Resource Recovery Research Articles

Public perceptions of opioid misuse recovery and related resources in a nationally representative sample of United States adults.

To understand how the US public defines recovery from opioid misuse and the recovery-related resources it views as most helpful, and to compare differences by opioid misuse history and demographic characteristics. Observational study of data from the nationally representative AmeriSpeak® Panel survey administered in October/November 2021. United States. 6515 adults (≥ 18 years). Respondents ranked 10 definitions of recovery (religious in nature; spiritual in nature; physical/mental in nature; contributing to society; enhanced quality of life; seeking professional help; having a sense of purpose; moderate/controlled substance use; no drug use; abstaining from all substance use) and 9 resources that might contribute to recovery (primary care physician; intensive inpatient program; residential rehabilitation program; self-help group; therapist/psychologist/social worker; prescribed medication; talking to family/friends; spiritual/natural healer; faith-based organization). We explored differences in rankings by opioid misuse history (personal vs. family/friend vs. no history) and demographic characteristics (race, sex, age) using multivariable ordinal logistic regression. Seeking professional help was the most endorsed recovery definition overall [mean (M) = 6.97, standard error (SE) = 0.03]. Those with personal opioid misuse history ranked enhanced quality of life (B = 0.16, P = 0.049) and having a sense of purpose (B = 0.16, P = 0.029) significantly higher, and ranked abstaining from substance use (B = -0.20, P = 0.009) significantly lower as recovery definitions than those without a history of opioid misuse. Compared with White respondents, Black (B = 0.60, P < 0.001) and Hispanic (B = 0.55, P < 0.001) respondents defined recovery as more religious in nature. Residential rehabilitation program was identified as the most helpful resource for recovery (M = 7.16, SE = 0.02), while prescribed medication received a relatively low ranking overall (M = 4.05, SE = 0.03). Those with family/friend opioid misuse history ranked prescribed medication as less helpful than others (B = -0.14, P = 0.003). The general US public's views around recovery from opioid misuse appear to focus on abstinence and formal treatment receipt, while people with a history of opioid misuse place less emphasis on abstinence and greater emphasis on other aspects of well-being.

Resource recovery in line with energy generation at an agro-food industry

Resource recovery in line with energy generation at an agro-food industry

Effect, Fate and Remediation of Pharmaceuticals and Personal Care Products (PPCPs) during Anaerobic Sludge Treatment: A Review.

Biomass energy recovery from sewage sludge through anaerobic treatment is vital for environmental sustainability and a circular economy. However, large amounts of pharmaceutical and personal care products (PPCPs) remain in sludge, and their interactions with microbes and enzymes would affect resource recovery. This article reviews the effects and mechanisms of PPCPs on anaerobic sludge treatment. Most PPCPs posed adverse impacts on methane production, while certain low-toxicity PPCPs could stimulate volatile fatty acids and biohydrogen accumulation. Changes in the microbial community structure and functional enzyme bioactivities were also summarized with PPCPs exposure. Notably, PPCPs such as carbamazepine could bind with the active sites of the enzyme and induce microbial stress responses. The fate of various PPCPs during anaerobic sludge treatment indicated that PPCPs featuring electron-donating groups (e.g., ·-NH2 and ·-OH), hydrophilicity, and low molecular weight were more susceptible to microbial utilization. Key biodegrading enzymes (e.g., cytochrome P450 and amidase) were crucial for PPCP degradation, although several PPCPs remain refractory to biotransformation. Therefore, remediation technologies including physical pretreatment, chemicals, bioaugmentation, and their combinations for enhancing PPCPs degradation were outlined. Among these strategies, advanced oxidation processes and combined strategies effectively removed complex and refractory PPCPs mainly by generating free radicals, providing recommendations for improving sludge detoxification.

