Rice Husk Research Articles

REVIEW: AN EXPERIMENTAL STUDY ON EFFECT OF NANO MATERIALS ON STRENGTH OF CONCRETE AND PLANE STRESS ANALYSIS USING ANSYS SOFTWARE

These days, making efficient and cost-effective use of resources has taken precedence. The main ingredient in concrete, cement has been under criticism in recent years for the quantity of CO2 released during production. Although cement has better mechanical properties, it hasn't been able to live up to the expectations in terms of durability. Owing to cement's shortcomings, scientists started looking into additives that would enhance concrete's qualities while also making it stronger and lighter. Fly ash, silica fume, and other micro particles were added to cementitious materials to improve their compactness, strength, and durability. These additives were also selected because they are eco-friendly by products of industrial waste that may be handled ethically. Fly ash has significant disadvantages because it is not good for initial strength increase and setting time. Because silica fume affects cementitious material performance, researchers have recently become interested in combining it with ceramic waste and rice husk ash. A more effective way to utilize rice husk ash, a by-product of rice cultivation, would be to replace 10% to 15% of cement. Studies have shown improvements in the durability performance of recycled ceramic waste concrete and rice husk ash concrete. There are issues since the RHA production process is quite time-consuming. With the discovery of nano-particles (NP) smaller than 100 nm, researchers have advanced the field of nanotechnology to new levels. The mechanical properties of many materials, including polymers and cementitious materials, can be enhanced by NP. NP is also helpful in the fields of food, engineering, and medicine. This led researchers to investigate the effects of nano-silica (NS) on concrete in further detail. Nano materials can improve the compressive strength and ductility of concrete. In this project an effort will be made to increase the compressive strength of concrete using Nano materials and waste product like GGBS. Also plane stress analysis of concrete cubes and cylinders is to be done using Ansys Software to find deformation, principal stresses and shear stresses. Keywords: Nano –Silica, Nano Titanium dioxide, Ansys, GGBS, Compressive strength

Effect of surface treatment hybridization of kenaf nanocellulose on the thermal stability and mechanical properties of rice husk nanohybrid dental composite

Effect of surface treatment hybridization of kenaf nanocellulose on the thermal stability and mechanical properties of rice husk nanohybrid dental composite

Optimising Factors for the Production of Amorphous Rice Husk Ash via Combustion Process for Sustainable Construction: A Review

Optimising Factors for the Production of Amorphous Rice Husk Ash via Combustion Process for Sustainable Construction: A Review

Preparation and Performance Analysis of New Multi stage Porous Carbon Materials for Air Pollution Treatmentials on Atmospheric Pollution Sources under the Background of Carbon Peak and Carbon Neutrality

The adsorption of toxic and harmful gases through porous materials is an effective means of air pollution control. A multi-level porous carbon material with ultra-high-specific surface area was made based on rice husk biomass to improve the air pollution controlling efficiency and reduce its cost. The rice husk substrate was pretreated using T.viride spore suspension during the preparation of this material. This changes the proportion of various components in the matrix, thereby achieving an increase in the multi-level porous carbon material’s specific surface area. Its performance was analyzed through various means in the study. The results confirmed that when the activation treatment time was 60 minutes, the porous carbon material’s specific surface area was the highest, reaching 3714 m2/g. After 30 days of treatment with T.viride spore suspension, the cellulose content in rice husks decreased by about 40 g/kg. Compared to untreated porous carbon materials, after 20 days of treatment, the micropores and mesopores of these materials significantly increased. The research has successfully increased the multi-level porous carbon material’s specific surface area and achieved rapid absorption of atmospheric volatile organic compounds. The multi-level porous carbon material can enhance the air pollution controlling efficiency and reduce its cost.

