Residual Sodium Bicarbonate Research Articles

Assessment of Groundwater Quality for Irrigation Suitability in Rajangaon Shenpunji and Surrounding Area, Aurangabad, Maharashtra, India.

The quality of irrigation water available to farmers has a significant impact on crop yield. Hence, it is need to better understand irrigation water quality. The present study mainly emphasizes the assessment of the suitability of 30 water samples from dug wells, bore wells and surface water bodies in Rajangaon Shenpunji and surrounding areas, Aurangabad, Maharashtra, India. The groundwater sample datasets of post-monsoon 2013 season were collected. The water quality parameters, viz. sodium adsorption ratio (SAR), percent sodium (%Na), residual sodium carbonate (RSC), residual sodium bicarbonate (RSBC), Kelly’s ratio (KR), magnesium adsorption ratio (MAR), permeability index (PI) have been calculated. Based on these calculated parameter results, prepared spatial distribution maps in Arc GIS 10.3 software. These parameters were correlated with standard permissible/desirable limits for irrigation use for the prevailing crops. Based on these factors, most of the samples fall into the category of water suitable for irrigation. A few samples that exceeded permissible limits were discovered in various geological and anthropogenic activities near the water samples in the study area. A complete investigation of groundwater quality may be suitable remedial action. Artificial recharge techniques are developed to increase the chemical concentrations in groundwater or suitable crops are working to continue the present water quality.

Assessment of surface Water Quality for Drinking and Irrigation Purposes for Two Dams in the Semi-Arid Region of Northeast Algeria

<p>The surface water quality of Timgad and Yabous dams in the semi-arid region of northeast Algeria was evaluated using physicochemical data collected monthly from May 2023 to April 2024. Parameters including temperature (T), pH, electrical conductivity (EC), total dissolved solids (TDS), chloride (Cl⁻), sulfate (SO₄²⁻), bicarbonate (HCO₃⁻), nitrate (NO₃⁻), sodium (Na⁺), potassium (K⁺), calcium (Ca²⁺), and magnesium (Mg²⁺) were analyzed to assess suitability for drinking and irrigation purposes. For drinking purposes, the Water Quality Index (WQI) and CCME-WQI were employed. Results showed permissible WQI values for Timgad Dam throughout the year, with Yabous Dam exhibiting good quality consistently. However, CCME-WQI classified Timgad Dam as marginal and Yabous Dam as fair annually, indicating a need for caution, particularly for Timgad Dam. For irrigation purposes, various indices including Sodium Adsorption Ratio (SAR), Sodium Percentage (NA%), Residual Sodium Carbonate (RSC), Permeability Index (PI), Potential Salinity (PS), Kelly’s Ratio (KR), Residual Sodium Bicarbonate (RSBC), and Magnesium Hazard (MH) were utilized. While both dams generally demonstrated suitable classes for irrigation, Timgad Dam exhibited unsuitability due to elevated Potential Salinity values, attributed to high chloride and sulfate concentrations that probably come from anthropogenic activities and natural processes, and MH values were unsuitable for both dams throughout the year.</p>

Numerical Verification of Groundwater Suitability for Irrigation Around the Subsurface Dam Area of Miyako Island, Japan

The sustainable management of water resources is essential for agricultural productivity, especially in areas with scarce water availability. This study focused on assessing groundwater quality for irrigation near the subsurface dam area of Miyako Island, Japan. Water samples from three observation points were tested for various parameters, including electrical conductivity (EC), sodium adsorption ratio (SAR), soluble sodium percentage (SSP), residual sodium bicarbonate (RSBC), permeability index (PI), Kelley's ratio (KR), and magnesium adsorption ratio (MAR). EC values ranged from 270 to 800 µS/cm, suggesting water quality ranging from doubtful to good. SAR values between 0.23 and 1.49 suggested excellent quality. SSP ranged from 7.90% to 31.71%, mostly indicating good to excellent quality. RSBC values fluctuated between -1.57 to 1.45 epm, largely within safe limits. PI values varied from 40.34 to 75.83, indicating good permeability. Total hardness (TH) ranged from 105.50 to 326.45 ppm, classifying the water as hard to very hard. MAR values were below 50, suggesting potential soil issues. A numerical model confirmed observed Ca²⁺ concentrations, showing an increasing trend due to enhanced CO₂ emissions and lower pH. The data analysis revealed strong positive relationships between SSP and KR (r = 0.984), SAR and SSP (r = 0.951), and SAR and KR (r = 0.960). Despite generally acceptable values, continuous monitoring is recommended, especially for hardness, to ensure sustainable crop production. This study underscores the need for regular assessment and management of groundwater quality in subsurface dam areas to mitigate potential adverse effects on soil and agricultural productivity.

