothermobarometric and P-T pseudosection studies show that dehydration-melting of amphibole (in mafic protolith) and of biotite (in quartzofeldspathic protolith) along a clockwise P-T path led to peak metamorphic conditions of 9.75 ± 0.5 kbar; 875 ± 30 °C. Mafic granulites from the Eastern Ghats Province had an earlier metamorphic history of isobaric cooling from unknown peak metamorphic conditions, but currently record P-T maximum values of 9.25 ± 0.25 kbar; 825 ± 25 °C. Followed by cooling through ~100 °C from the peak metamorphic conditions, mafic granulites from the Bastar craton were exhumed to mid-crustal levels by decompression-cooling, probably as a tectonic wedge. This decompression-cooling is also shared by charnockitic rocks of the Bastar craton and mafic granulites of the Eastern Ghats Province. We interpret further burial of the Bastar craton rocks as a result of underthrusting beneath the Eastern Ghats Province, consistent with available seismic data. Total absence of any evidence of ocean opening or closure between the Bastar craton and the Eastern Ghats Province at around 500 Ma, coupled with interpretation of deduced P-T paths, suggest the shear zone resulted from far-field stress related to the Kuunga orogeny in an intraplate setting. This would support a model of Tonian age amalgamation of the Bastar craton and the Eastern Ghats Province as a part of the Greater Indian Landmass.

Unravelling the evolution of regional-scale shear zones with the aid of microstructures and textural analysis: an example from the central Himalaya

Microstructure and texture data on the Main Central Thrust zone (MCTz) in central Himalaya, on two nearly N-S oriented valleys in the Manaslu range (Western Nepal), are provided. Kinematic indicators at the meso and microscale support a south-directed flow. From south to north, greenschist facies paragneiss in the garnet-zone pass to amphibolite facies rocks in the kyanite-zone, suggesting an up-section metamorphic temperature increase. Combining microstructures and data from two different texture analysers (X-ray Texture goniometry and crystal-fabric microanalyzer) allowed to link the temperature path (from 460°C to 600°C up-section) and kinematic vorticity estimates. The “orientation of oblique grain shape fabrics” method was applied, pointing out a general shear flow (40-56% of pure shear) at the MCTz top. Results are in line with a “decelerating strain-path” model, as relatively high simple shear components are recorded at deeper structural levels. This work highlights that the combination of X-ray texture goniometry and crystal-fabric microanalyzer techniques is a good strategy to ensure quartz full-fabric.

Episodes of fissure formation in the Alps: connecting quartz fluid inclusion, fissure monazite age, and fissure orientation data

Fluid assisted Alpine fissure-vein and cleft formation starts at prograde, peak or retrograde metamorphic conditions of 450–550 °C and 0.3–0.6 GPa and below, commonly at conditions of ductile to brittle rock deformation. Early-formed fissures become overprinted by subsequent deformation, locally leading to a reorientation. Deformation that follows fissure formation initiates a cycle of dissolution, dissolution/reprecipitation or new growth of fissure minerals enclosing fluid inclusions. Although fissures in upper greenschist and amphibolite facies rocks predominantly form under retrograde metamorphic conditions, this work confirms that the carbon dioxide fluid zone correlates with regions of highest grade Alpine metamorphism, suggesting carbon dioxide production by prograde devolatilization reactions and rock-buffering of the fissure-filling fluid. For this reason, fluid composition zones systematically change in metamorphosed and exhumed nappe stacks from diagenetic to amphibolite facies metamorphic rocks from saline fluids dominated by higher hydrocarbons, methane, water and carbon dioxide. Open fissures are in most cases oriented roughly perpendicular to the foliation and lineation of the host rock. The type of fluid constrains the habit of the very frequently crystallizing quartz crystals. Open fissures also form in association with more localized strike-slip faults and are oriented perpendicular to the faults. The combination of fissure orientation, fissure quartz fluid inclusion and fissure monazite-(Ce) (hereafter monazite) Th–Pb ages shows that fissure formation occurred episodically (1) during the Cretaceous (eo-Alpine) deformation cycle in association with exhumation of the Austroalpine Koralpe-Saualpe region (~ 90 Ma) and subsequent extensional movements in association with the formation of the Gosau basins (~ 90–70 Ma), (2) during rapid exhumation of high-pressure overprinted Briançonnais and Piemontais units (36–30 Ma), (3) during unroofing of the Tauern and Lepontine metamorphic domes, during emplacement and reverse faulting of the external Massifs (25–12 Ma; except Argentera) and due to local dextral strike-slip faulting in association with the opening of the Ligurian sea, and (4) during the development of a young, widespread network of ductile to brittle strike-slip faults (12–5 Ma).

