Mexico Reservoirs Research Articles

Draft genome sequence of rhamnolipid-producing bacteria Thermoanaerobacter thermocopriae strain CM-CNRG TB177 isolated from an oil reservoir in Mexico.

The draft genome of Thermoanaerobacter thermocopriae CM-CNRG TB177 isolated from an oil reservoir in Mexico was determined and annotated. The organism is a thermophilic and strict anaerobe bacterium that produces rhamnolipids, using glucose as a carbon source. The predicted genome size is 2,496,169 bp and 2,550 genes.

Polluted water from a storage dam (Villa Victoria, méxico) induces oxidative damage, AChE activity, embryotoxicity, and behavioral changes in Cyprinus carpio larvae

The Villa Victoria dam is one of the most important storage reservoirs in Mexico since it distributes water to more than 20 million inhabitants in the Metropolitan Zone of Mexico City. In this dam, the common carp (Cyprinus carpio) is an important food resource for the inhabitants, so the aim of this work was to evaluate the oxidative damage (lipoperoxidation, oxidized proteins, antioxidant enzymes activity and gene expression), AChE, embryotoxicity and behavioral changes in C. carpio embryos and larvae exposed to water from Villa Victoria dam for 24, 48, 72 and 96 h. The embryotoxicity was evaluated trough the General Morphology Score (GMS) and the teratogenic index. Behavioral changes in basal locomotor activity and thigmotaxis were evaluated in a DanioVision, Noldus ™. An increase in lipid and protein oxidation as well as modification of CAT, SOD and GPx enzymatic activity was observed during the exposure times. The GMS indicated a low development in the embryos, the teratogenic index was less than 1, however teratogenic effects as yolk edema, fin malformation, head malformation and scoliosis were observed. In parallel, an increase in AChE activity and gene expression was observed reflecting changes in distance traveled of the basal locomotor activity and thigmotaxis at the sampling points. In conclusion, pollutants in water from Villa Victoria dam caused oxidative damage, changes in SOD, CAT, GPx and AChE activity as well as embryotoxicity and modifications in the behavior of C. carpio larvae. This study demonstrates the need to implement restoration programs for this reservoir since, contamination in the Villa Victoria dam could eventually endanger aquatic life and human health.

Cyanotoxins bioaccumulation by fish in an anthropized reservoir in central Mexico

The bioaccumulation of cyanotoxins has been well documented in exposed organisms including fish, which represent a potential route to cyanotoxins transfer to humans by consumption of contaminated food. We determined the bioaccumulation of neurotoxic saxitoxins and hepatotoxic microcystins in muscle and liver/viscera of native (Goodea atripinnis), introduced (Poeciliopsis gracilis), and commercially important (Oreochromis niloticus) fish in Santa Catarina, an anthropized reservoir in Central Mexico. Additionally, we calculated the potential risk of human exposure due to the consumption of the studied species. The Santa Catarina Reservoir showed some physical and chemical water parameters generally associated with cyanobacterial blooms (e.g., high phycocyanin, chlorophyll-a, dissolved phosphorus concentrations, and alkaline pH) with presence of cyanotoxins produced by the cyanobacteria genera Microcystis, Dolichospermum, and Planktothrix, which were found in dissolved and particulate (sestonic) fractions of water. Moreover, we detected the presence of saxitoxins and microcystins in the tissues of all species studied. The risk of intoxication for humans was lower for the consumption of Nile tilapia muscle than for the other analyzed species, whose consumption should be avoided since it exceeds the recommended daily intake of microcystins for a short-term (i.e., two-week exposure time). These findings are remarkable because commercial fishing in reservoirs and the consumption of these fish could represent a route to human exposure to toxins, particularly microcystins. Our results highlight the need for the detection of cyanotoxins and the evaluation of their bioaccumulation by fish in unstudied eutrophic waterbodies, to reduce the potential health risk for humans and the environment.

