Resistive Layer Research Articles

Surface-Reconstructed CdNNi3 Antiperovskite Electrocatalyst: Unlocking Ampere-Level Current Density for Hydrogen Evolution.

Developing conductive electrocatalysts is crucial for decreasing the ohmic loss induced by electric resistance of the catalyst layer in the large-current-density hydrogen evolution reaction (HER), which has been overlooked previously. In this study, we screen a highly conductive antiperovskite CdNNi3 with negligible ohmic loss, as a highly active and durable HER electrocatalyst capable of unlocking ampere-scale current densities. CdNNi3 exhibits an impressive activity (an overpotential of 235 mV) at 1 A cm-2 and maintains its performance steadily at an ampere-scale current density (at 1 A cm-2 over 400 h). Besides, the CdNNi3-enabled anion-exchange membrane water electrolyzer outperforms that of the benchmark Pt/C, evidenced by a reduced cell voltage of 160 mV at 1 A cm-2, and presents a favorable stability at 1 A cm-2. Importantly, this study experimentally discovers the dynamic surface reconstruction phenomena of antiperovskite nitrides during alkaline HER. Theoretical analysis suggests that the presence of Cd in the reconstructed surface effectively adjusts the local electronic configuration of active sites, which promotes the adsorption of OH and reduces the binding strength to H, thereby facilitating the water dissociation step and reducing the energy barrier of the potential-determining step in the HER process.

SCAPS numerical modeling of CBTS/WO3 thin film solar cell

The quaternary compound Cu2BaSnS4 (CBTS) has emerged as a suitable and attractive light-harvesting material due to its promising optoelectronic features as well as nontoxic and low-cost constituent elements. Yet efficiency of CBTS-based solar cells did not reach the Shockley-Queisser limit. Here, what we believe to be a novel structure ITO/WO3/CBTS heterojunction solar cell is designed and modeled using a solar cell capacitance simulator in one-dimension (SCAPS-1D). In this work, a what we also believe to be a novel WO3 as a buffer layer is proposed for the first time for the efficiency enhancement of CBTS thin film solar cells. Numerical investigation of the performance of CBTS-based solar cells without and with cuprous oxide (Cu2O) back surface field (BSF) is explored. The impact of thickness, doping density, bulk, and interface defect density of an absorber, buffer and window layer, working temperature, shunt and series resistance, back contact work function, and back surface recombination velocity were analyzed and optimized without and with the BSF layer. In this work, the optimized solar cell achieved an efficiency of 18.8%, fill factor (FF) of 83.79%, short-circuit current density (JSC) of 15.99 mA/cm2, and open circuit voltage (VOC) of 1.4 V without Cu2O BSF layer at optimal CBTS absorber and WO3 buffer layer thickness of 2 µm and 0.04 µm respectively. Furthermore, the efficiency boosted to 21.12% with VOC of 1.43 V, JSC of 16.8 mA/cm2 and FF of 87.77% by inserting 0.1 µm Cu2O BSF layer. Therefore, these results will facilitate the fabrication of an efficient and low-cost CBTS-based solar cell with promising WO3 and Cu2O as buffer and BSF layer, respectively.

Analytical Model for Heat Transfer Around Energy Piles in Layered Soil With Interfacial Thermal Resistance by Integral Transform Method

ABSTRACTEnergy piles are commonly deployed in vertically layered geological conditions due to the geological structure and pile foundation backfill. The imperfect contact between adjacent soil layers results in resistance to heat transfer at the interface, known as the interfacial thermal resistance effect. In this paper, the energy pile was simplified as a finite‐length solid cylindrical heat source, and an analytical model was established for layered heat transfer of energy piles considering the interfacial thermal resistance effect. The Laplace‐domain solutions to the temperatures in the layered ground were derived by using the finite Hankel and Laplace transforms. The Crump method was subsequently employed to numerically invert Laplace‐domain solutions to the time‐domain solutions. The proposed model was validated by comparing with an analytical solution of a homogeneous model and COMSOL numerical solution. These solutions were used to analyze the temperature response around energy piles considering interfacial thermal resistance. Finally, a parametric study was performed to explore the effects of interfacial thermal resistance and other thermal properties of the soil layer on the layered heat transfer of energy piles.

