Residual Part Research Articles

On the features of authigenic minerals in bottom sediments of lakes formed during nival, humid and arid types of sedimentogenesis

The comparison of autigenic minerals from the bottom sediments of lakes located under conditions of nival, humid and arid sedimentation is carried out. The long-term presence of ice cover on the lake, which prevents the mixing of water masses, the introduction of terrigenous material, oxygen-free conditions in the residual part of the waters under the ice and their local supersaturation with gases, makes it possible to form autigenic minerals in fresh waters of lakes located under conditions of nival, humid and arid sedimentation. The shape of the crystalline aggregates of the newly formed phases is determined by the conditions of their crystallization, mainly by the ionic composition of the residual water and microbiological factors.

Finite Element Method in L-PBF of Ti-6Al-4V: Influence of Laser Power and Scan Speed on Residual Stress and Part Distortion

Laser powder bed fusion (L-PBF) is widely used in automotive, aerospace, and biomedical applications thanks to its ability to produce complex geometries. In spite of its advantages, parts produced with this technology can show distortion due to the residual stresses developed during the printing process. For this reason, numerical simulations can be used to predict thermal gradients and residual stresses that can result in part distortion. Thus, instead of performing experimental tests and using a trial and error approach, it is possible to use numerical simulation to save time and material. In this work, the effect of laser power and scan speed on residual stress and part distortion was analysed using a commercial finite element analysis (FEA) software DEFORM-3D™ with a layer-by-layer approach. Moreover, the accuracy of the numerical model with respect to process parameters and the utilised mesh was also studied. The results obtained from the numerical simulation were compared to the actual distortions to evaluate the accuracy of the FEM model. The predicted distortions using FEM analysis well fit the trend of the measured ones. The accuracy of the numerical model increases by considering a finer mesh.

Fabrication of β-Ga2O3 Nanotubes via Sacrificial GaSb-Nanowire Templates.

β-Ga2O3 nanostructures are attractive wide-band-gap semiconductor materials as they exhibit promising photoelectric properties and potential applications. Despite the extensive efforts on β-Ga2O3 nanowires, investigations into β-Ga2O3 nanotubes are rare since the tubular structures are hard to synthesize. In this paper, we report a facile method for fabricating β-Ga2O3 nanotubes using pre-synthesized GaSb nanowires as sacrificial templates. Through a two-step heating-treatment strategy, the GaSb nanowires are partially oxidized to form β-Ga2O3 shells, and then, the residual inner parts are removed subsequently in vacuum conditions, yielding delicate hollow β-Ga2O3 nanotubes. The length, diameter, and thickness of the nanotubes can be customized by using different GaSb nanowires and heating parameters. In situ transmission electron microscopic heating experiments are performed to reveal the transformation dynamics of the β-Ga2O3 nanotubes, while the Kirkendall effect and the sublimation process are found to be critical. Moreover, photoelectric tests are carried out on the obtained β-Ga2O3 nanotubes. A photoresponsivity of ~25.9 A/W and a detectivity of ~5.6 × 1011 Jones have been achieved with a single-β-Ga2O3-nanotube device under an excitation wavelength of 254 nm.

Bi-Layer nanoimprinting lithography for metal-assisted chemical etching with application on silicon mold replication

This paper reports a new type of nanoimprinting method called Bi-layer nanoimprinting lithography (BL-NIL), which can work along with metal-assisted chemical etching (MaCE) for fabricating nanostructures on silicon. In contrast to conventional nanoimprinting techniques, BL-NIL adds an interposing layer between the imprinting resist layer and silicon substrate. After the standard imprinting process, dry etching was used to etch away the residual imprinting layer and part of the interposing layer. Finally, the remaining interposing layer was wet-etched using its remover. This innovative approach can ensure cleanliness at the metal/silicon interface after metal lift-off processes, and therefore guarantees the success of MaCE. By combining BL-NIL and MaCE, expensive silicon molds with sub-micrometer/nanometer-scale feature sizes can be easily replicated and preserved. This is important for the application of nanoimprinting technologies in industrial manufacturing.