Hybrid low salinity water and surfactant process for enhancing heavy oil recovery

Combining low salinity water (LSW) with surfactants has an enormous potential for enhancing oil recovery processes. However, there is no consensus about the mechanisms involved, in addition to the fact that several studies have been conducted in model systems, while experiments with rocks and reservoir fluids are scarce. This study presents a core-flooding experiment of LSW injection, with and without surfactant, using the core and heavy oil samples obtained from a sandstone reservoir in southeastern Mexico. The effluents and the crude oil obtained at each stage were analyzed. The study was complemented by tomographic analysis. The results revealed that LSW injection and hybrid process with surfactants obtained an increase of 11.4 percentage points in recovery factor. Various phenomena were caused by LSW flooding, such as changes in wettability and pH, ion exchange, mineral dissolution, detachment of fines and modification of the hydrocarbon profile. In the surfactant flooding, the reduction of interfacial tension and alteration of wettability were the main mechanisms involved. The findings of this work also showed that the conditions believed to be necessary for enhanced oil recovery with LSW, such as the presence of kaolinite or high acid number oil, are not relevant.

Buildup Evaluation of a Tight Overpressured Naturally Fractured Carbonate Reservoir with the Use of a Semi-Empirical Model

Summary This paper examines the buildup (BU) pressure response of a vertical well that penetrates an unconventional tight naturally fractured carbonate reservoir in Mexico. Four BUs in the same well over a period of 4 months, with intermediate flow periods, suggest partial closure of natural fractures. Radial flow is dominant in the four BUs. This is recognized in semilogarithmic and pressure derivative crossplots. However, the formulations require a consistent empirical component to match the BU data. The four BU tests are evaluated with a semi-empirical dual porosity model with restricted interporosity flow. The restricted flow between matrix and fractures is the result of partial secondary mineralization (cementation) within the fractures, which can be visualized as a natural positive skin that reduces the oil flow from the matrix to the fractures. The empirical part of the method is provided by a severity exponent (SE), which helps improve the match between the BU semilog and derivative plots. The BU evaluations permit estimating several parameters of interest, including fracture capacity (k2·h), skin, storativity ratio (ω), and the extrapolated pressure (p*). Results suggest that although natural fractures are present, they tend to close once the well goes on production. Thus, the conclusion is reached that the carbonate reservoir is tight and likely stress dependent. The calculated skin goes from an improved condition around the wellbore to slightly damaged conditions, probably due to fracture closure. The value of ω increases continuously, suggesting a tendency of the reservoir to move from dual to single porosity behavior. The reservoir is overpressured (0.87 psi/ft) and the extrapolated pressures (p*) decrease because of the tight characteristics of the reservoir. However, given the large size of the reservoir, the likelihood of depletion is low. The novelty of this study is the development of a new easy-to-use semi-empirical well testing model for matching the BU pressure response of four tests performed in a well that penetrates an overpressured, unconventional, tight, naturally fractured carbonate reservoir. The tests could not be matched with conventional methods currently available in the literature.

Lessons Learned from a Prematurely Ended High-Pressure Air Injection Test in a Light Oil Naturally Fractured Reservoir

Summary Sixty billion barrels of oil still reside in the matrix of mature onshore and offshore Mexican reservoirs located in the southeast basins after primary and secondary recovery. Capillary and viscous forces are responsible for this amount of oil retained within the pore structure of the matrix (immobile oil). Gravitational forces are not enough to counterattack these forces due to the high fracturing intensity. On the other hand, laboratory testing demonstrates that oil residing in the matrix could be mobilized by the exothermic reaction that takes place with air injection. Air injection in homogeneous heavy and light oil sandstones and nonfractured limestones, at small or large scales during short and long periods of time, is feasible for producing resources technically and economically nonrecoverable by other means. However, to the best of our knowledge, the published literature does not report any application of an air injection project in naturally fractured reservoirs. During 2015, an air injection pilot test was performed in a light oil naturally fractured reservoir in Mexico, referred to as “A” field. The implementation of the pilot test was preceded by its corresponding laboratory study, which consisted of five accelerating rate calorimeter (ARC) tests and two combustion tube (CT) experiments. The analysis of the aforementioned experimental work led us to corroborate that air and oil react at reservoir conditions. Based on the above finding, the pilot test was conducted by injecting air at a rate of 10 MMscf/D with a wellhead pressure of 4,500 psia for 1.5 years, which was followed by a 1.5-year production period giving a total of 3 years for the pilot test. The results indicate that combustion was successfully applied in the reservoir. However, no oil was produced. This paper discusses the results of a prematurely ended air injection pilot test in “A” field and the main lessons learned from it, which could help in the design and its subsequent implementation in other naturally fractured reservoirs.

