Residual Mass Research Articles

Fabrication of CNC-AC bionanosorbents from the residual mass of Magnolia champaca l. Bark after methanol extraction for wastewater treatment: Continuous column adsorption study

In this current study, a new class of multifunctional biobased ecofriendly nanosorbents namely crystalline nanocellulose-activated char (CNC-AC) nanosorbents were fabricated by employing a much more innovative and beneficial solvent evaporation induced phase separation (EIPS) technique. While the crystalline nanocellulose (CNC) were extracted from a very much new, innovative, and beneficial agrowaste source namely banana tree (M. oranta) rachis fibers by conducting a series of chemical treatments like scouring, alkali treatment, bleaching, and acid hydrolysis reactions. Additionally, the biochar were synthesized from the residual mass of Magnolia champaca L. barks after methanol extraction and functionalized by 30 % H3PO4 to improve their overall properties. Besides these the fixed-bed continuous column adsorption study were carried out by optimizing the various influential factors such as preliminary concentration and flow rates of the inlet wastewater solution, along with the nanosorbent bed heights into the applied column. For better understanding the overall physicochemical, thermomechanical, and morphostructural behavior of the newly fabricated polyfunctional CNC-AC bionanosorbents the samples were characterized by conducting FTIR-ATR, FESEM, BET, XRD, TGA analysis. Meanwhile the treated and nontreated water specimens were examined by conducting AAS and UV–vis-NIR techniques. The obtained results recommended that the newly produced CNC-AC nanosorbents have contained a quite number of active edges/binding sites along with substantial sp. surface area (around 316.95 m2/g). Additionally, they possessed a crystallinity index about 59.98 ± 0.027 %, greater thermal steadiness up to 600 °C, and outstanding 2D honeycomb-like mesoporous peripheral surface microstructure with a promising spherical shapes and smaller size nearly 5–10 nm. The highest removal capacity were found at 538.91 mg/g and 455.70 mg/g for Pb2+ and CR respectively. Additionally, for better understanding the experimental breakthrough curves (BTC) were evaluated by several well established column models while the maximum R2 value was found around 0.999 for the Thomas model and reduced chi squire (χ2) value was around 0.0001.

Évaluation de la réponse thérapeutique par TEP-FDG des cancers solides (critères PERCIST 1.0)

18F-Fluoro-Deoxyglucose (FDG) Positron Emission Tomography (PET) is an imaging technique used to study glucose metabolism in cells. It is particularly useful in oncology, especially for initial diagnosis and the detection of recurrence. Thanks to its functional approach to tissues, its use has evolved towards the evaluation of anticancer treatments, both in a personalized approach to patients and as part of clinical trials of new biotherapies. This technique provides additional information compared to conventional imaging, which is not always able to assess tumor viability of potentially necrotic or fibrotic residual masses after treatment. However, the use of FDG-PET requires a rigorous methodology, both for the performance of the studies and for their interpretation. Based on a large body of literature, interpretation criteria for solid tumors have been published and updated. PERCIST 1.0 (Positron Emission Tomography Response Criteria In Solid Tumors), proposed by an American task force in 2009, aims to clarify and standardize practice. These criteria will evolve according to the specificities of new biotherapies such as immunotherapy.

Synergistic removal of malachite green and Cr(Ⅵ) using ethylenediamine disuccinic acid functionalized silica gel

