Repulsive Electron-electron Interactions Research Articles

Random singlet-like phase of disordered Hubbard chains

Local moment formation is ubiquitous in disordered semiconductors such as Si:P, where it is observed both in the metallic and the insulating regimes. Here, we focus on local moment behavior in disordered insulators, which arises from short-ranged, repulsive electron-electron interactions. Using density matrix renormalization group and strong-disorder renormalization group methods, we study paradigmatic models of interacting insulators: one dimensional Hubbard chains with quenched randomness. In chains with either random fermion hoppings or random chemical potentials, both at and away from half-filling, we find exponential decay of charge and fermion 2-point correlations but power-law decay of spin correlations that are indicative of the random singlet phase. The numerical results can be understood qualitatively by appealing to the large-interaction limit of the Hubbard chain, in which a remarkably simple picture emerges.

Superconducting critical temperature and isotope effect in the presence of electron-phonon,electron-paramagnon and electron-electron interactions in rhodium

An explicit expression for the superconducting critical temperature, TC, and the exponent of vibrating ionic mass, α, has been derived in the simultaneous presence of attractive electron-phonon,repulsive electron-paramagnon and repulsive electron-electron interactions. The dependence of TC, on these interactions is quite involved,but the observed value of TC in transition element Rhodium can be explained using realistic physical parameters.Variation of TC with λe−s, electron-paramagnon coupling constant and Ee−s, electron-paramagnon energy, has also been studied. Rhodium shows inverse isotope effect in the presence of spin fluctuations.

Long-range alternating spin current order in a quantum wire with modulated spin-orbit interactions

A key concept in the emerging field of spintronics is the electric field control of spin precession via the effective magnetic field generated by the Rashba spin orbit interaction (RSOI). Here, by extensive Density Matrix Renormalization Group computations, we demonstrate the presence of alternating spin current order in the gapped phases of a quantum wire with spatially modulated RSOI and repulsive electron-electron interactions. Our results are analytically supported by bosonization and by a mapping to a locally rotated spin basis.

Kohn-Luttinger Mechanism Driven Exotic Topological Superconductivity on the Penrose Lattice.

The Kohn-Luttinger mechanism for unconventional superconductivity (SC) driven by weak repulsive electron-electron interactions on a periodic lattice is generalized to the quasicrystal (QC) via a real-space perturbative approach. The repulsive Hubbard model on the Penrose lattice is studied as an example, on which a classification of the pairing symmetries is performed and a pairing phase diagram is obtained. Tworemarkable properties of these pairing states are revealed, due to the combination of the presence of the point-group symmetry and the lack of translation symmetry on this lattice. First, the spin and spacial angular momenta of a Cooper pair is decorrelated: for each pairing symmetry, both spin-singlet and spin-triplet pairings are possible even in the weak-pairing limit. Second, the pairing states belonging to the 2D irreducible representations of the D_{5} point group can be time-reversal-symmetry-breaking topological SCs carrying spontaneous bulk super current and spontaneous vortices. These two remarkable properties are general for the SCs on all QCs, and are rare on periodic lattices. Our work starts the new area of unconventional SCs driven by repulsive interactions on the QC.

Interacting topological edge channels

Electrical currents in a quantum spin Hall insulator are confined to the boundary of the system. The charge carriers can be described as massless relativistic particles, whose spin and momentum are coupled to each other. While the helical character of those states is by now well established experimentally, it is a fundamental open question how those edge states interact with each other when brought in spatial proximity. We employ a topological quantum point contact to guide edge channels from opposite sides into a quasi-one-dimensional constriction, based on inverted HgTe quantum wells. Apart from the expected quantization in integer steps of $2 e^2/h$, we find a surprising additional plateau at $e^2/h$. We explain our observation by combining band structure calculations and repulsive electron-electron interaction effects captured within the Tomonaga-Luttinger liquid model. The present results may have direct implications for the study of one-dimensional helical electron quantum optics, Majorana- and potentially para-fermions.

The study of thermal properties of f-electron systems in the ferromagnetic state

The rare earth and actinide series of compounds display anomalous physical properties below a characteristic low temperature with very high specific heat coefficient and high effective mass. Here we consider the periodic Anderson model with the repulsive electron-electron interaction within mean-field approximation leading to ferromagnetism in the system. We calculate conduction electron as well as f-electron Green's functions by using Zubarev's Green's function technique and calculate ferromagnetic magnetisation numerically and self consistently. The thermal properties like the temperature dependent entropy, specific heat coefficient and electronic specific heat are calculated from the electron free-energy of the f-electron system and are computed numerically. The specific heat coefficient displays high value in heavy fermion state of the system where the position of the f-electron level is away from the Fermi level with the lower strength of hybridisation between f and conduction electrons.