Effect of pulse on fragility curves of buckling-restrained braced frames

To investigate the effect of presence of the pulse in earthquake motions on the vulnerability of buckling-restrained braced frames (BRBFs), this technical note uses pulse-like ground motions (original records) and their residual parts obtained by extracting the pulse via wavelet analysis, as input vibrations. Conducting the numerical simulation of 4, 8, 12, and 15-storey BRBFs, their responses to the scaled original and residual motions are recorded using incremental dynamic analysis (IDA). Accordingly, the seismic performance of BRBFs is generally evaluated, and fragility curves are developed at collapse prevention (CP), life safety (LS), and immediate occupancy (IO) performance levels. The results indicate that a maximum difference of about 25%–30% may occur between the fragility curves due to the original and residual parts of ground motions at the maximum considered earthquake (MCE) intensity level for 8, 12, and 15-storey BRBFs, so that the original records lead to a severe damage in comparison with the residual ones. Also, the original records increase the probability by 20% on average compared to the residual records at the LS level for the considered BRBFs.

Ferrocenyl-Substituted Triazatruxenes: Synthesis, Electronic Properties, and the Impact of Ferrocenyl Residues on Directional On-Surface Switching on Ag(111).

We report on seven new ferrocenyl-(1, 3)- and ferrocenylethynyl-modified N,N',N″-triethyltriazatruxenes (EtTATs) 4-7 as well as the dodecyl counterpart 2 of compound 1 and their use as molecular switching units when deposited on a Ag(111) surface. Such functional units may constitute a new approach to molecule-based high-density information storage and processing. Besides the five compounds 1-3, 6, and 7, where the 3-fold rotational symmetry of the triazatruxene (TAT) template is preserved, we also included 2-ethynylferrocenyl-TAT 4 and 2,2'-di(ethynylferrocenyl)-TAT 5, whose mono- and disubstitution patterns break the 3-fold symmetry of the TAT core. Voltammetric studies indicate that the ferrocenyl residues of compounds 1-7 oxidize prior to the oxidation of the TAT core. We have noted strong electrostatic effects on TAT oxidation in the 2,2',2″-triferrocenyl-TAT derivatives 1 and 2 and the 3,3',3″-isomer 3. The oxidized complexes feature multiple electronic excitations in the near-infrared and the visible spectra, which are assigned to dδ/δ* transitions of the ferrocenium (Fc+) moieties, as well as TAT → Fc+ charge-transfer transitions. The latter are augmented by intervalence charge-transfer contributions Fc → Fc+ in mixed-valent states, where only a part of the available ferrocenyl residues is oxidized. EtTAT was previously identified as a directional three-level switching unit when deposited on Ag(111) and constitutes a trinary-digit unit for on-surface information storage. The symmetrically trisubstituted compound 6 retains this property, albeit at somewhat reduced switching rates due to the additional interaction between the ferrocenyl residues and the Ag surface. In particular, the high directionality at low bias and the inversion of the preferred sense of the on-surface rocking motion with either a clockwise or counterclockwise switching sense, depending on the identity of the surface enantiomer, are preserved. Unsymmetrical substitution in mono- and diferrocenylated 4 and 5 alters the underlying ratchet potential in a manner such that a two-state switching between the two degenerate surface conformations of 4 or a pronounced suppression of switching (5) is observed.

An Algorithmic Approach towards Remote Sensing Imagery Data Restoration Using Guided Filters in Real-Time Applications

The images captured from SAR sensors are inherently weakened by speckle noise. The SAR image processing community targeted this problem with many feature-based filters. Since SAR images are low-contrast images, edge retention is the most crucial aspect to consider. This helps in the efficient retrieval of information. This paper provides a two-step edge-preserving homomorphic SAR image despeckling technique that implements a guided filter as the first step, and a modified method of noise thresholding using the bivariate shrinkage rule and canny edge operator in the Discrete Orthonormal Stockwell Transform (DOST) domain as the second step. The use of a canny edge operator improves overall edge preservation after despeckling. The use of noise thresholding delivers the highest level of speckle reduction in the DOST domain. The detected edges are added to the residual part obtained after removing the noise to produce more informative content. According to several qualitative and quantitative criteria, the suggested approach is compared to some of the newest despeckling methods. The execution time of the proposed method is around 7.2679 seconds. Upon conducting qualitative and quantitative analysis, it has been determined that the proposed method surpasses all other despeckling methods that were compared.