Microblasting with vegetable and cellulosic media for heritage wood cleaning: effects on surface morphology

In this research, microblasting with powdered vegetable particles (almond and hazelnut husks, cork saw dust and rice husks) and cellulosic fibres was used to analyse their usefulness for cleaning unpainted wooden cultural heritage and their effects on surface morphology. Tests were made on mock-ups of old pine wood from wooden boards with original soiling. Before cleaning powdered particles were characterised by SEM–EDS to analyse their morphology and elemental composition. Wood surfaces were analysed before and after cleaning by means of digital microscope (white and UV light) and SEM–EDS to evaluate cleaning effectiveness, assess effects on the wood surface, and determine eventual soiling and powdered particles larger than 1 µm that might remain in the surface after the procedure. Results indicate that microblasting with powdered vegetable and cellulosic media is a useful and safe technique to remove soiling from wood, including micrometric particles embedded in its texture, with negligible surface changes. Furthermore, residues left after the cleaning procedure are very scarce and chemically compatible with the substrate because they are mainly composed of cellulose, hemicellulose and lignin, the main components of wood.

Microblasting with vegetable and cellulosic media for heritage wood cleaning: effects on surface morphology

In this research, microblasting with powdered vegetable particles (almond and hazelnut husks, cork saw dust and rice husks) and cellulosic fibres was used to analyse their usefulness for cleaning unpainted wooden cultural heritage and their effects on surface morphology. Tests were made on mock-ups of old pine wood from wooden boards with original soiling. Before cleaning powdered particles were characterised by SEM–EDS to analyse their morphology and elemental composition. Wood surfaces were analysed before and after cleaning by means of digital microscope (white and UV light) and SEM–EDS to evaluate cleaning effectiveness, assess effects on the wood surface, and determine eventual soiling and powdered particles larger than 1 µm that might remain in the surface after the procedure. Results indicate that microblasting with powdered vegetable and cellulosic media is a useful and safe technique to remove soiling from wood, including micrometric particles embedded in its texture, with negligible surface changes. Furthermore, residues left after the cleaning procedure are very scarce and chemically compatible with the substrate because they are mainly composed of cellulose, hemicellulose and lignin, the main components of wood.

Investigating the synergistic potential of Si and biochar to immobilize Ni in a Ni-contaminated calcareous soil after Zea mays L. cultivation

Abstract. In Iran, a significant percentage of agricultural soils are contaminated with a range of potentially toxic elements (PTEs), including Ni, which need to be remediated to prevent their entry into the food chain. Silicon (Si) is a beneficial plant element that has been shown to mitigate the effects of PTEs on crops. Biochar is a soil amendment that sequesters soil carbon and that can immobilize PTEs and enhance crop growth in soils. No previous studies have examined the potentially synergistic effect of Si and biochar on the Ni concentration in soil chemical fractions and the immobilization thereof. Therefore, the aim of this study was to examine the interactive effects of Si and biochar with respect to reducing Ni bioavailability and its corresponding uptake in corn (Zea Mays) in a calcareous soil. A 90 d factorial greenhouse study with corn was conducted. Si application levels were 0 (S0), 250 (S1), and 500 (S2) mg Si kg−1 soil, and biochar treatments (3wt %) including rice husk (RH) and sheep manure (SM) biochars produced at 300 and 500 °C (SM300, SM500, RH300, and RH500) were utilized. At harvest, the Ni concentration in corn shoots, the Ni content in soil chemical fractions, and the release kinetics of DPTA (diethylenetriaminepentaacetic acid)-extractable Ni were determined. Simultaneous utilization of Si and SM biochars led to a synergistic reduction (15 %–36 %) in the Ni content in the soluble and exchangeable fractions compared with the application of Si (5 %–9 %) and SM (5 %–7 %) biochars separately. The application of Si and biochars also decreased the DPTA-extractable Ni and Ni content in corn shoots (by up to 57 %), with the combined application of SM500 + S2 being the most effective. These effects were attributed to the transfer of Ni in soil from more bioavailable fractions to more stable iron-oxide-bound fractions, related to soil pH increase. SM500 was likely the most effective biochar due to its higher alkalinity and lower acidic functional group content which enhanced Ni sorption reactions with Si. The study demonstrates the synergistic potential of Si and SM biochar for immobilizing Ni in contaminated calcareous soils.