As common industrial raw materials, malachite green (MG) and Cr(Ⅵ) generally coexist in waste liquids discharged from the paper printing, leather, and textile industries, causing serious harm to humans and the environment. Therefore, developing an effective method for the synergistic removal of MG and Cr(Ⅵ) from aquatic environments is of great research value. In this work, the non-homogeneous Fenton-like catalysts, namely, EDDS-Silica and EDDS-Co2+-Silica were successfully prepared using ethylenediamine disuccinic acid (EDDS) and silica gel (Silica) as raw materials, and a non-homogeneous Fenton-like catalytic method was developed for the efficient and synergistic removal of MG and Cr(Ⅵ) from wastewater. EDDS-Silica and EDDS-Co2+-Silica were analyzed using Fourier infrared spectroscopy and X-ray photoelectron spectroscopy to determine their structural composition and elemental contents. The catalytic degradation and removal effects of these materials in an MG single-waste system were also investigated. The results demonstrated that the incorporation of both materials can overcome the limitation of the conventional Fenton reaction, which is its applicability to acidic environments only. Moreover, EDDS-Co2+-Silica showed better degradation effects on MG than EDDS-Silica. Quantitative calculations based on density functional theory were used to predict the optimal coordination forms between Co2+and EDDS-Silica as well as the MG structure. The lowest unoccupied and highest occupied molecular orbitals of the catalysts were then used to predict the active sites on which MG tends to capture or release electrons during the degradation reaction. The optimal conditions for the synergistic removal of MG and Cr(Ⅵ) from a binary system using EDDS-Co2+-Silica were further investigated under different influencing factors. The results showed that EDDS-Co2+-Silica still had excellent catalytic effect on the degradation rate of MG in the range of pH 3-7, and the optimal conditions were as follows: solution pH, 7; degradation time, 1 h; temperature, 25 ℃; H2O2 concentration, 20 mmol/L; and the initial mass concentration of Cr(Ⅵ), 25 mg/L. Under the above conditions, the degradation rate was increased from 87.25% to 96.67% compared with that in the MG monosystem. Obvious enhancements in degradation effect and efficiency confirmed that the incorporation of EDDS-Co2+-Silica was favorable for the synergistic removal of MG and Cr(Ⅵ) in the binary system. Strongly oxidizing Cr(Ⅵ) can participate in the Fenton reaction, thus promoting MG degradation over a wide pH range. Thus, a positive synergistic effect exists between MG and Cr(Ⅵ). Considering that a large number of metal ions remained in the solution after the degradation reaction, EDDS-Silica was added to the degradation solution, and adsorption experiments were performed for 4 h at 30 ℃to adsorb and remove Cr and Fe via the strong chelating property of EDDS. The total residual mass concentrations of Cr and Fe were 4.96 and 1.02 mg/L, respectively, which meet national emission standards. These findings indicate that EDDS-Silica has good effects on the removal of residual metal ions after the nonhomogeneous Fenton reaction. As heterogeneous Fenton-like catalysts, the aminopolycarboxylic acid-modified materials proposed in this study can simultaneously promote the Fenton reaction and remove residual metal ions, thereby effectively removing MG and Cr(Ⅵ) from the binary system while ensuring that the content of residual metal ions in the system meets environmental emission standards. This study has broad application prospects in dye degradation and heavy-metal-ion wastewater treatment, and provides a reference value and theoretical basis for the development of other similar ligand-modified materials.

The DEHVILS in the details: Type Ia supernova Hubble residual comparisons and mass step analysis in the near-infrared

Measurements of type Ia supernovae (SNe Ia) in the near-infrared (NIR) have been used both as an alternate path to cosmology compared to optical measurements and as a method of constraining key systematics for the larger optical studies. With the DEHVILS sample, the largest published NIR sample with consistent NIR coverage of maximum light across three NIR bands (Y, J, and H), we check three key systematics: (i) the reduction in Hubble residual scatter as compared to the optical, (ii) the measurement of a “mass step” or lack thereof and its implications, and (iii) the ability to distinguish between various dust models by analyzing slopes and correlations between Hubble residuals in the NIR and optical. We produce SN Ia simulations of the DEHVILS sample and find that it is harder to differentiate between various dust models than previously understood. Additionally, we find that fitting with the current SALT3-NIR model does not yield accurate wavelength-dependent stretch-luminosity correlations, and we propose a limited solution for this problem. From the data, we see that (i) the standard deviation of Hubble residual values from NIR bands treated as standard candles are 0.007–0.042 mag smaller than those in the optical, (ii) the NIR mass step is not constrainable with the current sample size of 47 SNe Ia from DEHVILS, and (iii) Hubble residuals in the NIR and optical are correlated in the data. We test a few variations on the number and combinations of filters and data samples, and we observe that none of our findings or conclusions are significantly impacted by these modifications.

