Resonance Effect Research Articles

Theoretical study of a triple-band tunable terahertz metamaterial absorber with polarization insensitive and high refractive index sensing based on bulk Dirac semimetal

In this paper, a triple-band metamaterial absorber in the terahertz frequencies is proposed, and its refractive index sensing characteristics are analyzed, where the bulk Dirac semimetal (BDS) periodic array is on top of a photonic crystal slab backed with a metal ground plane. The simulation results show that the absorber achieves three perfect absorption peaks in the range of 3.4–5.2 THz, whose absorption rates are over 96%, and a maximum quality factor (Q) of 74.1. The designed absorber exhibits excellent polarization insensitivity and dynamic tunability; further, the tuning of the Fermi energy level of BDS enables the dynamic adjustment of absorption frequencies and absorption rates of these peaks. By analyzing the distributions of the electromagnetic field and different structural parameters, it is revealed that the absorber mainly dissipates the electromagnetic wave through coupled resonance and localized surface plasmon resonance (LSPR) effects to achieve perfect absorption. Further, the metamaterial absorber shows the capacity to detect analytes with varying refractive indices, and the absorber has a maximum sensitivity S of 405 GHz/RIU with high detection accuracy. This work provides novel design options for triple-band terahertz metamaterial absorbers and their potential applications in refractive index sensing.

Titanium boride nanosheets with photo-enhanced sonodynamic efficiency for glioblastoma treatment

Sonodynamic therapy (SDT) has garnered significant attention in cancer treatment, however, the low-yield reactive oxygen species (ROS) generation from sonosensitizers remains a major challenge. In this study, titanium boride nanosheets (TiB2 NSs) with photo-enhanced sonodynamic efficiency was fabricated for SDT of glioblastoma (GBM). Compared with commonly-used TiO2 nanoparticles, the obtained TiB2 NSs exhibited much higher ROS generation efficiency under ultrasound (US) irradiation due to their narrower band gap (2.50 eV). Importantly, TiB2 NSs displayed strong localized surface plasmon resonance (LSPR) effect in the second near-infrared (NIR II) window, which facilitated charge transfer rate and improved the separation efficiency of US-triggered electron–hole pairs, leading to photo-enhanced ROS generation efficiency. Furthermore, TiB2 NSs were encapsulated with macrophage cell membranes (CM) and then modified with RGD peptide to construct biomimetic nanoagents (TiB2@CM-RGD) for efficient blood-brain barrier (BBB) penetrating and GBM targeting. After intravenous injection into the tumor-bearing mouse, TiB2@CM-RGD can efficiently cross BBB and accumulate in the tumor sites. The tumor growth was significantly inhibited under simultaneous NIR II laser and US irradiation without causing appreciable long-term toxicity. Our work highlighted a new type of multifunctional titanium-based sonosensitizer with photo-enhanced sonodynamic efficiency for GBM treatment. Statement of significanceTitanium boride nanosheets (TiB2 NSs) with photo-enhanced sonodynamic efficiency was fabricated for SDT of glioblastoma (GBM). The obtained TiB2 NSs displayed strong localized surface plasmon resonance (LSPR) effect in the second near-infrared (NIR II) window, which facilitated charge transfer rate and improved the separation efficiency of US-triggered electron-hole pairs, leading to photo-enhanced ROS generation efficiency. Furthermore, TiB2 NSs were encapsulated with macrophage cell membranes (CM) and then modified with RGD peptide to construct biomimetic nanoagents (TiB2@CM-RGD) for efficient blood-brain barrier (BBB) penetrating and GBM targeting. After intravenous injection into the tumor-bearing mouse, TiB2@CM-RGD can efficiently cross BBB and accumulate in the tumor sites. The tumor growth was significantly inhibited under simultaneous NIR II laser and US irradiation without causing appreciable long-term toxicity.