Behavior study of a thermo‐responsive hydrophobically associative water‐soluble terpolymer in laboratory test with heavy crude oil

AbstractIn this work, a thermo‐responsive hydrophobically associative water‐soluble terpolymer was prepared and evaluated as polymer flooding in laboratory tests versus a heavy crude oil from a carbonated reservoir in southern Mexico. Terpolymer of acrylamide, N‐isopropylacrylamide and N,N′‐dihexylacrylamide were synthesized via micellar free radical polymerization. Reaction was carried out at 50°C using sodium dodecyl sulfonate as surfactant and 4‐(4′‐azobis)cyanovaleric acid as initiator. The terpolymer was characterized by nuclear magnetic resonance. Steady shear viscosity of polymer solutions at different concentrations was determined in the presence of NaCl (from 1 to 5 wt%) at different temperatures (from 25 to 120°C). Heavy crude oil sample was characterized and revealed a viscosity of 2. 26 Pa s, 10.21° API with a content of Saturates, Aromatics, Resins, Asphaltenes of 26.4, 38.5, 22.3, and 12.8, respectively. The crude oil recovery of polymer at 2 and 3 wt% revealed a surface tensions of 49.6 and 48.2 mN × m and adsorption capacities of 1.33 and 1.77 wt%. Finally, polymer solutions at 2 and 3 wt% showed a contact angle between 29.6 and 26.5° and a crude oil recovery of 68.3 and 75.3%, respectively.

Effect of Eutrophication Control Methods on the Generation of Greenhouse Carbon Gases in Sediment

The accumulation of nutrients (eutrophication) in water bodies generally produces increased concentrations of organic matter that eventually are deposited in sediment, and partially mineralized, generating greenhouse carbon gases (GHCG). The application of eutrophication control methods includes the application of phosphate adsorbing materials such as Phoslock (PHOS), and hypolimnetic oxygenation systems (HOS). We evaluated the generation of GHCG in sediment subject to these eutrophication control methods. Combined water and sediment samples from the Valle de Bravo reservoir in Mexico, were incubated in reactors, where the following eutrophication control methods were applied: HOS, PHOS, HOS + PHOS, and compared to a reactor without treatment (CONTROL). Redox potential (Eh), pH, redox-sensitive ions, and GHCG emissions were monitored, observing the following rates: CONTROL (15.6 mmol m−2 d−1) > HOS (12.8) > HOS + PHOS (11.0) > PHOS (9.7 mmol m−2 d−1), with the CONTROL rate within values determined from published sediment core data. The GHCG emissions increased with time as Eh decreased, and sulfate reduction increased. Application of eutrophication control methods in the Valle de Bravo reservoir, would most probably result in lower GHCG generation and emission rates. This is due to the repression of sulfate-reduction in water-sediment systems where HOS and PHOS were applied both individually and combined.

Bioaccumulation of PCBs and PBDEs in Fish from a Tropical Lake Chapala, Mexico.