Double-layered phase change material microcapsules with enhanced solar thermal conversion performance and fire safety for buildings

Building energy saving is directly related to resource utilization optimization and residential comfort, which is important for the environment and production. At present, building energy saving is developing towards green, recyclable, and low-risk directions. Phase change materials, as effective energy storage materials, can pollution-freely regulate room temperature. Regarding the leakage, phase change materials are encapsulated into microcapsules. However, the flammability and slow thermal response of phase change material microcapsules hinder their application in building materials. Herein, novel double-layered phase change material microcapsules (D-MPCMs), with the inner poly melamine tetramethylene phosphonium sulfate (PMTMPS) shell layers and outer polydopamine (PDA) shell layers, are prepared by in-situ polymerization method, which are filled into epoxy resin (EP) coatings. This study is the first to use cross-linked flame retardants as the shells of microcapsules. The outer PDA shell layer improves the flame retardancy of microcapsules while overcoming the problem of slow thermal response rate. Thermogravimetric analysis and differential scanning calorimeter tests are considered to explore the thermal stabilities and properties of the resultant microcapsules. Results demonstrate that D-MPCMs have a residual mass of 10.8 % more at 600 ℃ and a faster thermal response rate. The study shows that the addition of the PDA shell layers not only reduces the total heat release from 64.29 MJ/m2 to 45.01 MJ/m2 but also enhances the solar thermal conversion performance which gives potential in the process solar energy storage design and fire safety design in actual building application of epoxy resin coatings.

Effects of water quality and nitrogen on wheat productivity: Experimental and modelling study using the SALTMED model

AbstractThe effects of different water qualities and nitrogen doses need to be investigated for wheat growth to determine the optimal management strategy for sustaining wheat production potential to ensure human food security. Therefore, a 2‐year study (2020–2021 to 2021–2022) was conducted on wheat irrigated with different water qualities, including canal water (Ca), tubewell water (Tu) and mixed Ca‐Tu water (Mx), each fertilized with two nitrogen doses, that is, N75 = 75 kgN.ha−1 and N100 = 100 kgN.ha−1. Ca⨯N100 performed best, with 5.12 t.ha−1 grain yield, 11.60 t.ha−1 biomass, 102.83 cm plant height and 1.32 kg.m−3 water productivity. The best values of the root mean square error (RMSE), normalized root mean square error (NRMSE), coefficient of determination (R2) and coefficient of residual mass (CRM) were 0.11, 0.12, 0.93 and −0.004, respectively, for calibration and 0.13, 0.15, 0.87 and ±0.01, respectively, for validation of the SALTMED model. The scenario simulation was performed for additional levels of water salinity (electrical conductivity [EC] = 8 and 12 dS.m−1) and nitrogen doses (50, 125, 150 and 175 kgN.ha−1). The results revealed improvements in wheat grain yield of 107%, 16% and −6% at EC = 8 dS.m−1 and 125%, 31% and 5% at EC = 12 dS.m−1, while the improvements in biomass were 113%, 22% and −2% at EC = 8 dS.m−1 and 137%, 29% and 8% at EC = 12 dS.m−1 with increasing nitrogen doses from 50–125 kg.ha−1, 125–150 kg.ha−1 and 150–175 kg.ha−1, respectively. It is recommended that high‐quality water with the lowest possible EC and nitrogen applications of up to 150 kgN.ha−1 be adopted for wheat production in semi‐arid areas of Punjab, Pakistan.