Thermoelectrics of Interacting Nanosystems—Exploiting Superselection Instead of Time-Reversal Symmetry

Thermoelectric transport is traditionally analyzed using relations imposed by time-reversal symmetry, ranging from Onsager's results to fluctuation relations in counting statistics. In this paper, we show that a recently discovered duality relation for fermionic systems -- deriving from the fundamental fermion-parity superselection principle of quantum many-particle systems -- provides new insights into thermoelectric transport. Using a master equation, we analyze the stationary charge and heat currents through a weakly coupled, but strongly interacting single-level quantum dot subject to electrical and thermal bias. In linear transport, the fermion-parity duality shows that features of thermoelectric response coefficients are actually dominated by the average and fluctuations of the charge in a dual quantum dot system, governed by attractive instead of repulsive electron-electron interaction. In the nonlinear regime, the duality furthermore relates most transport coefficients to much better understood equilibrium quantities. Finally, we naturally identify the fermion-parity as the part of the Coulomb interaction relevant for both the linear and nonlinear Fourier heat. Altogether, our findings hence reveal that next to time-reversal, the duality imposes equally important symmetry restrictions on thermoelectric transport. As such, it is also expected to simplify computations and clarify the physical understanding for more complex systems than the simplest relevant interacting nanostructure model studied here.

Two-electron bound states near a Coulomb impurity in gapped graphene

We formulate and solve the perhaps simplest two-body bound-state problem for interacting Dirac fermions in two spatial dimensions. A two-body bound state is predicted for gapped graphene monolayers in the presence of weakly repulsive electron-electron interactions and a Coulomb impurity with charge $Ze>0$, where the most interesting case corresponds to $Z=1$. We introduce a variational Chandrasekhar-Dirac spinor wave function and show the existence of at least one bound state. This state leaves clear signatures accessible by scanning tunneling microscopy. One may thereby obtain direct information about the strength of electron-electron interactions in graphene.

Interaction-driven topological superconductivity in one dimension

We study one-dimensional topological superconductivity in the presence of time-reversal symmetry. This phase is characterized by having a bulk gap, while supporting a Kramers' pair of zero-energy Majorana bound states at each of its ends. We present a general simple model which is driven into this topological phase in the presence of repulsive electron-electron interactions. We further propose two experimental setups and show that they realize this model at low energies. The first setup is a narrow two-dimensional topological insulator partially covered by a conventional s-wave superconductor, and the second is a semiconductor wire in proximity to an s-wave superconductor. These systems can therefore be used to realize and probe the time-reversal invariant topological superconducting phase. The effect of interactions is studied using both a mean-field approach and a renormalization group analysis.

Gapped tripletp-wave superconductivity in strong spin-orbit-coupled semiconductor quantum wells in proximity tos-wave superconductor

We show that the {\it gapped} triplet superconductivity, i.e., a triplet superconductor with triplet order parameter, can be realized in strong spin-orbit-coupled quantum wells in proximity to $s$-wave superconductor. It is revealed that with the singlet order parameter induced from the superconducting proximity effect, in quantum wells, not only can the triplet pairings arise due to the spin-orbit coupling, but also the triplet order parameter can be induced due to the repulsive effective electron-electron interaction, including the electron-electron Coulomb and electron-phonon interactions. This is a natural extension of the work of de Gennes, in which the repulsive-interaction-induced singlet order parameter arises in the normal metal in proximity to $s$-wave superconductor [Rev. Mod. Phys. {\bf 36}, 225 (1964)]. Specifically, we derive the effective Bogoliubov-de Gennes equation, in which the self-energies due to the effective electron-electron interactions contribute to the singlet and triplet order parameters. It is further shown that for the singlet order parameter, it is efficiently suppressed due to this self-energy renormalization; whereas for the triplet order parameter, it is the $p$-wave ($p_x\pm ip_y$) one with the ${\bf d}$-vector parallel to the effective magnetic field due to the spin-orbit coupling. Finally, we perform the numerical calculation in InSb (100) quantum wells. Specifically, we reveal that the Coulomb interaction is much more important than the electron-phonon interaction at low temperature. Moreover, it shows that with proper electron density, the minimum of the renormalized singlet and the maximum of the induced triplet order parameters are comparable, and hence can be experimentally distinguished.