Lake Chapala is the largest natural freshwater reservoir in Mexico and the third largest lake in Latin America. Lakes are often considered the final deposit of polluting materials; they can be concentrated in the organisms that inhabit them, the water, and the sediments. The PCBs and PBDEs are environmental pollutants highly studied for their known carcinogenic and mutagenic effects. PCB and PBDE bioaccumulation levels were determined in Chirostoma spp., Cyprinus carpio, and Oreochromis aureus. In addition, we monitored the concentrations of PCBs and PBDEs in sediment and water from Lake Chapala were monitored. Samples were collected during two periods, in October 2018 and May 2019. The samples were analyzed by gas chromatography coupled with mass spectrometry. Two bioaccumulation factors were determined in fish, one in relation to the concentration of PCBs and PBDEs in sediments and the other in relation to the concentration of PCBs and PBDEs in water. The PCB levels were 0.55–3.29 ng/g dry weight (dw) in sediments, 1.43–2.98 ng/mL in water, 0.30–5.31 ng/g dw in Chirostoma spp., 1.06–6.07 ng/g dw in Cyprinus carpio, and 0.55–7.20 ng/g dw in Oreochromis aureus. The levels of PBDEs were 0.17–0.35 ng/g dw in sediments, 0.13–0.32 ng/mL in water, 0.01–0.23 ng/g dw in Chirostoma spp., 0–0.31 ng/g dw in Cyprinus carpio, and 0.1–0.22 ng/g dw in Oreochromis aureus. This study provides information for a better understanding of the movement, global distribution, and bioaccumulation of PCBs and PBDEs. The results show that the fish, water, and sediments of Lake Chapala are potential risks to the biota and the local human population.

Sustainable Wastewater Management to Reduce Freshwater Contamination and Water Depletion in Mexico

At present, most rivers, lakes, and reservoirs in Mexico have significant anthropogenic contamination. The lack of sanitation infrastructure, the increase in the number of nonoperational or abandoned sanitation facilities, limited enforcement of environmental regulations, and limited public policies for the reuse of treated wastewater all contribute to the contamination and water availability problem. The reasons for this are identified as (1) the high maintenance and operational costs in sanitation facilities (including electricity consumption); (2) poor planning and practices of wastewater management and reuse by municipalities; (3) national policies that do not favor the reuse of treated wastewater for agriculture, industry, and municipal services instead of using groundwater as at present; (4) failure to adopt a governance model at the three levels of government; and (5) transparency in the management of financial resources. Some measures to improve this situation include (a) transparent decision-making; (b) participation and accountability in budgeting and planning at the national, state, and municipal levels; and (c) planning for the reuse of treated wastewater to reduce groundwater extractions and to reduce discharges to surface waters from the beginning of every WWTP project.

Assessment of Water Quality in A Tropical Reservoir in Mexico: Seasonal, Spatial and Multivariable Analysis.

Agricultural activities are highly related to the reduction of the availability of water resources due to the consumption of freshwater for crop irrigation, the use of fertilizers and pesticides. In this study, the water quality of the Adolfo López Mateos (ALM) reservoir was evaluated. This is one of the most important reservoirs in Mexico since the water stored is used mainly for crop irrigation in the most productive agricultural region. A comprehensive evaluation of water quality was carried out by analyzing the behavior of 23 parameters at four sampling points in the period of 2012-2019. The analysis of the spatial behavior of the water quality parameters was studied by spatial distribution graphs using the Inverse Distance Weighting interpolation. Pearson correlation was performed to better describe the behavior of all water quality parameters. This analysis revealed that many of these parameters were significantly correlated. The Principal Components Analysis (PCA) was carried out and showed the importance of water quality parameters. Ten principal components were obtained, which explained almost 90% of the total variation of the data. Additionally, the comprehensive pollution index showed a slight water quality variation in the ALM reservoir. This study also demonstrated that the main source of contamination in this reservoir occurs near sampling point one. Finally, the results obtained indicated that a contamination risk in the waterbody and further severe ecosystem degradations may occur if appropriate management is not taken.

Anthropogenic and climate induced trace element contamination in a water reservoir in northwestern Mexico.