Understanding the relationship between electric dipole polarizability and photonuclear (-2) moment in odd-A actinide nuclei

The nuclear electric dipole (E1) polarizability (α E1) is mainly dominated by the dynamics of the giant dipole resonance (GDR). α E1 is proportional to the (-2) moment of the total photo nuclear cross-section (σ −2). This research investigates the relationship between α E1 and σ −2, along with the effects of the Pygmy Dipole Resonance (PDR) and GDR in odd-mass actinide nuclei. For the first time, α E1 and σ −2 values have been calculated using the Translational and Galilean Invariant Quasiparticle Phonon Nuclear Model (TGI-QPNM) approach for odd-A actinide nuclei. According to TGI-QPNM results, E1 dipole transitions in the GDR region significantly contribute to σ −2 due to the energy weighting factor. Below the neutron separation threshold, the PDR in neutron-rich nuclei shows a contribution of about 5% to σ −2 values. In this region, E1 polarizability can reach values of 20%–25%. The α E1 values indicate the presence of PDR in these nuclei. Additionally, the Adaptive Neuro-Fuzzy Inference System (ANFIS), a new machine learning method, has been performed to analyze the relationship between α E1 and σ −2. The ANFIS results have been compared with those from the TGI-QPNM and experimental data. The TGI-QPNM model achieves an R2 of 0.85–0.95, while the ANFIS model achieves an R2 of 0.99. Moreover, the study suggests that the ANFIS model, consistent with TGI-QPNM results, could be an effective tool for estimating σ −2 in odd-A actinide nuclei.

On the search for the two poles of the Ξ(1820)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Xi (1820)$$\\end{document} in the ψ(3686)→Ξ¯+K¯0Σ∗-(π-Λ)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\psi (3686) \\rightarrow \\bar{\\Xi }^+ \\bar{K}^0 \\Sigma ^{*-}(\\pi ^- \\Lambda )$$\\end{document} decay

We propose the reaction ψ(3686)→Ξ¯+K¯0Σ∗-\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\psi (3686) \\rightarrow \\bar{\\Xi }^+ \\bar{K}^0 \\Sigma ^{*-}$$\\end{document}, with the Σ∗-\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Sigma ^{*-}$$\\end{document} decaying to π-Λ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\pi ^- \\Lambda $$\\end{document} in order to show evidence for the existence of two Ξ(1820)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Xi (1820)$$\\end{document} states, one around 1824 MeV and narrow, and another one around 1875 MeV and wide. The phase space for K¯0Σ∗-\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\bar{K}^0 \\Sigma ^{*-}$$\\end{document} production reduces the effect of the lower mass resonance, magnifying the effect of the higher mass resonance that shows clearly over the phase space. The estimated rate of the production is bigger than the one of the ψ(3686)→Ξ¯+K-Λ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\psi (3686) \\rightarrow \\bar{\\Xi }^+ K^- \\Lambda $$\\end{document} reaction, where a clear peak for Ξ(1820)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Xi (1820)$$\\end{document} was observed by the BESIII collaboration, what makes the Beijing facility ideal to carry out the reaction proposed.

Preparation of C@CuNi/TiO2 with a local surface plasmon resonance for photocatalytic degradation of organic dyes and antibiotics under visible light irradiation

A composite photocatalyst with carbon-coated CuNi nanoparticles-loaded TiO2 nanotubes (C@CuNi/TiO2) was synthesized via a microwave hydrothermal alkali stripping method combined with subsequent in-situ carbothermal reduction. The structure, morphology, and surface chemical composition were investigated using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. The findings demonstrate that the microwave hydrothermal alkali peeling enables the formation of a three-dimensional C@CuNi/TiO2 composite structure. The results of transient photocurrent response (i-t) and electrochemical impedance spectroscopy under visible light demonstrate that C@CuNi/TiO2 exhibits a reduced rate of electron-hole recombination and lower surface resistance compared to C@TiO2, C@Cu/TiO2, and C@Ni/TiO2. After a two-hour exposure to visible light, the composite photocatalyst C@CuNi/TiO2, featuring a molar ratio of 2 % CuNi nanoparticles to TiO2 nanotubes, exhibited remarkable degradation activity towards organic dyes (Rhodamine B (RhB), Methylene Blue (MB), Methyl Orange (MO)), as well as antibiotics (tetracycline (TC) and levofloxacin (LVFX)). After 5 cycles of photocatalytic reaction, the photodegradation activity of RhB remained above 79 %. It is indicated that CuNi nanoparticles effectively trap and enrich photoelectrons through the photoexcitation of TiO2 nanotubes. Additionally, the local surface plasmonic resonance (LSPR) effect of CuNi nanoparticles reduces the recombination rate of photogenerated electron/hole and the electron transport resistance in the composite photocatalyst, thereby enhancing its overall photocatalytic activity.