Magnetic catalysis and axionic charge density wave in Weyl semimetals

Three-dimensional Weyl and Dirac semimetals can support a chiral-symmetry-breaking, fully gapped, charge-density-wave order even for sufficiently weak repulsive electron-electron interactions, when placed in strong magnetic fields. In the former systems, due to the natural momentum space separation of Weyl nodes the ordered phase lacks the translational symmetry and represents an axionic phase of matter, while that in a Dirac semimetal (neglecting the Zeeman coupling) is only a trivial insulator. We present the scaling of this spectral gap for a wide range of subcritical (weak) interactions as well as that of the diamagnetic susceptibility with the magnetic field. A similar mechanism for charge-density-wave ordering at weak coupling is shown to be operative in double and triple-Weyl semimetals, where the dispersion is linear (quadratic and cubic, respectively) for the z (planar) component(s) of the momentum. We here also address the competition between the charge-density-wave and a spin-density-wave orders, both of which breaks the chiral symmetry and leads to gapped spectrum, and show that at least in the weak coupling regime the former is energetically favored. The anomalous surface Hall conductivity, role of topological defects such as axion strings, existence of one-dimensional gapless dispersive modes along the core of such defects, and anomaly cancellation through the Callan-Harvey mechanism are discussed.

Emergence of superconductivity in a doped single-valley quadratic band crossing system of spin-12fermions

For two-dimensional single-valley quadratic band crossing systems with weak repulsive electron-electron interactions, we show that upon introducing a chemical potential, particle-hole order is suppressed and superconductivity becomes the leading instability. In contrast to the two-valley case realized in bilayer graphene, the single-valley quadratic band touching is protected by crystal symmetries, and the different symmetries and number of fermion flavors can lead to distinct phase instabilities. Our results are obtained using a weak-coupling Wilsonian renormalization group procedure on a low-energy effective Hamiltonian relevant for describing electrons on checkerboard or kagom\'e lattices. In 4-fold symmetric systems we find that $d$-wave and $s$-wave superconductivity are realized for short-ranged (Hubbard) and longer-ranged (forward scattering), respectively. In the 6-fold symmetric case, we find either $s$-wave superconductivity or no superconducting instability.

Zero-energy bound state at the interface between ans-wave superconductor and a disordered normal metal with repulsive electron-electron interactions

In recent years, there has been a renewed interest in the proximity effect due to its role in the realization of topological superconductivity. Here, we study a superconductor--normal metal proximity system with repulsive electron-electron interactions in the normal layer. It is known that in the absence of disorder or normal reflection at the superconductor--normal metal interface, a zero-energy bound state forms and is localized to the interface [Fauch\`ere et al., Phys. Rev. Lett. 82, 3336 (1999).]. Using the quasiclassical theory of superconductivity, we investigate the low-energy behavior of the density of states in the presence of finite disorder and an interfacial barrier. We find that as the mean free path is decreased, the zero-energy peak in the density of states is broadened and reduced. In the quasiballistic limit, the bound state eliminates the minigap pertinent to a noninteracting normal layer and a distinct peak is observed. When the mean free path becomes comparable to the normal layer width, the zero-energy peak is strongly suppressed and the minigap begins to develop. In the diffusive limit, the minigap is fully restored and all signatures of the bound state are eliminated. We find that an interfacial potential barrier does not change the functional form of the density of states peak but does shift this peak away from zero energy.

Subgap Two-Photon States in Polycyclic Aromatic Hydrocarbons: Evidence for Strong Electron Correlations

Strong electron correlation effects in the photophysics of quasi-one-dimensional $\pi$-conjugated organic systems such as polyenes, polyacetylenes, polydiacetylenes, etc., have been extensively studied. Far less is known on correlation effects in two-dimensional $\pi$-conjugated systems. Here we present theoretical and experimental evidence for moderate repulsive electron-electron interactions in a number of finite polycyclic aromatic hydrocarbon molecules with $D_{6h}$ symmetry. We show that the excited state orderings in these molecules are reversed relative to that expected within one-electron and mean-field theories. Our results reflect similarities as well as differences in the role and magnitude of electron correlation effects in these two-dimensional molecules compared to those in polyenes.

