Resin System Research Articles

Evaluating priority strategies for decarbonising offshore wind turbine blades through lifecycle assessment

Abstract While offshore wind is at the early stage of expansion, global capacity is expected to increase rapidly, reaching 330 GW by 2031. This work uses lifecycle assessment (LCA) to evaluate the opportunity for offshore wind energy decarbonisation through wind blade sustainable developments. The findings from the LCA are used to give informed recommendations towards priority areas of development across the blade lifecycle, that are critical to accelerate the sector’s transition towards net-zero targets. The production of raw materials was found to be the largest contributor to cradle-to-gave global warming potential (GWP). The sector should prioritise the utilisation of more sustainable materials, with an emphasis on the decarbonisation of carbon fibre production. Waste produced during blade manufacturing alone accounts for 10% of the blade’s GWP; therefore, increasing the material efficiency in this phase of the lifecycle is a significant opportunity for blade decarbonisation and should be a focus for the sector going forward. O&M was found to be the second largest contributor to GWP, with full decarbonisation of O&M practices potentially realising an 8% reduction in GWP. A range of alterative blade material scenarios were analysed, finding that recyclable resin systems have the greatest potential to decarbonise offshore blades. There are currently no commercial recycling operations for these resins therefore scale up of the recycling technologies is needed before they can be recycled in practice. Additionally, the development of low impact, economically viable circular solutions for legacy blade waste must be an immediate priority for the wind energy sector, given the anticipated exponential growth in global wind turbine blade waste generation. Graphical abstract

Mitigating aging infrastructure risks: An optimized epoxy resin system for water supply pipeline rehabilitation

Urban water supply networks are crucial for ensuring the delivery of safe drinking water to urban populations; however, the aging infrastructure in these systems has led to a rising incidence of leaks and frequent pipeline failures, posing serious risks. Traditional repair approaches encounter limitations in terms of efficiency, durability, and environmental safety, particularly when employed in potable water pipelines. To address these challenges, we developed a novel multi-component amine-cured epoxy resin system specifically optimized for in-situ curing under ambient conditions. This study comprehensively examines the mechanical properties, water absorption behavior, and curing kinetics of this resin system, formulated to reduce volatile organic compound emissions while enhancing durability under prolonged water exposure. Experimental findings demonstrate that the E2 formulation exhibited superior tensile strength, flexural properties, and fracture toughness relative to other formulations, with a two-stage water absorption model accurately predicting resin behavior in moisture-laden environments. Moreover, finite element modeling and laboratory testing confirmed the influence of bubble defects on mechanical performance, and a negative pressure defoaming technique effectively reduced defect volume, resulting in a 17.6% improvement in tensile strength. Collectively, this research advances the practical application of rapid-curing resins, offering a resilient, safe, and sustainable solution for the rehabilitation of aging water pipeline networks.

Preparation and performance comparison of low‐dielectric epoxy resins cured by naphthalene‐ and phenyl‐based active esters

AbstractThe poor dielectric properties of epoxy resins limit their application in microelectronics, and active ester curing agent is an effective means to enhance the dielectric properties of epoxy resins. However, the phenyl active ester curing resins nowadays have the problem of low mechanical properties. In this work, a novel naphthalene‐based active ester‐cured resveratrol epoxy resin system (REP/NDA) was prepared for the first time. Compared with the phenyl‐active ester‐cured epoxy resin (REP/PDA), the naphthyl‐active ester prepared epoxy resin has obvious advantages in mechanical properties. The experimental results indicated a tensile strength measurement for REP/NDA at 91.9 MPa, the tensile strength of REP/PDA was 65.3 MPa, and the tensile strength of REP/NDA was 141% of that of REP/PDA. The prepared REP/NDA epoxy resin exhibits favorable dielectric properties, evidenced by a dielectric constant of 3.02 at 10 MHz and a dielectric loss of 0.0042, very good thermal stability (T5% of 379°C), excellent water absorption (only 0.49% for 7 days from 2 to 8°C) and good dimensional stability (coefficient of thermal expansion below Tg of 77 ppm). The first synthesis of naphthalene‐based active ester curing agent offers a reference for creating new low dielectric epoxy resin materials that work out exceptionally.

