Repetitive Pulsed Discharge Research Articles

Streamer propagation in CO2 and N2/CO2 mixtures at atmospheric pressure

Abstract This study investigated streamer discharge in CO₂ and N2/CO2 mixtures. Experiments were conducted at atmospheric pressure and room temperature conditions by using a point-to-plane electrode configuration. A repetitive pulse discharge at 50 Hz was used to stabilise the discharge in CO₂. Under these conditions, the discharge current and intensified charge-coupled device (ICCD) camera images were systematically analysed during streamer evolution in CO2. The results revealed that streamer propagation and electrical properties were considerably influenced by the N₂ concentration in CO₂. Analysis of the emission of secondary streamers indicated that the emission ratio of primary streamers and secondary streamers in CO2 differed considerably from that in air. The onset delay time of streamer discharge was measured and statistically processed based on previous studies of streamer onset processes. Findings indicated an increase in the discharge delay time and its dispersion when N₂ was added to CO2, which indicated that variations in the initial electron content affected the inception process of streamer discharge.

Experimental characterization and 3D simulations of turbulent flames assisted by nanosecond plasma discharges

This paper presents quantitative experimental data generated for the validation of plasma-assisted combustion (PAC) simulations. These data are then used to validate the phenomenological model of Castela et al. They are also useful to test other PAC models. In the experiment presented here, Nanosecond Repetitively Pulsed (NRP) discharges are applied to a lean-premixed turbulent methane-air flame initially near the lean blow-off limit. The discharges significantly enhance the combustion and stabilize the flame after a few pulses. Electrical and optical diagnostics are employed to extensively quantify the transient and steady state of the plasma-stabilization process. The flame shape is characterized by OH* chemiluminescence imaging. In the discharge region, OH density profiles are obtained by 1D laser-induced fluorescence, and the gas temperature is measured by optical emission spectroscopy measurements. The local gas temperature increases by 1250 K, and the OH number density rises sevenfold when NRP discharges are applied. These results evidence the cumulative thermal and chemical effects of NRP discharges, which are especially challenging to replicate numerically. A Large Eddy Simulation (LES) of the experiment is performed. Combustion chemistry is modeled by an analytically reduced mechanism, while the plasma discharge is described by the low-CPU cost phenomenological model of Castela et al., which aims to capture the main thermal and chemical effects induced by the discharges. The model of Castela et al. is validated in the burnt gases by the remarkable agreement between the simulations and the experiments regarding the flame shape, the local gas temperature, and the OH number density. More generally, this work demonstrates the relevance of simplified plasma models in LES solvers to simulate complex plasma-assisted burners.

Numerical investigation of lean methane flame response to NRP discharges actuation

This study investigates the response of a laminar methane-air flame to Nanosecond Repetitively Pulsed (NRP) discharges in a canonical wall-stabilized burner using a combined experimental and numerical approach. The flow and flame behaviors were modeled using Direct Numerical Simulation (DNS) with an Analytically Reduced Chemistry for a precise chemical description. A phenomenological model incorporating detailed plasma kinetics and experimental observations was developed to simulate plasma effects. Zero-dimensional plasma reactor simulations were used to build up a reduced-order model describing discharge energy distribution in the specific conditions studied. Experimental measurements of electrical profiles identified two discharge regimes: a low-energy Corona discharge and a higher-energy Glow discharge, characterized by distinct spatial energy distributions. Experimental flame response analysis revealed three major phases: marginal response up to 100 pulses, a downstream shift of the flame tip, and stabilization after 400 pulses. Numerical simulations indicated that the Corona regime is crucial for explaining initial flame responses, while the Glow regime influences later stages. Adjustments in the Vibrational–Translational (VT) energy relaxation time and energy deposition ratios between fresh and burnt gases were necessary to match experimental observations. Additionally, an accurate modeling of the transient and steady-state flame responses requires integrating both the specificity of the Corona and the Glow discharge regimes. Future work should focus on measuring or theoretically calculating N2(v) relaxation times in CH4-H2O-CO2 mixtures and analyzing the spatial energy distribution of discharges interacting with flames to enhance plasma-combustion coupled models.Novelty and significanceIn this work, a phenomenological plasma-assisted combustion model has been developed, to investigate a laminar premixed stagnation plate burner, focusing on VT energy relaxation time and spatio-temporal energy distribution modeling. For the first time, not only O2, N2 and O but also the fuel and combustion intermediates and products have been considered in the VT relaxation model. It revealed their strong influence on the overall flame response in a case where the discharge crosses a flame front, highlighting the strong beneficial effect of energy deposited in vibrational form. The study questions and investigates the energy distribution from fresh to burnt gases, challenging the conventional uniform energy distribution assumption. The experimental identification of two specific plasma regimes was necessary to predict the transient flame response. Additionally, energy deposited downstream of the flame, in fresh gases, was found to more efficient than in hot gases to enhance combustion.

