Rheological Insights Research Articles

Development of an Operational Map for the 3D Printing of Phytosterol-Enriched Oleogels: Rheological Insights and Applications in Nutraceutical Design

Three-dimensional (3D) printing attracts significant interest in the food industry for its ability to create complex structures and customize nutritional content. Printing materials, or inks, are specially formulated for food or nutraceuticals. These inks must exhibit proper rheological properties to flow smoothly during printing and form stable final structures. This study evaluates the relationship between rheological properties and printability in phytosterol-enriched monoglyceride (MG) oleogel-based inks, intended for nutraceutical applications. Key rheological factors, including gelation temperature (Tg), elastic (G′) and viscous (G″) modulus, and viscosity (µ) behavior with shear rate (γ˙), were analyzed for their impact on flow behavior and post-extrusion stability. Furthermore, this study allowed the development of an operation map to predict successful printing based on material µ and Tg. Oleogels (OGs) were prepared with high-oleic sunflower oil (HOSO) and 10 wt% MG, enriched with phytosterols (PSs) at concentrations between 0 and 40 wt%. While higher PS content generally led to an increase in both Tg and µ, the 10 wt% PS mixture exhibited a different behavior, showing lower Tg and µ compared to the 0 wt% and 5 wt% PS mixtures. The optimal PS concentration was identified as 20 wt%, which exhibited optimal properties for 3D printing, with a Tg of 78.37 °C and µ values ranging from 0.013 to 0.032 Pa.s that yielded excellent flowability and adequate G′ (3.07 × 106 Pa) at room temperature for self-supporting capability. These characteristics, visualized on the operational map, suggest that 20% PS OGs meet ideal criteria for successful extrusion and layered deposition in 3D printing.

Acrylamide/Alyssum campestre seed gum hydrogels enhanced with titanium carbide: Rheological insights for cardiac tissue engineering.

This study investigates the use of acrylamide and Alyssum campestre seed gum (ACSG) to create hydrogel composites with enhanced electrical and mechanical properties by incorporating titanium carbide (TiC). The composites were analyzed through techniques such as FTIR, SEM, TEM, TGA, swelling, rheology, tensile, electrical conductivity, antibacterial, and MTT assays. XRD analysis showed that 0.5 % TiC NPs were exfoliated in the hydrogel, while 1 % was intercalated. SEM images showed that ACSG created a semi-interpenetrating polymer network with interconnected cavities averaging 9.1 μm, which reduced to 3.6 μm with 0.5%TiC and 51.8 nm with 1%TiC due to increased crosslinking density. TGA results confirmed hydrogel stability at autoclave temperatures. Rheological testing revealed that the hydrogel exhibited a maximum resistance of 317 kPa. The addition of 1 % TiC enhanced its electrical conductivity to 1.5 × 10-2S/cm, making it suitable for applications in cardiac tissue engineering. MTT assays confirmed the hydrogel's biocompatibility and demonstrated its superior antibacterial activity against Staphylococcus aureus compared to Escherichia coli. The AM/ACSG/TiC hydrogel is a promising material for cardiac tissue engineering because of its adjustable mechanical properties, excellent electrical conductivity, and strong compatibility with cell cultures. The addition of ACSG improves the hydrogel's rheological behavior, which is crucial for promoting effective cell growth.

Thermophysical, and rheological insights of polyethylene/wax blends

Thermophysical, and rheological insights of polyethylene/wax blends

Advanced Refinement of Geopolymer Composites for Enhanced 3D Printing via In-Depth Rheological Insights

Advanced Refinement of Geopolymer Composites for Enhanced 3D Printing via In-Depth Rheological Insights

Rheological Insights and Optimization of Bio Nano Lubricants in Tribological Systems

Rheological Insights and Optimization of Bio Nano Lubricants in Tribological Systems

Self-healing injectable hydrogels incorporating hyaluronic acid and phytic acid: Rheological insights and implications for regenerative medicine