Appraising water resources for irrigation and spatial analysis based on fuzzy logic model in the tribal-prone areas of Bangladesh.

The lack of quality water resources for irrigation is one of the main threats for sustainable farming. This pioneering study focused on finding the best area for farming by looking at irrigation water quality and analyzing its location using a fuzzy logic model on a Geographic Information System platform. In the tribal-prone areas of Khagrachhari Sadar Upazila, Bangladesh, 28 surface water and 39 groundwater samples were taken from shallow tube wells, rivers, canals, ponds, lakes, and waterfalls. The samples were then analyzed for irrigation water quality parameters like electrical conductivity (EC), total dissolved solids (TDS), sodium adsorption ratio (SAR), soluble sodium percentage (SSP), residual sodium bicarbonate (RSBC), magnesium hazard ratio (MHR), Kelley's ratio (KR), and permeability index (PI). Fuzzy Irrigation Water Quality Index (FIWQI) was employed to determine the irrigation suitability of water resources. Spatial maps for parameters like EC, KR, MH, Na%, PI, SAR, and RSBC were developed using fuzzy membership values for groundwater and surface water. The FIWQI results indicate that 100% of the groundwater and 75% of the surface water samples range in the categories of excellent to good for irrigation uses. A new irrigation suitability map constructed by overlaying all parameters showed that surface water (75%) and some groundwater (100%) in the northern and southwestern portions are fit for agriculture. The western and central parts are unfit for irrigation due to higher bicarbonate and magnesium contents. The Piper and Gibbs diagram also indicated that the water in the study area is magnesium-bicarbonate type and the primary mechanism of water chemistry is controlled by the weathering of rocks, respectively. This research pinpoints the irrigation spatial pattern for regional water resource practices, identifies novel suitable areas, and improves sustainable agricultural uses in tribal-prone areas.

Hydrogeochemistry and Quality Assessment using Water Quality Indices of Surface and Groundwater of Konar Reservoir Region, Hazaribag District, Jharkhand, India

ABSTRACT In the present paper, the water quality of the Konar reservoir area in the Hazaribag district of Jharkhand, India, has been investigated and with this view, the different physico-chemical variables, including pH, Dissolved Oxygen, Electrical Conductivity, TDS, Temperature, cations (Ca2+, Mg2+, Na+, K+), anions (CO32−, HCO3−, Cl−, F−, SO42−, NO3−) have been analyzed. According to Schoeller diagram, the order of major cations and anions for groundwater are Ca2+ > Na+ > Mg2+ > K+ and HCO3− > SO42− > Cl− > NO3− and for surface water are Na+ > Ca2+ > Mg2+ > K+ and Cl− > HCO3− > NO3− > SO42− respectively. The calculated water quality index shows that 100% of the samples of surface water are of excellent water quality, while 17% of the samples of groundwater are of excellent and 83% fall under the good category. The Gibbs Plot indicates that the rock-water interaction mechanism is dominant, Giggenbach triangle indicates that the waters have not yet reached equilibrium and are still in an immature state, although the Piper plot demonstrates that most of the surface water samples (78%) are mixed facies of Ca2+-Mg2+-Cl− and 22% are of Na+–Cl− type. All groundwater samples are mixed facies of Ca2+– HCO3− type. According to the Durov plot, 100% of surface water samples exhibit simple dissolution or mixing and majority of the ions in all groundwater samples are calcium and bicarbonate, showing the influence of limestone deposits. Almost all of the water samples from the Konar reservoir area were found to be appropriate for irrigation, according to the Residual Sodium Carbonate, Residual Sodium Bicarbonate, Sodium Percentage, Permeability Index, Kelley’s Ratio, Sodium Adsorption Ratio, United States Salinity Laboratory (USSL) and Wilcox diagrams.