Equation for the Dynamic Viscosity of Propane for the Use in Mixture Models

In the present paper, a new equation for the dynamic viscosity of propane is presented, which is suitable for the application in mixture models. The dilute-gas contribution was adopted from Vogel and Herrmann (J Phys Chem Ref Data 45:043103, 2016). The residual part is an empirical approach designed following the example of thermodynamic Helmholtz equations of state. With this functional form, an approach is proposed, which will allow to combine pure-fluid equations in the manner of high precision Helmholtz equations of state in a multifluid mixture model in the future. The parameters of the equation are adjusted to experimental data, so that the data are mostly reproduced within their experimental uncertainty. The present equation is valid in a temperature range from 90 K to 525 K with a maximum pressure of 145 MPa.

Computer-aided anti-cancer drug discovery of EGFR protein based on virtual screening of drug bank, ADMET, docking, DFT and molecular dynamic simulation studies

Numerous malignancies, including breast cancer, non-small cell lung cancer, and chronic myeloid leukemia, are brought on by aberrant tyrosine kinase signaling. Since the current chemotherapeutic medicines are toxic, there is a great need and demand from cancer patients to find novel chemicals that are toxic-free or have low toxicity and that can kill tumor cells and stop their growth. This work describes the in-silico examination of substances from the drug bank as EGFR inhibitors. Firstly, drug-bank was screened using the pharmacophore technique to select the ligands and Erlotinib (DB00530) was used as matrix compound. The selected ligands were screened using ADMET and the hit compounds were subjected to docking. The lead compound from the docking was subjected to DFT and MD simulation study. Using the pharmacophore technique, 23 compounds were found through virtual drug bank screening. One hit molecule from the ADMET prediction was the subject of docking study. According to the findings, DB03365 molecule fits to the EGFR active site by several hydrogen bonding interactions with amino acids. Furthermore, DFT analysis revealed high reactivity for DB03365 compound in the binding pocket of the target protein, based on ELUMO, EHOMO and band energy gap. Furthermore, MD simulations for 100 ns revealed that the ligand interactions with the residues of EGFR protein were part of the essential residues for structural stability and functionality. However, DB03365 was a promising lead molecule that outperformed the reference compound in terms of performance and in-vitro and in-vivo experiments needs to validate the study. Communicated by Ramaswamy H. Sarma

Endoscopic hand-suturing combined with titanium clips for rectal defects closure after endoscopic submucosal dissection: a pilot study

Objective: To explore the feasibility of endoscopic hand-suturing (EHS) for rectal defects closure after endoscopic submucosal dissection (ESD), and the clinical practicability of EHS combined with titanium clips. Methods: This is a prospective study performed by two experienced endoscopists from the Cancer Hospital, Chinese Academy of Medical Sciences who had received EHS training in sixporcine gastric ESD defects in vivo before the study. From December 2022 to February 2022, 20 patients with rectal mucosal lesions or submucosal diseases underwent ESD. Then EHS combined with titanium clips was adopted to close the rectal ESD defects. Specifically, we first sutured the defects as much as possible through EHS, then use titanium clips to fix the tail of the suture, and finally use additional titanium clips to close the residual parts of the defects that cannot be sutured. The main observational indicators were complete closure of the wound and delayed bleeding within one month after surgery. Results: In the 20 rectal cases, the size of defects ranged from 2.2 to 3.6 cm, with a median of 2.7 cm. All cases achieved complete closure without delayed bleeding, of which 12 (60.0%) were completely sutured with EHS and 8 (40.0%) required additional titanium clips to achieve complete closure after suturing. Conclusion: EHS technique is feasible and safe for rectum. EHS combined with titanium clips can also effectively close the rectal ESD defects, prevent postoperative delayed bleeding, and may be easier to be implemented in clinical practice.