Eying the increasing impact of hyaluronic acid (HA) and its multifaceted applications, this study employs a non-toxic, one-pot strategy to develop injectable, self-healing hydrogels for biomedical applications. Phytic acid (PA), a plant-derived organic acid with high biocompatibility and numerous hydroxyl groups, can act as a cross-linking agent to form hydrogen-bonded networks with the HA chains. The study examined the optimal mass ratio of HA to PA to achieve superior hydrogel performance. Fourier transform infrared spectroscopy, rheological studies, and thermal analysis confirmed the successful formation of the hydrogels, which exhibited injectability, rapid self-healing, malleability, and elasticity. The investigation of different compositions revealed a sensitive influence of PA on the self-assembly phenomena of HA during flow. SEM cross-section images of the freeze-dried gels revealed a porous surface in the form of an interconnected network of microchannels. In addition, the hydrogel exhibits good tissue adhesion properties and promotes cell proliferation in biocompatibility tests on human gingival fibroblasts. The significance of this study lies in the ability of the proposed materials to be injected, to conform to the complex 3D structure of host tissues as well as their ability to recover after damage, indicating significant potential as scaffolds for wound healing.

Heat-induced lupin-whey protein emulsion-filled gels: Microstructural and rheological insights

This work investigates the rheological properties of lupin-whey emulsion-filled gels (EFGs) formed using a pilot scale plate heat exchanger. Samples were prepared with either lupin, whey, or a lupin-whey stabilized emulsion, mixed in a whey protein continuous phase. While whey protein in the continuous phase was mainly responsible for the formation of a primary gel network, differences were observed depending on the droplet-whey protein matrix interactions. Full or partial replacement of interfacial proteins with lupin proteins resulted in softer, more ductile gels. Amplitude sweeps showed that the structure was not only affected by the interactions between the droplets and the continuous network, but also by the droplet distribution within the matrix. This work demonstrates the importance of fine tuning the interactions and the distribution of oil droplets within the gel, as these properties will lead to structural heterogeneity at the micro-scale, causing profound differences in the rheological properties. Finally, continuous heating led to stiffer, more particulate gels compared to quiescent conditions, but similar mechanisms underpinned gel formation. Thus, it is demonstrated that the design of the interactions can be screened using an in situ rheometer, although the rheological properties are affected by the shear effect of the plate heat exchanger.

Nonlinear oscillatory rheology of aqueous suspensions of cellulose nanocrystals and nanofibrils

In this work, the nonlinear rheological behavior of aqueous suspensions composed of two typical nanocellulose [rod-like cellulose nanocrystals (CNCs) and filamentous cellulose nanofibrils (CNFs)] was examined and compared by using various large-amplitude oscillatory shear (LAOS) analysis methods, such as Fourier-transform rheology, stress decomposition, Chebyshev polynomials, and the sequence of physical processes. From our analysis, the nonlinear rheological parameters of higher harmonics, dissipation ratio, strain hardening ratio, shear thickening ratio, transient modulus, and cage modulus were obtained and quantitatively analyzed. CNCs tend to assemble to form anisotropic structures in an aqueous medium while the CNFs are entangled to form gels. The CNF suspensions demonstrated a significant viscous modulus overshoot and had stronger yield stresses, but the yield of CNC suspensions was more ductile. In the case of low concentrations, the CNF suspensions demonstrated stronger intracycle shear thickening behavior in medium-amplitude oscillatory shear region and lower dissipation ratios at small strain amplitudes. Although both nanocellulose suspensions revealed the existence of four intracycle rheological transition processes (viscoplastic deformation, structural recovery, early-stage yielding, and late-stage yielding), the CNF suspensions exhibited a stronger structural recovery ability. Larger strain amplitudes did not invariably result in a broader range of intracycle rheological transitions, which are also affected by the excitation frequency. The application of the various LAOS analysis methods provided valuable intracycle nonlinear rheological insights into nanocellulose suspensions, which are of great importance for enhancing their industrial perspectives.