Plasmonic molybdenum carbide MXene nanosheets for highly efficient and stable perovskite solar cells

Besides the excellent metallic electrical conductivity, high carrier mobility, and high optical transmittance, the two-dimensional MXenes exhibiting impressive optical and plasmonic properties have been explored to photodiodes. However, their potential use of surface plasmons oscillating in perovskite solar cells has not been studied. Herein, we incorporate, for the first time, Mo2CTx MXene nanosheets with characteristic plasmonic absorption in the whole visible region into the perovskite active layer. First, the presence of Mo2CTx nanosheets in the perovskite film increases the perovskite grain size due to the decreased growth rate and passivation of the defects around the grain boundaries through strong interaction with undercoordinated Pb2+. Furthermore, with the help of the localized surface plasmon resonance effect of Mo2CTx nanosheets, the exciton binding energy in the perovskite absorber is reduced, which suggests the efficient exciton dissociation and enhanced charge separation. Consequently, Mo2CTx nanosheets based perovskite solar cell device exhibits a champion power conversion efficiency (PCE) of 24.05 %. It is worth noting that the unencapsulated devices demonstrate considerably improved stability, maintaining about 89.25 % of the initial PCE after aging in air for 3000 h. This fascinating strategy provides more opportunities of the functional MXene materials for the perovskite optoelectronics.

Novel PtCu/MIL-101(Cr) for efficient degradation of bisphenol A: Photothermal synergism promoted by the localized surface plasmon resonance effect

Semiconductor photocatalysis is one of the most useful methods to solve environmental pollution problems. Herein, nanomaterial PtCu/MIL-101(Cr) was produced by an improved hydrothermal technique. The composite exhibited excellent photocatalytic performance with 99.7 % BPA degradation under 100 min visible light irradiation. First, the PtCu alloy has the effect of the local surface plasmon resonance effect, which can convert the photons to hot electrons and increase the reaction temperature. The synergistic effect (1+1>2) between photocatalysis and thermocatalysis significantly improved the photocatalytic efficiency. Second, the bimetallic alloying lowered the metals' work function and reduced the Schottky barrier between the PtCu alloy and MIL-101(Cr), which effectively promoted the carrier transfer. The ·O2-, ·OH and h+ were dominant reactive substances in the degradation process. The intermediates and degradation pathways of BPA were analyzed by 3D-EEM. The reaction mechanism was proposed based on theoretical calculations and experimental analysis. This work provides new directions for designing photothermal synergistic green catalysts and purifying the environment.

Secondary Resonances of Asymmetric Gyroscopic Spinning Composite Box Beams

A comprehensive theoretical investigation on the occurrence of secondary resonances in parametrically excited unbalanced spinning composite beams under the stretching effects is conducted numerically and analytically. Based on an optimal stacking sequence and Rayleigh’s beam theory, the governing equations of the system are derived using extended Hamilton’s principle. The system’s partial differential equations are then discretized using the Galerkin method. Numerical (Runge–Kutta technique) and analytical (multiple scales method) approaches are exploited to solve the reduced-order equations, and their results are compared and verified accordingly. Comparison and convergence investigations are performed to guarantee the validity of the outcomes. Stability and bifurcation analyses are accomplished, and resonance effects are thoroughly studied utilizing frequency-response diagrams, phase portraits, Poincaré maps and time-history responses. It is observed that among the various types of secondary resonance, only a combination resonance can be observed in the system dynamics. The outputs reveal that, in this resonance, the gyroscopic coupling results in the steady-state time response consisting of three main frequencies. By examining the effects of damping, eccentricity, and beam length, it is exhibited that this resonance does not occur in the system’s dynamics for any combination of these parameters. Therefore, these parameters can be adjusted in the design of asymmetric beams to prevent this type of resonance.

Stepwise One-Shot Borylation Reactions for Intersecting DABNA Substructures Exhibiting Bright Yellow‒Green Electroluminescence with EQE Beyond 40% and Mild Roll-Off.