Honeycomb‐Structured IrOx Foam Platelets as the Building Block of Anode Catalyst Layer in PEM Water Electrolyzer

AbstractAchieving robust long‐term durability with high catalytic activity at low iridium loading remains one of great challenges for proton exchange membrane water electrolyzer (PEMWE). Herein, we report the low‐temperature synthesis of iridium oxide foam platelets comprising edge‐sharing IrO6 octahedral honeycomb framework, and demonstrate the structural advantages of this material for multilevel tuning of anodic catalyst layer across atomic‐to‐microscopic scales for PEMWE. The integration of IrO6 octahedral honeycomb framework, foam‐like texture and platelet morphology into a single material system assures the generation and exposure of highly active and stable iridium catalytic sites for the oxygen evolution reaction (OER), while facilitating the reduction of both mass transport loss and electronic resistance of catalyst layer. As a proof of concept, the membrane electrode assembly in single‐cell PEMWE based on honeycomb‐structured IrOx foam platelets, with a low iridium loading (~0.3 mgIr/cm2), is demonstrated to exhibit high catalytic activity at ampere‐level current densities and to remain stable for more than 2000 hours.

Honeycomb-Structured IrOx Foam Platelets as the Building Block of Anode Catalyst Layer in PEM Water Electrolyzer.

Achieving robust long-term durability with high catalytic activity at low iridium loading remains one of great challenges for proton exchange membrane water electrolyzer (PEMWE). Herein, we report the low-temperature synthesis of iridium oxide foam platelets comprising edge-sharing IrO6 octahedral honeycomb framework, and demonstrate the structural advantages of this material for multilevel tuning of anodic catalyst layer across atomic-to-microscopic scales for PEMWE. The integration of IrO6 octahedral honeycomb framework, foam-like texture and platelet morphology into a single material system assures the generation and exposure of highly active and stable iridium catalytic sites for the oxygen evolution reaction (OER), while facilitating the reduction of both mass transport loss and electronic resistance of catalyst layer. As a proof of concept, the membrane electrode assembly in single-cell PEMWE based on honeycomb-structured IrOx foam platelets, with a low iridium loading (~0.3 mgIr/cm2), is demonstrated to exhibit high catalytic activity at ampere-level current densities and to remain stable for more than 2000 hours.

Microstructure and friction properties of NiTi2-based composite layer prepared by ultrasonic assisted underwater wet laser deposition

An in situ TiC-enhanced NiTi2-based composite deposition layer was prepared by ultrasonic assisted underwater wet laser deposition. The evolution of the microstructure and interface state, and the friction properties in the air and brine solution environments of the deposition layer were analyzed and researched. The results demonstrated that the thermal and steady-state cavitation from ultrasound effects increase the total energy of the melt pool and promote mixing. The dilution rate of the ultrasonic assisted underwater laser deposition layer increases to 86.72 % compared with that of the underwater laser deposition layer (78.75 %). Ultrasonic reduced underwater laser deposition defects such as lack of fusion and weld slag, and enhanced the wettability between the deposition layer and substrate. The contact angle of the UWNT layer (24.40°, in average) is smaller than the WNT layer (29.80°, in average). Ultrasonic shortened the contact time between the deposition layer surface and the solution, which reduced the reaction of the Ni element with the brine solution. It also transformed the deposition layer from hypereutectoid microstructure to hypoeutectic microstructure and from planar interface to cellular interface. With the effect of the ultrasonic field, the elements in the deposition layer become more uniformly distributed and the secondary phases undergo spheroidization. In the ultrasonic assisted deposition layer, stress-induced FCC-Ti was discovered. Ultrasonic field also reduced the dispersion of the microhardness and increased the average microhardness to 863.3 ± 45.1 HV0.3. Tribology properties show that ultrasonic field effectively improved the wear resistance and friction stability of the ultrasonic assisted deposition layer. The COF of the ultrasonic assisted deposition layer was less affected by the environment, with values of 0.25 and 0.24 observed in air and brine solution, respectively. Overall, the research results in this paper can provide a new insight to improve the surface properties of NiTi2-based alloy underwater laser deposition.