Rheological insights into the degradation behavior of PP/HDPE blends

The (re-)processing and degradation behavior of polypropylene (PP) blends with high-density polyethylene (HDPE) is a crucial topic in mechanical recycling due to the prevalence of PP/HDPE mixtures. In particular, small amounts of cross-contamination (below 10.0 wt.%) between these polyolefins are quite common. While much empirical data is available, systematic studies on such blends are scarce and rarely account for the polymers’ chain structure. This study employs time-resolved rheology, atomic force microscopy (AFM), differential scanning calorimetry (DSC) and chemiluminescence techniques to study the degradation of different PP types containing 0.5 to 10.0 wt.% of HDPE. It is observed that the addition of small amounts of HDPE can result in a prominent change in the viscoelastic properties of PP during the thermo-oxidative degradation. The substantial evolution of elasticity in the blends is mainly related to the gelation of fine PE particles dispersed within the PP matrix. It is also shown that a smaller viscosity ratio between the blend components can lead to a more significant degradation through morphology alterations. Remarkably, time-resolved rheology studies revealed that even a small amount of HDPE (2.5 wt.%) can lead to a reduction in the thermo-oxidative stability of the PP/HDPE blend through excessive branching/crosslinking of the HDPE phase. This effect was particularly more pronounced when the PP contained an ethylene comonomer in its backbone. The finer morphology of PE particles in PP copolymer can exacerbate the thermo-oxidative stability of the blend. These insights are essential in designing new life cycles for recycled PP cross-contaminated with HDPE, typically found in the light fraction of municipal solid plastic waste.

Rheological insights into 3D printing of drug products: Drug nanocrystal-poloxamer gels for semisolid extrusion

The importance of ink rheology to the outcome of 3D printing is well recognized. However, rheological properties of printing inks containing drug nanocrystals have not been widely investigated. Therefore, the objective of this study was to establish a correlation between the composition of nanocrystal printing ink, the ink rheology, and the entire printing process. Indomethacin was used as a model poorly soluble drug to produce nanosuspensions with improved solubility properties through particle size reduction. The nanosuspensions were further developed into semisolid extrusion 3D printing inks with varying nanocrystal and poloxamer 407 concentrations. Nanocrystals were found to affect the rheological properties of the printing inks both by being less self-supporting and having higher yielding resistances. During printing, nozzle blockages occurred. Nevertheless, all inks were found to be printable. Finally, the rheological properties of the inks were successfully correlated with various printing and product properties. Overall, these experiments shed new light on the rheological properties of printing inks containing nanocrystals.

Exploring Cellulose Triacetate Nanofibers as Sustainable Structuring Agent for Castor Oil: Formulation Design and Rheological Insights.

Developing gelled environmentally friendly dispersions in oil media is a hot topic for many applications. This study aimed to investigate the production of electrospun cellulose triacetate (CTA) nanofibers and to explore their potential application as a thickening agent for castor oil. The key factors in the electrospinning process, including the intrinsic properties of CTA solutions in methylene chloride (DCM)/ethanol (EtOH), such us the shear viscosity, surface tension, and electrical conductivity, were systematically studied. The impact of the CTA fiber concentration and the ratio of DCM/EtOH on the rheological properties of the gel-like dispersions in castor oil was then investigated. It was found that dispersions with a non-Newtonian response and above a critical concentration (5 wt.%), corresponding to approximately 2-2.5 times the entanglement concentration, are required to produce defect-free nanofibers. The average fiber diameter increased with CTA concentration. Further, the morphology and texture of the electrospun nanofibers are influenced by the ratio of solvents used. The rheological properties of dispersions are strongly influenced by the concentration and surface properties of nanofibers, such as their smooth or porous textures, which allow their modulation. Compared to other commonly used thickeners, such as synthetic polymers and metal soaps, CTA electrospun nanofibers have a much higher oil structuring capacity. This work illustrated the potential of using CTA nanofibers as the foundation for fabricating gel-like dispersions in oil media, and thus exerting hierarchical control of rheological properties through the use of a nanoscale fabrication technique.

Enhancing Cement Paste Properties with Biochar: Mechanical and Rheological Insights

Biochar, the solid sub-product of biomass pyrolysis, is widely considered an effective water retention material thanks to its porous microstructure and high specific surface area. This study investigates the possibility of improving both mechanical and rheological properties of cement pastes on a micro-scale. The results show that using biochar as a reinforcement at low percentages (1% to 5% by weight of cement) results in an increase in compressive strength of 13% and the flexural strength of 30%. A high fracture energy was demonstrated by the tortuous crack path of the sample at an early age of curing. A preliminary study on the rheological properties has indicated that the yield stress value is in line with that of self-compacting concrete.