Quantitative comparison of the benefits of cracking and nanosecond repetitive pulsed discharges on the lean blow-off, emissions, and topology of ammonia premixed swirl flames

In the last decade, ammonia has gained interest as an alternative fuel for the energy sector. The main advantages include its carbon neutrality and ease of storage at industrial scale. However, to consider ammonia as an alternative carbon-free fuel it is necessary to solve two main issues, namely flame stability and pollutant emission. In this work we compared two promising technologies used to enhance ammonia combustion, specifically partial cracking and plasma assisted combustion (PAC). The experiments were carried out for different blends of ammonia–hydrogen–nitrogen–air that reproduce the conditions of cracking as well as for pure ammonia assisted by nanosecond repetitive pulsed (NRP) discharges for the PAC. The cracking and PAC were compared for the same added power ratio at atmospheric conditions. Different added power ratios, from 0.1% to 4% of the flame’s total thermal power, were tested. The lean blow-off limits were measured for a range of bulk flow velocities between of 4 and 12 m/s. For the pollutant emissions, NOx, NH3, and N2O were considered. The effect of both strategies on the Laminar burning velocity (LBV) was explored by numerical simulations. For the same added power ratio, partial cracking extended the lean blow-off limits further than NRP discharges, even with a high pulse repetition frequency of 30 kHz. This result indicated that cracking was more effective in stabilizing the flame than PAC. Regarding NOx emissions, NRP discharges induced only a third of the increase observed with cracking. However, the reduction in N2O associated with cracking was twice as much as that for NRP discharges. Finally, cracking proved more efficient in reducing the flame height, which was supported by the simulations of LBV. These results suggest that PAC strategies optimized for hydrocarbon flames are less efficient on ammonia combustion, and that more work is needed to develop plasma actuators for NH3 combustion.Novelty and Significance statement This work marks the first one-to-one quantitative comparison between plasma actuation and thermal cracking on ammonia swirl flames. It serves as a pivotal exploration to assess and understand the economic aspects of these strategies, providing valuable insights into their efficiency and potential for practical implementation.

Effects of using nanosecond repetitively pulsed discharge and turbulent jet ignition on internal combustion engine performance