Investigating the synergistic potential of Si and biochar to immobilize Ni in a Ni-contaminated calcareous soil after Zea mays L. cultivation

Abstract. In Iran, a significant percentage of agricultural soils are contaminated with a range of potentially toxic elements (PTEs), including Ni, which need to be remediated to prevent their entry into the food chain. Silicon (Si) is a beneficial plant element that has been shown to mitigate the effects of PTEs on crops. Biochar is a soil amendment that sequesters soil carbon and that can immobilize PTEs and enhance crop growth in soils. No previous studies have examined the potentially synergistic effect of Si and biochar on the Ni concentration in soil chemical fractions and the immobilization thereof. Therefore, the aim of this study was to examine the interactive effects of Si and biochar with respect to reducing Ni bioavailability and its corresponding uptake in corn (Zea Mays) in a calcareous soil. A 90 d factorial greenhouse study with corn was conducted. Si application levels were 0 (S0), 250 (S1), and 500 (S2) mg Si kg−1 soil, and biochar treatments (3wt %) including rice husk (RH) and sheep manure (SM) biochars produced at 300 and 500 °C (SM300, SM500, RH300, and RH500) were utilized. At harvest, the Ni concentration in corn shoots, the Ni content in soil chemical fractions, and the release kinetics of DPTA (diethylenetriaminepentaacetic acid)-extractable Ni were determined. Simultaneous utilization of Si and SM biochars led to a synergistic reduction (15 %–36 %) in the Ni content in the soluble and exchangeable fractions compared with the application of Si (5 %–9 %) and SM (5 %–7 %) biochars separately. The application of Si and biochars also decreased the DPTA-extractable Ni and Ni content in corn shoots (by up to 57 %), with the combined application of SM500 + S2 being the most effective. These effects were attributed to the transfer of Ni in soil from more bioavailable fractions to more stable iron-oxide-bound fractions, related to soil pH increase. SM500 was likely the most effective biochar due to its higher alkalinity and lower acidic functional group content which enhanced Ni sorption reactions with Si. The study demonstrates the synergistic potential of Si and SM biochar for immobilizing Ni in contaminated calcareous soils.

Silicon Carbide-based Materials from Rice Husk

Background: Rice husk is an important agricultural waste that contains organic mass and bio-silica. Although some rice husks have been used as fuel, animal food, filler for wine fermentation, and fertilizer, the majority are discarded as agricultural waste, which does great harm to the environment. The conversion of rice husk to silicon carbide (SiC)-based materials satisfies the demand for the reutilization of solid wastes. Methods: The article reviews recent progress and patents on the SiC-based materials from rice husk. The possible development directions of the SiC-based materials from rice husks are also analyzed. Results: SiC materials with different morphologies, including microscale and nanoscale particles, nanoscale whiskers, and nanowires, can be prepared by high-temperature carbothermal reduction reaction from rice husk at the temperature of 1200-1800 °C, reaction time of 0.5-8 h, respectively. SiC-based composites, including SiC nanowires/C, Al/SiC, SiC/Si3N4, and SiC/Al2O3, can be obtained using rice husk as main source materials at 800-1800 °C. SiC-based materials exhibit great application potential in the fields of absorbents, optical devices, mechanical products, photocatalysts, semiconductors, and Li-ion batteries. Conclusion: The low cost of preparing SiC-based materials from rice husk, combining them with different compositions, and exploring new applications are important research directions in the future.

Compositional Analysis of the Lignocellulosic Biomass from Agricultural Waste (Rice Husk)

Rice husk, a byproduct of rice milling, represents a significant agricultural waste biomass with untapped potential for various industrial applications. This study provides a comprehensive compositional analysis of rice husk to explore its utility as a valuable resource. The chemical composition of rice husk such as initial moisture content, hemicellulose, cellulose, lignin, ash and extractives were analyzed. The result reported in mean value i.e 9.884 ±0.56 (%) moisture content, 8.077±0.27 (%) extractives, 17.210 ± 0.69 (%) lignin, 21.073 ± 0.62 (%) hemicellulose and 38.640 ± 0.94 (%) cellulose, 15.0 ±0.87 (%) ash. This study concludes that rice husk is an abundant source of cellulose and holds significant potential for cellulose isolation.