Flame retardant, transparent, low dielectric and low smoke density EP composites implemented with reactive flame retardants containing P/N/B

For the purpose of investigating the modified flame-retardant epoxy resin (FREP) with the low smoke density release during combustion, the flame retardant containing P/N/B elements named DBT was synthesized with the raw materials of 4-Acetylphenylboronic acid, 3,5-diaminotriazole and DOPO. The DBT was added as a co-curing agent to an amine-cured epoxy resin system, and based on the DSC results of the resin, it was revealed that -NH- in the structure of the DBT was capable of facilitating EP curing. With the introduction of DBT, the transparency of FREP samples was slightly affected. On account of the excellent flame retardancy exerted by the DBT in the FREP system, the FREP samples reached the V-0 grade in UL-94 testing with an LOI of 35.9% at 5 wt% DBT addition. Meanwhile, the results of the cone calorimetry test demonstrated that in comparison with the epoxy resin, the PHRR, THR and av-EHC of the EP/DBT7.5 sample decreased by 34.0%, 35.4% and 18.68%, respectively. The DBT was effective in reducing the smoke density of EP, and the EP/DBT7.5 sample attained the HL1 level for DS (4) and VOF4. The chemical analyses for residual char revealed that DBT was mainly employed for flame retardancy and smoke suppression by forming P/B-containing chars in the condensed phase. There was no loss of mechanical properties of the FREP samples as the rigid groups were present in the DBT structure. Furthermore, it was noted that the FREP samples exhibited a decrease in dielectric loss and dielectric constant as the content increased.

Root-filling materials for endodontic surgery: biological and clinical aspects

The placement of root filling materials aims to prevent the occurrence of post-treatment apical periodontitis following completion of endodontic treatment. Materials should possess properties that will not permit bacterial invasion and infection, namely excellent sealing ability and/or antibacterial properties. In root-end filling procedures or repair of root perforations, the root filling materials are placed in a particularly challenging clinical environment, as they interface with a relatively large area with the periradicular tissues. The biological properties of these materials are therefore of significant importance. The current review discusses the most widely used materials for endodontic surgery (i.e., root-end filling and perforation repair), with particular focus on their biological characteristics, namely antibacterial properties and interactions with host tissue cells, together with clinical studies. Properties of amalgam, glass ionomer cements (GICs), resin systems, zinc oxide eugenol-based cements and hydraulic calcium silicate cements (HCSCs), together with representative and well-researched commercial materials in the context of their use in endodontic surgery are presented. While the use of HCSCs seems to offer several biological advantages, together with addressing issues with the initial formulation in the most recent versions, materials with different chemical compositions, such as zinc oxide eugenol-based cements, are still in use and appear to provide similar clinical success rates to HCSCs. Thus, the significance of the currently available materials on clinical outcomes remains unclear.