Geoelectrical resistivity mapping for sustainable groundwater management in Umuahia South: Insights from vertical electrical sounding

The study of geoelectrical resistivity provides critical insights into subsurface characteristics and aquifer dynamics, particularly in regions with varying geological formations. This research investigates the geoelectrical properties of the aquifer system in Umuahia South, highlighting its significance for sustainable groundwater management. The primary aim of this study is to characterize the geoelectrical layers, assess aquifer thickness and resistivity, and evaluate the implications for groundwater resource management. Vertical Electrical Sounding (VES) was conducted across ten locations to measure the resistivity and thickness of subsurface layers. The data collected were analyzed to identify distinct geoelectrical layers, their respective resistivity values, and thicknesses. The study reveals significant variations in aquifer properties across the region, with VES 1 showcasing the largest thickness of 69.2 m and VES 9 the smallest at 5.2 m. Aquifer thickness decreases from the Benin Formation toward the Ameki and Ogwashi-Asaba Formations. Hydraulic conductivity ranges from 0.207 to 0.954 m/day, indicating varying groundwater flow potential, while transmissivity values vary from 4.965 to 30.441 m²/day, with 60% of aquifers classified as intermediate. Groundwater Potential Index (GWPI) highlights approximately 70% of the area as high potential, underscoring the need for targeted management strategies to optimize water resource extraction and sustainability. The variability in resistivity and thickness across the study area suggests significant subsurface heterogeneity. High resistivity values indicate favorable conditions for groundwater flow, particularly in areas like VES 6. Conversely, lower resistivity in locations such as VES 9 indicates potential challenges for groundwater storage. This study provides vital information on the aquifer system in Umuahia South, emphasizing the need for targeted groundwater management strategies based on the geoelectrical characteristics identified. The research contributes to a deeper understanding of the aquifer dynamics in the region and offers a framework for sustainable groundwater resource management, highlighting the importance of geoelectrical assessments.

A low-cost device for measuring TEER at cultivation of epithelial/endothelial cells on inserts.

Background: The barrier properties of epithelial and endothelial cells are usually studied in vitro when cells are cultured on mesh inserts in culture plates, and it is necessary to assess the state of the cell monolayer on the membrane of the inserts before the experiment. Typically, monolayer density is analyzed by passing a fluorescent label through the insert with cells or by measuring the transendothelial resistance (TEER) of the cell layer. Many studies use both methods of assessing monolayer integrity in parallel, depending on the purpose of the study. The TEER method also allows to record early changes in the monolayer state under the action of various substances. Aim of this work is to demonstrate the possibility of TEER measurements using the proposed device (conductometer) made from freely available components using endothelial/epithelial cells as an example. Materials and Methods. A device (conductometer) for measuring TEER, created on the basis of easily accessible components, is presented. The device was tested by culturing two cell lines – hybridoma of endothelial origin Ea.hy926 and human colon adenocarcinoma Caco-2. Caco-2 cells were cultured for 22 days and Ea.hy926 cells were cultured for 7 days. The integrity of the cell monolayer and the density of intercellular contacts were evaluated by the TEER value determined by the proposed conductometer, as well as by the fluorescein permeability of the cell monolayer. Results: The results of TEER measurements using the proposed device and at the same time, the fluorescein permeability of the cell monolayer during the cultivation of Caco-2 and EA.hy926 cells are presented. For Caco-2 cells from the moment of 100% confluence the TEER value gradually increased reaching maximum values by 20-21 days, after which it decreased slightly. The permeability values decreased as the cells were cultured, indicating the formation of dense contacts. For EA.hy926 cells the rise in TEER values are observed on day 3 and decrease was observed on day 7. The results of TEER and permeability obtained by the proposed conductometer have a strong inverse correlation for both cell lines and are in good agreement with each other. Conclusions. The presented device, made on the basis of simple and affordable components, is similar to commercially available devices and can be used to study the integrity and density of a monolayer in the cultivation of epithelial/endothelial cells, to study the processes of trans/paracellular transport under the action of various substances, as well as in experiments with the co-cultivation of various cell lines.

Fabrication and Characterization of Biocompatible Multilayered Elastomer Hybrid with Enhanced Water Permeation Resistance for Packaging of Implantable Biomedical Devices

This study presents the synthesis and characterization of hexadecyl-modified SiO2 (HD-SiO2) nanoparticles and their application in the fabrication of a multilayered elastomer hybrid sheet to enhance water resistance in implantable biomedical devices. The surface modification of SiO2 nanoparticles was confirmed via FT-IR and TGA analyses, showing the successful grafting of hydrophobic hexadecyl groups. FE-SEM and DLS analyses revealed spherical HD-SiO2 nanoparticles with an average size of 360 nm. A multilayered elastomer hybrid sheet, consisting of a PDMS-based circuit-protecting body, a water resistance layer of HD-SiO2, a planarization layer, and a biocompatible layer of polydopamine, was fabricated and characterized. The water resistance layer exhibited superhydrophobic properties, with a water contact angle of 154.7° and a 27% reduction in water vapor transmission rate (WVTR) compared to the circuit-protecting body alone. The device packaged with both the circuit-protecting body and water resistance layer demonstrated a tenfold increase in operational lifespan in water medium compared to the device without the water resistance layer. Cytotoxicity and cell proliferation tests on human dermal fibroblast cells (HDFn) confirmed the biocompatibility of the multilayered sheet, with no significant cytotoxicity observed over 48 h.

