The present work is aimed at analyzing the evolution of accidental scenarios deriving from the release of toxic materials inside a tunnel. This scenario, compared to the more frequently investigated cases of fire, followed by smoke dispersion, may involve a large variety of common products characterized by widely differing physical properties; nonetheless it has been analysed in the literature less than expected. The present study compares the dispersion of two common toxic chemicals (chlorine and ammonia), in order to derive some preliminary information about the influence of the physical properties and the release rate. A reference road tunnel geometry is assumed, while the release occurs from ground level, at the centre of one lane and in the middle of the tunnel. Two study cases involving a road tanker, transporting the product as liquefied gas under pressure, were considered: a catastrophic release, from a 220 mm hole, emptying the tanker in a few tens seconds (case A), and a continuous release, from a much smaller hole (15 mm), lasting 5 min (case B). For the sake of simplicity, the release is assumed to be in gaseous phase; the dispersion of the toxic is simulated for the 5 min period following the start of the release using a CFD (Computational Fluid Dynamics) analysis, according to an RANS (Reynolds-Averaged Navier–Stokes) approach with the standard k–ε turbulence model, assuming no ventilation conditions. Structured curvilinear grids with hexaedric cells, refined according to the local concentration gradient, are used. For case A scenarios, especially for the whole release duration, dispersion is mainly governed by the “plug-flow” effect caused by the large volume of toxic entering the tunnel in a rather short time; then, the role of diffusivity and gravity becomes more important. Chlorine, heavier than air and with lower diffusivity than ammonia, progressively accumulates towards the floor; the dispersion of ammonia, which is lighter than air, appears more influenced by diffusivity than by gravity, since a limited stratification is observed. These trends are more evident for case B scenarios, where the toxic flow rates are much lower. It is expected the results will give some useful insight into the dispersion phenomenon within highly confined spaces and maybe also provide some suggestion about ventilation systems design and emergency procedures.
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