Resonance Transitions Research Articles

Attosecond Raman time-delay in resonant transitions of ions

Attosecond Raman time-delay in resonant transitions of ions

Stimulated magneto-optics with different detunings for plasma local diagnostics

The polarization plane stimulated rotation angle of a probe signal in an intense laser field in plasma is calculated for arbitrary detunings of intense and weak laser waves compared with the resonant transition frequency of the medium. Estimates of the residual gas local density in a cesium plasma have been found based on the Faraday, Cotton–Mouton effects and on the effect of stimulated rotation of the polarization plane of the probe signal in an intense laser field. It is shown that the rotation in the medium has a complex structure consisting of the sum of only the influence of the magnetic field, only the influence of the intense laser field and the interfering part of the magnetic and intense laser fields.

Resonant detectors of gravitational wave in the linear and quadratic generalized uncertainty principle framework

In this work, we consider a resonant bar detector of gravitational waves in the generalized uncertainty principle (GUP) framework with linear and quadratic momentum uncertainties. The phonon modes in these detectors vibrate due to the interaction with the incoming gravitational wave. In this uncertainty principle framework, we calculate the resonant frequencies and transition rates induced by the incoming gravitational waves on these detectors. We observe that the energy eigenstates and the eigenvalues get modified by the GUP parameters. We also observe non-vanishing transition probabilities between two adjacent energy levels due to the existence of the linear order momentum correction in the generalized uncertainty relation which was not present in the quadratic GUP analysis (Class Quantum Gravity 37:195006, 2020). We finally obtain bounds on the dimensionless GUP parameters using the form of the transition rates obtained during this analysis.

Resonant transition metal Ti or Ta doping in high mobility transparent conducting CdO: The effects of doping concentration

Resonant transition metal Ti or Ta doping in high mobility transparent conducting CdO: The effects of doping concentration

Raman time-delay in attosecond transient absorption of strong-field created krypton vacancy

Strong field ionization injects a transient vacancy in the atom which is entangled to the outgoing photoelectron. When the electron is finally detached, the ion is populated at different excited states with part of coherence information lost. The preserved coherence of matter after interacting with intense short pulses has important consequences on the subsequent nonequilibrium evolution and energy relaxation. Here we employ attosecond transient absorption spectroscopy to measure the time-delay of resonant transitions of krypton vacancy during their creation. We have observed that the absorptions by the two spin-orbit split states are modulated at different paces when varying the time-delay between the near-infrared pumping pulse and the attosecond probing pulse. It is shown that the coupling of the ions with the remaining field leads to a suppression of ionic coherence. Comparison between theory and experiments uncovers that coherent Raman coupling induces time-delay between the resonant absorptions, which provides insight into laser-ion interactions enriching attosecond chronoscopy.

Magneto-optical and high-frequency electron paramagnetic resonance spectroscopy of Er3+ ions in CaMoO4 single crystal

We present the optical and magneto-optical spectroscopy and electron paramagnetic resonance (EPR) investigations of CaMoO4 single crystals doped with the erbium ions. Telecom-wavelength resonance transition inhomogeneous line width of Er3+ is relatively narrow for oxide crystals which makes this material promising for quantum technologies applications. The hyperfine structure in optical spectra of 167Er3+ isotope is well resolved. Energies and symmetries of wavefunctions of 39 energy levels of Er3+ ions in the crystal-field (CF) of S4 symmetry and g-factors of some CF Kramers doublets were measured and successfully simulated on the basis of CF calculations. The obtained set of CF parameters was used for modeling the hyperfine structure profiles observed in the optical absorption spectra.

