Vibration-rotation transitions of NH2 in the à 2A1 state were observed with sub-Doppler resolution, by using a Rh 6G dye laser and a CO2/N2O laser combined with the laser magnetic resonance technique. When the dye laser pumped the à 2A1 (0,9,0) 220←X̃ 2B1(0,0,0) 110 transition, 39 MJ components of (0,10,0) 211←(0,9,0) 220, and 5 MJ components of (0,10,0) 111←(0,9,0) 220 in à were observed by sweeping the magnetic field. Four additional lines which corresponded to changes in fluorescence intensity opposite in sign to those for the transitions mentioned above, were also observed and assigned to transitions from à 2A1(0,9,0) to a highly excited vibrational state of X̃ (“u’’ level). The rotational quantum numbers N and J and the spin splitting of the u level were determined as well as the interaction term between the u and à (0,10,0) 211 states. The u level is tentatively assigned to a rotational level in X̃(2,8,0), however, the observed spin splitting does not agree with that for X̃(0,8,0) calculated by Jungen, Hallin, and Merer.
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