Boron/nitrogen (B/N)-doped polycyclic aromatic hydrocarbons (PAHs) with the multiple resonance (MR) effect are promising for organic light-emitting diodes (OLEDs) because of their narrowband emission and thermally activated delayed fluorescence (TADF) characteristics. Nevertheless, exploring the variety of such emitters is challenging because of the tricky and limited synthetic protocols. Herein, we designed a novel B/N-doped PAH, L-DABNA-1, whose backbone (L-DABNA) could not be achieved via conventional routes (e.g., one-pot borylation or one-shot borylation). We successfully synthesized it through stepwise one-shot borylations with precisely introducing decorations. The unique MR backbone with intersecting DABNA substructures sharing an aniline group, avoiding any para-N-π-B motif, allows L-DABNA-1 to maintain narrowband TADF emission while significantly redshifting to the yellow-green region with a reverse intersystem crossing rate (kRISC) of 1.28 × 105 s-1. An L-DABNA-1-based OLED device achieved a maximum external quantum efficiency (EQE) of over 40% and maintained a high EQE of 36.3% at 1000 cd m-2, with a current efficiency reaching ~170 cd A-1. This work not only demonstrated the great potential of stepwise borylations in synthesizing B/N-doped PAH backbones, expanding their chemical space, but also provided a promising pathway for exploring MR-TADF emitters at longer wavelengths.

Donor-only substituted benzene achieves thermally activated delayed fluorescence

Thermally activated delayed fluorescence (TADF) is a promising mechanism for harvesting triplet excitons in organic light-emitting diodes (OLEDs). The donor–acceptor (D–A) design is the most conventional strategy for developing efficient TADF emitters. A subsequently emerged approach, known as the multiple resonance (MR) effect, also employs electron-donating and electron-withdrawing functional groups. Thus, developing TADF materials has traditionally relied on ingenuity in selecting and combining two functional units. Here, we have realized a TADF molecule by utilizing only a carbazole donor moiety. This molecule is an unusual example in the family of TADF materials and offers better insight into the electronic structures in the excited states for luminescent materials.

Excellent piezo-photocatalytic performance of plasmonic Bi/Bi4Ti3O12 heterojunction synthesized by in-situ reduction

Efficient catalytic conversion can be achieved by electro-mechanical coupling and solar energy-induced photogenerated carriers. In this work, an advanced semimetal Bi decorated Bi4Ti3O12 (Bi/BTO) heterojunction catalyst was constructed through in-situ reduction without organic solvent. The piezo-photocatalytic removal toward MB of Bi/BTO catalyst reaches 87.2% within 70 min, and the rate constant is 2.23 and 1.80 times higher than that of piezocatalysis and photocatalysis, respectively. The enhanced performance is attributed to not only surface plasmon resonance effect of Bi nanoparticles that enhances light absorption and accelerates charge separation, but also the piezoelectric effect of Bi4Ti3O12 which strengthens internal electric fields. Moreover, the metal titanium template can be recycled to synthesize Bi/BTO catalyst, thus favouring commercial-scale application. This work demonstrates an effective strategy to design efficient catalyst to utilize natural solar and mechanical energy.

The Effect of Electromagnetic Resonance in the Instrument Modules of an Aircraft on Induced Conductive Interference

The Effect of Electromagnetic Resonance in the Instrument Modules of an Aircraft on Induced Conductive Interference

Deep Learning-Driven Multi-Stage Product Visual Emotional Design Utilizing Web Semantics

With the rapid development of artificial intelligence, the generation of emotional expression images has become a key research field. This article introduces a novel multi-stage emotion generation model cascade method that utilizes CGAN, Pix2Pix, and CycleGAN to create images with enhanced emotional depth and visual quality. We have outlined our approach, which involves a continuous process from emotional initialization to texture refinement, and then to style transition. Our experiments on facial and automotive datasets show a significant improvement in image quality compared to traditional models, with an average increase of 40 percentage points in structural similarity (SSIM) and an average increase of 11.1 percentage points in peak signal-to-noise ratio (PSNR). The research findings emphasize the potential applications of our model in advertising, entertainment, and human-computer interaction, where visual effects of emotional resonance are crucial.

Manipulation of lasing modes in a deformed octagonal microcavity laser

We have demonstrated a deformed octagonal microcavity semiconductor laser with manipulated lasing modes for bistable operation and direct modulation. There are two sets of degenerated four-bounced modes, S01 and S02, in the octagonal microcavity, and the degeneracy between them is broken by introducing a square hole into the center of the cavity. In the deformed octagonal microcavity laser, mode S01 dominates the lasing process during the current rising process. However, mode S02 also lases when the current decreases and interacts nonlinearly with S01, which is caused by the non-uniform distribution of the refractive index induced by the square-ring-shaped current injection. We observe a counterclockwise bistable hysteresis loop with continuous injection current ranging from 31 to 13 mA at 288 K. We also study the small-signal modulation response of the laser at high and low states with different injection currents. By utilizing the photon-photon resonance effect between modes S01 and S02, we effectively increased the 3-dB bandwidth of the laser from 12 GHz to 16.2 GHz.