Quantum‐Defect‐Minimized, Three‐Photon‐Pumped Ultralow‐Threshold Perovskite Excitonic Lasing

AbstractThree‐photon‐pumped (3PP) excitonic lasing in inorganic semiconductor quantum dots (QDs) is of particular importance for near‐infrared biophotonics and optical communications. However, the implementation of such lasers has been hindered severely by the required high pump thresholds. Here, 3PP excitonic lasing of all‐inorganic cesium lead bromide perovskite QDs (CsPbBr3 PQDs) embedded in a whispering‐gallery microcavity is demonstrated, and achieving a record low threshold of 3 mJ cm−2 by tuning the 3P pump energy in resonance with the S exciton state. Wavelength‐dispersive Z‐scan spectroscopy reveals that such reduced lasing threshold is attributed to the exciton resonance enhanced multiphoton absorption, which, as disclosed by the kinetics analysis of transient absorption spectroscopy (TAS), leads to the appearance of net gain at a pump fluence as low as 2.2 mJ cm−2, corresponding to an average S exciton population of 1.5. A microscopic model incorporating the quantum master equation reproduces the TAS results and provides the intrinsic parameters of biexciton relaxation for lasing. The 3PP resonant excitonic transition is the most favored multiphoton pumping process that minimizes quantum defect (6.8% of the pump photon energy) to realize optical gain at low threshold, marking a major step toward using all‐inorganic perovskite QDs for on‐chip integrated microlasers and multiphoton bioimaging.

Resonant graviton-photon transitions with cosmological stochastic magnetic field

We explore the possibility of detecting resonant conversions of high frequency gravitational waves to radio-signals. We show how the graviton-photon transitions, from Gertsenshtein effect, can be resonantly amplified in a cosmological stochastic magnetic background. In particular, we found parametric resonances for both the monochromatic and scale invariant power spectrum models of magnetic field fluctuations. Our results substantially departs from those predicted in resonance-less magnetic domain-like models in a large region of magnetic and oscillation wavelength scales. Resonances can be tested by radio telescopes such as ARCADE 2 and EDGES as a probe of high frequency gravitational wave sources and new physics models for magnetogenesis. Analysis are performed with a robust perturbative approach in discrete scheme for including cosmological decoherence in graviton-photon oscillations.

One-Photon Femtosecond Laser Excitation of Photoluminescence from H3 and H4 Centers in Natural Diamond: A Method to Determine Their Concentration

The photoluminescence spectra of the dominant H3 and H4 centers in a natural diamond sample, which is preliminarily characterized by optical and infrared spectrophotometry, are excited by femtosecond laser pulses with a wavelength of 470 nm and varying intensity. Saturation of the photoluminescence intensity of the H3 and H4 centers normalized by the intensity of laser radiation is observed and attributed to the saturation of the resonance transition responsible for the excitation. This makes it possible for the first time to estimate the absorption cross sections of H3 and H4 centers, which can be compared with values known from the literature and those determined from photoluminescence kinetics. The total concentration of H3 and H4 centers can then be found. Taking into account the known absorption coefficient of the sample at a wavelength of 470 nm and the previously established ratio of the contributions from H3 and H4 centers, their concentrations have been estimated separately for the first time.

Spatially Resolved Observations of Meteor Radio Afterglows With the OVRO‐LWA

AbstractWe conducted an all‐sky imaging transient search with the Owens Valley Radio Observatory Long Wavelength Array (OVRO‐LWA) data collected during the Perseid meteor shower in 2018. The data collection during the meteor shower was motivated to conduct a search for intrinsic radio emission from meteors below 60 MHz known as the meteor radio afterglows (MRAs). The data collected were calibrated and imaged using the core array to obtain lower angular resolution images of the sky. These images were input to a pre‐existing LWA transient search pipeline to search for MRAs as well as cosmic radio transients. This search detected 5 MRAs and did not find any cosmic transients. We further conducted peeling of bright sources, near‐field correction, visibility differencing and higher angular resolution imaging using the full array for these 5 MRAs. These higher angular resolution images were used to study their plasma emission structures and monitor their evolution as a function of frequency and time. With higher angular resolution imaging, we resolved the radio emission size scales to less than 1 km physical size at 100 km heights. The spectral index mapping of one of the long duration event showed signs of diffusion of plasma within the meteor trails. The unpolarized emission from the resolved radio components suggest resonant transition radiation as the possible radiation mechanism of MRAs.