Correlations and renormalization of the electron-phonon coupling in the honeycomb Hubbard ladder and superconductivity in polyacene

We have performed extensive density matrix renormalization group (DMRG) studies of the Hubbard model on a honeycomb ladder. The band structure (with Hubbard $U=0$) exhibits an unusual quadratic band touching at half-filling, which is associated with a quantum Lifshitz transition from a band insulator to a metal. For one electron per site, nonzero $U$ drives the system into an insulating state in which there is no pair-binding between added electrons; this implies that superconductivity driven directly by the repulsive electron-electron interactions is unlikely in the regime of small doping, $x\ensuremath{\ll}1$. However, the divergent density of states as $x\ensuremath{\rightarrow}0$, the large values of the phonon frequencies, and an unusual correlation induced enhancement of the electron-phonon coupling imply that lightly doped polyacenes, which approximately realize this structure, are good candidates for high-temperature electron-phonon driven superconductivity.

ChemInform Abstract: Strongly Correlated Materials

AbstractReview: 208 refs.

Strongly Correlated Materials

Strongly correlated materials are profoundly affected by the repulsive electron-electron interaction. This stands in contrast to many commonly used materials such as silicon and aluminum, whose properties are comparatively unaffected by the Coulomb repulsion. Correlated materials often have remarkable properties and transitions between distinct, competing phases with dramatically different electronic and magnetic orders. These rich phenomena are fascinating from the basic science perspective and offer possibilities for technological applications. This article looks at these materials through the lens of research performed at Rice University. Topics examined include: Quantum phase transitions and quantum criticality in "heavy fermion" materials and the iron pnictide high temperature superconductors; computational ab initio methods to examine strongly correlated materials and their interface with analytical theory techniques; layered dichalcogenides as example correlated materials with rich phases (charge density waves, superconductivity, hard ferromagnetism) that may be tuned by composition, pressure, and magnetic field; and nanostructure methods applied to the correlated oxides VO₂ and Fe₃O₄, where metal-insulator transitions can be manipulated by doping at the nanoscale or driving the system out of equilibrium. We conclude with a discussion of the exciting prospects for this class of materials.

Electronic liquid crystalline phases in a spin-orbit coupled two-dimensional electron gas

We argue that the ground state of a two-dimensional electron gas with Rashba spin-orbit coupling realizes one of several possible liquid crystalline or Wigner crystalline phases in the low-density limit, even for short-range repulsive electron-electron interactions (which decay with distance with a power larger than 2). Depending on specifics of the interactions, preferred ground-states include an anisotropic Wigner crystal with an increasingly anisotropic unit cell as the density decreases, a striped or electron smectic phase, and a ferromagnetic phase which strongly breaks the lattice point-group symmetry, i.e. exhibits nematic order. Melting of the anisotropic Wigner crystal or the smectic phase by thermal or quantum fluctuations can gives rise to a non-magnetic nematic phase which preserves time-reversal symmetry.

Seeing Many-Body Effects in Single- and Few-Layer Graphene: Observation of Two-Dimensional Saddle-Point Excitons

Significant excitonic effects were observed in graphene by measuring its optical conductivity in a broad spectral range including the two-dimensional π-band saddle-point singularities in the electronic structure. The strong electron-hole interactions manifest themselves in an asymmetric resonance peaked at 4.62 eV, which is redshifted by nearly 600 meV from the value predicted by ab initio GW calculations for the band-to-band transitions. The observed excitonic resonance is explained within a phenomenological model as a Fano interference of a strongly coupled excitonic state and a band continuum. Our experiment also showed a weak dependence of the excitonic resonance in few-layer graphene on layer thickness. This result reflects the effective cancellation of the increasingly screened repulsive electron-electron (e-e) and attractive electron-hole (e-h) interactions.

Electron and phonon correlations in systems of one-dimensional electrons coupled to phonons

Electron and phonon correlations in systems of one-dimensional electrons coupled to phonons are studied at low temperatures by emphasizing on the effect of electron-phonon backward scattering. It is found that the $2{k}_{F}$-wave components of the electron density and phonon displacement field share the same correlations. Both correlations are quasi-long-ranged for a single conducting chain coupled to one-dimensional or three-dimensional phonons, and they are long-ranged for repulsive electron-electron interactions for a three-dimensional array of parallel one-dimensional conducting chains coupled to three-dimensional phonons.