Removal Of Nickel Research Articles

Site-Specific for CO2 Photoreduction with Single-Atom Ni on Strained TiO2-x Derived from Bimetallic Metal-Organic Frameworks.

The photocatalytic reduction of CO2 in water to produce fuels and chemicals is promising while challenging. However, many photocatalysts for accomplishing such challenging task usually suffer from unspecific catalytic active sites and the inefficient charge carrier's separation. Here, a site-specific single-atom Ni/TiO2-x catalyst is reported by in situ topological transformation of Ni-Ti-EG bimetallic metal-organic frameworks. The loading of nickel nanoparticles or individual atoms, which act as specific active sites, can be precisely regulated by chelating agents through the partial removal of nickel and adjacent oxygen atoms. Furthermore, the degree of lattice strain in Ni/TiO2-x catalysts, which improves the separation efficiency of charge carriers, can be modulated by fine-tuning the transformation process. By leveraging the anchored nickel atoms and the strained TiO2, the optimized NiSA0.27/TiO2-x shows a CO generation rate of 86.3 µmol g-1 h-1 (288 times higher than that of NiNPs/TiO2-x) and CO selectivity of up to 92.5% for CO2 reduction in a pure-water system. This work underscores the importance of tailoring lattice strain and creating specific single-atom active sites to facilitate the efficient and selective reduction of CO2.

Cell Morphology, Material Property and Ni(II) Adsorption of Microcellular Injection-Molded Polystyrene Reinforced with Graphene Nanoparticles

Graphene’s incorporation into polymers has enabled the development of advanced polymer/graphene nanocomposites with superior properties. This study focuses on the use of a microcellular foamed polystyrene (PS)/graphene (GP) nanocomposite (3 wt%) for nickel (II) ion removal from aqueous solutions. Adsorption behavior was evaluated through FTIR, TEM, SEM, TGA, and XRD analyses. Key factors, including initial ion concentration, pH, temperature, and sorbent dosage, were examined. Results showed optimal nickel removal at specific pH levels with removal efficiency decreasing from 91 to 80% as Ni (II) concentrations increased from 10 to 100 mg/L. The adsorption capacity improved from 11 to 130 mg/g. Equilibrium data aligned with Langmuir and Freundlich isotherm models, while adsorption kinetics followed a second-order kinetic model. These findings highlight the potential of PS/GP nanocomposites for nickel ion removal, offering a promising solution for small-scale industrial applications.

Study of effective removal of nickel and cobalt from aqueous solutions by FeO@mSiO2 nanocomposite

Study of effective removal of nickel and cobalt from aqueous solutions by FeO@mSiO2 nanocomposite

Poly(acrylic acid) and Poly(acrylic acid-b-acrylamide) via RAFT: Effect of Composition on Ni2+ Binding Capacity

Two poly(acrylic acid-b-acrylamide) copolymers, and a poly(acrylic acid) homopolymer were synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization and tested for nickel removal from aqueous media. RAFT was used for better interchain composition homogeneity and to facilitate the synthesis of the block copolymers. Liquid-phase polymer-based retention (LPR) was used to compare the nickel binding capacity. Uptake tests were carried out at pH 3.0, 4.0, and 5.0. Nickel adsorption isotherms in the range of 1 to 7 mmol L-1 were achieved and the Langmuir adsorption model was applied. Maximum binding capacity (Qm) of Ni2+ at 298 K depended on the composition of the copolymers and pH. The polyacid block (PAA) was the major structural feature responsible for high values of nickel binding. All materials presented better uptake at higher pH, probably due to polyacid deprotonation and the increase in the electrostatic interactions. Up to approximately 100 mg of nickel per gram of homopolymer could be retained at pH = 5.0. Even though the presence of a poly(acrylamide) block decreases the binding capacity compared to PAA, that block has a specific contribution to nickel binding and can also provide better features to the material as better solubilization, and others.

