Rich Mineral Waters Research Articles

Preliminary studies on radon concentration in CO2-rich mineral waters of the Elbrus area (Caucasus, Russia)

The geological and geochemical conditions as well as radon concentrations of ten manifestations of СО2-rich waters in the Elbrus area are considered in this paper. Also, content of uranium and thorium were measured in waters and in host rocks. The data were compared with chemical and isotopic composition of associated gases. It is established that water bearing rocks are classified into rocks of low and normal radioactivity. The contents of uranium (<1.37 μg/L) and thorium (<0.3 μg/L) in the water are low. Measurements of radon concentrations in water and gas flux of mineral springs in the Elbrus area indicate that most of them are weakly radioactive (6–33 Bq/L, 25-350 Bq/m3, respectively). The CO2-rich mineral waters of the Tyrnyauz exhibit the highest level of radioactivity (33 Bq/L) within the Elbrus area. Isotopical gas studies have shown that within the Elbrus region there is a connection with the deep horizons of the Earth's crust, from which various fluids (water and gases) can rise to the surface. Although Rn values are low and cannot be used for medical purposes, natural objects with similar characteristics can be used to observe the state of the geological environment (e.g. earthquakes) and as natural laboratories to establish the mechanisms of deep gas migration to the surface.

Pilot Trial on the Efficacy and Safety of a Natural Mineral Water Rich in Hydrogen Carbonate on Functional Dyspepsia and Heartburn

Background: Dyspepsia and heartburn are among the most frequent complaints of the upper gastrointestinal tract impacting quality of life. The present study aimed to investigate the impact of drinking a natural mineral water (medicinal product category “Heilwasser” in Germany) high in hydrogen carbonate (Staatl. Fachingen STILL) on functional dyspeptic complaints and heartburn. Methods: 56 men and women with self-reported heartburn were enrolled to this one-arm pilot study. They had to drink 1.5 L of a hydrogen carbonate rich mineral water each day over a course of six weeks. Participants reported the number and duration of heartburn episodes in a daily dairy. The Reflux Disease Questionnaire (RDQ), Quality of Life in Reflux and Dyspepsia questionnaire (QOLRAD) and the Gastrointestinal Quality of Life Index (GILQI) were used to assess the therapeutic course of the treatment and the Short Form Health Survey (SF-12) to assess general quality of life. Mean ± standard deviation were calculated and pre- and post-treatment changes were compared using the Wilcoxon test. Results: The consumption of a hydrogen carbonate rich mineral water decreased the number of heartburn episodes per week significantly by 4.8 ± 8.2 at the end of the study (p < 0.001). The duration of episodes was also significantly reduced by 25.7 minutes after six weeks of intervention (p < 0.001). Accordingly, the subjectively perceived severity of heartburn, regurgitation and dyspeptic complaints as well as the GERD dimension as assessed by Reflux Disease Questionnaire improved significantly. There was a significant improvement in the disease-specific quality of life as measured by the Gastrointestinal Quality of Life Index (p < 0.001) and by the Quality Of Life in Reflux and Dyspepsia (p < 0.001) questionnaires and the general health-related quality of life as assessed by SF-12 (p < 0.007). Conclusions: The present pilot study provides evidence that supplementation with natural mineral water rich in hydrogen carbonate may improve heartburn and dyspeptic symptoms, which finally resulted in an improvement of the subjectively perceived quality of life. Drinking mineral water rich in hydrogen carbonate may be an alternative remedy for the treatment of dyspeptic symptoms and heartburn. Trial Registration: Eudra CT No 2013-001256-36.