Unravelling metamorphic ages of suture zone rocks from the Sabzevar and Makran areas (Iran): Robust age constraints for the larger Arabia–Eurasian collision zone

AbstractIn this study we establish a time frame for metamorphic processes affecting Neotethyan suture zones at the northern (Sabzevar) and southern (Makran) margin of the Central Iranian Microcontinent. For this purpose, we have applied Rb–Sr and U–Pb geochronology to blueschist‐ and amphibolite facies rocks from these occurrences. So far, no isotopic ages are available for high‐P/low‐T rocks from the Sabzevar area which are exposed in the Govain and Chili mountains near Soltanabad. Three newly dated blueschists from the Govain mountain yielded Rb–Sr ages of 56.52 ± 0.32, 57.20 ± 0.32, and 55.12 ± 0.33 Ma respectively. These ages provide the first unambiguous evidence for late Palaeocene to early Eocene high‐P metamorphism in the Sabzevar zone and confirm the accuracy of earlier age assignments that were derived indirectly. The clearly confirmed age difference between late Palaeocene–early Eocene blueschists of the Govain mountain and kilometre‐scale dismembered HP granulites with Early Cretaceous (Albian) metamorphic ages from outcrops c. 60 km to the west of Soltanabad further corroborates interpretations that these rocks are not related to the same subduction zone complex. The blueschists record closure of an Albian to Late Cretaceous back‐arc basin, whereas the granulites formed due to subduction of older oceanic lithosphere. Uranium–Pb zircon dating of an amphibolite from the Iranshahr region in the Makran Zone yielded an intercept age of 87.8 ± 1.8 Ma and weighted mean age of 88.1 ± 1.7 Ma. Rb–Sr mineral isochrons for seven blueschist‐ and amphibolite facies samples from the same area generated very consistent ages of c. 84 Ma (± <1–3 Ma), regardless of metamorphic grade. The apparent contradiction that rocks recording different P–T conditions have identical metamorphic ages either indicates tectonic mixing of rocks during exhumation that originally had formed at the same time at different depths of the subduction system, or very rapid exhumation so that differences in closure temperatures became indistinguishable. The new data are similar, but much more precise, than previously reported K–Ar ages and suggest that most of the existing data had not been significantly compromised by contamination with extraneous Ar. Potassium–Ar indications for older blueschist‐ and/or amphibolite facies metamorphism (>85 Ma) have not yet been confirmed but can be reconciled with the larger geological frame implying that northward subduction of the Arabian plate beneath the Bajgan–Durkan continental block started shortly after c. 120 Ma.

An intracontinental orogen exhumed by basement-slice imbrication in the Longmenshan Thrust Belt of the Eastern Tibetan Plateau

AbstractThe Longmenshan Thrust Belt in Eastern Tibet resulted from a Mesozoic orogeny and Cenozoic reworking. It is generally believed that the Cenozoic tectonics along the Longmenshan Thrust Belt are mostly inherited from the Mesozoic. Reconstructing the Mesozoic tectonics of the Longmenshan Thrust Belt is therefore important for understanding its evolutionary history. On the basis of detailed structural analysis, we recognized a Main Central Boundary that divides the Longmenshan Thrust Belt into a Southeastern Zone and a Northwestern Zone. Both zones underwent a main D1 event characterized by D1E top-to-the-SE thrusting in the Southeastern Zone and D1W top-to-the-NW/N thrusting in the Northwestern Zone. In the Southeastern Zone, a D2 top-to-the-NW/N normal faulting that cuts the D1E structures is developed along the NW boundary of the basement complexes. Newly obtained and previous geochronological data indicate that the D1E and D1W events occurred synchronously at ca. 224–219 Ma, and the D2 top-to-the-NW/N normal faulting was episodically activated at ca. 166–160 Ma, 141–120 Ma, 81–47 Ma, and 27–25 Ma. Episodic and synchronously activated top-to-the-NW normal faulting and top-to-the-SE thrusting along the northwestern and southeastern boundaries of the basement complexes, respectively, leads us to propose that the basement slices were episodically imbricated to the SE during the Late Jurassic–Early Cretaceous and Late Cretaceous–earliest Paleocene. The D1 amphibolite facies metamorphic rocks above the basement complexes recorded fast exhumation during the Late Jurassic–Early Cretaceous. We propose that the early Mesozoic northwestward basement underthrusting along a crustal “weak zone” was responsible for the D1 double-vergent thrusting and amphibolite facies metamorphism. Subsequent basement-slice imbrications reworked the Longmenshan Thrust Belt and exhumed the amphibolite facies rocks. Our results highlight the importance of basement underthrusting and imbrication in the formation and reworking of the intracontinental Longmenshan Thrust Belt in Eastern Tibet.