Comparative assessment of hydrochemical characterization and groundwater quality for irrigation in an autochthonous karst aquifer with the support of GIS: case study of Altinova, Turkey

This study aims to present a comparative assessment of hydrochemical characterization and groundwater quality in karst aquifers with the support of GIS which is essential to correlate the source of water with climate and geology, and to evaluate suitability of water for various uses. The study area is the Altinova region in Turkey where intensive agricultural activities prevail and travertine covers 85% of the study area. A total of 25 groundwater wells were monitored by seasonal field measurements and extensive water quality analyses for a period of one year to establish correlation between groundwater quality, its source, regional climate, and geology. A comprehensive analysis was conducted to assess the groundwater's suitability for irrigation based on electrical conductivity, sodium adsorption ratio, sodium percentage, magnesium hazard, permeability index, residual sodium bicarbonate, Kelly’s ratio, and an irrigation water quality (IWQ) index. This multi-parameter evaluation was further integrated with geospatial analysis using ArcGIS, providing a detailed spatial understanding of hydrochemical variations across the area. Major cations and anions dominance were identified as Ca2+ > Na+ > Mg2+ > K+ and HCO3− > Cl− > SO42−, respectively. Spatial mapping identified high concentrations of Ca2+, TDS, TH, and SO42− in non-karstic areas, occasionally exceeding WHO guidelines. Nitrate concentrations displayed varied spatial distribution. The SAR values generally matched C2-S1 and C3-S1 classes, suggesting medium to high salinity risks and low sodium presence. Based on the IWQ index and observed correlations with total dissolved solids, the groundwater in Altinova’s karstic aquifer is considered suitable for irrigation, with salinization largely due to ionic interactions and geology. The presented comparative assessment provides a holistic approach for understanding hydrochemical characteristics of karst aquifers, and analyzing the impacts of natural factors and anthropogenic pollution sources on groundwater quality.

Appraisal of Water Quality Measurements for Canal and Tube Well Water Systems for Agriculture Irrigation in Rechna Doab, Pakistan

The present study was an attempt to assess the surface and ground water quality for irrigation suitability inRechna Doab. Irrigation water quality at canals and tube well water were analyzed by physicochemical parametersincluding pH, Electric Conductivity (EC), important cations such as Calcium (Ca2+) Magnesium (Mg2+), Potassium (K+),Sodium (Na+), important anions such as Chloride (Cl-), Bicarbonate (HCO3-), Sulphate (SO42-), three heavy metalsincluding Zinc (Zn), Nickel (Ni) and Copper (Cu). Twelve water samples were collected from the main canals (LowerGogera canal, Jhang branch canal and Rakh branch canal) while fifty water samples were collected from the tube wells.Statistically, data were analyzed by generating correlation coefficients. Canal water quality parameters i.e. SodiumAdsorption Ratio (SAR), Magnesium Adsorption Ratio (MAR), Sodium Percentage (Na %), Kelly Ratio (KR), SolubleSodium Percentage (SSP), Residual Sodium Bicarbonate (RSBC), Permeability Index (PI) and Potential Salinity (PS)with their mean values 0.16,38.18, 8.03, 0.08, 10.17, 0.08, 28.34 and 0.024 respectively were calculated. Piper and Durovdiagrammatic representations provided the suitability of the canal water regarding ionic composition. Results revealedthat the status of the canal water was fit for agriculture. On the contrary, the data about Electric Conductivity (EC),Sodium Adsorption Ratio (SAR) and Residual Sodium Carbonate (RSC) of tube well water (with their maximum values4.80, 29.65 and 13.60, respectively) was exceeding the FAO limits owing of sodium hazards. Thus, the scenario ofgroundwater is alarming due to unfit status of tube well water regarding irrigation purposes. Out of total 50 water samplesof tube wells, 11 samples were found to be fit. While 39 samples were unfit for crop irrigation. Geo-statistical analysiswas performed by using Inverse Distance Weighted (IDW) technique created in Arc map.

A multivariate approach to assessing the water quality of the Bamako reach of the Niger River in Mali as irrigation water.