Optimizing Hyaluronic Acid: A Comprehensive Review of Rheological Insights for Clinical Practice

Optimizing Hyaluronic Acid: A Comprehensive Review of Rheological Insights for Clinical Practice

Structural and rheological insights of oxidized cellulose nanofibers in aqueous suspensions

Structural and rheological insights of oxidized cellulose nanofibers in aqueous suspensions

Enhancing drilling mud performance through CMITS-modified formulations: rheological insights and performance optimization.

In the context of deep well drilling, the addition of functionalized additives into mud systems becomes imperative due to the adverse impact of elevated borehole temperatures and salts on conventional additives, causing them to compromise their intrinsic functionalities. Numerous biomaterials have undergone modifications and have been evaluated in drilling muds. However, the addition of dually modified tapioca starch in bentonite-free mud systems remains a notable gap within the existing literature. This study aims to examine the performance of dually modified carboxymethyl irradiated tapioca starch (CMITS) under high temperature and salt-containing conditions employing central composite design approach; the study evaluates the modified starch's impact on mud rheology, thermal stability, and salt resistance. The findings indicated that higher DS (0.66) and CMITS concentrations (8 ppb) improved plastic viscosity (PV), yield point (YP) and gel strength (GS), while increased salt and temperature decreased it, demonstrating the complex interplay of these factors on mud rheology. The developed empirical models suggested that DS 0.66 starch addition enhanced rheology, especially at elevated temperatures, demonstrating improved borehole cleaning potential, supported by quadratic model performance indicators in line with American Petroleum Institute (API) ranges. The optimized samples showed a non-Newtonian behavior, and Power-law model fitting yields promising results for improved cuttings transportation with starch additives.

Rheological insights on the evolution of sonicated cellulose nanocrystal dispersions

Cellulose nanocrystals (CNCs) are promising biomaterials, but their tendency to agglomerate when dried limits their use in several applications. Ultrasonication is commonly used to disperse CNCs in water, bringing enough energy to the suspension to break agglomerates. While the optimized parameters for sonication are now well defined for small volumes of low concentration CNC suspensions, a deeper understanding of the influence of the dispersing process is needed to work with larger volumes, at higher concentrations. Herein, rheology is used to define the distribution and dispersion states upon ultrasonication of a 3.2 wt% CNC suspension. After considering the importance of the measurement sampling volume, the behavior of a more concentrated suspension (6.4 wt%) is examined and compared with a never-dried suspension of the same concentration to validate the dispersion state.

Quantification ofSorReduction during Polymer Flooding Using Extensional Capillary Number

SummarySince the introduction of viscous/capillary concepts by Moore and Slobod (1956), several modifications and advancements have been made to the capillary number (Nc) so that it could have a better correlation with residual oil saturation (Sor) during enhanced oil recovery (EOR). In subsequent years, laboratory-scale studies have indicated that the viscoelastic polymers can influence the Sor reduction at relatively higher fluxes and Nc. Although the flux rate of at least 1 ft/D is reported to be needed for viscoelastic polymers to reduce Sor to a noticeable extent, significant Sor reductions were reported to occur only at higher fluxes that are likely to be seen in the reservoir closer to the wellbore. At similar levels of flux and Nc, the polymer solutions with significant elastic properties have shown higher Sor reduction than viscous polymer of similar shear rheology. However, the existing models used for correlating the polymer’s viscoelastic effect on Sor reduction relies on either core-scale Nc and/or the oscillatory Deborah number (De). De also has limitations in quantifying the polymer’s viscoelastic effects at different salinities.In this paper, a modified capillary number called an extensional capillary number (Nce) is developed using the localized pore-scale extensional viscosity. For viscoelastic polymer solutions, pore-scale apparent viscosity dominated by localized extensional viscosity is calculated to be significantly higher than core-scale apparent viscosity. We provide rheological insights using the variable-strain-rate concept to explain why and when the pore-scale apparent viscosity could become significantly higher, even at a flux of approximately 1 to 4 ft/D, and why it will not be reflected on the core-scale apparent viscosity or pressure drop. An exponential correlation was developed between Nce and Sor using the extensive coreflood experimental data sets extracted from various literature. Performance of Nce for predicting the viscoelastic polymer’s residual oil recovery is compared with conventional Nc, De, and a recent correlation. The results show that newly developed Nce can predict the Sor during polymer flooding for a wide range of operational and petrophysical conditions, including brine-salinity effects.