Water reservoirs are essential for regional economic development, as populations depend on them for agriculture irrigation, flood control, hydroelectric power generation, water supply for human consumption, and subsistence fishing activities. However, the reservoir environmental quality can be disturbed by enhanced sediment input and trace metal contamination, affecting human health as a consequence of contaminated water and fish consumption. With the purpose to understand the trends and extent of sediment accumulation and trace element contamination in the Oviachic reservoir (OV, northwestern Mexico) since its construction, the temporal variations of sediment accumulation, and As, Cr, Cu, Hg, Ni, Pb, and Zn concentrations, enrichment, and fluxes, were evaluated through the study of two 210Pb-dated sediment cores. We assumed that siltation and trace element contamination were driven by the development of anthropogenic activities in the region within the past ~ 70 years. Elemental concentrations accounted from null to minor enrichment for most elements, but moderate to significant enrichment by Hg. Mercury, As, and Cu fluxes have notably increased since the past decade, most likely because of a combination of anthropogenic and natural processes, including catchment erosion, artisanal gold mining, and recent drought conditions in the region. Arsenic and Hg concentrations may pose deleterious risks to biota in the reservoir, and consequently to humans through fish consumption, for which further biological and toxicological tests are advisable. This study highlights the importance of using sediment dating to assess historical trends of metal contamination and identify possible sources, to support decision-making in programs addressed to reduce environmental and health risks in aquatic ecosystems.

The northern Gulf of Mexico offshore super basin: Reservoirs, source rocks, seals, traps, and successes

The northern Gulf of Mexico federal offshore area easily qualifies as a super basin based upon estimated petroleum endowment of more than 100 BOE and cumulative production of 60 BOE. Like other super basins, it has multiple petroleum systems and stacked reservoirs. Examination of four key elements of these petroleum systems (reservoirs, source rocks, seals, and traps) yields important insights to the geologic processes that result in such an exceptional habitat for conventional hydrocarbons. The bulk of hydrocarbon resources in federal offshore waters is in Cenozoic sandstone reservoirs such as the Paleogene Wilcox reservoir of deep-water subsalt areas. Overall, Cenozoic sandstone reservoirs in both suprasalt and subsalt fields yield the highest flow rates and cumulative production volumes. Notable is the recent addition of the deep-water Jurassic Norphlet sandstone play, the newest and second largest by ultimately technically recoverable resources. Overall, Gulf of Mexico reservoirs are diverse, formed in paleoenvironments ranging from aeolian to deep water. Powering this super basin are three primary marine source rocks centered in the Oxfordian, Tithonian, and Cenomanian–Turonian Stages. These source rock intervals commonly act as top seals, but other Neogene and Mesozoic shales and even carbonate mudstones are also important trap-sealing elements, as proven by analytical work and downhole pressure measurements. The extensive salt distribution and relatively late Cenozoic burial delayed source rock maturation and migration until the culmination of trap formation in many areas. High rates of Cenozoic deposition on a mobile salt substrate also generated a myriad of salt tectonic structures, ranging from simple diapiric closures and extensional fault traps to complex subsalt configurations such as salt-cored compressional anticlines, salt-cutoff traps, and bucket weld traps. Exploration success in the past 20 yr is a direct result of improved seismic imaging around and below salt, as well as advances in drilling, completing, and producing wells and fields.

Microplastics and metal burdens in freshwater Tilapia (Oreochromis niloticus) of a metropolitan reservoir in Central Mexico: Potential threats for human health

In the present study, microplastics (MPs) and metal concentrations were studied in the widely consumed tilapia (Oreochromis niloticus) fishes (n = 15) collected from a metropolitan reservoir of the Atoyac River basin, Mexico. Nearly 139 fibers were extracted from the gastrointestinal tracts and assessed using optical microscopy to evaluate their physical characteristics. The colour distribution of the fibers was mainly black (40%), blue (19%), red and white (14%). SEM images represented the surface morphology, while the elemental composition of the fibers was studied using EDX spectra. Polymer characterization using μFTIR aided in confirming the fibers as plastics (polyamide, polyester, and synthetic cellulose) and non-plastics (natural cellulose). Henceforth, ∼33% of the fibers, provisionally thought to be plastics, were natural fibers. The total metal concentrations were higher in the liver (259.24 mg kg−1) than the muscle (122.56 mg kg−1) due to diverse metabolic functions in the hepatic tissues. Human health risk assessment in terms of Hazard Index (HI) presented Pb and Zn values above unity in both adults and children, prompting regulatory measures. Statistical tests between MPs and fish biometry did not present any substantial correlations. The present study also affirmed that the presence of MPs and metals in fishes of a highly contaminated region is not only governed by their bioavailabilities, but also on the physiological characteristics of the individual organism.