Robust ignition of hard-to-ignite fuels is essential for future spark ignited internal combustion engines, particularly for introducing efficiency-enhancing diesel-like process parameters like air excess or high amounts of exhaust gas recirculation (EGR). On the one hand, novel plasma-based ignition systems like Nanosecond Repetitively Pulsed Discharge (NRPD) are promising in extending the ignition limits and the early flame development speed. On the other hand, Turbulent Jet Ignition is effective for shortening the combustion duration and decreasing the unburned hydrocarbon emissions.This article investigates experimentally the combination of NRPD ignition and TJI. The aim is to use a technology for robust inflammation (NRPD) in combination with a technology for fast combustion of the bulk charge (TJI). For this purpose, a turbocharged light-duty four-cylinder engine operated with natural gas is used. The engine can be fitted with a classical Open Chamber (OC) spark plug or with Pre-Chambers (PC). The PCs can be filled uniquely with fuel and air coming from the Main Chamber (MC) (“passive PC”), or additional fuel can be added to the PCs (“active PC”). The air-to-fuel ratio and EGR rate can be freely controlled. Five different combustion strategies are investigated with NRPD ignition and compared against an inductive discharge ignition system. The combustion strategies are passive PC with air and EGR dilution, active PC with air dilution, and Open Chamber (OC) with air and EGR dilution. HRR evaluations and a loss analyses are performed to interpret the results.Despite the faster inflammation present with NRPD ignition, similar peak efficiencies and emissions are reached in OC configuration using the inductive discharge and NRPD ignition systems, which are achieved by varying air-to-fuel ratios (AFR) and EGR rates. Above dilution levels for peak efficiency, the efficiency using NRPD ignition decreases at a slower pace and tolerates higher AFR and EGR rates, thanks to a more complete and shorter combustion.For the PC experiments using NRPD ignition, an efficiency increases and a reduction of emissions compared to inductive discharge ignition are present for the investigated AFR and EGR rates for both active and passive PC operations. The efficiency increase is present due to a stronger pre-chamber discharge and thanks to a faster end phase of combustion. Actively fueling the PC results in faster and more complete combustion that is overcompensated by the increased wall heat losses, reducing the overall efficiency. The results show that passive PC with NRPD ignition may be an ideal ignition concept that maximizes engine efficiency and minimizes emissions.

Experimental and numerical study of stabilized flame in inverse coflow turbulent jet using nanosecond repetitively pulsed discharges

Methane has become increasingly popular in rocket propulsion, but low stability and limited flammability range have always been a concern about methane-powered systems. Many stabilization methods have been developed to change the geometrical or flow characteristics of the burner. However, most of these efforts have yet to be practically successful due to cost and compatibility issues. Alternatively, other methods such as microwave, dielectric barrier, and nanosecond repetitive pulse (NRP) discharges have been proven to be efficient by modifying the kinetic and transport pathways. NRP discharges have shown promising results as one of the most effective low-temperature plasma (LTP) methods. In this paper, chemiluminescence imaging is used to study the effect of NRP discharge on liftoff and blowout, as the important stabilization parameters, by recording the liftoff height and liftoff/blowout velocities under a wide range of discharge (f=0–10 kHz and V=11–19 kV) and jet velocity (ν=2–60 m/s). Depending on these parameters, four different discharge regimes of corona, diffuse, filamentary, and arc were observed. The results have shown that high-intensity plasma in a filamentary discharge regime can provide a significant advantage in delaying the liftoff conditions, but no improvements in the blowout were observed. It was also found that NRP discharge can reduce the liftoff height. To explore the cause of the increased stability, a parametric numerical study is conducted using detailed plasma-assisted methane kinetic modeling coupled to a 1D opposed diffusion flame simulation. Results show that the extinction limits of diffusion flames can be dramatically enhanced by LTP due to the local formation of high radical and excited species concentrations, with subsequent recombination leading to increased temperature and higher reactivity in the flame zone. In addition, a 1D laminar flame speed evaluation shows that the plasma-generated active species can dramatically increase the flame speed, which, in turn, reduces the lifted flame height above the burner surface.

Dynamic response of nanosecond repetitively pulsed discharges to combustion dynamics: regime transitions driven by flame oscillations

When using nanosecond repetitively pulsed discharges to actuate on dynamic combustion instabilities, the environment the discharge is created in is unsteady and changing on the timescale of the combustion processes. As a result, individual discharge pulses are triggered in a background gas that evolves at the timescale of combustion dynamics, and pulse-to-pulse variations may be observed during the instability cycle. Prior work has studied nanosecond pulsed discharges in pin-to-ring configurations used to control instabilities in lean-operating swirl-stabilized combustors, and observed variable discharge behavior. The focus of this work is on characterizing how the pulse-to-pulse discharge morphology, energy deposition, and actuation authority, evolve during the combustion instability cycle. This has important implications for designing effective plasma-assisted combustion control schemes. The discharge is observed in two distinct modes, a streamer corona and a nanosecond spark, with the occurrence of each regime directly linked to the phase of the combustor instability. Variation of pulse repetition frequency affects the total fraction of pulses in each mode, while variation of voltage affects the onset of the nanosecond spark mode. The transitions are described in terms of ratios of the relevant combustion and plasma timescales and the implications of this coupled interaction on the design of an effective control scheme is discussed.