Preliminary chemical characterization of groundwater in the Rome Municipality

In summer 2015 a geochemical survey on groundwater was carried out at 31 sampling points (wells and piezometers) belonging to the new “Official monitoring groundwater network of Rome Municipality” (GMNR). The following parameters were measured: temperature, pH, electrical conductivity (i.e. salinity) and alkalinity; these data were used to compute partial pressure of CO2 (pCO2). Furthermore, samples were collected to characterise waters from a chemical point of view (major elements). To implement our data - base, chemical analyses of 6 CO2 - rich mineral waters of Rome were considered. Hydrochemical survey was mainly devoted to: i) classify waters in chemical facies; ii) investigate the main water-rock interaction processes governing the water’s chemical evolution, also affected by variable amounts of dissolved CO2 and iii) define the pCO2 level in groundwater in the frame of the knowledge so far acquired in the Tyrrhenian sector of central Italy.. Groundwater shows a dominant Ca-HCO3 chemistry; some samples belong to Na-HCO3, Na-Cl and CaCl2 hydrochemical facies. In the dominant facies waters show a large variability in the abundance of chemical elements, in their salinity (ranging between 0.46 e 3.83 g/l) and pH (in the interval 5.87-7.22); these features are mainly due to different water-rock interaction processes together with the presence of variable CO2 contents. Na-HCO3 waters show the lowest salinity values (TDS up to 0.32 g/l) and strongly alkaline pH; cation exchange processes with clays, causing Na enrichment and Ca and Mg removal from solution, can be invoked to justify the observed chemistry. Waters of the Castel Fusano Natural Reserve (CFNR) belong to the Na-Cl and Ca-Cl2 facies; the different chemistry reflects the geochemical processes going on in the considered coastal aquifers such as: i) mixing between freshwater and saline waters of marine origin (fossil waters, seawater intrusion) and ii) cationic exchanges with clays that make up the less permeable sediments of the area. Two samples of the CFNR group have Ca-HCO3 chemistry and represent aquifers not affected by salinization processes. Calculated pCO2 distribution is highly variable, from low (0.03 bar) to high values (0.72 bar), implying different CO2 input (and origin) in the studied aquifers. Highest levels of carbon dioxide are linked to the degassing processes going on in the Tyrrhenian sector of Central Italy.

Hypolipidemic activity of a natural mineral water rich in calcium, magnesium, and bicarbonate in hyperlipidemic adults.

This study compared the effects of a mineral water rich in calcium, magnesium, bicarbonate, and sulfate and a marketed mineral water with a composition similar to that of urban water on the lipid profile of dyslipidemic adults. In a randomized controlled trial, 32 adults received one liter of "rich mineral water" daily for one month, and 37 adults drank the same amount of normal mineral water for the same period. Changes in lipid profiles were compared separately in each studied group at the end of one month. RESULTS showed that mean cholesterol and low density lipoprotein LDL levels were significantly decreased in both studied groups after one month of drinking mineral water (P<0.05); however, no significant differences in high density lipoprotein (HDL) and triglyceride (TG) levels were seen in either group one month after drinking. There were no statistically significant differences between the "rich mineral water" and the normal mineral water groups in any of the above-mentioned lipid levels ( P>0.05). A one-month intake of mineral water rich in calcium, magnesium bicarbonate, and sulfate decreased cholesterol and LDL levels but not TG or HDL levels in dyslipidemic adults.

Radiocarbon application in dating “complex” hot and cold CO2-rich mineral water systems: A review of case studies ascribed to the northern Portugal

Abstract The use of radioactive isotopes plays a very important role in dating groundwater, providing an apparent age of the systems in the framework of the aquifers conceptual modelling making available important features about the water fluxes, such as recharge, horizontal flow rates and discharge. In this paper, special emphasis has been put on isotopic constraints in the use of δ 13 C and 14 C content as a dating tool in some hot (76 °C) and cold (17 °C) CO 2 -rich mineral waters discharging in the Vilarelho da Raia–Pedras Salgadas region (N-Portugal). The radiocarbon content determined in these CO 2 -rich mineral waters ( 14 C activity from 4.3 up to 9.9 pmc) is incompatible with the systematic presence of 3 H (from 1.7 to 7.9 TU). The δ 13 C values of the studied CO 2 -rich mineral waters indicate that the total C in the recharge waters is being masked by larger quantities of CO 2 ( 14 C-free) introduced from deep-seated (upper mantle) sources. This paper demonstrates that a good knowledge of mineral water systems is essential to allow hydrologists to make sound conclusions on the use of C isotopic data in each particular situation.

Dissolved inorganic carbon effect in the determination of arsenic and chromium in mineral waters by inductively coupled plasma-mass spectrometry

The analysis of some Italian mineral waters by ICP-MS has revealed errors in the determination of As and Cr in natural effervescent or carbonated waters due to the presence of dissolved inorganic carbon (DIC). This leads to overestimate As and Cr in 1% (v/v) HNO 3 acidified samples, analysed within 1–2 h after the acidification. The overestimation of As concentration is caused by matrix interferences producing a signal enhancement due to the presence of dissolved inorganic carbon. This effect is analogous to that observed in the presence of organic carbon and occurs at millimolar DIC levels. The overestimation of Cr concentration is due to the 40Ar 12C + species interfering with 52Cr + despite the use of the octopole reaction system. The optimization of the He flow in the collision cell can solve the latter problem, but the required increase in the flow rate decreases the sensitivity of the ICP-MS technique. The observed effects in CO 2 rich mineral waters and artificial NaHCO 3 solutions suggest that 5–10 mM DIC levels may affect the determination of As and Cr concentration in thermal waters, rivers, lakes and groundwaters.