Pulmonary Aneurysmal Arteriovenous Malformation Treated With a Vascular Plug

Purpose To report a case of an asymptomatic patient with a pulmonary aneurysmal arterio-venous malformation successfully treated with a vascular plug. Case report An active 30-year-old male patient, residing at 3000 ft above sea level was referred due to an incidental finding on a CT scan of a 37 mm vascular mass localized in the lower lobe of the right lung, which corresponded to a pulmonary arteriovenous malformation with a single feeding artery. The patient was treated with an Amplatzer vascular plug, which effectively excluded the afferent vessel. An angio CT at 19 months follow-up revealed a hypodense residual mass of 9.0 mm in diameter with no arterial filling or venous drainage. The patient is fully active and remains asymptomatic at 24 months follow-up. Conclusion An unusual case of a pulmonary aneurysmal arteriovenous malformation successfully treated with a vascular plug is presented, highlighting the efficiency of this procedure.

Enhanced enzymatic hydrolysis of corn stover by γ-valerolactone pretreatment and the characteristics of enzymatic residues

Efficient pretreatment methods are crucial for the generation of fermentable sugars from the renewable lignocellulose. In this study, γ-valerolactone (GVL), a biomass-derived green solvent, was used to fractionate corn stover (CS). The impact of different additives on the enzymatic hydrolysis and pretreatment of CS within the GVL/water system was carefully investigated. The results demonstrate that the use of H2SO4-assisted GVL/H2O (80:20, w/w) pretreatment at mild conditions successfully facilitates the depolymerization of CS, thereby improving the cellulase accessibility. Furthermore, by increasing the GVL pretreatment temperature to 160 °C with 100 mM H2SO4 addition, the pretreated CS led to nearly 100 % of hydrolysis yield at 2 % (w/v) solid load. Finally, the thermogravimetric analysis (TGA) was performed to evaluate the thermal decomposition characteristics of untreated CS and enzymatic residues based on the H2SO4-assisted GVL/H2O pretreatment. The results indicate that the enzymatic residues had two depolymerization stages from 200 °C to 500 °C with a final residual mass of 22.73 %, which was higher than that of untreated CS (20.56 %). Overall, this study provides an efficient lignocellulose pretreatment for fermentable sugars production and valorization of enzymatic residues.

397 Effect of corn harvest with a chopping head on performance of cattle grazing corn residue

Abstract The addition of stalk chopping equipment on combine heads has become more common. An advantage of grazing residue compared with baling, is the ability of cattle to select the more digestible plant parts (husk and leaf). Chopping may impact this ability and decrease the feeding value. Thus, this study was designed to evaluate the effects of chopping residue at harvest on grazing cattle performance. A cornfield (16 Mg grain/ha) was divided into 12 paddocks blocked by location within field and assigned randomly to be harvested using a chopping or non-chopping combine head, with 4 paddocks assigned to be grazed (1.05 ha) from each harvest method (HM) and 4 ungrazed. Growing steers [n = 40; body weight (BW) = 230 ± 3.5 kg] were stratified by BW and assigned randomly to a grazed paddock, with 6 steers in the west block and 4 steers in the east block, with 1 rumen canulated steer (484 ± 33 kg BW) being assigned to each of the east paddocks and used as diet samplers. This resulted in the same grazing pressure (2.9 animal units/ha) in grazed paddocks. Cattle were supplemented at 0.6 % of initial BW with a distillers dried grains plus solubles and mineral mix daily. Cattle grazed for 56 d resulting in 5.4 Animal Units Months/ha. Residue mass of three 0.58 m2 frames was sampled in each paddock before (d -1), during (d 36) and after grazing. Husks were collected from three 5.81 m2 areas per paddock at each of the three timepoints. For residue mass, there was a significant (P < 0.01) HM by time interaction. There was no difference (P = 0.34) in residue mass between HM prior to grazing. However, at 36 d into grazing, residue mass of standard was greater (P = 0.03) than chopped, and post-grazing residue mass of chopped was greater (P = 0.01) than standard. When husk (kg/ha) was evaluated, there was a significant (P < 0.01) HM by time by grazing interaction. Prior to grazing, there was no difference (P ≥ 0.66) in husk between the grazed and ungrazed paddocks within HM. However, husk was less (P < 0.01) for chopped than standard. On d 36, within HM, grazed had less (P < 0.01) husk than the ungrazed. However, within grazing status on d 36 there was no effect (P ≥ 0.52) of HM. Post-grazing there were no differences (P ≥ 0.19) in husk among treatments. Within grazed treatments there was greater (P < 0.01) husk prior to grazing initiation compared with both D36 and post-grazing which did not differ (P ≤ 0.85). Within ungrazed treatments, pre-grazing and D36 did not differ (P ≥ 0.10) in husk, however, husk was lesser (P > 0.01) at the post-grazing sampling. For ADG there was no difference (P = 0.20) between HM, with 0.37 and 0.31kg/d for standard and chopped, respectively. Overall, HM had no effect on grazing cattle performance.