Agricultural production in the Bamako region has been raised, and its output quality has been questionable due to the discharge of wastewater into the Niger River. This study assessed the Niger River water body variations for irrigation application temporally and spatially. Thirteen parameters, potential of hydrogen, electrical conductivity, nitrate, total dissolved solids, phosphate, sulfate, chloride, ammonium, calcium, magnesium, potassium, sodium, and bicarbonate, were analyzed at the 15 sampling locations. Parameters examination indicated that most pollutants had higher concentrations over the high-flow phase than in the low-flow period. All parameters were within the Food and Agriculture Organization's recommended values levels. Irrigation variables, sodium adsorption ratio, sodium percentage, soluble sodium percentage, residual sodium bicarbonate, Kelly's ration, permeability index, total hardness, and potential salinity showed the water samples' convenience for irrigation. However, the magnesium hazard concentration exceeded the recommended values levels. Besides, the chloroalkaline indices indicated a trend of degradation that should be addressed. Therefore, a river management plan and regular irrigation water quality monitoring are needed to reduce water hardness in Bamako. The Niger River's sustainable management process must be thrived on all actors' participation. A scientific assessment will be conducted using appropriate methods to identify pollution sources in Bamako. The results of this study will serve as a cornerstone for future investigations concerning the quality of surface water, which is essential for irrigation purposes. PRACTITIONER POINTS: Human activities affected the Niger River water bodies in Bamako city. Quantitative and qualitative assessments reveal the pollution status and trend of the Niger River. The water quality trend is better in the low-flow season, which is an ideal period for vegetable production in Bamako. Most multivariate approaches indicated that the Niger River water is healthy for irrigation purposes. Magnesium hazard exceeded the standard levels, and the chloroalkaline indices indicated a trend of the Niger River water quality deterioration.

Deployment of entropy information theory in the Indian Sundarban region using hydrogeochemical parameters and GIS for assessment of irrigation suitability.

The evaluation of irrigation suitability plays a crucial role for the socio-economic development of the society, especially in the region of Sundarban. For sustainable agricultural practices, groundwater quality must be suitable for irrigation; otherwise, it can degrade soil and diminish crop yield. The entropy information theory, several irrigational indices, multivariate statistics, GIS, and geostatistics are used in this work to evaluate the geographical distribution and quality of groundwater in the Indian Sundarban region. In total, 33 groundwater samples were collected in 2018 (April and May), and they were evaluated for major cations, anions, as well as other parameters like electrical conductivity (EC), soluble sodium percentage (SSP), potential salinity (PS), total dissolved solids (TDS), Kelly ratio (KR), sodium absorption ratio (SAR), permeability index (PI), residual sodium carbonate (RSC), magnesium hazard (MH), and residual sodium bicarbonate (RSBC). The overall trend of the principal cations and anions is in the sequence of Na+ ≥ Mg2+ ≥ Ca2+ ≥ K2+ and HCO3- ≥ Cl- ≥ NO3- ≥ SO42- ≥ F-, respectively, whereas the spatial variation of %Na, SAR, RSBC, and MH demonstrate very poor irrigation water quality, and spatial variation of KR, RSC, SSP, PI, and PS signifies that the irrigation water quality is excellent to good. In order to identify the specific association and potential source of the dissolved chemical in the groundwater, statistical techniques like correlation and principal component analysis were also employed. The hydrochemical facies indicates that mixed type makes up the bulk (51.51%) of the water samples. Following the Wilcox plot, more than 75% of the water samples are good to doubtful; however, by the US salinity hazard map, roughly 60.60% of the samples had high salinity (C3-S1 zone). The EWQII reports that no samples fall into the very good (no restriction) category, whereas 30.30%, 30.30%, and 39.40% of the sample wells record good (low restriction), average (moderate restriction), and poor (severe restriction) irrigation water quality, respectively. Based on this study, the bulk of the groundwater samples taken from the study area are unsuitable for cultivation. The findings of this study will also help decision-makers develop adequate future plans for irrigation and groundwater resource management.

Assessment of Stormwater Quality in the Context of Traffic Congestion: A Case Study in Egypt

The aim of this study was to investigate the effect of traffic congestion in urbanized areas (parking lots and highways) on stormwater quality. Three separate locations in Egypt’s heavily urbanized and populous Giza Governorate were picked for the purpose of monitoring and evaluating the stormwater quality: Faisal (A), El Dokki (B), and Hadayek El-Ahram (C), with catchment areas of 10,476, 7566, and 9870 m2, and with monthly average daily traffic (MADT) values of 47,950, 20,919, and 27,064 cars, respectively. The physio-chemical and heavy metal stormwater quality parameters of six water samples were investigated and compared with Egypt’s water criteria and the World Health Organization (WHO) guidelines. The water quality index (WQI) and the irrigation water quality indices were used to assess the uses of stormwater. The results showed that the WQI varied from 426 to 929, with an average of (661 ± 168), indicating that the stormwater was contaminated at each location under examination and needed pretreatment in order to be useful. As a result, the allowed stormwater quality standards were exceeded for heavy metals such as Al, Cr, Cd, Fe, and Cu. The indicators of the stormwater quality for irrigation—the total dissolved solids (TDS), sodium adsorption ratio (SAR), soluble sodium percentage (SSP), permeability index (PI), magnesium adsorption ratio (MAR), and Kelley’s ratio (KR)—show excellent stormwater for irrigation, while the total hardness (TH) and residual sodium bicarbonate (RSBC) indicate poor irrigation water quality. It is advised to sweep the streets to remove particle-bound pollution before it reaches storm drain water, and to put in place an adequate stormwater sewerage system to catch rainwater.