Heat Release in a Nanosecond Repetitively Pulsed Discharge in an Ar–He Mixture at the Atmospheric Pressure

Heat Release in a Nanosecond Repetitively Pulsed Discharge in an Ar–He Mixture at the Atmospheric Pressure

Numerical study of nitrogen oxides chemistry during plasma assisted combustion in a sequential combustor

Plasma Assisted Combustion (PAC) is a promising technology to enhance the combustion of lean mixtures prone to instabilities and flame blow-off. Although many PAC experiments demonstrated combustion enhancement, several studies report an increase in NOx emissions. The aim of this study is to determine the kinetic pathways leading to NOx formation in the second stage of a sequential combustor assisted by Nanosecond Repetitively Pulsed Discharges (NRPDs). For this purpose, Large Eddy Simulation (LES) associated with an accurate description of the combustion/NOx chemistry and a phenomenological model of the plasma kinetics is used. Detailed kinetics 0-Dimensional reactors complement the study. First, the LES setup is validated by comparison with experiments. Then, the NOx chemistry is analyzed. For the conditions of operation studied, it is shown that the production of atomic nitrogen in the plasma by direct electron impact on nitrogen molecules increases the formation of NO. Then, the NO molecules are transported through the turbulent flame without being strongly affected. This study illustrates the need to limit the diatomic nitrogen dissociation process in order to mitigate harmful emissions. More generally, the very good agreement with experimental measurements demonstrates the capability of LES combined with accurate models to predict the NRPD effects on both turbulent combustion and NOx emissions.

A numerical investigation of plasma-assisted ignition by a burst of nanosecond repetitively pulsed discharges

Nanosecond repetitive pulse discharges (NRP) are a promising technology to promote the ignition of a lean reactive mixture. The success or failure of ignition results from complex interaction phenomena between the plasma generated by the discharge and the properties of the turbulent flow. This work presents two approaches for modeling plasma-assisted ignition scenarios resulting from NRP discharges. The first consists of a low-order model based on dimensionless analysis, while the second involves a Large Eddy Simulation (LES) of the reactive turbulent flow that requires high-performance computing. Both methods are presented and successfully applied to an experimental setup, which was specifically designed to study the influence of flow operating conditions and electrical discharge properties on plasma-assisted flame ignition.The simple dimensionless analysis can identify coupled and decoupled regimes, which always lead to ignition success or failure, respectively. However, the model is too crude to predict the fine interactions between plasma kinetics, combustion chemistry, and flow dynamics that control the formation of the reactive core in partially coupled regimes. The LES provides a means to capture these complex interaction mechanisms. A quantitative analysis of the reactive kernel growth has been performed by numerically reconstructing the OH-PLIF signal measured by the camera. A very good agreement is observed, validating the numerical strategy for plasma assisted combustion.

Thermoacoustic stabilization of a sequential combustor with ultra-low-power nanosecond repetitively pulsed discharges

This study demonstrates the stabilization of a sequential combustor with Nanosecond Repetitively Pulsed Discharges (NRPD). Sequential combustors offer advantages such as enhanced fuel flexibility and broader operational range compared to the conventional combustors. However, thermoacoustic instabilities limit their potential. While passive control strategies like Helmholtz dampers have been utilized, active control methods have been hindered by the lack of robust actuators for harsh conditions with sufficient control authority. This study demonstrates successful suppression of instabilities using NRPD in a lab-scale atmospheric sequential combustor, even at low plasma power (1.1 W, about 1.5×10−3 percent of thermal power of 73.4 kW). We also examine the effect of pulse repetition frequency and plasma generator voltage on NO emissions and the sequential flame topology. Notably, higher plasma power can further enhance suppression, albeit with a slight increase in NO emissions. However, the highest plasma power in our study (81 W, 1.1×10−1 percent of flame thermal power) shows a slight improvement in acoustic suppression while significantly elevating NO emissions. Intriguingly, specific plasma parameter combinations can excite another acoustic mode, necessitating further exploration for optimized control. This pioneering study highlights the potential of ultra-low-power plasma-based thermoacoustic control in sequential combustors, paving the way for enhanced stability and performance.