Palaeogeographical reconstruction and provenance of Oxfordian aeolian sandstone reservoirs in Mexico offshore areas: comparison to the Norphlet aeolian system of the northern Gulf of Mexico

Abstract Palaeogeographical reconstruction of the Oxfordian-age (Jurassic) depositional systems in the southern Gulf of Mexico is supported by detailed sedimentological analyses, detrital zircon geothermochronology and plate tectonic restorations. This integrated approach departs from prior local studies by placing the Bacab Sandstone, a major reservoir in offshore Mexico, in a larger basin- to regional-scale context. Sedimentary characteristics derived from detailed core description show how remarkably similar the Bacab Sandstone is to coeval sandstones of the Norphlet Formation of the northern Gulf of Mexico. A comparison of lithofacies associations suggests similar depositional processes and palaeoclimate regimes, with aeolian dunes forming near base level with adequate wind, sediment supply and arid climatic conditions promoting development of dunes and adjacent sabhkas. Construction of prominent ergs (aeolian sand seas) with lateral transitions to updip fluvial–wadi systems is envisioned in Mexico, comparable to the Norphlet of the northern Gulf of Mexico. Reservoir quality over the southern Mexican offshore area is variable, as numerous well penetrations over several decades have demonstrated. However, in the core area of the Ek-Balam Field, the best reservoirs have surprisingly good porosity and permeability for their age (Jurassic) and present-day depth of burial (>4000 m). However, published information is not definitive on the factors mitigating subsurface reservoir quality destruction. It is possible that similar processes preserving or enhancing porosity under deep burial conditions for the Norphlet are likely to have operated in the Ek and Balam well locations. Available petrographical data on framework grains are similar for Oxfordian sandstones in both the northern and southern Gulf of Mexico. Detrital zircon U–Pb geochronology, however, indicates that different source terranes supplied clastics to the Oxfordian Bacab and Norphlet sandstones. Detrital zircon geothermochronology age spectra indicate that the Mayan (Yucatán) Block was the primary terrane for the Bacab Sandstone. This is separate and distinct from Norphlet source areas that vary from Appalachian (Laurentian) to Pan-African (Gondwanan and peri-Gondwanan) terranes. While it possible that the Bacab and Norphlet sandstones were continuous and connected across the Yucatán margin that lies between the two areas, detrital zircon provenance results do not show any indication of common source terranes. Dimensional considerations, such as the contrasting ratios of Bacab and Norphlet source areas to their respective documented areas of deposition, also support the notion of separated aeolian palaeoenvironments.

Monitoring Water Quality of Valle de Bravo Reservoir, Mexico, Using Entire Lifespan of MERIS Data and Machine Learning Approaches

Remote-sensing-based machine learning approaches for water quality parameters estimation, Secchi Disk Depth (SDD) and Turbidity, were developed for the Valle de Bravo reservoir in central Mexico. This waterbody is a multipurpose reservoir, which provides drinking water to the metropolitan area of Mexico City. To reveal the water quality status of inland waters in the last decade, evaluation of MERIS imagery is a substantial approach. This study incorporated in-situ collected measurements across the reservoir and remote sensing reflectance data from the Medium Resolution Imaging Spectrometer (MERIS). Machine learning approaches with varying complexities were tested, and the optimal model for SDD and Turbidity was determined. Cross-validation demonstrated that the satellite-based estimates are consistent with the in-situ measurements for both SDD and Turbidity, with R2 values of 0.81 to 0.86 and RMSE of 0.15 m and 0.95 nephelometric turbidity units (NTU). The best model was applied to time series of MERIS images to analyze the spatial and temporal variations of the reservoir’s water quality from 2002 to 2012. Derived analysis revealed yearly patterns caused by dry and rainy seasons and several disruptions were identified. The reservoir varied from trophic to intermittent hypertrophic status, while SDD ranged from 0–1.93 m and Turbidity up to 23.70 NTU. Results suggest the effects of drought events in the years 2006 and 2009 on water quality were correlated with water quality detriment. The water quality displayed slow recovery through 2011–2012. This study demonstrates the usefulness of satellite observations for supporting inland water quality monitoring and water management in this region.