Kinetics and thermodynamics of unimolecular dissociation of n-C3H7I

Abstract The present work expands previous studies on the kinetics of the n-C3H7I unimolecular decomposition and the thermodynamic properties of n-C3H7I and i-C3H7I molecules, by providing combined experimental and theoretical data on the rate constant for reaction of n-C3H7I + Ar ⇌ n-C3H7 + I + Ar, as well as thermodynamic data for iodopropane isomers, calculated based on the density functional theory. The n-C3H7I dissociation rate constant has been precisely determined in shock-tube experiments by applying atomic resonance absorption spectrometry (ARAS) at the resonance transition wavelength of atomic iodine (183.0 nm) in a temperature range from 830 to 1230 K at a pressure of 3–4 bar. The resulting expression is presented in the Arrhenius form: k 1st = 1.17 × 1013exp(−191.4 kJ mol−1/RT) (s−1). Theoretical RRKM/ME calculation of the temperature- and pressure-dependent rate constant and channel branching ratio have been based on quantum chemical calculations and were performed over a wide range of thermodynamic conditions (T = 300–2000 K, p = 10−4 to 102 bar). Additionally, the thermochemistry of the reactions of n-C3H7I dissociation and isomerization has been calculated on B3LYP/cc-pVTZ-PP level of theory. Thermodynamic data, which are provided in NASA polynomial format, are in a better agreement with the available experimental data and previous theoretical estimates.

Radiative capture of proton through the 14N(p,γ)15O reaction at low energy

The CNO cycle is the main source of energy in stars more massive than our Sun. This process defines the energy production, the duration of which can be used to determine the lifetime of massive stars. The cycle is an important tool for determining the age of globular clusters. Radiative proton capture via , at energies of astrophysical interest, is an important process in the CNO cycle. In this project, we apply a potential model to describe both non-resonant and resonant reactions in the channels where radiative capture occurs through electric transitions. We employed the R-matrix method to describe the ongoing reactions via resonant transitions, when it was not possible to correctly reproduce the experimental data using the potential model. The partial components of the astrophysical S-factor are calculated for all possible electric and magnetic dipole transitions in 15O. The linear extrapolated S-factor at zero energy (S(0)) agrees well with earlier reported values for all transition types considered in this work. Based on the value of the total astrophysical S-factor, depending on the collision energy, we calculate the nuclear reaction rates for . The computed rates agree well with the results reported in the NACRE II Collaboration and most recent existing measurements.

Tune-out wavelengths of Rydberg atoms

The atomic polarizability represents the response characteristics of atoms to externally applied electro-magnetic fields. The wavelength (or frequency) at which the dynamic polarizability of an atom is equal to zero is referred to as the tune-out wavelength (or frequency). Spectroscopy technology based on the tune-out effect has potential applications in quantum precision measurement, quantum computation and quantum communication. Related research topics include the measurement of fundamental physical constants and strong interactions. The tune-out wavelengths of atoms in low-lying states primarily fall within the optical band, where the theoretical calculations and experimental measurements have significant progress. However, for Rydberg atoms in highly excited states, theoretical calculations are challenging due to their high density of atomic states. The difficulty of experimental measurement arises from small splitting of adjacent atomic energy levels. In this paper, we demonstrate the tune-out wavelengths measurement for Rydberg atoms in a cesium vapor cell at room temperature. We utilize a two-photon cascade excitation to prepare Rydberg states and employ amplitude-modulation electromagnetically-induced transparency (AM-EIT) spectroscopy to measure the tune-out wavelength. By continuously scanning the microwave frequencies, we obtain AM-EIT signals of Rydberg atoms. At near-resonant microwave transition wavelengths, strong AM-EIT signals are observed due to microwave-atom coupling. Conversely, at tune-out wavelengths, the dynamically polarization-induced destructive interference in neighboring energy states occurs which leads to the weak AM-EIT signals. The AM-EIT provides a spectral resolution of about 10 MHz. We have developed a simplified three-level model to calculate the tune-out wavelength. The results of our theoretical calculations are consistent with the experimental findings within a range of ±90 MHz.