Biocompatibility and performance of new generation dental composites

Dental composites have undergone significant advancements in recent years, with new-generation materials being developed to improve both biocompatibility and mechanical performance. These innovations have led to the increased use of dental composites in restorative dentistry, particularly in both anterior and posterior restorations. Biocompatibility remains a key concern, as the release of unreacted monomers, such as bisphenol A glycidyl methacrylate (Bis-GMA), can cause local tissue irritation or systemic effects. Modern composites aim to reduce these risks by incorporating alternative resin systems and advanced photo initiators. Nanotechnology has further enhanced the performance of these materials by improving mechanical strength and wear resistance, but questions about the safety of nanoparticles and their long-term biological effects continue to be explored. In addition to biocompatibility, the mechanical properties of new-generation composites have been significantly optimized. The introduction of bulk-fill composites allows for deeper polymerization and faster placement, reducing clinical procedure times while maintaining high mechanical integrity. Polymerization shrinkage, a common issue in traditional composites, has been minimized in newer formulations, reducing the risk of marginal gaps and microleakage. The effectiveness of different light-curing units, such as light-emitting diode (LED) versus halogen lights, plays a crucial role in achieving optimal polymerization depth, especially in posterior restorations where light penetration can be limited. Long-term clinical outcomes depend on several factors, including material choice, placement technique, and patient adherence to oral hygiene. Despite the improvements in composite materials, the longevity of restorations still faces challenges such as wear, fracture, and degradation over time. Continued research into the safety, effectiveness, and clinical performance of new-generation composites is essential to ensuring patient safety and enhancing the durability of restorations in the future. These advancements promise to address many of the limitations seen in earlier dental materials while offering superior performance and patient satisfaction.

Curing reactions, reaction kinetics, and latency of epoxy resin cured with L‐tryptophan and L‐tyrosine

AbstractIn the research on amino acids as bio‐based curing agents for epoxy resins, L‐tryptophan and L‐tyrosine have emerged as promising alternatives. Understanding the curing reactions and reaction kinetics is crucial for designing an appropriate curing regime to tailor the mechanical properties of thermosets. This study provides a comprehensive analysis of the curing reactions, curing kinetics, and latency of epoxy resin cured with L‐tryptophan or L‐tyrosine in the presence of urea‐based accelerators. L‐tryptophan involves three distinct curing reactions, corresponding to its three functional groups, while data on L‐tyrosine as a curing agent is less definitive. The degree of cure can be reliably predicted using model‐free kinetics for all resin systems studied. Overall, the inclusion of accelerators facilitates rapid curing at elevated temperatures while maintaining adequate processability for up to four weeks of storage at room temperature.

Molecular insights of DGEBA/MeTHPA three-dimensional resin network from design to heat transfer mechanism: Dynamic simulation and experimental research

The epoxy resin composed of bisphenol A diglycidyl ether (DGEBA) and methyl tetrahydrophthalic anhydride (MeTHPA) has been found to enhance its thermal conductivity by increasing its molecular weight and crosslinking density. This was achieved through experiments and all-atom molecular dynamics simulations. Molecular dynamics was employed to calculate the root-mean-square displacement, free volume fraction, potential energy, density, and quantity of hydrogen bonds. The results showed the influence of molecular weight and crosslinking density on the system's thermal conductivity. The results showed that the high molecular weight epoxy resin system exhibited high thermal conductivity at elevated crosslinking densities. During the crosslinking process, the epoxy resin's thermal conductivity increased, starting with the center portion weakening and then strengthening. In addition, a simulation-verified free volume was found to have an inversely proportional connection with thermal conductivity. This study explored the thermal conductivity mechanism of epoxy resin by analyzing the structural changes at the micro level and correlating them with the changes in thermal conductivity at the macro level to enhance guidance for industrial production and practical application.

The Effect of Inorganic Filler Content on the Properties of BPA-Free Bulk-Fill Dental Resin Composites.