Tailoring thermal transport and confinement effect of GaN/Si3N4 nanowires utilizing core–shell architecture

The thermal transport properties of nanowires (NWs) can be significantly influenced by the implementation of a core-shell structure, which introduces interface scattering and phonon localization effects, opening avenues for novel applications. In this paper, we use the method of non-equilibrium molecular dynamics to simulate the effects of system temperature, cross-sectional width, and nanopillar interface on the thermal transport of GaN/Si3N4core-shell NWs. The thermal transport process of phonons in core-shell NWs is studied by calculating the vibrational density of states, phonon participation rate, and dispersion curve. The results show that the core-shell NWs characterized by smooth interfaces exhibit a 17.4% decrease in thermal conductivity (TC) at room temperature when contrasted with pristine GaN NWs. Furthermore, the TC of GaN/Si3N4core-shell NWs can be further reduced by adding nanopillars at the interface. Due to resonance effect, thus effectively regulating the thermal transport. The presence of nanopillars increases phonon-surface scattering intensity at low-frequency and modifies phonon dispersion to decrease the group velocity. In addition, the hybridization of phonon modes between those of the nanopillars and the Si3N4shell gives rise to numerous dispersionless resonance phonon modes that span the entire phonon spectrum. This research delves into the effects of nanopillars and interfaces on thermal transport, providing important guidance for understanding confinement effects and establishing a robust theoretical basis for the regulation of thermal transport.

Janus-structured evaporator with multiple optimization strategies for sustainable solar desalination

Solar-driven interfacial evaporation (SIE) is an environmentally-friendly and sustainable approach to seawater desalination and offers a promising solution for addressing water scarcity challenge. However, the intricate nature of SIE technology as a complex three-phase system calls for more holistic design strategies. Therefore, we present a comprehensive optimization strategy that integrates various design concepts spanning from optical characteristics and thermal localization enhancement to thermal convection intensification. The enhancement of the localized surface plasmon resonance (LSPR) effect is initially demonstrated by uniformly introducing TiN-NH2 nanoparticles onto the SWCNTs-COOH surface, showcasing remarkable absorbance properties (95.49%). Subsequently, the integration of a dual-network hydrogel is utilized to create a Janus architecture, which can enhance the thermal localization effect with an impressive evaporative efficiency of 92.25%. Finally, perforations are introduced to further improve heat convection, resulting in an exceptional evaporation rate of TiN@CNT/GOF-H1 (3.33 kg m−2 h−1, when calculated according to the real area, the evaporation rate value is 3.75 kg m−2 h−1). Both experimental findings and numerical simulations underscores the efficacy of this multiple-optimization engineered design. Experiment conducted within a customized device has substantiated the enduring cyclic stability and pH resistance to variations, potentially facilitating the spread of practical applications. The integration of multiple optimization strategies is expected to provide valuable insights for the holistic performance enhancement of the SIE evaporators.

Mitigating thermal burden and enhancing minor phase emission energy transfer in perovskite by introducing dopamine-mediated silver nanoparticles

Perovskite-based light-emitting diodes (PeLEDs) suffer from low wavelength and intensity instability during excited emission. This study incorporates dopamine-mediated silver nanoparticles (DA@AgNPs) into perovskite to enhance the performance of blue-light PeLEDs. Characterization studies highlight the crucial role of dopamine’s hydroxyl group in controlling the size and distribution of AgNPs. Due to the presence of amine group, dopamine acts as a “bridging linker,” facilitating precise integration of AgNPs with perovskite. DA@AgNPs–perovskite comprises a uniform cubic phase, indicating improved crystal quality and fewer defects than in pristine perovskite. DA@AgNPs prevent pinhole-defect-induced heat accumulation, reducing nonradiative energy and Joule heat. Additionally, DA@AgNPs enhance thermal conductivity and thus cooling efficiency. The energy transfer between minor and primary phase emissions is found to be highly efficient and to enhance primary phase emission through the surface plasmon resonance effect of DA@AgNPs. Finally, DA@AgNPs–perovskite is successfully employed in a high-performance blue-light PeLED (wavelength = 476 nm); the device’s external quantum efficiency is 11.2 %, luminance is 380.2 cd/m2, and emission stability is favorable (firmly maintained at 476–478 nm after strong excitation under 4.25 V for 1 h). This work provides insights into one means of improving blue-light PeLEDs, opening avenues for advancements in optoelectronics.