Polygeneration Study of Low-to-Medium Enthalpy Geothermal Reservoirs in Mexico

This study combines the thermodynamic analysis of a polygeneration system along with the numerical modelling of the thermal behavior of geothermal reservoirs in Mexico to exploit their energy. Each reservoir was modeled as a porous medium assuming a five-spot well configuration and local thermal equilibrium. The heat conduction-convection along with the Laplace equations were solved to compute temperature distributions, the useful life and the optimum distance between injection-extraction wells. The predicted temperature and pressure of the geothermal fluid at the outlet of the reservoir were exploited in the polygeneration system consisting of: (1) a Rankine cycle, (2) an absorption refrigeration cycle, and (3) a heat exchanger. The developed approach allows calculating both the optimal distance between injection-extraction wells and the global (utilization) efficiency of six arrangements (each composed by a reservoir connected to a polygeneration system) by assuming that reservoirs have a lifespan of 30 years. Results also show that: (a) due to the low efficiency of the Rankine cycle, very little thermal energy is converted into electrical one; (b) not only the temperature and the size are important when evaluating the power production performance of reservoirs, but also the permeability plays a fundamental role; (c) the first law efficiency of the polygeneration system ranges from 41.9% to 43.7%; (d) the utilization efficiency of the six arrangements lies in the range between 25.8% and 31%.

Production-Logging Technologies Enhance Inflow Profiling in Deepwater Gulf of Mexico

This article, written by JPT Technology Editor Judy Feder, contains highlights of paper SPE 196188, “Third-Generation Production-Logging Technologies Enhance Inflow Profiling in Deepwater Gulf of Mexico Reservoirs,” by Glenn Donovan, SPE, Sagar Kamath, and Elizabeth Tanis, SPE, Shell, et al., prepared for the 2019 SPE Annual Technology Conference and Exhibition, Calgary, 30 September–2 October. The paper has not been peer reviewed. This paper discusses the effectiveness of third-generation (Gen3) production-logging-tool (PLT) technology, which uses co-located digital sensors for simultaneous acquisition of flow data to provide the most accurate characterization of the flow condition at each depth surveyed. The resulting data allow for much-improved processing. The probabilistic interpretive model used in the processing has been updated to incorporate this and future developments in PLT architecture. Introduction The first generation of PLT provided a single, discrete measurement for each sensor along the tool assembly’s length, resulting in long tool assemblies and measurements taken at different points along the flow path. This approach had several drawbacks: long toolstrings, point sensors that only provided a measurement at a single point in the cross section of the flow, and measurements that were not acquired simultaneously at each depth logged. Second- generation PLTs represented an improvement because sensors were arranged as an array, enabling multiple measurements to be made at a single depth. However, the toolstrings were still long and not all were arranged optimally to capture data in the flow path. The Gen3 PLT is one-tenth the length of the first-generation versions and roughly one-third that of the shortest second-generation tools. Digitalization allows for direct measurement of flow conditions and rapid interpretation of results. In multiphase flow and deviated wells, co-locating sensors in a spatial geometry provides the optimal information with which to create a fully accurate picture of the downhole flow. Description of Gen3 PLT The PLT described in the paper exemplifies how miniaturization and digitalization are enabling transformational improvements over traditional systems in terms of efficiency and capability. The tool encompasses, within a 3-ft length, up to 24 sensors that collect multiple measurements of fluid properties and fluid movements in a wellbore. These include oil, gas, and water holdup and bubble count, fluid conductivity, phase velocities, pressure, temperature, inclination, rotation, and depth correlation, plus power and communication. The fluid characteristics are locally screened by an array of 8 to 16 tube-shaped probe sensors that are interchangeable, depending on the targeted measurements (Fig. 1). The tool relies on a refractive index needle-shaped probe with a triphasic sensor to identify and quantify the oil, gas, and water holdups and bubble counts at each point of the array. The geometric design of the sensitive tip, along with the optoelectronics of the sensor, are optimized to discriminate oil, water, and gas with high confidence, overcoming the fact that the refractive indexes of oil and water are close to each other.