Numerical modeling of plasma assisted ignition of CH4/O2/He mixture by the nanosecond repetitive pulsed surface dielectric barrier discharge

A nanosecond repetitive pulsed surface dielectric barrier discharge (NRP-SDBD) is a promising method for generation of non-equilibrium plasma with more kinetic activity. This paper presents numerical studies on the effects of pulse repetition frequency (PRF) on low temperature ignition of lean and stoichiometric CH4/O2/He mixture in NRP-SDBD plasma. A skeletal plasma kinetics mechanism is primary developed and calibrated, to mitigate the computationalloads of modeling SDBD discharge by the two-dimensional plasma solver PASSKEy coupled with Poisson's equation. The discharge current was well predicted, meanwhile the sequential and spatial reduced electric field (E/N) is revealed as the ionization wave propagates forward. Special attention is placed on time-evolution of electric field strength used as inputs in simulation of plasma assisted ignition (PAI) conducted by zero-dimensional ZDPlasKin-CHEMKIN code. The principle of PAI on lean and stoichiometric CH4/O2/He mixture via varied PRF is analyzed in details from view of plasma kinetics and chemical kinetics. Ultimately, the important role of plasma active species O, O(1D), O2(a1Δg) on promoting ignition chain reactions is highlighted. It is also concluded that high PRF is beneficial for the accumulation of short lifetime species such as CH4(v13) and O(1D), which participate in the formation of important intermediate CH3.

Efficiency analysis of ignition by Nanosecond Repetitively Pulsed discharges using a low-order model

Plasma-assisted combustion is an interesting method to promote the ignition of a lean reactive mixture instead of conventional spark plugs. Especially, Nanosecond Repetitively Pulsed (NRP) discharges technique is an energy-efficient way to initiate and control combustion processes. Ignition success or failure results from the competition between the discharge energy accumulation, the gas residence time in the discharge region, and the combustion chemistry. Plasma-assisted ignition is modeled here by a Perfectly-Stirred Reactor (PSR) whose volume represents the one surrounding the interelectrode region. NRP discharges are applied inside the reactor to initiate the combustion of the injected mixture. This model numerically identifies a plasma-assisted ignition efficiency map in terms of the amount of energy per pulse and the pulse repetition frequency, at low CPU cost. A criterion based on the residence time, interpulse time, and chemical time is introduced to predict the successful formation of a reactive kernel. This criterion is successfully validated by analyzing the plasma-assisted PSR solutions.

Large-Eddy Simulation of swirled flame stabilisation using NRP discharges at atmospheric pressure

In this work, the use of Nanosecond Repetitively Pulsed (NRP) discharges is investigated numerically to improve the stabilisation of the flame in a swirl burner. The studied configuration is the PACCI burner test rig set up at KAUST, in which it was experimentally demonstrated that NRP discharges can effectively enhance flame stability. Simulations are performed with the reactive compressible Navier–Stokes solver AVBP, using a recently developed phenomenological model for plasma-assisted combustion of methane-air premixed flame. The ability of the numerical model to reproduce the main flow behaviours is first assessed by comparison with PIV measurements in cold flow conditions. Then, a lean atmospheric pressure case (ϕ=0.67) without plasma actuation is simulated and compared with OH* chemiluminescence image from experiment. Both numerical and experimental results reveal an unstable turbulent flame, with intermittent attachment to the burner exit. Finally, two operating conditions with NRP discharges are simulated. The NRP discharges correspond to 10 kV pulses applied at a frequency of 20 and 30 kHz, respectively corresponding to a discharge power 0.72 and 1.17% of the thermal flame power. First, a significant stabilisation effect is observed when applying the discharges, which efficiently mitigate the flame lifting. This effect is quantitatively demonstrated by tracking the flame centre of gravity, which shows that the flame moves upstream under the influence of the plasma, in good agreement with experimental observations. Results also show that a net power gain is obtained by applying NRP discharges to combustion by comparing the thermal flame power to the plasma power. In particular, an increase of plasma actuation efficiency from 4 to 6 as been observed in the cases studied by increasing the plasma power.