Enhanced carbon sequestration via phosphogypsum utilization in conjunction with concrete wastewater treatment

The simultaneous utilization of concrete wastewater (CW) and phosphogypsum (PG) to mineralize CO2 for carbon reduction is a green and low-carbon treatment method. In this work, the combined carbonation process of CW and PG and the role of ammonia as an additive were investigated. The addition of ammonia balances the excess anions, inhibits CaCO3 resolvation, and enhances the gas–liquid mass transfer. The higher pH and ionic strength of CW help to accelerate the PG dissolution and increase the PG conversion rate. Simultaneously, a decalcification efficiency of 100 % for CW and a PG conversion rate of 98.00 % were achieved. This process resulted in a CO2 capture of 215.76 g CO2/kg PG, with the pH of the synergistically treated wastewater ranging from 6.43 to 7.54. Additionally, the common ionic effect of Ca2+ and SO42−, the salting effect of CW, and the salting-out effect of CO2 influenced the reaction. The formation of vaterite under pressurized conditions was primarily governed by pH, which played a key role in determining the crystal morphology. The interaction between CW and PG was further confirmed in 5 L scale-up experiments, during which ammonia recycling was also achieved. This study fully utilized CW, combining it with PG to efficiently repurpose wastewater and solid waste for resource recovery.

Vision-based sorting in mixed food-inorganic waste stream

Processing food waste is crucial for environmental conservation and resource recovery, but inadequate sorting can lead to inorganic waste mixing with food waste. The mixed waste stream reduces the efficiency of food waste treatment facilities, and the preliminary sorting relies heavily on manual labor. To address the challenge of a non-homogeneous food-inorganic waste stream, this study proposes a vision-based system for effective sorting. A real-life Mixed Food-Inorganic Waste (MFIW) dataset containing over 13,000 samples and four categories of inorganic waste was created. Based on the dataset analysis, a Waste detection model using Deformable Convolution v3 was employed, and the appropriate positioning and classification algorithm was chosen for optimal detection performance. The Waste detection model achieves an mAP50 of 85.21 %, and the average recalls for packages, trash bags, and animal bones exceed 94 %. Additionally, the model runs at a real-time frame rate of 33.61 FPS, highlighting its suitability for industrial applications.

Separation of molybdenum and tungsten using selective adsorption with zirconium based metal organic framework

BackgroundThe separation of tungsten and molybdenum has always been a significant challenge. Metal organic frameworks (MOFs) has potential to solve the problem. In this study, the adsorption and separation performance of UiO-66 for tungsten and molybdenum and adsorption mechanism were investigated. MethodsUiO-66 was synthesized by solvothermal method. The physical and chemical properties of UiO-66 and adsorption mechanism were characterized and analyzed by XRD, SEM-EDS, FT-IR, Zeta-potential, XPS and thermodynamic analysis, the adsorption and separation performance of Mo/W using UiO-66 were evaluated by ICP-OES. Significant findingsUiO-66 with uniform pore size could be obtained under the conditions of crystallization for 24 h at 180 °C. This study revealed superior Mo/W separation performance under acidic conditions, where the adsorption capacity for Mo (QMo) of UiO-66 was 219.4 mg⋅g−1 and the highest separation factor (βMo/W) was 52.3. It was found that the mechanism involved the effect of pore size, electrostatic attraction and the metal point Zr had stronger affinity for Mo. This material was expected to serve as an eco-friendly and reusable adsorbent for separation of tungsten and molybdenum in resource recovery, aiming for high-quality regeneration of both metals.

Water hyacinth biorefinery: Improved biofuel production using Trichoderma atroviride pretreatment

AbstractThe pyrolysis of water hyacinth is gaining attention and acceptance as a resource recovery technique due to its availability and economic viability. However, the presence of lignin, one of the three major biomass fractions, presents significant challenges for profitable water hyacinth processing for biofuel production. Fungal pretreatment of water hyacinth for lignin breakdown has been explored but the application of Trichoderma atroviride as a pretreatment for pyrolysis is relatively novel. The efficacy of T. atroviride pretreatment in improving water hyacinth's pyrolytic products using a fixed‐bed reactor was therefore investigated in this study. The optimization process was studied using a central composite design in response surface methodology with Design Expert 13. Delignification of the biomass was established because the elemental analysis showed a 25.42% increase in cellulose content and a 23.40% and 3.37% decrease in lignin and hemicellulose content, respectively. The biomass pretreatment applied influenced the physical and chemical characteristics of the pyrolytic products. The highest pyrolysis oil yield increased by 25.81% at 575 °C and particle size 2290 μm, and the highest char yield decreased by 4.23% at 273 °C and particle size 1500 μm. This research is crucial for policy and research conversations as it offers a scientific basis for the application of T. atroviride pretreatment in biomass pyrolysis technology and emphasizes the optimal utilization of water hyacinths to obtain socio‐environmental benefits.