Metamorphic history and Neoarchean–Paleoproterozoic crustal growth of the central Trans-North China Orogen: Evidence from granulite- to amphibolite-facies rocks of the Hengshan complex

The Trans-North China Orogen (TNCO) is a major Paleoproterozoic collisional orogen exposed within the North China Craton (NCC). The orogen has undergone a complex tectonic evolution, but its role in the growth of continental crust is contentious. High-grade metamorphic rocks may carry key information required to clarify these issues. Here, using petrography, mineral chemistry, and zircon U–Pb–Hf isotopes, we investigate a suite of Neoarchean–Paleoproterozoic high-grade metamorphic rocks in the Hengshan Complex within the central TNCO. Garnet-bearing mafic granulites and amphibolites occur as lenses or dikes within tonalite–trondhjemite–granodiorite (TTG) gneisses. Three stages of metamorphic mineral assemblages are identified in a mafic granulite from the northern Hengshan Complex: (1) the prograde assemblage is preserved as small plagioclase and apatite inclusions within garnet porphyroblasts; (2) the peak mineral assemblage is recorded by a high-Ca garnet core coexisting with clinopyroxene, plagioclase, hornblende, biotite, and quartz; and (3) the retrograde assemblage is represented mainly by vermicular symplectites of hornblende + plagioclase and plagioclase coronae surrounding low-Ca garnet rims. Phase equilibria modeling and conventional geothermobarometry suggest that the mafic granulite records a clockwise P–T path, including decompression and cooling from the granulite-facies peak (12.5–14 kbar and >750 °C) to amphibolite-facies conditions during retrogression (7.3–8.3 kbar and 615–721 °C). In contrast, the amphibolite in the southern Hengshan Complex preserves only amphibolite-facies assemblages (hornblende + plagioclase + quartz), consistent with the metamorphic pressures of <7.1 kbar and temperatures below 720 °C.Zircon U--Pb dating of magmatic zircons shows that the protoliths of the TTG gneisses and amphibolite were emplaced at ca. 2.5 and 2.1 Ga, respectively. The metamorphic zircons reveal ages of 1.92–1.80 Ga for the mafic granulite (weighted mean of ca. 1.87 Ga) and 1.92–1.83 Ga for the amphibolites (weighted mean of ca. 1.88 Ga). These 1.88–1.87 Ga metamorphic ages are interpreted to represent the time when the rocks cooled to the solidus. By comparing Paleoproterozoic metamorphic ages across the TNCO, we infer that the subduction–collision–amalgamation between the Western and Eastern Blocks of the NCC lasted from 1.95 to 1.80 Ga at least, marking the final cratonization of the NCC. The ca. 2.5 Ga magmatic zircons within the TTG gneisses show positive εHf(t) values (+0.49 to +7.12) with model ages of 2.8–2.7 Ga, suggesting that the protoliths were derived from the partial melting of Neoarchean juvenile mafic crust. Zircon Hf model ages (TDM = 2.1–2.0 Ga) of the mafic granulite may represent the approximate time at which the mafic magma was generated in the mantle. Thus, the Hengshan Complex within the central TNCO records two episodes of crustal growth at 2.8–2.7 and 2.1–2.0 Ga, respectively. To further understand the processes involved in crustal evolution, we reconstructed a layered crust model for the Hengshan Complex, and the layered crust was strongly influenced by Paleoproterozoic thermal events.