The silicon link between aluminium and Alzheimer's disease

Christopher Exley and colleagues report in this issue of JAD [15] the results of a clinical study showing that drinking silicic acid (Si(OH)4)-rich mineral water for five days significantly reduces the urinary excretion of aluminium, but not iron in Alzheimer disease (AD) patients. The authors argue that the long-term dietary supplementation of Si(OH)4 might qualify as a non-invasive therapy for reducing the body burden of aluminium in AD. This study opens a new chapter of the investigations of J. Derek Birchall’s hypothesis of a silicon link between aluminium and AD, for it offers a direct demonstration of the efficacy of dietary silica supplementation in increasing the excretion of aluminium in AD. But what can we expect in terms of therapeutic effects from stimulating the aluminium urinary excretion in AD? We will briefly discuss here the context and implications of this study. The systematic interest for the utilization of silicon in medicine can be traced back to the late nineteenth century, when the emulation of physiologists for research on this element led Luis Pasteur to predict that silicon reserved important therapeutic applications in many human diseases. However, the recognition of silicon as an essential trace element came only in 1972 when two reports showed that dietary silicon deprivation in chicks and rats was associated with retarded growth and bone deformities [6,28]. Subsequent research has established that silicon is indeed important for the calcification of bone and cartilage, and it may be thus involved in disorders characterized by an imbalance between bone formation and resorption (e.g., osteoporosis), joint disorders (e.g., osteoarthritis), and even heart disease and aging (for review see [27]). In contrast to the rather straightforward demonstrations of the roles of silicon in bone and connective tissue homeostasis, the link between silicon and neuropathology and particularly AD was put forward via the aluminium hypothesis in AD. Taking account of the high chemical affinity of silicon for aluminium, and the typical inverse relation between the concentrations of aluminium and silicon in water supplies, the British chemist J.D. Birchall suggested that silicon might mediate the effect of aluminium from drinking water on AD incidence [2,3]. This suggestion was partly based on an earlier finding reported by Birchall, Exley and coworkers that Si(OH)4 in water protected salmon against fatal ionoregulatory, osmoregulatory and respiratory dysfunctions caused by toxic aluminium binding to the gill epithelium [4,14]. Following Birchall’s suggestion, several epidemiological studies reviewed in [19] (see also [20]) indicated that the protective effect of silicon from drinking water against AD was only modest. Nonetheless, in spite of this apparent rebuttal of Birchall’s hypothesis, the silicon link between aluminium and AD continued to be supported on other lines of research. For instance, silicon, more specifically as silica oligomers [21], reduced by several folds the gastrointestinal absorption of aluminium in humans [11] and increased its urinary excretion [1], as originally suggested [2]; high serum silicon was shown

Conditions of formation mineral waters in Sarissky Stiavnik and Radoma

Mineral waters in Sarissky Stiavnik and Radoma are formed on the tectonic fault zones of the Zlin formation and Makovica sandstones. Precipitation waters flow downwards thus becoming enriched in TDS content. The process is enhanced by inflow of CO2 rich mineral waters of the Obidowa-Slopnice-Zboj unit, pushed by carbon dioxide and methane. Mineral waters in Sarissky Stiavnik and Radoma are of the Na-HCO3 chemical type, typical for the mineral water springs of the Magura unit in this part of the flysch belt. The origin of chloride component in the TDS content can be found in the waters with thalasogenic mineralization beneath the Magura unit, where the Obidowa-Slopnice-Zboj unit is to be found. Hydrogeological structures in Sarissky Stiavnik and Radoma can be classified as combined hydrogeological structures, where the upper partial hydrogeological structure is opened (Magura unit) and the lower structure is semi-closed (unit Obidowa-Slopnice-Zboj).

A geochemical and geophysical approach to derive a conceptual circulation model of CO 2 -rich mineral waters: A case study of Vilarelho da Raia, northern Portugal

The Vilarelho da Raia-Chaves region, located in northern Portugal adjacent to the Spanish border, is characterized by both hot and cold CO2-rich mineral waters issuing from springs and drilled wells. The present paper updates the conceptual circulation model of the Vilarelho da Raia cold CO2-rich mineral waters. Vilarelho da Raia mineral waters, dominated by Na and HCO3 ions, have formed mainly by interaction with CO2 of deep-seated mantle origin. The δ18O, δ2H and 3H values indicate that these waters are the result of meteoric waters infiltrating into Larouco Mountain, NW of Vilarelho da Raia, circulating at shallow depths in granitic rocks and moving into Vilarelho da Raia area. The conceptual geochemical and geophysical circulation model indicates that the hot and cold CO2-rich mineral waters of Chaves (76 °C) and Vilarelho da Raia (17 °C) should be considered manifestations of similar but not the same geohydrological systems.