Theoretical calculation of “tune-out” wavelengths for clock states of Al<sup>+</sup>

In quantum optical experiments, the polarizabilities of atomic systems play a very important role, which can be used to describe the interactions of atomic systems with external electromagnetic fields. When subjected to a specific electric field such as a laser field with a particular frequency, the frequency-dependent electric-dipole (E1) dynamic polarizability of an atomic state can reach zero. The wavelength corresponding to such a frequency is referred to as the “turn-out” wavelength. In this work, the “turn-out” wavelengths for the 3s<sup>2</sup> <sup>1</sup>S<sub>0</sub> and 3s3p <sup>3</sup>P<sub>0</sub> clock states of Al<sup>+</sup> are calculated by using the configuration interaction plus many-body perturbation theory (CI+MBPT) method. The values of energy and E1 reduced matrix elements of low-lying states of Al<sup>+</sup> are calculated. By combining these E1 reduced matrix elements with the experimental energy values, the E1 dynamic polarizabilities of the 3s<sup>2</sup> <sup>1</sup>S<sub>0</sub> and 3s3p <sup>3</sup>P<sub>0</sub> clock states are determined in the angular frequency range of (0, 0.42 a.u.). The “turn-out” wavelengths are found at the zero-crossing points of the frequency-dependent dynamic polarizability curves for both the 3s<sup>2</sup> <sup>1</sup>S<sub>0</sub> and 3s3p <sup>3</sup>P<sub>0</sub> states. For the ground state 3s<sup>2</sup> <sup>1</sup>S<sub>0</sub>, a single “turn-out” wavelength at 266.994(1) nm is observed. On the other hand, the excited state 3s3p <sup>3</sup>P<sub>0</sub> exhibits four distinct “turn-out” wavelengths, namely 184.56(1) nm, 174.433(1) nm, 121.52(2) nm, and 119.71(2) nm. The contributions of individual resonant transitions to the dynamic polarizabilities at the “turn-out” wavelengths are examined. It is observed that the resonant lines situated near a certain “turn-out” wavelength can provide dominant contributions to the polarizability, while the remaining resonant lines generally contribute minimally. When analyzing these data, we recommend accurately measuring these “turn-out” wavelengths to accurately determine the oscillator strengths or reduced matrix elements of the relevant transitions. This is crucial for minimizing the uncertainty of the blackbody radiation (BBR) frequency shift in Al<sup>+</sup> optical clock and suppressing the systematic uncertainty. Meanwhile, precisely measuring these “turn-out” wavelengths is also helpful for further exploring the atomic structure of Al<sup>+</sup>.

Photo-physical characteristics of color N3-center in diamond studied via UV femtosecond-laser pumped luminescence.

Micro-joule UV-range (350-415 nm) femtosecond-laser pulses generated via frequency-doubled parametric conversion of 525-nm 150-fs pulses of Yb-glass laser were used for "hot" photoluminescence excitation in a diamond plate enriched by blue-emitting N3-centers (zero-phonon line, ZPL, at 415 nm). Photoluminescence spectra acquired in the range of 400-500 nm exhibited wavelength-independent well-resolved ZPL and phonon progression bands, where the involved phonons possessed the only energies of 0.09 eV (LA-phonons) and 0.15 eV (softened LO/TO-phonons), potentially, as a result of a Clemens decay mechanism. Photoluminescence yield in the ZPL and other phonon bands exhibited the power slope of 1.8 at lower energies and ≈1 at higher energies. The transition zone at fluence ∼1014-15 photons/cm2 was related to the saturation of the pumped resonance transition and the slower non-radiative vibrational relaxation to the ZPL-related excited electronic state and the nanosecond spontaneous photoluminescence transition to the ground state. As a result, the absorption cross section σ(370-390 nm) ≈1·10-15 cm2 and concentration [N3] ≈6·1014 cm-3 were determined along with the ZPL absorption cross section σ(415 nm) ≈2.5·10-15 cm2, and the non-radiative vibrational relaxation rate was estimated, providing altogether the crucial information on lasing possibilities in N3-doped diamonds.