Comparative metabolomics and antioxidant activities of residual part of Broccoli and Cauliflower

Comparative metabolomics and antioxidant activities of residual part of Broccoli and Cauliflower

The Structure of Working Memory and Its Relationship with Intelligence in Japanese Children.

There is a host of research on the structure of working memory (WM) and its relationship with intelligence in adults, but only a few studies have involved children. In this paper, several different WM models were tested on 170 Japanese school children (from 7 years and 5 months to 11 years and 6 months). Results showed that a model distinguishing between modalities (i.e., verbal and spatial WM) fitted the data well and was therefore selected. Notably, a bi-factor model distinguishing between modalities, but also including a common WM factor, presented with a very good fit, but was less parsimonious. Subsequently, we tested the predictive power of the verbal and spatial WM factors on fluid and crystallized intelligence. Results indicated that the shared contribution of WM explained the largest portion of variance of fluid intelligence, with verbal and spatial WM independently explaining a residual portion of the variance. Concerning crystallized intelligence, however, verbal WM explained the largest portion of the variance, with the joint contribution of verbal and spatial WM explaining the residual part. The distinction between verbal and spatial WM could be important in clinical settings (e.g., children with atypical development might struggle selectively on some WM components) and in school settings (e.g., verbal and spatial WM might be differently implicated in mathematical achievement).

Partially overlapped grain shape restoration of the granular rock images

This paper introduces a novel method for restoring each grain's original shape from an image of a granular rock sample whose grains partially overlap with each other. Image-based grain shape restoration provides a promising way to understand the generation of the rock that involves sedimentary and diagenesis processes. The difficulties of this task are: 1) how to effectively identify the region of each grain that is partially overlapped with its neighbor grains; and 2) how to recover the overlapped part of a grain based on the residual part. To solve the first problem, a differential erosion strategy that combines concave-points-constraint and pore-skeleton-extension-erosion is proposed to overcome the under-partitioning issue that popularly occurs in the current erosion-dilation grain partitioning method. To address the second problem, closed B-spline interpolation is applied to recover the original shape of the grains based on the partially presented grain edges. The proposed method successfully processed some synthetic and real granular rock images and presented a competent ability to deal with the moderately compressed granular rock samples consisting of relatively high-roundness grains that each grain can be treated as a convex polygon.

Three-dimensional nonlocal models of deformable ferroelectrics: A thermodynamically consistent approach

Within the framework of continuum thermodynamics, the paper develops a scheme for the study of piezo-ferroelectric materials undergoing large deformations. The ferroelectric polarization is decomposed into the sum of a reversible and a residual part which is considered as an independent variable. The modeling of the constitutive properties is made simpler by using referential, Euclidean invariant quantities. Constitutive functions depend on a set of variables that includes their time derivatives and gradients, and therefore must be consistent with a nonlocal statement of the second law of thermodynamics where the entropy production is represented as the sum of a non-negative supply and a flux. Both terms are also assigned by means of constitutive functions. A new and quite general model relating the residual-polarization rate and the ‘electric Gibbs free entropy’ is established. This thermodynamic potential is modeled according to the Landau-Devonshire approach and appropriate explicit expressions are proposed for anisotropic materials. Consequently, a new explicit evolution equation for the polarization vector is obtained for both high and low temperatures. In particular, the Landau-Devonshire scalar model is recovered in the isotropic case. Under the assumption of small strains and small polarization gradients, hysteresis and electromechanical coupling are described for a simple one-dimensional model. The advantage of our original approach is that a few constitutive parameters provide a good fit of material behavior.