Hydrogeochemical characterization of ground and surface water in the eastern part of the Adamawa-Yade domain, Bertoua-Cameroon

Groundwater and surface water are major sources of water supply to the inhabitants of Bertoua. Hydrogeochemical study conducted in the study area aimed at identifying the processes that control the chemistry of groundwater sources and to examine the quality of the water sources for domestic and agricultural purposes. Fifty water samples were collected from boreholes, open wells, springs, and rivers within the study area in January 2022 (the dry season). The samples were analyzed for physicochemical characteristics including pH, electrical conductivity (EC), total dissolved solids (TDS) and major ions. The water samples were acidic with 94% of pH values less than 6.5. The EC varied from 21 to 776 µS/cm and TDS (8.5–388 mg/l). The low EC and TDS indicate low mineralization and fresh water. The relative abundance of major ions (meg/l) was Ca2+> Mg2+> K+>Na+ for cations and {text{H}text{C}text{O}}_{3}^{-}>Cl−>NO3−>SO42− for anions. These major ions concentrations were low and within the WHO guideline values for drinking water. From Piper diagram three water facies were observed; Ca-SO4, Ca-HCO3 and mixed Ca-Mg-Cl. Rock-water interaction, ion exchange, silicate weathering and anthropogenic activities were the processes responsible for the groundwater chemistry with some minor evaporative effects. Based on Sodium Adsorption Ratio and Residual Sodium Bicarbonate all samples fall in the excellent category for agriculture.

Application of fuzzy C-means clustering and fuzzy EDAS to assess groundwater irrigation suitability and prioritization for agricultural development in a complex hydrogeological basin.

The current research is focused on detecting a river basin suitable for agriculture and priority for management using a new clustering tool of groundwater quality with fuzzy logic technique in R and Geographical Information System. A new fuzzy clustering-soft computing technique has been executed to determine the different hydrochemical zones considering 13 essential parameters such as electrical conductivity, hardness, chloride, sodium adsorption ratio, residual sodium carbonate, soluble sodium percent, magnesium hazard, permeability index, potential salinity, residual sodium bicarbonate, Kelly's ratio, synthetic harmful coefficient, and exchangeable sodium percentage. The derived fuzzy C-mean clustering (FCM) outperformed other available hard computing techniques like hierarchical clustering, K-means clustering, and agglomerative clustering. It divided the sampling sites into 2 clustering groups (FCM I and FCM II) which has been validated using fuzzy silhouette index (0.85), the partition coefficient (0.76), the partial entropy (0.68), and the modified partition coefficient (0.52). The hydrogeochemical analysis confirmed that the rock-water interaction, chemical weathering, and ion exchange process are predominant in the aquifer system of the study area. According to the correlation plots, the studied groundwater samples largely evolved from [Formula: see text], mixed [Formula: see text] types, and [Formula: see text] types. The spatial distribution map and the hydrochemical analysis also gives a clear depiction of the fluoride (> 1.0mg/l) and high iron (> 0.3mg/l) contamination in groundwater quality, making it unsuitable for both drinking and irrigation. A fuzzy EDAS priority map has been prepared based on all the irrigation suitability parameters which concludes that the groundwater at the upstream and downstream section of the basin requires the most attention. Based on the highest priority for management, five zones have been delineated: very high (5.98%), high (22.31%), medium (16.39%), low (32.30%), and very low (23.02). The findings of this study will be beneficial to planners and policymakers as they can develop schemes to solve similar problems across the country.

