In this work, a wave-equation-based discontinuous Galerkin (DG) method hybridized with the Robin transmission condition (DG-RTC) is developed to solve the frequency-domain electromagnetic (EM) problems. The proposed DG method directly discretizes the vector electric field wave equation in each subdomain, and subsequently, a term named numerical flux is introduced at the subdomain interfaces to connect the solutions between neighboring subdomains. However, the numerical flux depends not only on the electric field <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mathbf {E}$ </tex-math></inline-formula> but also on the magnetic field <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mathbf {H}$ </tex-math></inline-formula> residing over the interface. Thereby, another equation is essential for solving <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mathbf {E}$ </tex-math></inline-formula> and <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mathbf {H}$ </tex-math></inline-formula> simultaneously. Realizing that <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mathbf {H}$ </tex-math></inline-formula> only situates at the interface of adjacent subdomains, it is thus desired that the auxiliary equation also merely involves <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mathbf {H}$ </tex-math></inline-formula> at the interfaces. To reach this aim, at the subdomain interfaces, a Robin transmission condition (RTC) based on the tangential continuity of EM fields across the interface is introduced as the second equation. With this proposed DG-RTC algorithm, only <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mathbf {E}$ </tex-math></inline-formula> is a volume variable, while <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mathbf {H}$ </tex-math></inline-formula> is a two-dimensional (2-D) one, and the degrees of freedom (DoFs) are thus greatly reduced compared with the traditional DG method. On the other hand, in the frequency domain, the established subdomain matrix equations are implicitly coupled with each other, resulting in a global matrix system. Directly solving it is not yet cheap. To alleviate the computational cost, a finite-element tearing and interconnecting (FETI)-like approach resorts. With the block-diagonal preconditioner and a restriction operator, the global matrix is decomposed into a surface matrix equation and several local matrix equations pertinent to each subdomain. In this way, a direct solver can be applied to solve these small matrix equations efficiently. To validate the proposed DG method in solving various EM problems, several representative examples are presented.