White dwarf eccentricity fluctuation and dissipation by AGB convection

ABSTRACT Millisecond pulsars with white dwarf companions have typical eccentricities $e\sim 10^{-6}{\!-\!}10^{-3}$. The eccentricities of helium white dwarfs are explained well by applying the fluctuation–dissipation theorem to convective eddies in their red giant progenitors. We extend this theory to more massive carbon–oxygen (CO) white dwarfs with asymptotic giant branch (AGB) progenitors. Due to the radiation pressure in AGB stars, the dominant factor in determining the remnant white dwarf’s eccentricity is the critical residual hydrogen envelope mass $m_{\rm env}$ required to inflate the star to giant proportions. Using a suite of mesa stellar evolution simulations with $\Delta m_{\rm c}=10^{-3}\, {\rm M}_{\odot }$ core-mass intervals, we resolved the AGB thermal pulses and found that the critical $m_{\rm env}\propto m_{\rm c}^{-6}$. The resulting eccentricity $e\sim 3\times 10^{-3}$ is almost independent of the remnant CO white dwarf’s mass $m_{\rm c}$. Nearly all of the measured eccentricities lie below this robust theoretical limit, indicating that the eccentricity is damped during the common-envelope inspiral that follows the unstable Roche lobe overflow of the AGB star. Specifically, we focused on white dwarfs with median masses $m_{\rm c}\gt 0.6\, {\rm M}_{\odot }$. These massive white dwarfs begin their inspiral with practically identical orbital periods and eccentricities, eliminating any dependence on the initial conditions. For this sub-sample, we find an empirical relation $e\propto P^{3/2}$ between the final period and eccentricity that is much tighter than previous studies – motivating theoretical work on the eccentricity evolution during the common envelope phase. The eccentricities of lower mass CO white dwarfs may be explained by alternative formation channels.

Исследование характера изменения твердости композиционных материалов с алюминиевой матрицей, упрочненной золой кокосовой скорлупы и красным шламом, с использованием анализа Тагучи

Introduction: in present scenario, light and high strength aluminium metal matrix composite are extensively used due to its high mechanical and tribological properties. Aluminium metal matrix composite reinforced with ceramic and industrial waste can customize its mechanical-chemical behavior. The purpose of the work: to create an aluminum matrix composite material using ceramic (primary) and industrial (secondary) waste represented by red mud and coconut shell ash, respectively. The mass fraction of the strengthening phase varied from 5 to 12.5 wt. % respectively with the residual mass percentage of the aluminum alloy. Method of investigation: nine specimens of composite materials were prepared by stir casting. Stirring was carried out at a speed of 50 to 100 rpm for 20 minutes at a temperature of 800 °C. Result and Discussion: the hardness behavior of the aluminum metal matrix composite was studied at an indentation load of 10, 15 and 20 kN. Taguchi method with L27 orthogonal array was selected to conduct analysis of variance (ANOVA) and regression analysis by selecting the mass percentage of red mud and mass percentage of coconut shell ash. The indentation load was used as an input parameter, and the hardness behavior was taken as an output parameter. The signal-to-noise ratio, response rank table, contour plot, and normal probability plot are investigated and it is found that hardness values improve with the addition of both reinforcing components and indenter load. The results show that the hardness value varies from 33.34 HB to 53.44 HB, and the effect of red mud mass percentage is more significant than the indenter load and coconut shell ash mass percentage.

