Abundant high-pressure exhaust gas is generated during industrial production processes. The direct release of this exhaust gas not only leads to energy dissipation but also increases the accident risk. Therefore, it is essential to utilize and monitor high-pressure exhaust gas. This study designed a triboelectric nanogenerator (TENG) driven by high-pressure pulse airflow to realize energy harvesting and pressure monitoring at the gas–solid interface. The silver nanoparticles (Ag NPs)/ copper foam (CF)-based TENG (SC-TENG) were fabricated and exhibited excellent output characteristics. Compared to the copper-based TENG, the short-circuit current and output power were increased by 68.72 % and 63.34 %, respectively, which could directly light up 111 light-emitting diodes (LEDs). Furthermore, the effects of pipeline mateal, valve material, preparation environment (AgNO3 concentration), and air pressure were investigated to optimize the electric output of SC-TENG. The SC-TENG exhibited excellent pressure sensing capabilities and could be applied for rapid and sensitive long-term monitoring. Based on this, a wireless high-pressure warning system was designed to realize signal transmission and safety pre-warning. Lastly, a novel information encryption method based on pulse airflow was developed, and its potential applications in various fields were discussed. This work not only proposes a utilization and solution strategy for high-pressure exhaust gas issues to realize the principle of “turning waste into treasure”, but also provides valuable insights into the extended applications of TENG technology.