Exploring Resilience Among College Students in Recovery from Substance Misuse During the COVID-19 Pandemic

AbstractResearch has shown that both college students and people in recovery from substance use disorder were adversely impacted by the COVID-19 pandemic. For example, mental health and substance use challenges accrued for each group. However, less is known about how people who are both college students and in recovery experienced the pandemic. And, generally, little is known about the experiences of college students in recovery without access to the institutional support of a collegiate recovery program. We conducted a study including college students in recovery on a campus without a collegiate recovery program (N = 17) to explore how students experienced adversity during the pandemic and how they demonstrated resilience in overcoming adversity. We utilized thematic analysis to document patterns in the data. Students grappled with attrition from their recovery communities, loss of personal connections, and substance use and mental health challenges. To mitigate these hardships, students employed strategies to avoid substance use, applied principles of recovery programs, took advantage of new resources for recovery, and found ways to maintain connection with some supports. Our findings, documenting the resilience shown by these college students, can be utilized to improve collegiate recovery services, with an eye toward the ongoing popularity of virtual learning and toward potential future disruptive events.

Enhanced hydrothermal liquefaction of tires using zinc and MoS2

This study introduces a novel approach for tire liquefaction employing zinc and unsupported catalyst MoS2 to mitigate oxygen, nitrogen, and sulfur content, while inhibiting poly-aromatic formation. Autoclave experiments were conducted under subcritical water conditions at 360 and 410 °C. Comprehensive characterization of char and oil was performed, encompassing elemental analysis, functional-group assessment, and composition analysis using gas chromatography-mass spectrometry (GC-MS) and Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR MS). During the liquefaction, zinc metal pellets react with water to form ZnO and hydrogen, aiding hydrogenation, and MoS2 preserves its catalytic stability. ZnO shows a catalytic effect on deoxygenation, desulfurization, and denitrification reactions. However, the reaction between ZnO and H2S is not favorable under hydrothermal conditions. Zinc and MoS2 synergistically promote cracking of heavier compounds into lighter ones, particularly evident at higher temperatures, without diminishing the overall oil yield. Incorporating zinc pellets and MoS2 slightly facilitates sulfur and oxygen migration from liquid to solid and gas phases. FT-ICR MS analysis reveals oxygen, sulfur, and nitrogen-containing compounds in heavy fraction of oils. The oxygen-containing compounds, predominantly comprised of stearic acid and its derivatives, are identified. Concurrently, the nitrogen-containing compounds manifest primarily as basic nitrogen compounds. MoS2 possesses the capability of forming more N-containing compounds, leading to the generation of a broader spectrum of N-containing compounds. This work elucidates the synergistic role of zinc-assisted catalysis and MoS2, offering insights into tire liquefaction mechanisms and product composition, vital for sustainable waste management and resource recovery.

Impact of Nanoparticle Addition and Ozone Pre-Treatment on Mesophilic Methanogenesis in Temperature-Phased Anaerobic Digestion

Biodegradable organic waste offers significant opportunities for resource recovery within the frame of the circular economy. In this work, the effects of carbon-encapsulated iron nanoparticles and ozone pre-treatments in the mesophilic methanogenic stage of a temperature-phased an-aerobic digestion have been studied using biochemical methanogenic potential (BMP) tests and modeling simulation. To do that, digestates from a pre-treated thermophilic acidogenic reactor that co-digested sludge and wine vinasse were used. The addition of nanoparticles favored the removal of particulate matter, which increased by 9% and 6% in terms of total solids and volatile solids, respectively. When combined with ozone pre-treatment, these increases were 27% and 24%, respectively, demonstrating enhanced AD efficiency. The dose of iron nanoparticles encapsulated in carbon did not result in a statistically significant increase in methane production when sludge and vinasse were used as feedstock. The combination of nanoparticles with the ozone pre-treatment significantly improved the methanogenic phase of the second stage, increasing the methane production yield by 22% and reducing the lag phase from 10 days to 3 days, according to the modified Gompertz model.