Transmission of substituent effects in para-disubstituted benzenes: 13C chemical shift and Mulliken charge modeling of para carbon atoms via the Reynolds DSP model

The PM3 calculations of the Mulliken charge and the experimental 13C substituent chemical shifts (SCS) of para carbon for 17 para-disubstituted benzene series were investigated by correlation analysis. A significant correlation between the charge and the 13C SCS of the para carbon of the same series was observed. In mono-substituted benzene, the correlation of para13C SCS with Mulliken charges calculated by PM3 and Mulliken charge calculated by DFT(B3LYP) with basis set 6 311(dp)G of the same carbon is similar. All the substituent effects on the charge and 13C SCS were modeled by the Reynolds’ dual substituent parameter model (charge or 13C SCS = ρF σF + ρRσRo), where σF and σRo are the Reynolds’ field and resonance constants, respectively, and ρF and ρR are the field and resonance effects, respectively. The coefficients of determination for all series were significant. The concept of π-polarization was used to analyze variation in ρF. The interpretation of ρF showed parallels between the charge and 13C SCS. An enhanced ρF for a given series was attributed to the stabilization of the π-polarization charge at the para carbon. The ρR was a function of extended conjugation within the side chain. Parallelism of charge and 13C SCS of the ρR of the compared series were also observed, except in series with the reverse-substituent effect and the possession of a strong electronegative group, such as a nitro or azo group.

Silk Fabric Functionalized by Nanosilver Enabling the Wearable Sensing for Biomechanics and Biomolecules.

Integrating biomechanical and biomolecular sensing mechanisms into wearable devices is a formidable challenge and key to acquiring personalized health management. To address this, we have developed an innovative multifunctional sensor enabled by plasma functionalized silk fabric, which possesses multimodal sensing capabilities for biomechanics and biomolecules. A seed-mediated in situ growth method was employed to coat silver nanoparticles (AgNPs) onto silk fibers, resulting in silk fibers functionalized with AgNPs (SFs@Ag) that exhibit both piezoresistive response and localized surface plasmon resonance effects. The SFs@Ag membrane enables accurate detection of mechanical pressure and specific biomolecules during wearable sensing, offering a versatile solution for comprehensive personalized health monitoring. Additionally, a machine learning algorithm has been established to specifically recognize muscle strain signals, potentially extending to the diagnosis and monitoring of neuromuscular disorders such as amyotrophic lateral sclerosis (ALS). Unlike electromyography, which detects large muscles in clinical medicine, sensing data for tiny muscles enhance our understanding of muscle coordination using the SFs@Ag sensor. This detection model provides feasibility for the early detection and prevention of neuromuscular diseases. Beyond muscle stress and strain sensing, biomolecular detection is a critical addition to achieving effective health management. In this study, we developed highly sensitive surface-enhanced Raman scattering (SERS) detection for wearable health monitoring. Finite-difference time-domain numerical simulations ware utilized to analyze the efficacy of the SFs@Ag sensor for wearable SERS sensing of biomolecules. Based on the specific SERS spectra, automatic extraction of signals of sweat molecules was also achieved. In summary, the SFs@Ag sensor bridges the gap between biomechanical and biomolecular sensing in wearable applications, providing significant value for personalized health management.

Ultrasound frequency-controlled microbubble dynamics in brain vessels regulate the enrichment of inflammatory pathways in the blood-brain barrier

Microbubble-enhanced ultrasound provides a noninvasive physical method to locally overcome major obstacles to the accumulation of blood-borne therapeutics in the brain, posed by the blood-brain barrier (BBB). However, due to the highly nonlinear and coupled behavior of microbubble dynamics in brain vessels, the impact of microbubble resonant effects on BBB signaling and function remains undefined. Here, combined theoretical and prospective experimental investigations reveal that microbubble resonant effects in brain capillaries can control the enrichment of inflammatory pathways that are sensitive to wall shear stress and promote differential expression of a range of transcripts in the BBB, supporting the notion that microbubble dynamics exerted mechanical stress can be used to establish molecular, in addition to spatial, therapeutic windows to target brain diseases. Consistent with these findings, a robust increase in cytotoxic T-cell accumulation in brain tumors was observed, demonstrating the functional relevance and potential clinical significance of the observed immuno-mechano-biological responses.