Coherent structure detection and the inverse cascade mechanism in two-dimensional Navier–Stokes turbulence

Coherent structures in two-dimensional Navier–Stokes turbulence are ubiquitously observed in nature, experiments and numerical simulations. The present study conducts a comparison between several structure detection schemes based on the Okubo–Weiss criterion, the vorticity magnitude and Lagrangian coherent structures (LCSs), focusing on the inverse cascade in two-dimensional hydrodynamic turbulence. A recently introduced vortex scaling phenomenology (Burgess & Scott, J. Fluid Mech., vol. 811, 2017, pp. 742–756) allows the quantification of the respective thresholds required by these methods based on physical properties of the flow. The resulting improved comparability allows us to identify characteristic relative differences in the detection sensitivity between the employed structure detection techniques. With respect to the inverse cascade of energy, coherent structures contribute, as expected, substantially less to the cross-scale flux than the residual incoherent parts of the flow although the energetically dominant coherent structures lead to an important large-scale deformation of the energy spectrum. This cascade inactivity can be understood by an increased misalignment of strain-rate and subgrid stress tensors within coherent structures. At the same time, the structures exhibit strong and localised nonlinear cross-scale interactions that appear to stabilise them. We quantify and interpret the resulting shape preservation of coherent structures in terms of a multi-scale gradient approach (Eyink, J. Fluid Mech., vol. 549, 2006, pp. 191–214) as the depletion of strain rotation and vorticity gradient stretching whereas the dynamics of the residual fluctuations are consistent with the vortex thinning picture.

Computed tomography, functional and cognitive changes in the long-time period of surgery of cerebral aneurysms

Assessment of patients with intracranial aneurysms in the late postoperative period consists of both determining structural changes in computed tomography (CT) and the neurological and cognitive status of the patient. Meantime, the topic of the relationship between structural pathology in CT and cognitive impairment has not been suffi ciently disclosed. Objective: to determine CT, functional and cognitive outcomes in the long-term period of surgical treatment of cerebral aneurysms. Material and methods. The data of CT angiography of 49 patients operated on for intracranial aneurysms were analyzed. 39 patients were examined neurologically for 2.3 years using a range of rating scales. Results. The residual part of the aneurysm after surgery was found in 50% of patients with complex aneurysms, more often in patients with PMA-PSA aneurysms. The connection between the method of surgery and the preserved cervical part with structural changes in the brain and the development of cognitive impairment in the late postoperative period has not been proven. Conclusion. CT angiography preoperatively makes it possible to identify a group of complex aneurysms with a high risk of preservation of the cervical part and the development of brain structural changes. The predictors of the development of ischemic changes in the brain, hydrocephalus, and cognitive dysfunctions was the advanced age of patients, the duration of the operation, and a history of hypertension.

Extended concentric arches model for piled beam-supported embankments

Geosynthetic-reinforced embankments founded on piled beams have emerged as a new ground modification technique for supporting earth embankments over deep soft subsoil. This paper presents an analytical model for this technique that combines parts of two existing analytical design models. The soil arching behaviour that divides the vertical embankment load into a part that is transferred to the piled beams directly, and the residual load part that rests on the geosynthetic, is described by the 3D part of the Concentric Arches (CA) soil arching model of van Eekelen et al. (2013 and 2015), which was adopted in CUR226:2016. The paper also compares the difference between adopting the 2D or the 3D part of this CA model. The tensioned geosynthetic effect was described by the membrane action equation of Pham (2020b). This equation calculates the geosynthetic strain and includes load–deflection behaviour, adhesion, and friction along the geogrid/soil interface. Two field studies and fully coupled hydromechanical finite element analyses were used to verify the proposed analytical approach and its assumptions. The paper compares the effect of founding geosynthetic-reinforced embankments on piles or piled beams. Finally, a parametric study showed the impact of beam width, center-to-center pile spacing, and geogrid stiffness on load transfer efficiency.