Simultaneous treatment and enrichment of total phosphorus from livestock sewage using hydrate technology

The presence of phosphorus in livestock sewage is a key factor that causes eutrophication and the degradation of ecological water quality. Cyclopentane (CP) hydrate-based water treatment technique was utilized for the efficient total removal of phosphorus in effluents. This study assesses the treatment effectiveness and enrichment potential of hydrate technology when applied to real-world samples, specifically livestock wastewater. The treatment process was applied under atmospheric pressure and optimized appropriate conditions comprising the CP-to-sample volume ratio of 1:4, reaction duration of 3 h, and temperature of 2 °C because of the high subcooling and ability to enhance the number of hydrate crystals formed along with water. In addition, various methods, such as vacuum filtration, cold centrifugation, and washing, were employed for the effective and comprehensive removal of phosphorus from water samples with the efficiency exhibited from approximately 30 % to 80 %. The structure and composition of the CPHs formed in wastewater were analyzed via Raman spectroscopy and the phosphorus content was determined according to ISO 6878:2004. After a single-stage hydrate process without pretreatment and posttreatment, the water recovered from the extracted hydrates showed that the phosphorus removal efficiency in livestock sewage was approximately 85 % with a remarkable water recovery above 25 %. The study findings provide insights into the development of hydrate-based treatment technology for the removal of phosphorus and explore opportunities for resource enrichment and recovery from sewage.

Sustainable fluoride removal with scrap aluminum: Co-producing cryolite and hydrogen

This study presents a novel continuous process for fluoride removal and re- source recovery as cryolite, using a scrap aluminum-packed column. Efficient aluminum dissolution in hydrofluoric acid (HF) generates hydrogen gas and provides cost-saving alkalinity. The process achieves high efficiency (Al/F molar ratio of 2/6) within short Empty Bed Contact Times (15 min) and at low HF concentrations (500 mg/L). Solution pH plays a crucial role, with Al/F ratios above 1 achievable at pH below 4. The exothermic reaction requires temperature control, with a strong correlation (R²=0.99) between HF concentration and heat generation. Hydrogen production matches theoretical predictions. Cryolite synthesis was confirmed at optimized pH (5–5.5) with a 1:1 bypass ratio, achieving 98 % fluoride removal. XRD and SEM- EDS analyses verified cryolite formation. This approach offers a promising solution for industrial fluoride management, resource recovery, and clean hydrogen production.

A New Life for Tionite Industrial Waste: Regeneration Strategy towards Photocatalytic Applications.

Industrial waste management is an urgent problem to solve possibly by recycling, reuse and recovery of resources. In this framework, the sludge of the TiO2manufacturing, called tionite, is of certain interest because it contains metallic oxide-bearing impurities, dangerous to the environment. Hence, we propose a strategy to recover TiO2from tionite, towards its effective re-use as a photocatalyst. In detail, tionite was treated under acidic or alkaline conditions to remove impurities and improve the TiO2accessibility, and each single purification step was monitored by a thorough multi-technique characterization. The photocatalytic activity of the modified tionite materials was tested for the partial oxidation of ferulic acid to vanillin, a relevant sustainable green reaction, being vanillin an industrially relevant high added value compound and ferulic acid an abundant component of lignin present in industrial waste. All the tionite catalysts have shown significant efficiency in terms of vanillin selectivity respect to the benchmark TiO2P25. In particular, the sample treated under acidic conditions showed the best performances, due to specific interaction between the organic substrates and the catalyst. Results demonstrated that an industrial waste such as tionite can be valorized by proposing a tailored regeneration strategy.