This study aimed to enhance the performance of dental resin composites (DRCs) by increasing the content of inorganic fillers while addressing potential health risks associated with Bisphenol A (BPA). To achieve this, the BPA-based resin monomer Bis-GMA was replaced with BPA-free Bis-EFMA. The study then explored the impact of varying inorganic filler contents on the physiochemical properties of Bis-EFMA-based bulk-fill dental resin composites (BF-DRCs). Four distinct Bis-EFMA-based BF-DRCs were formulated, each with different inorganic filler contents ranging from 70 wt% to 76 wt%. The study tested the depth of cure (DOC), double-bond conversion (DC), water sorption (WS), solubility (SL), and cytotoxicity of the system. It notably investigated the effects of increasing filler content on mechanical properties through flexural strength (FS), flexural modulus (FM), Vickers microhardness (VHN), and wear resistance, as well as the impact on polymerization shrinkage, including volumetric shrinkage (VS) and shrinkage stress (SS). To assess the commercial application potential of Bis-EFMA-based BF-DRC, the research used the commercially available BF-DRC Filtek Bulk-Fill Posterior (FBF) as a control. The results indicated that a higher filler content did not affect the DOC of Bis-EFMA-based BF-DRCs. Inorganic fillers at higher concentrations significantly enhanced overall mechanical properties while significantly reducing volumetric shrinkage (VS; p < 0.05). When the concentration of inorganic fillers in the resin system reached 76 wt%, most of the performance of the Bis-EFMA-based BF-DRC surpassed that of the commercial control FBF, except for FS, FM, and SS. These findings highlight the potential of Bis-EFMA-based BF-DRC as a long-term restorative material for dental applications.

Bubble-Free Frontal Polymerization of Acrylates via Redox-Initiated Free Radical Polymerization.

Thermal frontal polymerization (FP) of acrylate monomers mixed with conventional peroxide initiators leads to significant bubble formation at the polymerizing front, limiting their practical applications. Redox initiators present a promising alternative to peroxide initiators, as they prevent the formation of gaseous byproducts during initiator decomposition and lower the front temperature, thereby enabling bubble-free FP. In this study, we investigate the FP of acrylate monomers of varying functionalities, including methyl methacrylate (MMA), 1,6-hexanediol diacrylate (HDDA), and trimethylolpropane triacrylate (TMPTA), using N,N-dimethylaniline/benzoyl peroxide (DMA/BPO) redox couple at room temperature and compare their front behavior, pot life, and bubble formation with those of same resin systems mixed with a conventional peroxide initiator, Luperox 231. The use of redox couples in FP of acrylates shows promise for rapid, energy-efficient manufacturing of polyacrylates and can enable new applications such as 3D printing and composite manufacturing.

A novel biobased prepreg from flax and thermosetting poly(lactic acid): Synthesis, curing and processing

Flax fiber-reinforced thermosetting poly (lactic acid) (PLA) composites, a fully degradable plant fiber-reinforced composites, were prepared by hot-melt pre-impregnation, which consists of two processes, the preparation and curing of the prepreg. Firstly, thermosetting PLA with intrinsic flame-retardancy was synthesized and its molecular structure was verified by Fourier transform infrared spectroscopy and nuclear magnetic resonance hydrogen spectroscopy. The non-isothermal viscosity of the thermosetting PLA resin system was investigated to determine the film-formation temperature (55°C) and the impregnation temperature (65°C) during the preparation of the prepreg. On this basis, novel flax fiber-reinforced thermosetting PLA prepreg was prepared and its curing kinetics was investigated using differential scanning calorimetry (DSC). A curing simulation model of the prepreg was developed using the finite difference method, which was used to design and optimize the curing cycle of the flax fiber-reinforced thermosetting PLA prepreg. Finally, the flax fiber-reinforced thermosetting PLA composites with different lay-ups were prepared using the optimal curing cycles and their mechanical and flame retardant properties were investigated, with tensile and flexural strengths up to 128 MPa and 98.8 MPa, and flame retardant ratings up to UL-94 V-1. Overall, the results of this study can provide an important basis for expanding the application of flax fiber reinforced thermosetting PLA composites.