Carrier Scattering Analysis in AlN/GaN HEMT Heterostructures with an Ultrathin AlN Barrier

Experimental AlN/GaN heterostructures (HSs) with an ultrathin AlN barrier were obtained using molecular beam epitaxy with plasma activation of nitrogen. The layer resistance of the optimized structures was less than 230 Ω/¨. The scattering processes that limit the mobility of two-dimensional electron gas in undoped AlN/GaN HSs with an ultrathin AlN barrier have been studied. It is shown that in the ns range characteristic of AlN/GaN HEMT HSs (ns 1 × 1013 cm–2), a noticeable contribution to the scattering of charge carriers is made by the roughness of the heterointerface.

An improved 4H-SiC trench MOS barrier Schottky diode with current spreading layer and low resistance layer

This paper investigates an improved trench MOS barrier Schottky (TMBS) structure with extra double epitaxial layers (DE-TMBS) based on the conventional TMBS (C-TMBS) featuring a high-doped N-type current spreading layer (CSL) and a high-doped low resistance layer (LRL). Compared to the C-TMBS, the CSL in the improved structure is grown on the N-type drift region, and the LRL is extended on the CSL. According to the numerical simulations and analytical models, the specific on-resistance (Ron,sp) of DE-TMBS can be significantly reduced compared to the conventional one. This is primarily due to the high doping concentration in CSL, which effectively lowers both the JFET resistance and spreading resistance. Additionally, the increased doping concentration in LRL reduces the channel resistance and JFET resistance. Moreover, the doping concentration and thickness of CSL and LRL are optimized to maximize the figure of merit (FOM), that Ron,sp is reduced by 40.9 % and the FOM (BV2/Ron,sp) is improved by 67.9 % compared to the C-TMBS structure.

Microstructure and properties of TiC ceramic powder on a cobalt-based alloy obtained via electromagnetic-assisted laser metal deposition

The crack sensitivity of laser metal ceramic deposition is an important factor restricting its development. In this paper, a TiC-reinforced cobalt-based alloy was deposited on 300M steel using electromagnetic-assisted laser metal deposition technology. The electromagnetic composite effect on the microstructure, mechanical properties, magnetic properties, wear resistance and crack sensitivity of the laser metal deposition layer was discussed. Under the action of an electromagnetic field, the size of the TiC decreased by 54.6% compared with that of the deposited layer without an electromagnetic field. The effect of the electromagnetic composite field can reach the bottom of the molten pool, thus refining the grain size at the bottom of the coating. This resulted in a 22% increase in the hardness of the deposition layer. The electromagnetic field effect reduces the elastic modulus of the deposition layer, thus improving the mechanical properties of the coatings. In addition, compared with that of the deposition layer without an external field, the wear of the deposition layer with an electromagnetic force is obviously reduced. With increasing electromagnetic parameters, the wear resistance of the deposit increased gradually, and the thermal expansion coefficient decreased significantly, which played an important role in improving the crack resistance and comprehensive properties of the deposition layer under extreme working conditions.

Eutectic resolidification and ultrafast self-quenching of the microstructure in the surface layer of high-speed steel by scanning electron beam treatment

Improving the service life and efficiency of high-speed steel (HSS) tools remains a formidable challenge. Herein, scanning electron beam (SEB) was employed to modify the surface of M2 HSS. Results revealed that SEB induced eutectic resolidification and ultrafast self-quenching of microstructure in surface layer of HSS. The melted layer exhibited a microstructure comprising martensite, residual austenite, dispersed finely rod-like MC and lamellar M2C eutectic carbides along grain boundaries. Martensite and eutectic carbide grid structure significantly enhanced the hardness and wear resistance of surface layer. Compared to substrate, the microhardness of SEB sample was elevated by more than threefold, reaching 914.7HV0.2, which exceeded the hardness (828.6HV0.2) of conventional quenching treatment. Notably, the wear volume of SEB sample had been reduced to 0.54 × 10−11 m3, resulting in a wear resistance that was 3.8 times greater than that of quenched sample.