Conversion of rice husks into carbonaceous materials with porous structures via hydrothermal process.

Carbonaceous materials hydrothermally produced using waste biomass have small specific surface areas (SSA) and poor porosity properties. In this study, we prepare a novel carbonaceous material with excellent porosity properties by suppressing the formation of a secondary char phase (spheres) and promoting biomass hydrolysis by controlling the hydrothermal conditions. Rice husk powders, as the starting material, are hydrothermally treated using acidic solvents of different types and concentrations at 180 °C. The surfaces of the samples hydrothermally prepared using the acidic solvents have no spheres. In the case of 0.1-0.2 mol L-1 hydrochloric acid (HA), the amorphous carbonaceous materials contain numerous mesopores and exhibit a larger SSA (approximately 100 m2 g-1) than those prepared using acetic acid and distilled water. An increase in the hydrothermal temperature reduces the porosity properties of the materials. Finally, the high-porosity amorphous carbonaceous material showed excellent trimethylamine adsorption ability.

Silicon Carbide-based Materials from Rice Husk

Silicon Carbide-based Materials from Rice Husk

Conversion of rice husks into carbonaceous materials with porous structures via hydrothermal process.

Carbonaceous materials hydrothermally produced using waste biomass have small specific surface areas (SSA) and poor porosity properties. In this study, we prepare a novel carbonaceous material with excellent porosity properties by suppressing the formation of a secondary char phase (spheres) and promoting biomass hydrolysis by controlling the hydrothermal conditions. Rice husk powders, as the starting material, are hydrothermally treated using acidic solvents of different types and concentrations at 180 °C. The surfaces of the samples hydrothermally prepared using the acidic solvents have no spheres. In the case of 0.1-0.2 mol L-1 hydrochloric acid (HA), the amorphous carbonaceous materials contain numerous mesopores and exhibit a larger SSA (approximately 100 m2 g-1) than those prepared using acetic acid and distilled water. An increase in the hydrothermal temperature reduces the porosity properties of the materials. Finally, the high-porosity amorphous carbonaceous material showed excellent trimethylamine adsorption ability.

Electrochemical treatment of textile wastewater using electrodes from pyrolyzed rice husk

Rice husk char (RHC) electrodes were used for the first time in electrochemical treatment of textile wastewater. SEM analysis revealed RHC's porous structure, while TGA showed it decomposes in four stages and is stable up to 189 °C. BET analysis indicated a high surface area of 734 m2/g and a microporous structure with 11.7 Å pore diameter and 0.213 mL/g pore volume. RHC electrodes pyrolyzed at 700 °C for 2 h and placed 15 cm apart worked best in a 2 L batch reactor with methylene blue (MB) as the model pollutant and 6 g/L NaCl as the electrolyte. The process followed first-order kinetics, with fastest reaction at 100 mg/L initial MB. Reduced TOC and changed FTIR spectra confirmed MB breakdown. The batch system removed 85.8 % of dye from real textile wastewater in 150 min. In continuous flow, lower rates achieved higher efficiencies, up to 90 % at 0.45 L/h after 210 min. Although RHC electrodes had lower conductivity and strength than metal, they represent a sustainable, cost-effective alternative for electrochemical wastewater treatment.

Enhancing agricultural output: Investigating the impact of advanced organic formulations on crop productivity, nutrient use efficiency, and profitability in a multi-crop system