SAFIRA NA SERRA DA MANTIQUEIRA, SUL DO ESTADO DO RIO DE JANEIRO: ESTUDOS DE PROVENIÊNCIA COM USO DE ANÁLISE MINERALÓGICA E QUÍMICA MINERAL

O Brasil é detentor de reservas significativas de pedras preciosas, com destaque para aquelas oriundas das Províncias Pegmatíticas Oriental e da Borborema, como turmalina paraíba, esmeralda e topázio imperial. As explorações de coríndon (rubi e safira) ainda são reduzidas no país e estão localizadas principalmente nos estados de Mato Grosso, Goiás, Santa Catarina e Minas Gerais. Campanhas prospectivas realizadas em drenagens na porção sul do estado do Rio de Janeiro coletaram 25 grãos de coríndon, com dimensões menores que 2 mm e entre 2 e 5 mm. Análises de química mineral por microfluorescência de raios X permitiram o estudo de proveniência, com base nas razões Cr2O3/Ga2O3, indicando formação por processo metamórfico. As análises de MEV/EDS identificaram inclusões sólidas de biotita, apatita e ilmenita. A presença das associações minerais espinélio, cianita e cordierita nos metassedimentos neoproterozóicos reforçam a associação genética do coríndon com rochas metamorfizadas em fácies anfibolito superior a granulito.

Cenozoic retrogression and exhumation of the amphibolites in the eastern Gangdese Belt, SW China

Abstract The collision between India and Asia is marked by the Yarlung Zangbo suture zone, which can be traced from Tibet into northwest Yunnan. The suture zone provides a record of the subduction of Neotethyan oceanic lithosphere beneath the Lhasa Block, creating the Gangdese magmatic belt, prior to the India–Asia collision. This paper reports petrological, zircon U–Pb, and whole-rock elemental and isotope data for amphibolite from the extension of the Gangdese belt in northwestern Yunnan. Two metamorphic stages are identified in relict amphibolite-facies rocks preserved in granitic gneisses from the belt. They are early amphibolite-facies metamorphism (M1) and late amphibolite-facies retrograde metamorphism (M2). The assemblage of M1 comprises garnet, amphibole, and plagioclase that formed at 0.89–0.97 GPa and 658–700 °C. Dating of syn-metamorphic zircons assigns this event to the middle Eocene (44–38 Ma). Symplectites (corona) of amphibole, plagioclase, and quartz surrounding garnet formed during retrograde stage M2, at 30–29 Ma, under P–T conditions of 0.41–0.68 GPa and 549–716 °C. The amphibolites display geochemical characteristics similar to those of mid-ocean ridge basalt, with eNd(t) values of +1.8 to +8.9, and are inferred to have formed in a back-arc-basin setting, suggesting that they constitute part of the lithospheric mantle of the Tengchong terrane that lies to the east. The amphibolite-facies metamorphism was related to underplating of the Indian plate during the India–Asia collision, which led to clockwise rotation of eastern Tibet during the middle Eocene, generating amphibolite recrystallization and, subsequently, with ongoing convergence of the two plates, exhumation of the region during the middle Oligocene.

Collage of tectonic slivers abutting the eastern Romeral Fault System in central Colombia

We investigated the U–Pb zircon geochronology of the metamorphic basement that abuts the east Romeral Fault System in north-central Colombia between the San Jerónimo Fault and the western border of the Antioquia Batholith. Our results indicate that this basement is more heterogeneous than previously realized, bearing crustal components with Cambro-Ordovician, Triassic, Late Jurassic–earliest Cretaceous, and middle Cretaceous ages. Metamorphic rocks with Ordovician and older protoliths are the La Aguadita Amphibolites and the La Miel Gneiss and associated amphibolites; the age of their metamorphism is poorly constrained. High-grade, Triassic metamorphic units also occur near the Romeral Fault System, and they are analogous to the bulk of the basement of the Central Cordillera (Tahamí terrane). In contrast, Late Jurassic–Early Cretaceous metamorphic units and middle Cretaceous amphibolite-facies rocks seem restricted to the studied area. The contacts among metamorphic units of disparate age is invariably tectonic. Whereas the older metamorphic units show no evidence of recrystallizations produced by the events that metamorphosed the younger units, the latter do not contain inherited zircon populations that would undoubtedly indicate recycling of the former. We conclude that the studied area is characterized by relatively small but distinct tectonic slivers (mostly <103 km2) and that the length scale of geologic heterogeneity is comparable to that of blocks within the Romeral Fault System. We propose that strike slip displacement along early strands of the long-lived fault system produced anastomosed slivers of diverse origin in the area between the San Jerónimo Fault and the western Antioquia Batholith. As the Romeral Fault System evolved, these strands were mostly abandoned as evidenced by their near absent morphotectonic expression.