Research on the Stability and Response of Food Packaging Polystyrene Resin Materials to γ-ray Irradiation.

Radiation stability of food packaging materials is the key to ensuring food quality. In this study, 60Co γ-ray was selected to investigate the radiation resistance of food packaging polystyrene (PS) resin material, although the FTIR analysis showed that the intensity of several peaks decreased slightly. The gel permeation chromatography (GPC) results displayed that the value of peak molecular weight (Mp) of PS went from 2.68 × 105 g/mol down to 2.22 × 105 g/mol. Moreover, the residual mass (Res) of PS increased from 7.208 to 30.23%, indicating that the tendency of coking of PS was stronger after irradiation. In addition, the peak intensities of the three main pyrolysis products -CH2-, CH4, and CH2=CH2 increased by more than 30% compared to unirradiated PS, and a large number of them were detected in the whole pyrolysis process. Moreover, mechanical property analysis finds that both breaking strength and elongation data increased before irradiation dose of 50 kGy, then, decreased sharply with further increase of irradiation dose. The theoretical bond order analysis confirmed that the tertiary carbon bond attaching the benzene ring had the lowest bond energy. This study can give helpful guidance when using PS for food packing materials.

Association between partial remission phase in type 1 diabetes and vitamin D receptor Fok1 rs2228570 polymorphism.

The aim of the current study was to assess the natural course of partial remission (PR) phase of type 1 diabetes (T1D) and to highlight the putative association between vitamin D receptor (VDR) (Fok1) gene polymorphism and PR phase. Ninety participants with newly diagnosed T1D were followed up for a total of 12months. The VDR (Fok1) rs2228570 gene polymorphism was genotyped using allelic discrimination (AD) assay. Fifty-four patients (60 %) reached PR with an average duration of 5.63±2.9months. Among remitters, the frequency of CC "FF" genotype and allelic frequency of C "F" were significantly higher (p<0.001). Furthermore, participants expressing "CC" genotype had earlier onset of PR and spent a significantly longer duration in remission (p<0.001). Younger age (p<0.001; OR 41.6; CI 12.12-142.99), absence of DKA (p<0.001; OR 16, CI 4.36-50.74), higher C-peptide levels (p<0.001; OR 19.55; CI 6.52-58.63), and presence of CC "FF" genotype of VDR (p<0.001; OR 6.74; CI 2.41-18.86) best predicted the overall occurrence of PR. Younger age, less extent of metabolic derangements, and expression of a CC "FF" genotype were found to influence the occurrence of PR. Data from the current study showed that the "C" allele could have a protective role on preserving residual β-cell mass and could predict both onset and duration of PR among newly diagnosed T1D. These findings support the growing concept of future tailored precision medicine.

Effective move of Polypyrrole/TiO2 hybrid nanocomposites on removal of methylene blue dye by photocatalytic activity