The significance of integrating agricultural by-products such as paddy husk ash (PHA) and potato peels with organic fertilizers lies in enhancing soil fertility, increasing crop yields, and reducing reliance on traditional organic fertilizers like farmyard manure (FYM) or compost alone. Grounded in sustainable agriculture and nutrient management frameworks, this study examines the impact of diverse formulations derived from agricultural waste on productivity, nutrient efficiency, and profitability in a pigeon pea–vegetable mustard–okra cropping system. A two-year field experiment (2020-2022) at ICAR-IARI, New Delhi tested seven nutrient sources viz., (T1) control, (T2) 100% RDN through FYM, (T3) 100% RDN through improved RRC, (T4) 100% RDN through PHA based formulation, (T5) 75% RDN through PHA based formulation, (T6) 100% RDN through PPC based formulation and (T7) 75% RDN through PPC based formulation that were tested in RBD and replicated thrice. Treatment T4 had significant effect on seed yield of pigeon pea (1.89±0.09 and 1.97±0.12 t ha-1), leaf yield of vegetable mustard (81.57±4.59 and 82.97±4.17 t ha-1), and fruit yield of okra (13.54±0.82 and 13.78±0.81 t ha-1) grown in rotation, followed by treatment T6 and T2 during both the years respectively over control. Enhanced system uptake of N, P and K along with system gross and net returns in T4, showed increases of 78.9%, 83.8%, 72.4%, 54.4% and 56.8% in the first year and 77.5%, 80.8%, 77.7%, 54.8% and 57.4% in the second year, respectively, over control. Treatment T4 significantly improved apparent recovery by 66.3% and 69.2% in pigeon pea, 64.7% and 47.9% in vegetable mustard, and 72.7% and 79.4% in okra over T3, averaged across two years. Based on the above findings, (T4) 100% RDN through PHA-based formulation, and (T6) 100% RDN through PPC-based formulation can be recommended for areas with a shortage of FYM but availability of rice husk ash/ potato peels for sustainable agricultural wastes and improved sustainability.

Cryptococcus laurentii: a wild yeast for xylanase production from agricultural by-products.

The development of technologies that allow the production of enzymes at a competitive cost is of great importance for several biotechnological applications, and the use of agro-industrial by-products is an excellent alternative to minimize costs and reduce environmental impacts. This study aimed to produce endo-xylanases using agro-industrial substrates rich in hemicellulose as sources of xylan in culture media. For this purpose, the yeast Cryptococcus laurentti and five lignocellulosic materials (defatted rice bran, rice husk, corn cob, oat husks, and soybean tegument), with and without pretreatment, were used as a source of xylan for enzyme production. To insert the by-products in the culture medium, they were dried and treated (if applicable) with 4% (w.v-1) NaOH and then added in a concentration of 2% (w.v-1). The cultures were agitated for 96h, and the aliquots were removed to determine the enzymatic activities. Among the by-products studied, the maximum activity (8.7 U. mL-1 at pH 7.3) was obtained where rice bran was used. In contrast, corn cob was the by-product that resulted in lower enzyme production (1.6 U.mL-1). Thus, the defatted rice bran deserves special attention in front of the other by-products used since it provides the necessary substrate for producing endo-xylanases by yeast.

Accelerated Charge Transfer through Interface Chemical Bonds in MoS2/TiO2 for Photocatalytic Conversion of Lignocellulosic Biomass to H2.

Solar photocatalytic H2 production from lignocellulosic biomass has attracted great interest, but it suffers from low photocatalytic efficiency owing to the absence of highly efficient photocatalysts. Herein, we designed and constructed ultrathin MoS2-modified porous TiO2 microspheres (MT) with abundant interface Ti-S bonds as photocatalysts for photocatalytic H2 generation from lignocellulosic biomass. Owing to the accelerated charge transfer related to Ti-S bonds, as well as the abundant active sites for both H2 and ●OH generation, respectively, related to the high exposed edge of MoS2 and the large specific surface area of TiO2, MT photocatalysts demonstrate good performance in the photocatalytic conversion of α-cellulose and lignocellulosic biomass to H2. The highest H2 generation rate of 849 μmol·g-1·h-1 and apparent quantum yield of 4.45% at 380 nm was achieved in α-cellulose aqueous solution for the optimized MT photocatalyst. More importantly, lignocellulosic biomass of corncob, rice hull, bamboo, polar wood chip, and wheat straw were successfully converted to H2 over MT photocatalysts with H2 generation rate of 10, 19, 36, 29, and 8 μmol·g-1·h-1, respectively. This work provides a guiding design approach to develop highly active photocatalysts via interface engineering for solar H2 production from lignocellulosic biomass.