Saturable absorption and third-order nonlinear refraction of 2D CdSe nanoplatelets resonant with heavy-hole excitonic transitions

We report on the nonlinear optical response of CdSe nanoplatelets and CdSe/CdS core/shell nanoplatelets in the heavy-hole resonant excitonic transition spectral regions with femtosecond pulses. The nonlinear refraction and saturable absorption coefficients were obtained using the Z-scan technique, and the results were explained theoretically. The nonlinear optical response under nonresonant excitation has been previously examined; comparing with the results presented in this work, at least a one order of magnitude increase in the nonlinear refraction coefficient is evident.

Global Dynamics and Bifurcations of an Oscillator with Symmetric Irrational Nonlinearities

This study’s objective is an irrationally nonlinear oscillating system, whose bifurcations and consequent multi-stability under the circumstances of single potential well and double potential wells are investigated in detail to further reveal the mechanism of the transition of resonance and its utilization. First, static bifurcations of its nondimensional system are discussed. It is found that variations of two structural parameters can induce different numbers and natures of potential wells. Next, the cases of mono-potential wells and double wells are explored. The forms and stabilities of the resonant responses within each potential well and the inter-well resonant responses are discussed via different theoretical methods. The results show that the natural frequencies and trends of frequency responses in the cases of mono- and double-potential wells are totally different; as a result of the saddle-node bifurcations of resonant solutions, raising the excitation level or frequency can lead to the coexistence of bistable responses within each well and cause an inter-well periodic response. Moreover, in addition to verifying the accuracy of the theoretical prediction, numerical results considering the disturbance of initial conditions are presented to detect complicated dynamical behaviors such as jump between coexisting resonant responses, intra-well period-two responses and chaos. The results herein provide a theoretical foundation for designing and utilizing the multi-stable behaviors of irrationally nonlinear oscillators.

Changes in the kinetic characteristics of free charge carriers in a narrow-gap semiconductor Pb<sub>1 – <i>x</i></sub>Gd<sub><i>x</i></sub>Te under the influence of electron paramagnetic resonance processes of Gd<sup>3+</sup> ions

In crystals of the narrow-gap semiconductor Pb1 – xGdxTe (x = 1.5 · 10–4) at temperatures T = 5–100 K, the method of electron paramagnetic resonance (EPR) revealed unusual dependences of the line shape of the EPR spectra of paramagnetic Gd3+ centers on temperature and the microwave power level in the spectrometer cavity. Based on the results of the analysis of the shape parameters of resonance lines recorded in the X-band, it was concluded that the most probable cause of changes in the observed EPR spectra is the effect of resonance transitions between the spin levels of Gd3+ centers on the kinetic characteristics of free charge carriers bound by exchange interactions with Gd3+ ions.

Resonant Laser Induced Breakdown Spectroscopy for quantitative elemental depth profile analysis of WTa coating

This work reports on the procedure of Resonant-LIBS, in which ablation and subsequent excitation is achieved by fine-tuning an Optical Parametric Oscillator (OPO) laser to the resonant transition of tungsten (W I) at 255.14 nm and analyzing the optical emission spectroscopy results. Compared to conventional LIBS, the ablation rate is significantly reduced in the resonant regime, resulting in finer resolution of depth profiles. This reduction in ablation rate can be attributed to a process called Resonance Laser Ablation (RLA) where a part of the laser energy is employed for ablation, while the rest is dedicated to resonant excitation. The sample under consideration is a WTa-coated (7μm) Mo substrate prepared by a dual magnetron sputtering system. These efforts are motivated by the need for improvement in quantitative depth analysis of W-based Plasma-Facing Components (PFC). Particularly to target the undesirable surface modifications due to the interaction with H isotopes in fusion plasma, such as fuel retention or erosion/deposition.

Spatially resolved macroscopic near-threshold harmonics generated from harmoniclike and resonant transitions using an artificial neural network

Spatially resolved macroscopic near-threshold harmonics generated from harmoniclike and resonant transitions using an artificial neural network