Efficiency of Penicillium sp. and Aspergillus sp. for bioleaching lithium cobalt oxide from battery wastes in potato dextrose broth and sucrose medium

Lithium-ion batteries, a primary power source, generate electronic hazardous waste at the end of their lifespan, which is a richer source of highly concentrated metals such as cobalt and lithium than those in natural resources. The waste is a potential renewable resource for the extraction of metals. Bioleaching, a process utilizing microbial activity, was used in this study to investigate the cobalt and lithium leaching efficiency from battery wastes. Two fungal strains, Aspergillus sp. strain JMET 15 and Penicillium sp. strain JMET 24 were used with different organic carbon sources (sucrose medium and potato dextrose broth) at 1 % pulp density. The sucrose medium derived a higher acid quantity and leached higher concentration of cobalt and lithium than in potato dextrose broth. Leaching efficiency by JMET 24 was higher than JMET 15. Cobalt (32.57 % and 27.19 %) and lithium (65.07 % and 40.58 %) were bioleached by JMET 24 and JMET 15, respectively, after 30 d cultivation in the sucrose medium. Lower pulp density was conducted to achieved higher leaching efficiency by JMET24, cobalt (77.87 % and 74.5 %) and lithium (99.88 % and 78.4 %) were bioleached at 0.1 % and 0.5 % pulp density, respectively. Cobalt oxide (Co3O4) was the product of the one-step recovery (leaching and precipitation) process. Cobalt was transformed from lithium cobalt oxide to cobalt phosphate-oxalate by JMET 24 in the sucrose medium. Thus, the potential of bioleaching as an effective method for recovering valuable metals from lithium-ion battery waste is demonstrated, presenting a promising approach for both waste management and resource recovery.

Anthropogenic impacts on the terrestrial subsurface biosphere.

The terrestrial subsurface is estimated to be the largest reservoir of microbial life on Earth. However, the subsurface also harbours economic, industrial and environmental resources, on which humans heavily rely, including diverse energy sources and formations for the storage of industrial waste and carbon dioxide for climate change mitigation. As a result of this anthropogenic activity, the subsurface landscape is transformed, including the subsurface biosphere. Through the creation of new environments and the introduction of substrates that fuel microbial life, the structure and function of subsurface microbiomes shift markedly. These microbial changes often have unintended effects on overall ecosystem function and are frequently challenging to manage from the surface of the Earth. In this Review, we highlight emerging research that investigates the impacts of anthropogenic activity on the terrestrial subsurface biosphere. We explore how humans alter the constraints on microbial life in the subsurface through drilling, mining, contamination and resource extraction, along with the resulting impacts of microorganisms on resource recovery and subsurface infrastructure.

Correction: More et al. Indirect Freeze Crystallization—An Emerging Technology for Valuable Resource Recovery from Wastewater. Minerals 2024, 14, 427

Johannes P [...]

Efficient Electrocatalytic Hydrodechlorination and Detoxification of Chlorophenols by Palladium-Palladium Oxide Heterostructure.

Electrocatalytic hydrodechlorination is a promising approach for simultaneous pollutant purification and valorization. However, the lack of electrocatalysts with high catalytic activity and selectivity limits its application. Here, we propose a palladium-palladium oxide (Pd-PdO) heterostructure for efficient electrocatalytic hydrodechlorination of recalcitrant chlorophenols and selective formation of phenol with superior Pd-mass activity (1.35 min-1 mgPd-1), which is 4.4 times of commercial Pd/C and about 10-100 times of reported Pd-based catalysts. The Pd-PdO heterostructure is stable in real water matrices and achieves selective phenol recovery (>99%) from the chlorophenol mixture and efficient detoxification along chlorophenol removal. Experimental results and computational modeling reveal that the adsorption/desorption behaviors of zerovalent Pd and PdO sites in the Pd-PdO heterostructure are optimized and a synergy is realized to promote atomic hydrogen (H*) generation, transfer, and utilization: H* is efficiently generated at zerovalent Pd sites, transferred to PdO sites, and eventually consumed in the dechlorination reaction at PdO sites. This work provides a promising strategy to realize the synergy of Pd with different valence states in the metal-metal oxide heterostructure for simultaneous decontamination, detoxification, and resource recovery from halogenated organic pollutants.