Study of the effect of phytoextract based on rice husk and germ film, green tea on the functional properties of cells involved in bone tissue metabolism

Study of the effect of phytoextract based on rice husk and germ film, green tea on the functional properties of cells involved in bone tissue metabolism

Investigation of performance of potential adsorbents for emissions mitigation in a diesel generator.

Globally, the release of greenhouse gases primarily carbon dioxide (CO2) emissions to our Earth's surface has climbed by about 45% to its present atmospheric concentration rate of 420 parts per million (ppm) during the industrial era. An unprecedented rise in atmospheric CO2 concentration has been claimed to lead to significant factors such as global warming potential (GWP) and climate change effects. An increase in atmospheric CO2 concentrations is a serious threat to the environment. Recent research efforts have focused on mitigating emissionsfrom anthropogenic point sources. Adsorption-based post-combustion CO2 capture using solid adsorbents is the most effective and efficient method for mitigating gas adsorption in the exhaust system. In the current study, activated carbons are obtained from three potential biomass, namely, (i) coconut shell, (ii) rice husk, and (iii) eucalyptus wood, through a - single-stageactivation method. The prepared activated carbon materials are analyzed using proximate and ultimate analyses. Further investigations are performed using different characterization techniques to ensure their adsorption efficiency. Adsorbents are packed one after the other in an in-house fabricated double adsorption chamber and coupled to the exhaust unit of a generator. Test experiments are conducted to examine adsorbents' capture efficiency in emissions mitigation. Adsorbents' adsorption parameters are evaluated in experimental investigations. At 2.5bar and 50°C, a maximum loading capacity of samples is achieved by 4.85mmol/g, 4.58mmol/g, and 5.96mmol/g for coconut shell, rice husk, and eucalyptus wood adsorbents, respectively. With a post-combustion carbon adsorption chamber, CO2 and NO are captured about40-64% and 38-58%, respectively, for all three adsorbents. The thermodynamic parameter of isosteric heat of adsorption value is below 40kJ/mol, ensuring physisorption for all adsorbents.

Comparison of physical and mechanical properties of traditional bricks in Deli Serdang with no-burn bricks using rice husk ash

Population growth has increased, causing more and more housing needs; Indonesia is one of the countries where bricks are still used as the primary material in building walls. It has resulted in increased demand for bricks. One of Indonesia’s regions, Deli Serdang Regency, produces traditional bricks that burn a lot, but the process of making traditional bricks can cause environmental pollution. This research aims to find a way to reduce the effects of environmental pollution by making pressed bricks without burning and utilizing agricultural waste, namely rice husk ash (RHA). After that, a comparison was made between traditional burnt bricks from 15 sub-districts in Deli Serdang Regency and unburnt bricks made from rice husk ash (RHA). This study uses two methods, namely the method of sampling burned bricks and the method of making bricks without burning, both of which are tested for physical and mechanical properties. The results of this study use the requirements of SNI 15-2094-2000, where the test of physical properties of fuel bricks obtained a value of 76%, which meets the requirements, while bricks without burning obtained a value of 87.5%, which meets the requirements. For the results of the size of fuel bricks obtained, 66.6% of the value meets the requirements, while for bricks without burning, 100% meet the requirements. Mechanical properties test for absorption testing on fuel bricks obtained 0.135% while unburned bricks 0.130%, where the value meets the SNI requirements of a maximum absorption of 20%. Salt content testing obtained a value of 0.15% for burned bricks and 0.002% for unburned bricks, where the value meets the SNI requirements that are below 50%. Testing the compressive strength of bricks with a standard value of 5 MPa from the test results of the compressive strength of fuel bricks 3.01 MPa decreased by 39.8%, while the test of compressive strength of unburned bricks 5.17 MPa increased by 3.45%, but unburned bricks with added rice husk ash 1.98 MPa decreased by 60.4%. Based on the study’s results, the absorption and salt content parameters follow the standard. At the same time, the strength test of firebricks and unburned bricks with added rice husk ash does not meet the SNI 15-2094-2000 standard, but the results of the compressive strength test of unburned bricks meet the SNI 15-2094-2000 standard.