Influence of different composite curing agents on the rapid curing characteristics and mechanical performance of epoxy resins

To address the need for rapid in situ plugging and repair of hydraulic machinery and chemical pipelines and to resolve the issue that a single curing agent cannot simultaneously achieve rapid curing and excellent mechanical properties in epoxy resin systems, this study explores the use of composite curing agents. In particular, effective formulations are designed for mixing fast and slow curing agents, studying their effects on the curing behavior, curing quality, and mechanical properties of epoxy resins and elucidating their influence mechanisms. The results indicate that three resin systems meet the requirements for rapid curing (curing time within 30 min): 4A6B/EP, 2A8B/EP, and 0A10B/EP. Among them, 4A6B/EP exhibits the best curing quality and mechanical properties. In particular, 4A6B/EP demonstrates the lowest values of curing shrinkage rate, internal curing stress, average pore size, porosity, and cumulative pore volume. Its low internal stress and low defects reduce the stress concentration, while more efficient deflection and branching of internal cracks enhance its deformation resistance. Consequently, 4A6B/EP shows the highest microhardness, fracture toughness, tensile strength, Young’s modulus, and elongation after fracture. Based on the comprehensive evaluation of rapid curing characteristics and mechanical properties, the 4A6B/EP system offers the best overall performance. Therefore, it is recommended as the preferred resin system for rapid plugging and repair of composite materials, providing a theoretical basis and technical support for boosting the application of epoxy resin composite materials in high-tech fields.

Preparation and Application of a Novel Liquid Oxygen-Compatible Epoxy Resin of Fluorinated Glycidyl Amine with Low Viscosity

A liquid oxygen-compatible epoxy resin of fluorinated glycidyl amine (TFEPA) with a low viscosity of 260 mPa·s in a wide range of temperatures, from room temperature to 150 °C, was synthesized and used to decrease the viscosity of phosphorus-containing bisphenol F epoxy resins. And the forming process and application performances of this resin system and its composite were investigated. The viscosity of the bisphenol F resin was decreased from 4925 to 749 mPa·s at 45 °C by mixing with 10 wt.% TFEPA, which was enough for the filament winding process. Moreover, the processing temperature and time windows were increased by 73% and 186%, respectively. After crosslinking, the liquid oxygen compatibility was preserved, and its tensile strength, elastic modulus, and breaking elongation at −196 °C were 133.31 MPa, 6.59 GPa, and 2.36%, respectively, which were similar to those without TFEPA. And the flexural strength and modulus were 276.14 MPa and 7.29 GPa, respectively, increasing by 21.73% in strain energy at flexural breaking, indicating an enhanced toughness derived from TFEPA. Based on this resin system, the flexural strength and toughness of its composite at −196 °C were 862.73 MPa and 6.88 MJ/m3, respectively, increasing by 4.46% and 10.79%, respectively.

Design and Characterization of Epoxy Resin Systems Based on Mixtures of Imidazolium-Based Ionic Liquids with Docusate and Dicyanamide Anions

This study focuses on the synthesis, characterization, and application of four ionic liquids (ILs), three of which are being reported for the first time, with unique thermal properties and diverse anion-cation combinations, specifically in the context of epoxy resin polymerization. 1-3-Didodecylimidazolium dicyanamide (dDDIM DCA), 1-3-Didodecylimidazolium docusate (dDDIM DOSS), 1-ethyl-3-methylimidazolium dicyanamide (EMIM DCA), and 1-ethyl-3-methylimidazolium docusate (EMIM DOSS) were used to prepare six different mixtures with the same cation and with varying concentrations of DCA components, which is the main factor of an efficient polymerization, while the other component is intended to modify the properties of the cured resin. Mixtures based on EMIM cation demonstrated increased enthalpy and lower onset polymerization temperatures, indicating more efficient curing processes. The hardness of cured epoxy resins can be adjusted by altering the curing temperature and IL composition, with EMIM DCA and EMIM DOSS mixtures displaying high Shore A hardness, suitable for durable surface applications. In contrast, mixtures with higher dDDIM DCA proportions offered a balance between rigidity and flexibility, ideal for applications requiring both mechanical strength and elasticity.

A Solidified Controllable Resin System Suitable for Fracture Cavity Formation Plugging and Its Performance Characterization.