Provenance of detrital rutiles from the Jurassic sandstones in the Central Sakarya Zone, NW Turkey: U-Pb ages and trace element geochemistry

This provenance study focuses on detrital rutile grains from Jurassic sandstones of the Bayırköy Formation in the central Sakarya Zone. Cr and Nb concentrations of detrital rutile grains in the Jurassic sandstones vary from 18 to 6855 μg/g and 70–13440 μg/g, respectively. Source area discrimination based on the Cr-Nb concentrations shows that 79 % of the detrital rutile grains originated from metapelitic and 21 % from metamafic rocks. The calculated rutile formation temperatures vary from 471 to 798 ℃ with an average temperature of 635 ℃ at P=10 kbar. Zr-in-rutile thermometer gives overlapping temperatures for all detrital rutile grains from both the metapelitic and metamafic sources. This demonstrates that most of the detrital rutiles sourced from metapelitic and metamafic rocks underwent similar metamorphic conditions and have similar metamorphic history. The U-Pb rutile dating yielded ages for the detrital rutiles in the time range of 346 to 319 Ma, which gives the age of metamorphism for the potential source rocks. Trace element compositions, Zr-in-rutile thermometer and U-Pb rutile geochronology show that detrital rutile grains were predominantly derived from early Carboniferous rocks that underwent metamorphism in amphibolite-facies conditions. Amphibolite-facies rocks of the Sarıcakaya Massif in the central Sakarya Zone seem to be the primary source lithologies for the detrital rutiles in the Jurassic Bayırköy Formation as it comprises previously-mentioned source lithologies and has a close geographic position to the area studied. Carboniferous Variscan metamorphism was followed by emplacement of numerous post-collisional granitoids in the central Sakarya Zone.

Evaporite-bearing orogenic belts produce ligand-rich and diverse metamorphic fluids

Detailed petrologic and chemical investigation of mid-amphibolite facies calcareous, scapolite-rich metasedimentary rocks from the Mount Isa region in northern Australia is used to explore changing fluid chemistry with prograde metamorphism. The presence of widespread scapolite with Cl- and variably SO4-rich compositions in upper amphibolite facies rocks makes it unavoidable that the regional metamorphic fluids were locally highly saline and oxidised, and that high salinities persisted throughout metamorphism. Electron microprobe analyses and chemical maps of individual scapolite grains show zoning in Cl and S, likely to reflect buffering of the metamorphic fluid by scapolite during progressive metamorphism. The zoning in Cl and S demonstrates that scapolite has the potential to record changes in fluid chemistry during metamorphism. The variation in scapolite composition between samples, in combination with whole rock geochemistry, shows that different layers within this heterogenous rock package generated fluids of different chemistries. Interaction between scapolite-bearing rocks and externally-derived magmatic or metamorphic fluids that are out of equilibrium drives scapolite breakdown, releasing Cl to the fluid. In the Mount Isa region, metamorphic fluid production was enhanced by periods of magmatism, which promoted development of a regionally extensive and unusually saline fluid system that was active at multiple stages over a 250 million-year period. The highly saline and oxidised fluids formed through interaction with scapolite are well suited to transporting a broad range of metals, and may explain the diverse range of syn-orogenic mineral deposits in the Mount Isa Inlier. Metamorphic belts with large volumes of evaporitic material are ideal for generating a broad spectrum of syn-orogenic hydrothermal ore deposit types - including Fe oxide Cu-Au, Fe sulphide Cu-Au, Mo-Re and U-REE, but lacking the Au-only deposits found in typical orogenic belts. Unlike regions hosting traditional orogenic gold deposits, belts containing evaporitic sequences can preserve Cl-rich minerals such as scapolite in the metamorphosed source region, allowing them to remain active as ore forming systems through relatively high-grade metamorphism and multiple stages of tectonism. Periods of supercontinent breakup, such as the Mesoproterozoic, may have resulted in the formation of large, intracontinental basins well suited to the development of widespread evaporitic sequences. This, in combination with overprinting orogenesis and high temperature magmatism, may have provided the ingredients for widespread ore deposit formation at a global scale.