Nanosecond plasma actuation by a bending actuator mounted on a sharp edge in quiescent air

An experimental investigation of the actuation characteristics of a repetitive nanosecond pulsed dielectric barrier discharge from bending plasma actuators mounted on a sharp edge is conducted. Four bending actuators with different bending angles are tested and compared with a planar actuator in quiescent air using schlieren imaging and electrical measurements. The results show that when fed by the same pulse, the plasma morphology, current waveform, and energy consumption of the bending and planar actuators are very similar. However, the thermal perturbations and induced flows differ significantly. In this experiment, at a low load voltage (V = 10–14 kV), when the plasma discharge is in the diffuse mode, the bending actuator can induce a stronger vortex and near-wall jet than the planar actuator, and as the bending angle decreases, the strength of the induced jet increases rapidly. At a higher load voltage (V = 18–20 kV), when the discharge is in the constricted mode, the plasma filaments produce hot plumes with both the bending and planar actuators, but the hot plumes from the bending actuator are injected into the air with a larger incidence. During the streamer-to-filament transition (V = 16 kV), induced flows from small-bending-angle (30° and 60°) actuators are characterized by a thickened near-wall jet, while those from the planar actuator are characterized by hot plumes.

Effects of pulse rise time on electron dynamics properties in nitrogen–oxygen mixture under repetitive nanosecond pulses

The effects of pulse rise time on the temporal evolution of electron energy and density under repetitive nanosecond pulses in atmospheric nitrogen with 100 ppm oxygen impurities are investigated in this paper by a two-dimensional particle-in-cell/Monte Carlo collision model. It is found that the peak value of mean electron energy increases with decreasing pulse rise time in the single pulsed discharge. However, in the repetitive pulsed discharge approximated by pre-ionization, the peak value of mean electron energy no longer varies with the pulse rise time, showing a saturation trend with decreasing pulse rise time. Whether or not pre-ionization is present, the time required for the mean electron energy to reach its peak is approximately equal to the pulse rise time. It is worth noting that the presence of pre-ionization enhances the tracking ability of the mean electron energy to the pulse waveform during the pulse rise edge. Although after the peak of the pulse, the mean electron energy terminates the tracking process to pulse waveform due to the formation of high-density avalanches and even streamers, its energy decay rate gradually decreases with the increase in the pre-ionization density. Therefore, when the pulse repetitive frequency is greatly increased or the pre-ionization density is increased by other means, it is possible to achieve the complete control of the mean electron energy by pulse waveform modulation.

Repetitive pulsed gas-liquid discharge in different atmospheres: from discharge characteristics to plasma-liquid interactions.

Gas-liquid discharges enable efficient plasma-liquid interactions and thus have promising applications, but many concerns remain unanswered regarding working gas, an important influencing factor. Investigations of a pulsed needle-to-water gas-liquid discharge in Ar, He, and N2 are carried out in this study. Voltage-current waveforms and intensified charge-coupled device (ICCD) images were combined to explore discharge modes and evolution processes. Experimental results demonstrate that the Ar tip spark discharge develops all the way to liquid compared with the He and N2 discharges concentrated in the tube, considerably increasing the plasma-liquid interaction efficiency. According to the optical emission spectra (OES), plasma properties are found to be strongly influenced by interactions between gas particles and interfering particles (H2O, etc.). For instance, excess water vapor causes quenching of excited species, resulting in OH (A-X) in Ar and NO (A-X) in N2 concentrated in the middle region with weak discharge. By adding dimethyl sulfoxide, it is demonstrated that OH dominates H2O2 production in Ar and contributes to both NO2- and NO3- generation in Ar and He, whereas in N2 it only affects NO3- generation. This study advances the "bridge building" between practical application and gas-liquid discharge employing different working gases.