Thermosetting resins have good temperature resistance and high strength and have been widely used as plugging agents in oil fields. However, the current resin materials have high costs, and unmodified thermosetting resins are brittle or have deteriorated properties such as flame retardancy after curing to form a crosslinked network structure. In this study, the resin was modified via physical blending. The curing strength and temperature resistance were used as the main indicators. The resin matrix, curing agent, rheology modifier, and filling materials were modified and formulated optimally to form a high-strength resin gel plugging system. The resin gel system exhibited good fluidity and pumpability. When the shear rate was 200 s-1 at 25 °C, the initial viscosity was 300-400 mPa·s. The viscosity gradually decreased with increasing shear rate, and the apparent viscosity had good long-term stability at room temperature. A contamination test of different types of drilling fluids on the resin gel system showed that this system had good anti-contamination capability and could maintain a high curing strength even after being contaminated. At the same time, the system exhibited good plugging capability. A wedge-shaped fracture with an inlet size of 7 mm and an outlet size of 5 mm was plugged at 12.84 MPa for 10 min without leakage. A sand-filling pipe (with a diameter of 3.8 cm and pipe length of 30 cm) connected to the pipeline with a 6 mm outlet was subjected to a constant pressure of 11.29 MPa and plugged for 8 min before breaking through. Therefore, it exhibited good capability for plugging fissures and cavities. The resin gel leakage-plugging system has significant potential to realize effective plugging of the deep large-fracture leakage layer.

Synthesis of P/Si liquid flame retardant via the covalent modification and in-situ dispersion strategies for improving comprehensive performance of epoxy resin

Maintaining the balance between thermal stability, smoke suppression and mechanical properties of flame retardant epoxy resin (EP) systems has been very challenging in industry and academia. Herein, we prepared a P/Si flame retardant fluid (KHDOPO) to modify expandable graphite (EG) through covalent modification strategy for flame retardant EP. The comprehensive performance of EP/KEG was further enhanced via the in-situ dispersion strategy. The covalent modification strategy provided a synergistic P/Si flame retardant effect for EG. The in-situ dispersion strategy further improved the dispersion properties of KEG in EP. Surprisingly, EP/KEG exhibits a UL-94 V-0 rating, limit oxygen index (LOI) value of 30.9 % and total smoke production (TSP) value of 15.5 m2 with an ultralow loading of 4 wt% KEG. Besides, EP/KEG maintains superior thermal stability and mechanical properties due to ultra-low addition and better dispersion of KEG.

Partially bio-derived phosphazene-tannic acid microspheres as fire retardant additives for an epoxy tannic acid resin system

In this work, partially bio-derived colloidal microspheres are synthesised from tannic acid (TA) and hexachloro-cyclophosphazene (HCCP), then investigated for their effectiveness as a fire-retardant additive to a partially bioderived epoxy resin system. The epoxy resin system is based upon diglycidyl ether of bisphenol A (DGEBA) and tannic acid (TA), a bio-derived highly aromatic phenolic curative noted for its inherent fire retardancy. This study presents the impact of increasing the concentration of the phosphazene-TA microspheres (TAPZ) and varying the DGEBA-TA stoichiometry to determine the optimum formulation required to achieve the greatest improvement in fire retardancy. At 15 wt% TAPZ addition, the DGEBA-TA resin system easily achieves a V-0 rating according to the UL-94 vertical burn test, measures 29 % for the limiting oxygen value (LOI) and displays a 62 % reduction in peak heat release rate (PHRR) compared with the unmodified DGEBA-TA network. TAPZ addition however reduces the glass transition temperature (Tg) from 187 °C to 155 °C, flexural strength by up to 30 % and increases viscosity significantly. Varying the stoichiometry between DGEBA and TA shows that additional surface hydroxyl groups from the TAPZ microspheres accelerate the DGEBA-TA reaction through enhancing interfacial reaction between residual epoxide groups of the cured epoxy network. Overall, these results present a promising approach to the development of a highly fire retardant, high performance, and highly bio-derived epoxy network and composite.