Eocene seismogenic reactivation of a Jurassic ductile shear zone at Cap de Creus, Pyrenees, NE Spain

The Cap de Creus peninsula in NE Spain exposes Variscan amphibolite-facies rocks, transected by greenschist-facies mylonitic shear zones accommodating displacements of up to 1 km. One of these shear zones contains pseudotachylytes with 1–4 mm thick fault veins and cm-scale high-angle injection veins and breccias. The pseudotachylyte matrix encloses mm-to μm-scale wallrock fragments and consists of ultrafine biotite and feldspar, often with a microporphyritic structure suggesting crystallization from a melt. Recent dating of the host shear zone yielded a Jurassic (170-160 Ma) age. Here we present 40Ar/39Ar dating of the pseudotachylytes yielding Early Eocene ages between 52.76 ± 1.64 Ma and 44.55 ± 0.77 Ma, indicating Alpine brittle faulting at times that Jurassic low-angle ductile shears had been tilted to their present vertical position following Alpine thrusting in the Pyrenees. The kinematics of the pseudotachylytes suggest strike-slip reactivation along the host shear zone, consistent with plate-kinematic analyses indicating coeval Iberia - Europe motion dominated by strike-slip. The dimensions of the pseudotachylyte-bearing zone and estimated brittle displacements suggest a moment magnitude of ~4.7–4.9. The average thicknesses of the fault veins indicate deformation at ≥4 km depth, an energy density of ~9.106 J/m2 and a frictional resistance of ~23 MPa.

Microstructurally controlled trace element (Zr, U–Pb) concentrations in metamorphic rutile: An example from the amphibolites of the Bergen Arcs

AbstractAs a common constituent of metamorphic assemblages, rutile provides constraints on the timing and conditions of rock transformation at high resolution. However, very little is known about the links between trace element mobility and rutile microstructures that result from synmetamorphic deformation. To address this issue, here we combine in situ LA‐ICP‐MS and sensitive high‐resolution ion microprobe trace element data with electron back‐scatter diffraction microstructural analyses to investigate the links between rutile lattice distortions and Zr and U–Pb systematics. Furthermore, we apply this integrated approach to constrain further the temperature and timing of amphibolite facies metamorphism and deformation in the Bergen Arcs of southwestern Norway. In outcrop, the formation of porphyroblastic rutile in dynamically hydrated leucocratic domains of otherwise rutile‐poor statically hydrated amphibolite provides key contextual information on both the ambient conditions of hydration and deformation and the composition of the reactive fluid. Rutile in amphibolite recorded ambient metamorphic temperatures of ~590–730°C during static hydration of the granulitic precursor. By contrast, rutile from leucocratic domains in the directly adjacent shear zone indicates that deformation was accompanied by a localized increase in temperature. These higher temperatures are recorded in strain‐free rutile (~600–860°C) and by Zr concentration measurements on low‐angle boundaries and shear bands (620–820°C). In addition, we also observe slight depletions of Zr and U along rutile low‐angle boundaries relative to strain‐free areas in deformed grains from the shear zone. This indicates that crystal–plastic deformation facilitated the compositional re‐equilibration of rutile upon cooling to slightly below the peak temperature of deformation. Cessation of deformation at mid‐crustal conditions near ~600°C is recorded by late stage growth of small (&lt;150 µm) rutile in the high‐strain zones. U–Pb age data obtained from the strain‐free and distorted rutile grains cluster in distinct populations of 437.4 ± 2.7 Ma and c. 405–410 Ma, respectively. These different ages are interpreted to reflect the difference in closure for thermally induced Pb diffusion between undeformed and deformed rutile during post‐deformation exhumation and cooling. Thus, our results provide a reconstruction of the thermochronological history of the amphibolite facies rocks of the Lindås Nappe and highlight the importance of integration of microstructural data during application of thermometers and geochronometers.

Thermal modelling of very long-lived (>140 Myr) high thermal gradient metamorphism as a result of radiogenic heating in the Reynolds Range, central Australia