Hydrogeochemical studies of groundwater in semi-arid areas of northern Ethiopia using geospatial methods and multivariate statistical analysis techniques

The present study focused on evaluating the groundwater hydrogeochemical of shallow aquifers in the semi-arid areas of northern Ethiopia, using geospatial modelling and multivariate statistical techniques. Physico-chemical parameters, including pH, major ions, electrical conductivity (EC), total dissolved solids (TDS), total hardness (TH), pollution index (PI) and other parameters, from 22 samples have been used to assess water quality, sources of various ions, water types and factors controlling groundwater chemistry. Results showed that the spatial distribution of major ions, EC, TDS, TH and PI values in these samples significantly differ from one location to another due to geological variations and anthropogenic activities of the area. The quality of most groundwater is generally unfit for drinking due to their PI, EC, TH, calcium, potassium, total iron and bicarbonate (HCO3−) values that found to be above the permissible limits of WHO and Ethiopian standards. The parameters like sodium percentage, sodium adsorption ratio (SAR), residual sodium bicarbonate, permeability index, magnesium hazard and Kelly’s ratio revealed good quality of groundwater for irrigation utilization, whereas EC of irrigation water (ECiw), combined effects of ECiw − SAR and bicarbonate hazard values indicated that majority of groundwater are not suitable for irrigation use. Piper trilinear diagram classified majority of samples under temporary hardness with Ca–Mg–HCO3 type. Further, Gibbs diagram reveals that water–rock interaction is the major hydrogeochemical processes governing the water chemistry of the study area. Therefore, it is recommended to perform a constant water quality checking program and improvement of tangible management practices for sustainable utilization of groundwater resources.

Assessment of shallow groundwater aquifer in an arid environment, Western Saudi Arabia

In arid and semi-arid regions like the Kingdom of Saudi Arabia (KSA), groundwater is considered the main source for drinking and agricultural uses due to low precipitation and limited surface water resources. The aim of this research is to evaluate the hydrogeological and hydrochemical characteristics of groundwater in Wadi Marawani basin for sustainable development. To achieve this goal, standard analytical methods have been used to determine the physicochemical parameters in sixty-four samples. Groundwater quality and controlling factors were evaluated using diagrams (Piper, Gibbs, Chadha, and HEF) and irrigation indices such as Sodium percentage (Na%), Soluble Sodium Percentage (SSP), Permeability Index (PI), Residual Sodium Bicarbonate (RSBC) and Kelly Index (KI). Also, the Support Vector Machine for Regression (SVMR) and the Multiple Linear Regression (MLR) models have been applied to predict the irrigation parameters. The results revealed that the Quaternary aquifer of unconfined condition is the main source of groundwater in Wadi Marawani basin. Depth to water measurements in sixty-two wells indicated that the groundwater flows from east to west towards the Red Sea coast. The ionic composition of the analyzed water samples showed that, Ca–HCO3, Na–Cl, mixed Ca–Mg–Cl–SO4, and Na–Ca–HCO3 are the main water types. Assessment of groundwater quality indicates that, 33%, 86%, 100%, 100% and 69% of groundwater samples are suitable for irrigation based on the calculated irrigation indices Na%, SSP, PI, RSBC and KI respectively. The SVMR model is outperformed the MLR in prediction of the irrigation indices. There was no overfitting or underfitting in the datasets used to measure, calibrate, and validate the SVMR model of four irrigation indices. Finally, this study can provide a holistic view of groundwater management for agricultural uses in the Wadi Marawani basin.

Groundwater quality assessment using the WQI and GIS mapping: Suitability for drinking and irrigation usage in the Sirdala block of Nawada district

Abstract In the present study, the suitability of groundwater for drinking and irrigation purpose were analyzed. A total of 65 groundwater samples were collected and analyzed for relevant water quality parameters from Sirdala block of Nawada district Bihar (India). To estimate the WQI for the drinking purpose, various parameters such as pH, TDS, TH, AS and major ions (Ca2+, Mg2+, Na+, K+, Cl−, F−, HCO3−, NO3−, SO42−) were considered. The WQI for irrigation, various irrigation indices namely soluble sodium percent (Na%), sodium adsorption ratio (SAR), residual sodium bicarbonate (RSCB), permeability index (PI), magnesium hazards ratio (MHR), Kelly's ratio (KR), potential salinity (PS), Cl−: HCO3−, Mg(2+): Ca(2+) and Na+: Ca(2+) were employed and discussed in addition with Wilcox and USSL diagram. Plots, namely Gibbs ratio and Piper diagram, were used to understand chemical characteristics of groundwater. The WQI for drinking purpose was observed between 57.67 and 929.90 in which most samples (70.76%) were unsuitable for drinking. However, the WQI for irrigation purpose varied from 87.88 to 434.67 in which 50% of samples were suitable. Gibb's plots determined in this study reveal that evaporation-precipitation was the dominant factor that influences hydrochemistry. Piper plots suggest that Na-HCO3− water type was major hydrochemical facies in groundwater.