Coulomb drag induced non-local resistance in double graphene layers.

We study the effect of Coulomb drag between graphene layers in presence of viscosity term. To do this, we use the simple model of Stokes equations for drift velocities in active and passive layers, known as Pogrebinskii's approach. The solution to these equations allows us to find the potential distribution, and thus the non-local drag resistance of passive layer. It is shown that in viscous regime the non-local resistance may take negative values, in contrast, the ohmic regime results in positive non-local resistance for all drag strengths. Additionally, we discuss the influence of magnetic field on the non-local drag magnetoresistance.

Reliable fabrication of 3D freestanding nanostructures via all dry stacking of incompatible photoresist

Three-dimensional (3D) free-standing nanostructures based on electron-beam lithography (EBL) have potential applications in many fields with extremely high patterning resolution and design flexibility with direct writing. In numerous EBL processes designed for the creation of 3D structures, the multilayer resist system is pivotal due to its adaptability in design. Nevertheless, the compatibility of solvents between different layers of resists often restricts the variety of feasible multilayer combinations. This paper introduces an innovative approach to address the bottleneck issue by presenting a novel concept of multilayer resist dry stacking, which is facilitated by a near-zero adhesion strategy. The poly(methyl methacrylate) (PMMA) film is stacked onto the hydrogen silsesquioxane (HSQ) resist using a dry peel and release technique, effectively circumventing the issue of HSQ solubilization by PMMA solvents typically encountered during conventional spin-coating procedures. Simultaneously, a dry lift-off technique can be implemented by eschewing the use of organic solvents during the wet process. This pioneering method enables the fabrication of high-resolution 3D free-standing plasmonic nanostructures and intricate 3D free-standing nanostructures. Finally, this study presents a compelling proof of concept, showcasing the integration of 3D free-standing nanostructures, fabricated via the described technique, into the realm of Fabry-Perot cavity resonators, thereby highlighting their potential for practical applications. This approach is a promising candidate for arbitrary 3D free-standing nanostructure fabrication, which has potential applications in nanoplasmonics, nanoelectronics, and nanophotonics.

Bubble Printing of Liquid Metal Colloidal Particles for Conductive Patterns.

Bubble printing is a patterning method in which particles are accumulated by the convection of bubbles generated by laser focusing. It is attracting attention as a method that enables the high-speed, high-precision patterning of various micro/nanoparticles. Although the bubble printing method is used for metallic particles and organic particles, most reports have focused on the patterning of solid particles and not on the patterning of liquid particles. In this study, liquid metal wiring patterns were fabricated using a bubble printing method in which eutectic gallium‒indium alloy (EGaIn) colloidal particles (≈diameter 0.7 µm) were fixed on a glass substrate by generating microbubbles through heat generation by focusing a femtosecond laser beam on the EGaIn colloidal particles. The wiring was then made conductive by replacing gallium oxide, which served as a resistance layer on the surface of the EGaIn colloidal particles, with silver via galvanic replacement. Fine continuous lines of liquid metal colloids with a line width of 3.4 µm were drawn by reducing the laser power. Liquid metal wiring with a conductivity of ≈1.5 × 105 S/m was formed on a glass substrate. It was confirmed that the conductivity remained consistent even when the glass substrate was bent to a curvature of 0.02 m-1.

Assessing thermal resistance in fusion bond layers of 3D heterogeneous electronics packaging

We investigated thermal management challenges in semiconductor devices that use fusion bonding, with a focus on measuring the thermal resistance of the bonded interface. Starting with two fusion-bonded silicon wafers, we thinned the top wafer to below 100 μm and used frequency domain thermoreflectance to measure the effective thermal boundary resistance of the fusion bond. We established the measurement uncertainty with a multilayer thermal diffusion model, considering the effects of the top Si layer thickness and laser spot size. The thermal boundary resistance was measured to be 0.2 and 0.5 m2K/MW for two types of bonded wafers, with total SiO2 film thicknesses of 200 and 470 nm at the fusion bond layer, respectively. We also created defects at the interface and imaged these defects with the thermal phase response at specific frequencies chosen according to a thermal model. The method described can be applied to other types of wafer-to-wafer or die-to-die bonding including direct, polymeric, and metallic bonds.