Polypyrrole (PPy) was synthesized effectively by chemical oxidative polymerization of pyrrole. Organic-inorganic hybrid materials PPy-TiO2 with different PPy weight percents were prepared by mechanical mixing, by using titanium oxide nanoparticles. The characterizations of PPy-TiO2 hybrid nanocomposites were analyzed by FTIR, UV–Vis, XRD, TGA & DSC and SEM & EDAX. Fourier transform infrared (FTIR) spectra and X-ray diffraction (XRD) were used to distinguish the structure of the attained PPy-TiO2 hybrid nanocomposites. UV–vis techniques are proved the polymerization of pyrrole monomer and the strong interaction between PPy and TiO2 nanoparticles. Thermogravimetric analyzer (TGA-DSC) curves revealed that TiO2 can decrease the weight loss of nanocomposite and increase the thermal stability of synthesized nanocomposites. The residual mass of the pure Pyy-36.51 %, PPy-TiO2 (25 %)-64.82 %, PPy-TiO2 (50 %)-60.82 %, PPy-TiO2 (75 %)-70.50 % and pure TiO2- 96.69 % nanocomposites at the residual temperature 497.80 °C. The morphology and molecular structure of the hybrid nanocomposite were characterized by scanning electron microscope & Energy dispersive X-ray analysis spectroscopy (SEM & EDAX). These characterization results confirmed the polymerization of pyrrole and the strong interaction between PPy and TiO2. The material with outstanding absorption capability that meet in optical application is the challenging way, thus the photocatalytic analysis of PPy-TiO2 hybrid nanocomposites is merely a admissible results. It is notably the favorable degradation efficiency of pure PPy, the PPy+TiO2 (25 % 50 % & 75 %) nanocomposites are 82 %, 66 %, 67 % and 53 % respectively.

The encapsulation of noble metal over metal oxide semiconductor TiO2@Ag for the degradation of sulphur dye in effluent water by photocatalysis and electrochemical water splitting

Metal Oxide Semiconductor - Metal core-shell nanostructure with TiO2 as core and Ag nanoparticles as shell (TiO2@Ag) have been synthesized by a simple, environmentally friendly room temperature wet chemical method. The prepared TiO2@Ag core-shell nanoparticle was characterized by using various analytic techniques. X-ray diffraction analysis confirms the formation of tetragonal bcc structure anatase phase of TiO2 and Face-Centred Cubic structure (fcc) of silver in core-shell nanostructure. Fourier Transform Infrared Spectroscopy (FTIR) study proved the presence of characteristic peaks of both TiO2 and Ag. XPS study revealed the existence Ti4+ and metallic silver in core-shell nanostructure, High - Resolution Transmission Electron Microscopy (HR–TEM) and High - Resolution Scanning Electron Microscopy (HR–SEM) revealed the covering of Ag nanoparticles at the surface of TiO2 spheres. The TiO2@Ag core-shell nanoparticles exhibit a high residual mass of 95.9 % and stability to withstand up to 1000 °C. The prepared TiO2@Ag core-shell nanoparticles as photocatalyst showed enhanced photocatalytic degradation (240 min) of sulphur dye in effluent water with a degradation efficiency of 81 % and capable of employing in wastewater treatment to eliminate toxic elements present in it. In the current study, we have used core-shell nanoparticles prepared using the wet chemical method at room temperature. The prepared core-shell nanoparticles were used to study the photocatalytic degradation of sulphur black dye directly collected from textile effluent water. They were also used for the production of oxygen and hydrogen through the electrolysis process. The synthesized TiO2@Ag core-shell nanoparticles act as effective electrocatalyst for the production of oxygen and hydrogen through oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) using the electrolysis process.

PE079 Retroperitoneal lymph node dissection for post-chemotherapy residual masses: Comparison of peri-operative outcomes after open versus robot-assisted approach

PE079 Retroperitoneal lymph node dissection for post-chemotherapy residual masses: Comparison of peri-operative outcomes after open versus robot-assisted approach

VJY32 Supine approach for RA-RPLND for post chemotherapy residual mass in testicular cancer: Video based illustration and long term experience

VJY32 Supine approach for RA-RPLND for post chemotherapy residual mass in testicular cancer: Video based illustration and long term experience

Vanillin-derived co-curing agent for enhanced flame retardancy and mechanical properties in epoxy resin