Stepwise-Induced Synthesis and Excellent Corrosion Protection of Ce/Eu Codoped ZnO Solid Solution Materials.

Under purely inorganic conditions, a synthesis route was devised wherein elements were introduced stepwise via coprecipitation based on differences in compound solubility. This synthesis method can change the microscopic morphology of the material without relying on a templating agent, resulting in the formation of the multilayered lamellar Ce/Eu codoped zinc oxide solid solution (ZCEOSS) with a self-assembled nested imbrication structure. The study improves the critical matter of corrosion by focusing on the electron and energy transfer mechanisms. By introduction of the bandgap modulator cerium element and fluorescence enhancer europium element into the ZnO material, the anticorrosion material has been successfully endowed with both photocathodic protection and luminescent initiative/stress dual corrosion defense functions. Due to the energy level staircase protection mechanism synergistically generated by the 4f electron shell of rare-earth elements in concert with semiconductor zinc oxide, the energy band positions were modulated to progressively guide the direction of electron flow, thereby suppressing corrosion reactions. In particular, the ZCEOSS material synthesized by doping 1% cerium and 7% europium and adding rare-earth elements at pH 7 exhibited the best corrosion inhibition performance. After immersion in simulated seawater for 96 h, Tafel polarization test results showed that compared to epoxy resin and ZnO anticorrosion systems, the ZCEOSS anticorrosion system exhibited significantly improved corrosion inhibition efficiency with enhancements of 1028.3 and 402.9%, respectively. This study provides new insights into the development of highly efficient inorganic anticorrosion materials.

An Investigation into Mechanical Properties of 3D Printed Thermoplastic-Thermoset Mixed-Matrix Composites: Synergistic Effects of Thermoplastic Skeletal Lattice Geometries and Thermoset Properties.

This study aims to develop thermoplastic (TP) and thermoset (TS) based mixed matrix composite using design dependent physical compatibility. Using thermoplastic-based (PLA) skeletal lattices with diverse patterns (gyroid and grid) and different infill densities (10% and 20%) followed by infiltration of two different thermoset resin systems (epoxy and polyurethane-based) using a customized FDM 3D printer equipped with a resin dispensing unit, the optimised design and TP-TS material combination was established for best mechanical performance. Under uniaxial tensile stress, the failure modes of TP gyroid structures with polyurethane-based composites included 'fiber pull-out', interfacial debonding and fiber breakage, while epoxy based mixed matrix composites with all design variants demonstrated brittle failure. Higher elongation (higher area under curve) was observed in 20% infilled gyroid patterned composite with polyurethane matrix indicating the capability of operation in mechanical shock absorption application. Electron microscopy-based fractography analysis revealed that thermoset matrix properties governed the fracture modes for the thermoplastic phase. This work focused on the strategic optimisation of both toughness and stiffness of mixed matrix composite components for rapid fabrication of construction materials.

Study on the UV aging resistance of ZnO‐modified epoxy resin by experiments and MD simulation

AbstractThis study investigates the impact of zinc oxide nanoparticles on epoxy resin systems and the ultraviolet (UV) aging resistance of modified epoxy resin composites using molecular dynamics (MD) simulations and experimental methods. Initially, various epoxy resin cross‐linking models are established through MD simulations to understand the influence of different nano ZnO contents on resin modification, further validated by experiments. Subsequently, the UV radiation resistance of nano ZnO–epoxy resin composites is assessed by subjecting them to high‐intensity UV radiation equivalent to 3 years of natural environmental conditions, analyzing changes in tensile properties, impact performance, hardness, and glass transition temperature of epoxy resin before and after UV radiation exposure. The findings suggest that the addition of nano zinc oxide reduces the impact of UV radiation on epoxy resin, with optimal UV radiation resistance observed at a nano zinc oxide mass fraction of 0.3 wt%.