The Reynolds Range in the Paleo-Mesoproterozoic Aileron Province of central Australia exposes a differentially exhumed metamorphic rock system varying from greenschist-to granulite-facies. Calculated P–T pseudosections indicate that peak metamorphic conditions in greenschist-facies areas reached temperatures of ∼480 °C and pressures of 3.2–5 kbar. Peak conditions at amphibolite-facies are constrained to 500–620 °C and 1.3–3.8 kbar. P–T modelling of two petrologically different granulite-facies samples indicate that peak conditions in the exhumed granulite-facies rocks reached 780–920 °C and 3.5–5.4 kbar, corresponding to high apparent thermal gradients of 152–218 °C/kbar. In the amphibolite-facies rocks, in situ LA–ICP–MS U–Pb monazite geochronology records ages that range between 1680 and 1550 Ma. In contrast, in the granulite-facies rocks, monazite records ages of ca. 1560 Ma. The terrane contains significantly elevated rates of crustal heat production compared to global norms, and when incorporated into lithospheric thermal models with reasonable boundary conditions and average thermal properties, can plausibly account for the long-lasting metamorphic conditions. The thermal modelling shows that the long lasting (>100 Myr) record of monazite U–Pb ages, supported by previous studies, reflects a continuous duration of elevated crustal temperatures, an interpretation consistent with texturally simple mineral assemblages that lack any evidence for polymetamorphism. In high-crustal heat production terranes, high thermal gradients and high temperatures will persist until exhumation removes the upper crust. This physical reality provides a basis for the existence of arbitrarily long-lived metamorphic systems, even under high thermal gradients that are generally considered to be thermally anomalous. However, such thermal anomalism is not remarkable, as there is abundant evidence for elevated rates of crustal heat production in the Reynolds Range and worldwide. In terranes where accessory minerals record large continuous ranges of age, robust volumetric measurements of crustal heat production rates are a necessary step in evaluating the potential thermal significance of such geochronological records. Failure to document rates of crustal heat generation invalidates many interpretations for drivers of metamorphism.

Hydrothermal Alteration Mineralogy and Geochemistry of the Archean World-Class Canadian Malartic Disseminated-Stockwork Gold Deposit, Southern Abitibi Greenstone Belt, Quebec, Canada

AbstractThe Canadian Malartic stockwork-disseminated gold deposit is an Archean world-class deposit located in the southern Abitibi greenstone belt. It contains over 332.8 tonnes (t; 10.7 Moz) of Au at a grade of 0.97 ppm, in addition to 160 t (5.14 Moz) of past production (1935–1981). Although the deposit is partly situated within the Larder Lake-Cadillac fault zone, most of the ore occurs up to ~1.5 km to the south of the fault zone. The main hosts of the mineralized zones are greenschist facies turbiditic graywacke and mudstone of the Pontiac Group (~2685–2682 Ma) and predominantly subalkaline ~2678 Ma porphyritic quartz monzodiorite and granodiorite. These intrusions were emplaced during an episode of clastic sedimentation and alkaline to subalkaline magmatism known as the Timiskaming assemblage (&lt;2680–2670 Ma in the southern Abitibi). The orebodies define two main mineralized trends, which are oriented subparallel to the NW-striking S2 cleavage and the E-striking, S-dipping Sladen fault zone. This syn- to post-D2 ductile-brittle to brittle Sladen fault zone is mineralized for more than 3 km along strike.The ore mainly consists of disseminated pyrite in stockworks and replacement zones, with subordinate auriferous quartz veins and breccia. Gold is associated with pyrite and traces of tellurides defining an Au-Te-W ± Ag-Bi-Mo-Pb signature. The orebodies are zoned outward, and most of the higher-grade (&gt;1 ppm Au) ore was deposited as a result of iron sulfidation from silicates and oxides and Na-K metasomatism in carbonatized rocks. The alteration footprint comprises a proximal alteration envelope (K- or Na-feldspar-dolomite-calcite-pyrite ± phlogopite). This proximal alteration zone transitions to an outer shell of altered rocks (biotite-calcite-phengitic white mica), which hosts sub-ppm gold grades and reflects decreasing carbonatization, sulfidation, and aNa+/aH+ or aK+/aH+ of the ore fluid.Gold mineralization, with an inferred age of ~2664 Ma (Re-Os molybdenite), was contemporaneous with syn- to late-D2 peak metamorphism in the Pontiac Group; it postdates sedimentation of the Timiskaming assemblage along the Larder Lake-Cadillac fault zone (~2680–2669 Ma) and crystallization of the quartz monzodiorite. These chronological relationships agree with a model of CO2-rich auriferous fluid generation in amphibolite facies rocks of the Pontiac Group and gold deposition in syn- to late-D2 structures in the upper greenschist to amphibolite facies. The variable geometry, rheology, and composition of the various intrusive and sedimentary rocks have provided strain heterogeneities and chemical gradients for the formation of structural and chemical traps that host the gold. The Canadian Malartic deposit corresponds to a mesozonal stockwork-disseminated replacement-type deposit formed within an orogenic setting. The predominance of disseminated replacement ore over fault-fill and extensional quartz-carbonate vein systems suggests that the mineralized fracture networks remained relatively permeable and that fluids circulated at a near-constant hydraulic gradient during the main phase of auriferous hydrothermal alteration.