Herein, we present the synthesis and characterization of a novel phosphorus-containing epoxy co-curing agent, ANVD, fabricated via a one-pot method utilizing vanillin, 1,5-diaminonaphthalene, and DOPO as raw materials. Structural analysis conducted through FTIR and NMR spectroscopy confirmed the composition of ANVD. Differential scanning calorimetry (DSC) results indicated ANVD has significant contribution to the curing crosslinking of DGEBA, resulting in a slightly decreased Tg value for EP/ANVD compared to EP/DOPO, albeit still notably higher. Thermogravimetric analysis (TGA) revealed a reduction in the T5% and Tmax values of EP/ANVD, yet ANVD’s superior char-forming ability increased char residue mass at elevated temperatures. Combustion tests showcased the outstanding flame retardancy of EP/ANVD, with EP/ANVD-5 exhibiting a limiting oxygen index (LOI) value of 33.2 % and achieving a V-0 rating in the UL-94 test. Furthermore, EP/ANVD-5 displayed a notable decrease of 38.6 % and 32.1 % in pHRR and av-HRR, respectively, compared to pure EP, surpassing EP/DOPO with equivalent phosphorus content. Analysis of decomposition products in both condensed and gas phases revealed ANVD’s role in forming dense and continuous expanded char layers during combustion, releasing phosphorus radicals and non-combustible gases, thus exhibiting dual-phase flame retardant effects. Additionally, EP/ANVD-3 exhibited enhanced mechanical properties, with tensile strength and modulus increasing from 68.5 MPa and 0.75 GPa to 76.5 MPa and 0.86 GPa, respectively, compared to pure EP. Overall, the introduction of the bio-based flame retardant ANVD presents promising opportunities for the utilization of bio-based materials in flame retardancy applications.

An analytical model for the penetration of flat-nosed long rods into semi-infinite concrete targets

An analytical model is presented herein on the penetration of a flat-nosed long rod into a semi-infinite concrete target based on the previous theoretical studies and experimental observations. The nose shape of the flat-nosed long rod in deformable penetration state is assumed to be a circular arc and the length of plastic region of the long rod in hydrodynamic penetration is taken into account. The behavior of an erosive penetrator is further divided into two penetration stages (namely semi-hydrodynamic penetration and hydrodynamic penetration) and a new critical impact velocity (i.e. erosive velocity) is derived to characterize the beginning/incipient erosion in accordance with plastic wave propagation theory. According to the new theoretical considerations, the relationship of dimensionless instantaneous mushrooming head radius versus impact velocity is rewritten and the method for predicting semi-hydrodynamic penetration tunnel radius is proposed. It transpires that the present model predictions are in good agreement with available experimental results for the penetration of flat-nosed long rods into semi-infinite concrete targets in terms of penetration depth, penetration modes, penetration tunnel size, residual mass and residual length.

Extraction, characterization and evaluation of antimicrobial activity of chitosan from adult Zophobas morio (Fabricius, 1776) (Coleoptera: Tenebrionidae)

The increasing demand for chitosan has led to the exploration of alternative sources, including insects. In this study, chitosan was extracted from Zophobas morio beetles with 19.17 % yield. FTIR and Raman Spectroscopy showed similar peaks in Z. morio chitosan (ZC) and commercial chitosan (CC). ZC showed low crystallinity (40.96 %) and high thermal residual mass (42.7 %) than CC. SEM imaging of ZC displayed pores ranging from 10 μm to 0.3 μm. EDX mapping revealed the homogenous presence of C, N and O elements. ZC exhibited low molecular weight (435.95 kDa) and low intrinsic viscosity (317.95 cm3/g) than CC (680.20 kDa and 480.87 cm3/g, respectively). Degree of deacetylation of ZC and CC was 96.24 % and 78.26 %, respectively. ZC showed antimicrobial activity against Escherichia coli (ATCC 25922), Klebsiella pneumoniae (ATCC 13883), Proteus mirabilis (ATCC 29906), Staphylococcus aureus (ATCC 25923), Enterococcus faecalis (ATCC 29212) and Candida albicans (ATCC 90028) with zones of inhibition ranging from 5 mm to 11 mm. The minimum bactericidal concentration of ZC against K. pneumoniae and P. mirabilis was lower than CC. This study suggests the applicability of insect chitosan as an antimicrobial agent in the food and pharmaceutical industries.