Study on bearing characteristics of single pile in heterogeneous layered foundation

Based on a project in Lanzhou City, Gansu Province, China, the bearing and internal force characteristics of 2 piles of different lengths under vertical load were tested and analyzed by using BOFDA technology and anchor pile method static load test. The results show that long pile has higher vertical bearing capacity and greater elastic working range, but the axial force of long pile and short pile has the same trend. The lateral friction resistance of the soil layer around the pile plays a role earlier than the pile tip resistance, and the lateral friction resistance of the upper soil layer plays a role earlier than the lower soil layer. The increasing amplitude of lateral friction resistance in different soil layers is also different. The settlement of short pile top is mostly caused by the displacement of pile bottom, and the pile tip resistance is more affected by the pile tip sediments. The relationship between pile end resistance and displacement under the influence of sediments can be analyzed by three-fold line model.

Presenting a transdisciplinary robust approach for comprehensive assessment of large-scale underground water resources in western Indo-Gangetic Basin

Overexploitation, pollution, and anthropogenic activities threaten the sustainability of groundwater resources in the western Indo-Gangetic Basin. Meanwhile, distinguishing regions prone to contamination and understanding the natural and anthropogenic factors affecting groundwater quality is challenging due to the heterogeneous nature of aquifer systems and the lack of high-resolution spatial and temporal data on aquifer protective hydrogeological layers. This study presents a transdisciplinary robust approach combining regional electrical resistivity surveys, hydrogeological data, physicochemical analyses, and geospatial datasets to identify regions prone to contamination and understand the impacts of natural and anthropogenic factors on groundwater resources. This approach involves three key steps: evaluating the geohydraulic nature of aquifer protective hydrogeological layers, mapping the aquifer vulnerability index (AVI), and conducting comparative analyses of potentially vulnerable areas with groundwater quality index (GWQI) and hydrological factors. Firstly, model-based inversion of ID Vertical Electrical Sounding (VES) data provides insights into geoelectrical indices such as depth, thickness, apparent resistivity, longitudinal conductance, transverse resistance, and longitudinal resistivity of aquifer protective hydrogeological layers. Second, the Artificial Neural Network (ANN) model is used as a multilayer perceptron network to simulate hydraulic conductivity (K) using geoelectrical indices of aquifer protective hydrogeological layers. Subsequently, by considering ANN-derived K and VES-derived h of aquifer protective hydrogeological layers, the dynamic hydraulic resistance to the vertical flow of wastewater through the protective hydrogeological layers evaluated the index of the potentially vulnerable areas. Comparative analyses of potentially vulnerable areas with GWQI and hydrological factors (e.g., digital elevation model, soil, drainage density, lineament density, slope) enhance understanding regions prone to contaminants and land surface stress. Findings show that the ANN approach to simulate K, reducing effort with costs associated with slug testing is significant for AVI assessment. Furthermore, the geohydraulic characteristics, vulnerability indexing, and comparative analyses assist in identifying contamination-prone areas, improving groundwater resource protection and exploration activities.

Nanoscale friction and wear of graphite surface in ambient and underwater conditions

The tribological properties of graphite are extremely sensitive to surrounding environment, which affects its longevity and friction reduction performance. This study aims to develop a comprehensive understanding of the effects of a liquid environment on interactions at the sliding interface, thereby influencing the nanoscale tribological properties of graphite surfaces. By combining atomic force microscopy experiments and molecular dynamics simulations, we conducted a comparative analysis of friction and wear behavior of graphite under two different environmental conditions: ambient (air) and underwater condition. Our investigations explored both the step edge and interior (step-free) graphite surfaces. The experimental results revealed a notable contrast in the frictional and wear behavior of graphite at nanoscale in these two environments. The interior surface exhibited a friction coefficient (COF) of approximately 0.003 and 0.006 against a diamond-coated surface in ambient and underwater conditions, respectively. Interestingly, the underwater environment not only increased friction but also significantly compromised the wear resistance of graphene layers near the graphite surface compared to the ambient environment, as evidenced in both step edge and interior step-free regions. The interior region sustained up to ∼7400 nN load in ambient condition but failed at ∼1500 nN under water. Similarly, the step edge failed at ∼375 and ∼187.5 nN in ambient and underwater conditions, respectively. Our simulations revealed that the increased friction in underwater condition is due to resistance of surrounding water molecules during tip sliding. The presence of water at tip-graphite contact interface generated substantial localized stress, leading to the initiation of wear and revealing the pronounced effect of water on the wear characteristics of graphite in underwater condition.