Silk Fibroin-Sodium Dodecyl Sulfate Gelation: Molecular, Structural, and Rheological Insights.

A gelling agent is necessary to accelerate sol to gel transition in an aqueous solution of silk fibroin (SF), which otherwise takes several days to complete. In this paper, we investigate the mechanism of gelation of Bombyx mori SF by a model anionic surfactant, sodium dodecyl sulfate (SDS). Even though interactions between SDS and proteins have been extensively investigated, most of these studies have focused on globular proteins, which undergo denaturation. The interaction with a fibrous protein such as SF is different and results in an altered secondary structure leading to gelation. In this work, the concentration-dependent gelation process of the SF-SDS system is examined using rheology, SANS, FTIR, and NMR. We observed preferential binding of SDS to specific regions on the SF chain, which aids structural changes favoring β-sheet formation. We propose a mechanism for the accelerated sol-gel transition in the SF-SDS system.

Interfacial rheological insights of sulfate-enriched smart-water at low and high-salinity in carbonates

Lowering the injection water salinity or modifying its chemistry can improve waterflooding displacement efficiency. This water modification has been frequently alluded to increase rock water-wetness. However, the presence of sulfate anions in the aqueous phase is shown here to also alter the crude oil–water interfacial rheology drastically, in ways similar to that associated to the reduction of water salinity. Under the right conditions, oil recovery could, in principle, be increased to a considerably degree by alteration of fluid–fluid interactions at high salinity. The purpose of this research is to contrast oil recovery behavior in cases when smart-water is designed based on either increasing the sulfate anion concentration in a high-salinity brine or by decreasing salinity considerably, when using seawater as the base aqueous phase. Interfacial rheological and coreflooding results are compared to the case of seawater injection. The effect of various ions on the interfacial shear rheological response of several crude oils and modified seawater were examined. Carefully designed corefloods using Indiana Limestone were run to evaluate the effect of each brine on recovery behavior. Mild temperature and short ageing time were imposed to hinder wettability alteration. Interfacial rheological results show that the visco-elasticity of the crude oil-brine interface is higher for a low-salinity brine compared to the higher-salinity counterpart represented by seawater. However, when the sulfate anion concentration is increased, the interfacial visco-elasticity increases noticeably. Coreflooding results show that brines leading to more a visco-elastic interface, including low salinity and sulfated seawater, yield higher oil recovery factor. Ion analysis of the effluent brine shows that for the model rock used, brine composition does not change significantly from contact with rock surfaces. The recovery response is found to be consistent with changes in interfacial rheology. After the injection of high salinity smart-water in secondary mode, the low-salinity water injection in tertiary mode apparently triggers connection and mobilization of oil ganglia, as hypothesized from the recovery response. Tracking water droplet size distribution seems to support this hypothesis. Low-salinity brine injection is generally conducive to increasing oil production. On the other hand, our findings reveal that the injection of sulfate-enriched water can modify fluid–fluid interactions and consequently the final oil recovery. However, this smart-water appears to lose effectiveness entirely, if injected as residual oil saturation is reached, indicating an apparent threshold in the oil saturation to draw benefits of high-salinity sulfated-water.

Inline rheological behavior of dispersed water in a polyester matrix with a twin screw extruder

Solvent‐free extrusion emulsification (SFEE) is a complex process using twin‐screw extrusion to prepare solid‐liquid dispersions of high viscosity polymers and has received little study to date on its inherent mechanisms. To gain rheological insights into the earliest stage of SFEE as the interfacial boundary between water and polymer grows, prior to phase inversion, an inline orifice‐plate type viscometer is introduced to monitor transient behavior over a wide range of viscosities. The presented work examines rheological changes of a polyester‐water system produced by varying two factors thought to significantly control the final state of the dispersion, specifically polar group contributions to surface energy and viscosity. A processing modifier was combined with the polyester to study the influence of these two factors. The inline viscometer revealed an abrupt transition in viscosity occurred with the developed state of water dispersion, confirming observations of a prior batch study. Analysis of the rheological response indicated that a higher polar surface energy contribution had the greatest influence on the state of this transition, and that a steeper transition was related to greater incorporation of water within the polyester matrix. POLYM. ENG. SCI., 2017. © 2017 Society of Plastics Engineers