The Variation of Water Parameters along the Bandawaya Valley, Northern Iraq

Wadi Bandawaya, which is 40 km north of Mosul in Iraq, pierces Mount Dahqan and creates a small valley that is ideal for the construction of a dam for harvesting rainwater. Water quality is evaluated for domestic and agricultural uses using chemical analyses of the main cations (Ca2+, Mg2+, Na+, K+), anions (HCO3-, SO42-, Cl-, NO3-), as well as measurements of the acidity function (pH), electrical conductivity (Ec), concentration of total dissolved salts (TDS), and total hardness (TH). The valley water is considered to be within the limits permitted for drinking by the World Health Organization. If held inside the water harvesting project of the Bandawaya dam, the water of Bandawaya Valley is freshwater, suitable for drinking and domestic applications, according to the water quality index (WQI). It is also suitable for irrigation of agricultural lands adjacent to the valley in accordance with standards of the percentage of sodium (SSP), the rate of sodium adsorption (Sodium Adsorption Ratio, SAR), the quantity of residual sodium carbonate (Residual Sodium Bicarbonate, RSBC), and the percentage of magnesium (MAR). When there is little rain, the harvested water will be used for irrigation, as well as for supplemental irrigation techniques.

Hydrogeochemical assessment of streamwater quality for its suitability for irrigation: the case of Manthong village, Kanglung (Bhutan)

Abstract Mountain streams/springs are the primary irrigation water resource in Bhutan Himalaya, besides supporting drinking and other domestic needs. Successful crop production implies an adequate supply of high-quality irrigation water, among other factors. Thus, this study was conducted to assess the suitability of spring-fed streamwater for irrigation use and evaluate hydrogeochemical processes that regulate streamwater chemistry at the Manthong village in Kanglung, Bhutan. The water samples were analyzed for temperature, pH, electrical conductivity (EC), turbidity, total dissolved solute (TDS) and major ions. Piper and Durov diagrams indicated that most samples are of the intermediate type and simple dissolution or linear mixing is the primary hydrochemical process regulating streamwater chemistry. All the measured physicochemical parameters were within the acceptable thresholds of the FAO guidelines recommended for agricultural use. Analytical results of the streamwater water quality indices, including EC, %Na, residual sodium bicarbonate (RSBC), sodium adsorption ratio (SAR), Kelley's ratio (KR) and permeability index (PI), revealed its suitability for irrigation use except for magnesium hazard (MH). The Irrigation Water Quality Index (IWQI) results confirmed that the WS-1 has no restriction as irrigation water; however, WS-2 falls under the high-restriction category. The findings of this study will serve as the baseline data and guide irrigation water management and sustainable irrigation development in the region.

Hydrochemical appraisal of surface water from a subtropical urban river in southwestern Bangladesh using indices, GIS, and multivariate statistical analysis.

The Gorai River is a significant river in Bangladesh's southwestern region, where residents make great use of the water despite a lack of adequate and reliable information concerning water quality and pollution levels. Thus, the goal of this research was to examine the spatio-temporal variations in water quality and determine whether it was suitable for drinking, agriculture, industrial, or livestock purposes, as well as the influencing factors and potential sources of water pollution. Surface water samples were collected in wet and dry seasons from ten sampling sites, and twenty water quality parameters were evaluated. The results showed that some studied water quality parameters, e.g., temperature, electrical conductivity, alkalinity, and nitrate, exceeded the maximum allowable limit. Water quality index values exhibited that the water quality of all sampling sites was found to be poor to very poor during the wet season, while only St-4 and St-5 were found to be poor and the rest of the investigated sites were good category during the dry season. Based on sodium adsorption ratio, soluble sodium percentage, residual sodium carbonate, residual sodium bicarbonate, and permeability index values, it was depicted that river water was suitable for irrigation purposes, but when compared to Kelly's ratio (KR) and magnesium hazard ratio values, river water was found to be unfit for irrigation. Moreover, potential salinity (PS) and sodium-to-calcium activity ratio (SCAR) values allow the water as moderately suitable for use in irrigation purposes. Langelier saturation index (LSI) and aggressive index (AI) values revealed that the river water was under saturated to supersaturated and moderate to non-aggressive in nature. However, Ryznar stability index (RSI), Puckorius scaling index (PSI), and Larson-Skold index (LS) values describe whether the water was high or severely corrosive, signifying its inappropriateness for industrial consumption. Principal component analysis (PCA) analysis depicted that the fluctuations in water quality are mostly related to point and non-point contaminations, such as urban and industrial effluent discharged and agricultural runoff of fertilizers. Cluster analysis (CA) revealed relative geographical and seasonal changes in water quality, showing the impact of hydrological changes and contamination.