A Fast Kernel-Based Optimal Control Framework for Autonomous Driving

A novel, promising strategy to improve path-tracking performance for autonomous driving is to combine a nominal model with an additive residual model. The residual part is identified by a kernel method Gaussian process (GP) regression from continuous data streaming. However, the high computational complexity of simultaneously using both numerical optimization and supervised learning is a critical challenge for applications with fast dynamics. This also limits the generalization capability in untrained circumstance. To address these issues, we design a feedforward compensator to handle the stochastic GP model. This allows an analytical solution to optimize the formulation, and therefore greatly lowers the computational burden. Our experimental results show that the computational time was reduced by 40 ms in comparison to the classical general-source solver. Consequently, the learning part can now track 19% more data points in one control step, saving more computation power to be allocated to prediction. In addition, we optimize the prediction dimension and apply the local technology to cluster intractable dictionary. Together, these improvements allow our fast kernel-based optimal control (FKB-OPT) framework to exhibit superior performance under inexperienced trajectories in the road tests.

A Dam Deformation Residual Correction Method for High Arch Dams Using Phase Space Reconstruction and an Optimized Long Short-Term Memory Network

Dam safety is an important basic part of national water network security. Building a dam deformation prediction model based on monitoring data is crucial to ensure dam safety. However, traditional statistical regression methods have shortcomings, such as a weak nonlinear fitting ability when constructing dam deformation monitoring and prediction models. The residual part of the statistical regression results usually contains parts that cannot be effectively explained by the linear regression method, that is usually highly variable and noisy. In this study, the phase space reconstruction method is used to smooth the residual term of the statistical regression model to eliminate noise interference. On this basis, an improved long short-term memory (LSTM) neural network is used to learn the nonlinearity contained in the residual term of the linear regression. Considering the impact of parameter selection on model performance, the gray wolf optimization (GWO) algorithm is used to determine the optimal parameters of the model for better performance. A high arch dam is used as a case study, with multiple measuring points used as research objects. The experimental results show that the phase space reconstruction can effectively smooth the high-frequency components in the residual term and remove noise interference. In addition, the GWO algorithm can effectively determine the hyperparameters of the LSTM network, thereby constructing a residual prediction model with high prediction accuracy. The combination of statistical models and deep learning prediction methods can effectively improve the model prediction performance while preserving the model interpretability and transparency.

Residual Carbon Derived from Different Maize Parts Differed in Soil Organic Carbon Fractions as Affected by Soil Fertility

Maize straw returning is one of the important measures to improve dryland soil organic carbon (SOC). However, the effects of different maize parts on SOC fractions with different soil fertility levels in situ are not exactly clear. Therefore, an in situ field incubation experiment over 540 days, by adding different 13C-labeled maize parts (root, stem and leaf) into low- (no fertilizer treatment) and high- (manure treatment) fertility soils, was conducted at a long-term brown earth experimental site in Shenyang of China to figure out the effects of different maize parts on SOC fractions (dissolved organic carbon (DOC) and particulate organic carbon (POC)). The results showed that the distribution–DOC ratio of low-fertility treatment was higher than that of high-fertility treatment in the period of rapid decomposition of straw. In both low- and high-fertility soils, the ratio of carbon to DOC in leaf residue was higher than that in root and stem residues. The proportion of root, stem and leaf residue converted to DOC in low-fertility soil was 4.51%, 3.89% and 5.00%, respectively. The proportion of root, stem and leaf residue converted to DOC in high-fertility soil was 4.10%, 3.65% and 4.11%, respectively. As for the distribution–POC ratio, during the period of rapid decomposition of straw, the ratio of carbon conversion from root and stem residue to POC was generally higher than that from leaf residue. The ratio of carbon conversion to POC of root, stem and leaf residues in high-fertility treatment was higher than that in low-fertility treatment. In low-fertility treatment, the proportion of root, stem and leaf residues converted to POC was 41.34%, 46.33% and 36.11%, respectively. The proportion of root, stem and leaf residue converted to POC in high-fertility soil was 46.48%, 44.45% and 41.14%, respectively. The results showed that, for DOC, a low fertility level and more leaf residue types were beneficial. While, for POC, root and stem residues with a high fertility level were beneficial. These results provide evidence that the addition of different parts of maize residues would have differing effects on DOC and POC. Leaf residues in low-fertility soils were more suitable for increasing DOC. Root and stem residues in high-fertility soils were more suitable for increasing POC. Nevertheless, we could not ignore the unmeasured SOC fractions that some of the residues could be converted to.