Identifying thermogenic and microbial methane in deep water Gulf of Mexico Reservoirs

The Gulf of Mexico (GOM) produces 5% of total U.S. dry gas production (USEIA, 2016). Despite this, the proportion of microbial and thermogenic methane in discovered and producing fields from this area is still not well understood. Understanding the relative contributions of these sources in subsurface environments is important to understanding how and where economically substantial amounts of methane form. In addition, this information will help identify sources of environmental emissions of hydrocarbons to the atmosphere. We apply stable isotopes including methane clumped-isotope measurements to solution and associated gases from several producing fields in the U.S. Gulf of Mexico to estimate the proportions, properties and origins of microbial and thermogenic endmembers. Clumped isotopes of methane are unique indicators of whether methane is at thermodynamic isotopic equilibrium or affected by kinetic processes. The clumped methane thermometer can provide insights into formation temperatures and/or into kinetic processes such as microbial methanogenesis, early catagenetic processes, mixing, combinatorial processes, and diffusion. In this data set, we find that some fluids have clumped isotope methane apparent temperatures consistent with the methane component being produced solely by the thermogenic breakdown of larger organic molecules at substantially greater temperatures than those reached in shallow reservoirs. A portion of these reservoirs with hot clumped isotope methane temperatures are consistent with exhibiting a kinetic isotope effect. Other reservoirs have clumped isotope methane apparent temperatures, and other isotopic and molecular proportions, consistent with mixtures of microbial and thermogenic methane. We show that in certain cases the evidence is most consistent with formation of the microbial methane in the current reservoir. However, in other cases the methane is produced at significantly shallower depths and is then transported to greater depths as a result of post generation burial of methane bearing sedimentary sequences to the current reservoir conditions. For the first time, we show that methane of an unambiguously purely microbial origin (i.e. those that do not contain obvious contributions of thermogenic methane) is dominantly generated at temperatures less than 60 °C, despite burial to greater depths. This finding suggests that, while microorganisms are able to generate methane at temperatures up to 105 °C under laboratory conditions (Brock, 1985), in the Gulf of Mexico, microbial methane is dominantly produced in the 20–60 °C window.

Temporal and Spatial Study of Water Quality and Trophic Evaluation of a Large Tropical Reservoir

A water quality study was carried out at the Adolfo López Mateos (ALM) reservoir, one of the largest tropical reservoirs in Mexico, located within an intensive agricultural region. In this study, the seasonal and spatial variations of nine water quality parameters were evaluated at four different sites along the reservoir semiannually over a period of seven years (2012–2018), considering the spring (dry) and fall (rainy) seasons. An analysis of variance was performed to compare the mean values of the water quality parameters for the different sampling sites. Then, a multiparametric classification analysis was carried out to estimate the spatial density of the sampling points by using a probabilistic neural network (PNN) classifier. The observations (seasonal and spatial) of the water quality parameters at the ALM reservoir revealed no significant influence. The trophic status was evaluated using the Carlson Modified Trophic State Index, finding the trophic state of the reservoir at the mesotrophic level, with nitrogen being the limiting nutrient. The PNN revealed neural interactions between total suspended solids (TSS) and the other four parameters, indicating that the concentration ranges of five parameters are equally distributed and classified.