Research trends in innovation ecosystem and circular economy

Understanding innovation ecosystems and the circular economy is crucial for systemic change in business and industry, fostering eco-innovation and advancing sustainable development. This study uses bibliometric analysis to uncover the research trends, patterns, and collaborations, revealing a significant gap in understanding the interactions between innovation ecosystems and the circular economy and offering potential avenues for future research that align with sustainable development. The analysis was carried out with the help of Biblioshiny and VOSviewer on the final selected documents of 2981 from the Scopus database through a search query and the SPAR-4-SLR stages of filtration. The key findings of the study are as follows: collaboration among countries involves accessing countries’ resources, knowledge, markets, and location. The study explores research trends in the innovation ecosystem and circular economy, focusing on five key clusters: the circular economy for eco-innovation and resource recovery, circular business models for fostering sustainable innovation in the bioeconomy, sustainability through renewable energy and sdgs, the sustainable business model for enhancing green innovation through entrepreneurship, and Artificial Intelligence (AI) and the circular business model in Industry 4.0. The bibliometric analysis identifies trends, research gaps, and collaboration patterns, revealing potential avenues for future exploration in industrial symbiosis, energy transition, and the system of innovation. The study analyzed only the documents available in Scopus. The exclusion of papers based on the search period, language, document type, and incomplete details are the limitations of this research and open the scope of potential future research. The findings will help existing researchers in this field as well as new researchers interested in this field by clearly understanding trends and further research scopes. The study also offers actional recommendations and practices to policymakers. Practices, and entrepreneurs for the attainment of global sustainability goals. The novelty and originality of this study rely on a thorough literature review that describes the state of the art in the innovation ecosystem and circular economy.

Efficient Toluene Decontamination and Resource Utilization through Ni/Al2O3 Catalytic Cracking.

Volatile organic compounds (VOCs), particularly aromatic hydrocarbons, pose significant environmental risks due to their toxicity and role in the formation of secondary pollutants. This study explores the potential of catalytic pyrolysis as an innovative strategy for the effective remediation and conversion of aromatic hydrocarbon pollutants. The research investigates the high-efficiency removal and resource recovery of the VOC toluene using a Ni/Al2O3 catalyst. The Ni/Al2O3 catalyst was synthesized using the impregnation method and thoroughly characterized. Various analytical techniques, including scanning electron microscopy, X-ray diffraction, and N2 adsorption-desorption isotherms, were employed to characterize the Al2O3 support, NiO/Al2O3 precursor, Ni/Al2O3 catalyst, and the resulting solid carbon. Results indicate that Ni predominantly occupies the pores of γ-Al2O3, forming nano/microparticles and creating interstitial pores through aggregation. The catalyst demonstrated high activity in the thermochemical decomposition of toluene into solid carbon materials and COx-Free hydrogen, effectively addressing toluene pollution while recovering valuable resources. Optimal conditions were identified, revealing that a moderate temperature of 700 °C is most favorable for the catalytic process. Under optimized conditions, the Ni/Al2O3 catalyst removed 1328 mg/g of toluene, generated 915 mg/g of carbon material, and produced 1234 mL/g of hydrogen. The prepared carbon material, characterized by its mesoporous structure and high specific surface area graphite nanofibers, holds potential application value in adsorption, catalysis, and energy storage. This study offers a promising approach for the purification and resource recovery of aromatic volatile organic compounds, contributing to the goals of a circular economy and green chemistry.

Sustainable Wastewater Treatment: Recent Progress in the use of Bio-Waste-Derived Adsorbents for Organic Dye Removal

There are serious health and environmental hazards associated with the growing amount of organic dyes in wastewater from sectors like food processing, leather, and textiles. These pollutants are frequently ineffectively removed by traditional wastewater treatment techniques. Adsorbents made from bio-waste have become a viable substitute because of their high removal efficiency, affordability, and sustainability. The adsorption of organic dyes is facilitated by the distinct surface chemistries of these adsorbents, which are made from a variety of biomass sources. Through synthesis and modification approaches, recent research has concentrated on enhancing these materials' adsorption capacity, selectivity, and overall performance. Adsorbents made from bio-waste have potential uses in pollutant degradation, nutrient recovery, and value addition in addition to dye removal. But issues like leaching and long-term stability need to be carefully thought out. This review highlights the recent advancements in the application of bio-waste-derived adsorbents for organic dye removal from wastewater, emphasizing their potential contributions to sustainable wastewater treatment and resource recovery.