Hydrochemistry characteristics of groundwater with the influence of spatial variability and water flow in Hetao Irrigation District, China.

Groundwater is an important resource of water in arid and semi-arid agricultural regions. Thus, identification of hydrogeochemical characters and the influence of geospatial variability and flow pooling are of significance on groundwater resources management and making irrigation decisions in salinized areas. The study specifically focused on the Hetao Irrigation District located in the semi-arid region of northern China. A total of 85 groundwater samples (42 from the upstream Shenwu Irrigation Area (SWIA), 43 from the downstream Wulate Irrigation Area (WLTIA)) were collected, and 15 water quality indexes were analyzed. Methods including mathematical statistics, Piper diagram, Gibbs model, forward succession model, and ionic rations were used to analyze the hydrochemical characteristics and evolution mechanisms, RSBC, PS, SAR, WQI were selected to evaluate water quality and irrigation suitability from the perspective of salt and alkali damage. Results showed that the groundwater of the study area is weakly alkaline, SWIA is mainly fresh water (47.62%), WLTIA is mainly brackish water (65.12%), and the hydrochemistry of the groundwater consists of Cl-Na type and Cl·SO-Ca·Mg. The solute content of downstream (WLTIA) is higher than that of upstream (SWIA), Na+ and Cl- have obvious advantages in WLTIA, and they are the main contribution indicators of groundwater TDS in the study area. The groundwater is subjected to the ongoing influence of rock weathering, ions exchange, and evaporate crystallization Na+ mainly originates from the dissolution of evaporate salt rock and silicate rock, and Ca2+ from the dissolution of gypsum and carbonate. The order of contribution of different rocks is evaporation rock > silicate rock > carbonate rock. Based on the classifications of sodium absorption ratio (SAR), residual sodium bicarbonate (RSBC), and potential salinity (PS), most of the groundwater samples are unsuitable for irrigating, and the groundwater quality of the SWIA is better than that of the WLTIA.

EVALUATION OF GROUNDWATER SUITABILITY FOR IRRIGATION PURPOSE USING GIS AND IRRIGATION WATER QUALITY INDICES

As a major source of water for irrigation, the evaluation and assessment of groundwater to ensure it meets the quality for sustainable agriculture is key. This research presents the findings of the quality of groundwater and its suitability for irrigation purposes. This was carried out using the irrigation water quality indices and the Geographic Information System (GIS). The Inverse Distance Weighted (IDW) method of the GIS was used to study the spatial distribution of these indices. Indices considered include Sodium Absorption Ratio (SAR), Percentage Sodium (%Na), Permeability Index (PI), Kelly Ratio (KR), Magnesium Hazard (MH), Total Hardness (TH), Residual Sodium Bicarbonate (RSBC) and Potential Salinity (PS). The values obtained were SAR (0.00 to 10.99, mean of 3.43), Percentage Sodium (26.00% to 94.42%, mean of 70.33%), Permeability Index (94.14% to 379.47%, mean of 161.45%), Kelly Ratio (0.00 to 8.62, mean of 3.19) and Magnesium Hazard (0.00% to 80.33 %, mean of 39.21%). Total Hardness (12.49 mg/L to 77.50 mg/L, mean of 31.35 mg/L), Residual Sodium Bicarbonate (-0.55 meq/L to 5.46 meq/L, mean of 1.41 meq/L), Potential Salinity (0.88 meq/L to 2.53 meq/L, mean of 1.69 meq/L) and Electrical Conductivity (110µS/cm to 910µS/cm, mean of 277.14µS/cm). The computed water indices when compared with known standards show that the groundwater from the study area is generally fit and can be applied for irrigation purposes.