Mineral indicators of reactions involving fluid salt components in the deep lithosphere

The salt components of H2O and H2O–CO2 fluids are very important agents of metasomatism and partial melting of crustal and mantle rocks. The paper presents examples and synthesized data on mineral associations in granulite- and amphibolite-facies rocks of various composition in the middle and lower crust and in upper-mantle eclogites and peridotites that provide evidence of reactions involving salt components of fluids. These data are analyzed together with results of model experiments that reproduce some of these associations and make it possible to more accurately determine their crystallization parameters.

Metamorphic P–T paths for the Archean Caozhuang supracrustal sequence, eastern Hebei Province, North China Craton: Implications for a sagduction regime

Archean supracrustal rocks of amphibolite-facies occur as enclaves within granitoids gneiss domes and belts between domes, representing collision or sagduction regimes. In order to distinguish between tectonic regimes using metamorphic patterns, systematic data on metamorphic evolution and zircon age dating are presented for the Caozhuang supracrustal sequence of eastern Hebei Province, China, which occurs as enclaves in gneisses. A garnet biotite gneiss records a P–T path involving pre-peak isobaric heating to peak conditions at 780–800 °C and 10–11 kbar (medium-P/T type), followed by decompression to 5–6 kbar. Two Mg/Al-rich schists from the same locality show low P/T conditions of 6–7 kbar/690–750 °C and 4–7 kbar/750–780 °C, similar to that of the decompression stage for the biotite gneiss. Zircon age dating suggests that the amphibolite-facies metamorphism occurred at ∼2.49 Ga, coeval with TTG magmatic activities. Combined with a summary of the metamorphism from Kaapvaal and Pilbara Cratons, we concluded that Archean amphibolite-facies supracrustal rocks occurring as enclaves and belts show different metamorphic patterns. The former exhibits the metamorphic patterns the same as those recovered for the Caozhuang rocks, characteristic of pre-peak isobaric heating to 600–800 °C at 10–12 kbar followed by isothermal decompression with the overprinting of medium- and/or low-P/T assemblages in different enclaves. The latter shows medium- or high-P/T peak conditions mostly lower than 600–650 °C followed by decompression, lacking the pre-peak heating. These metamorphic patterns could be good indicators of a sagduction regime.

Slow cooling versus episodic fluid injections: Deciphering the Caledonian orogeny in Vestvågøy, Lofoten islands, Norway

AbstractThe determination of the thermal (temperature–time) histories of high‐P metamorphic terranes has been commonly based on the concepts of slow cooling and closure temperatures. In this paper, we find that this approach cannot reconcile a geochronological data set obtained from the amphibolite‐facies allochthonous Leknes Group of the Lofoten islands, Norway, which reveals an extremely complex thermal history. Using detailed results from several different geochronometers such as 40Ar/39Ar, Rb–Sr and U–Pb, we show that a model invoking multiple, short‐lived thermal pulses related to hot‐fluid infiltration channelized by shear zones can reconcile this complicated data set. This model suggests that hot fluids infiltrated throughout basement shear zones and affected the overlying cold allochthon, partially resetting U/Pb rutile and titanite ages, crystallizing new zircon and produced identical 40Ar/39Ar and Rb/Sr ages in muscovite, biotite and amphibole in various rocks throughout the region. This paper shows the enormous potential of coupling laser Ar‐spot data with thermal modelling to identify and constrain the duration of short‐lived events. An optimal P–T–t history has been derived by modelling the age data from a previously dated large muscovite crystal (Hames &amp; Andresen, 1996, Geology, 24:1005) and using Zr‐in‐rutile thermometry which is consistent with all geochronological data and geological constraints from the basement zones and allochthon cover. This tectonothermal model history suggests that there have been three episodic hot‐fluid and 40Ar‐free infiltration events, resulting in the total resetting of Ar ages during the Scandian (425 Ma) for 1 Ma at 650°C and two reheating events at 415 Ma for 400 ka at 650°C and at 365 Ma for 50 ka at 600°C, which are modelled as thermal spikes above an ambient temperature of 300°C. Independent confirmation of these parameters was provided by Pb‐diffusion modelling in rutile and titanite. The model suggests that the amphibolite facies rocks of the Leknes Group probably remained cold before being exhumed for at least 60 Ma (425–365 Ma) and successfully explains the presence of different minerals that crystallized or were totally/partially reset in the allochthon and in the basement. The migration of hot fluids for short periods of times within conduits extending through the basement and allochthon rock units is likely associated with episodic seismic activity during the Caledonian orogeny.