Formation and consumption of HO2 radicals in ns pulse O2–He plasmas over a liquid water surface

Hydroperoxyl (HO2) radicals are an important precursor in the formation of hydrogen peroxide (H2O2), a key species in plasma-liquid interactions, such that their formation and consumption pathways need to be understood. In this work, the generation and decay of HO2 have been studied in a controlled environment, in ns pulse discharge O2–He plasmas in contact with a liquid water surface. For this, time-resolved, absolute number densities of HO2 in O2–He mixtures excited by a repetitive ns pulse discharge are measured in situ by cavity ring down spectroscopy (CRDS). The discharge cell with external electrodes to generate the plasma and a water reservoir are integrated into the CRDS cavity. The high-reflectivity cavity mirrors are purged with helium to protect them from water vapor condensation. The experimental results are obtained at near room temperature, both during the discharge pulse burst and in the afterglow. The HO2 number density is inferred from the CRDS data using a spectral model exhibiting good agreement with previous measurements of absolute HO2 absorption cross sections. HO2 is generated during the discharge burst and decays in the afterglow between the bursts. The HO2 number density is also measured vs. the O2 fraction in the mixture. Comparison with the kinetic modeling predictions demonstrates good agreement with the data and identifies the dominant HO2 generation and decay processes. HO2 in the plasma is formed predominantly by the recombination of H atoms, generated by the electron impact dissociation of water vapor, with O2 molecules. Reactions with O atoms and hydroxyl (OH) radicals are among the main HO2 decay processes in the afterglow. HO2 is also detected when O2 is not present in the mixture. In this case, it is generated primarily by the recombination of OH radicals, via the formation of H2O2. The results demonstrate that CRDS can also be used for HO2 and other plasma chemical reaction product measurements in atmospheric pressure plasma jets impinging on a liquid water surface in ambient air.

Plasma thermal-chemical instability of low-temperature dimethyl ether oxidation in a nanosecond-pulsed dielectric barrier discharge

Plasma stability in reactive mixtures is critical for various applications from plasma-assisted combustion to gas conversion. To generate stable and uniform plasmas and control the transition towards filamentation, the underlying physics and chemistry need a further look. This work investigates the plasma thermal-chemical instability triggered by dimethyl-ether (DME) low-temperature oxidation in a repetitive nanosecond pulsed dielectric barrier discharge. First, a plasma-combustion kinetic mechanism of DME/air is developed and validated using temperature and ignition delay time measurements in quasi-uniform plasmas. Then the multi-stage dynamics of thermal-chemical instability is experimentally explored: the DME/air discharge was initially uniform, then contracted to filaments, and finally became uniform again before ignition. By performing chemistry modeling and analyzing the local thermal balance, it is found that such nonlinear development of the thermal-chemical instability is controlled by the competition between plasma-enhanced low-temperature heat release and the increasing thermal diffusion at higher temperature. Further thermal-chemical mode analysis identifies the chemical origin of this instability as DME low-temperature chemistry. This work connects experiment measurements with theoretical analysis of plasma thermal-chemical instability and sheds light on future chemical control of the plasma uniformity.

Investigation of the impact of NRP discharge frequency on the ignition of a lean methane-air mixture using fully coupled plasma-combustion numerical simulations

The ignition of an atmospheric pressure laminar premixed methane/air mixture by Nanosecond Repetitively Pulsed (NRP) discharges in a pin-pin configuration is studied using fully coupled plasma-combustion numerical simulations. These simulations are performed using the AVIP code specifically developed for low temperature plasma modeling and coupled to the combustion code AVBP. A reduced chemical scheme for plasma-assisted combustion previously derived and validated is used to investigate the effect of the frequency of NRP discharges and the benefits of their chemical enhancement. It is observed that the induced shock wave produced by strong discharges is of major importance for ignition and can lead to quenching of the ignition kernels through strong induced recirculation of gases. Increasing the frequency of the discharges reduces this effect by depositing less energy at each discharge and accumulating energy more homogeneously between the electrodes, leading to a faster and more stable ignition. The minimum energy necessary to ignite decreases with increasing frequency and at the highest studied frequency (100 kHz) ignition has been achieved with 30% less energy than with a single-pulse discharge.