The lower visibility in the nighttime environment makes higher accident risks during driving. Using self-luminous materials in pavement construction can effectively improve the luminance of load surface, thus significantly improve nighttime driving safety. This study has designed three types of self-luminous pavement materials (SLPM) with different optical properties by incorporating long-persistent luminescent aggregates into the mixture and using polymer binders with varying degrees of light transmittance, such as transparent polyurethane, transparent asphalt, and traditional asphalt. On this basis, utilizing digital image processing techniques to compare the optical performance differences among these three SLPM and established corresponding computational models based on the obtained data to enable efficient and accurate evaluation of the optical properties of pavement materials. The experimental results indicate that the durability performance of SLPM gradually diminishes over time, and this degree of attenuation is negatively correlated with the light transmittance of the binder. Specifically, a higher light transmittance of the binder results in a smaller decline in SLPM durability, whereas a lower transmittance leads to a more significant reduction. The optical performance calculation model established by this research can predict the reflective performance of SLPM through the optical parameters of aggregate, binders, and the doping amount of long persistent luminescent materials. In addition, the model can accurately calculate the minimum content of self-luminous materials according to the optical requirements required by the project, which can provide a reference for the performance evaluation of self-luminous pavement materials and the selection of optimal proportioning scheme.