Nickel Remediation by Adsorption Technique Achieving the Concept of Zero Residue Level

Nickel is a major threat to the wastewater discharged from industries, where it is used, because it is classified as a carcinogenic heavy metal. Due to the need to treat polluted water with the highest efficiency and lowest cost, the promising adsorption technology using agricultural waste has proven to be an effective solution for treating water pollution with various pollutants. This study is concerned with determining the ability of a household waste to remove nickel from contaminated aqueous solutions by the adsorption method at different operating conditions. Waste tea leaves (WTL), which are discarded in huge quantities annually, showed noticeable nickel removal efficiency at more than 74% at acidity, shaking, concentration, time, temperature, and adsorption dose of 6, 350 rpm, 42 ppm, 120 min, 20°C, and 5.5 g, respectively. Although the adsorbent used had a low surface area of 12.251 m2/g, FTIR test before and after adsorption confirmed the presence of various functional groups capable of efficiently performing the adsorption function. Furthermore, FESEM test showed that the adsorption medium suffered significant changes compared to what it was before treatment with contaminated solutions. The use of toxic adsorption residues in a beneficial way was tested by adding them to concrete mixtures and studying the compressibility performance. The results showed that the additives increased the compressive strength of the concrete by more than double before it reached the failure point. Thus, this investigation confirmed the possibility of achieving the concept of zero residue level through waste management in an eco-friendly manner. Keywords: Adsorption, Concrete additives, Nickel, Waste tea leaves, Zero residue level.

Experimental and theoretical study of nickel removal by electrodeposition on RVC-M (M=Cu, Fe, Mn) cathode

Experimental and theoretical study of nickel removal by electrodeposition on RVC-M (M=Cu, Fe, Mn) cathode

Nickel removal from synthetic wastewater by novel zeolite-doped magnesium- iron- and zinc-oxide nanocomposites by hydrothermal-calcination technique

This study aims to modify raw zeolite with metal oxide nanocomposites to remove nickel (Ni) ions from synthetic wastewater. Novel zeolite-doped magnesium oxide (MgO), iron oxide (Fe3O4), and zinc oxide (ZnO) nanocomposites were synthesized by hydrothermal-calcination methods. The novel zeolite-doped metal oxide nanocomposites were used as adsorbents to remove Ni (II) ions from synthetic wastewater. Several advanced techniques, including X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and vibrating sample magnetometer (VSM) were applied to study the structural, morphological, chemical, and magnetic properties of the prepared materials. Doped zeolite with ZnO, MgO, and Fe3O4 significantly enhances the removal of Ni (II) ions from synthetic wastewater. The zeolite-doped MgO + Fe3O4 + ZnO sample achieved a Ni (II) ions removal efficiency of 99.6%, compared to 58.9% for raw zeolites. The removal efficiencies of Ni (II) ions (Ci = 30 mg/L) from highest to lowest were 99.56%, 99.53%, 91.4%, 67.8%, and 58.93% by zeolite-doped MgO + Fe3O4 + ZnO, zeolite-doped MgO, zeolite-doped ZnO, zeolite-doped Fe3O4, and raw zeolite sample, respectively. The highest adsorption capacity was 17.13 mg/g of zeolite-doped MgO + Fe3O4 + ZnO samples. The experimental adsorption data collected were fitted using five isotherm models, and four kinetic models. The Langmuir adsorption isotherm model and the pseudo-second-order kinetic model provided the best fit for the experimental adsorption data. This suggests that the adsorption process is complex, possibly involving electron interactions between the active sites of doped zeolite and Ni (II) species. The obtained data indicates that zeolite-doped with MgO, Fe3O4, and ZnO notably enhances the adsorptive properties of Ni (II) from synthetic wastewater. The obtained thermodynamic values confirmed that the adsorption process is spontaneous and endothermic, with increased randomness at the solid-solution interface during the adsorption process.

Hydrogen Peroxide Modification Enhances the Ability of Metakaolin based Alkali Activated Materials Adsorbent to Remove the Ni2+ Ions

The presence of nickel ions in wastewater is a significant environmental concern due to its toxicity, which can cause severe health problems. Metakaolin is a pozzolanic material that can be activated by alkali to produce a highly porous and reactive material that can be utilised as a heavy metal ion adsorbent. However, the adsorption capacity of metakaolin-based adsorbents is limited by their surface chemistry and porosity. Metakaolin-based alkali-activated materials adsorbent modified with hydrogen peroxide can effectively remove nickel ions from wastewater. The modification process increases the surface area and porosity of the adsorbent, enhancing its adsorption capacity. The modified adsorbent (1.00 wt.% H2O2) showed a higher sorption capacity of 26.57 mg/g and efficiency of 85.22% compared to the non-modified adsorbent (10.55 mg/g) sorption capacity and 45.63% nickel removal efficiency, indicating the potential of hydrogen peroxide-modified adsorbents as an economical and ecologically sustainable solution for environmental applications, particularly for metal immobilization.

Enhanced nickel removal by N, S co-doped hierarchical porous biochar in capacitive deionization process: Performance and application

Enhanced nickel removal by N, S co-doped hierarchical porous biochar in capacitive deionization process: Performance and application

Fixed-Bed Columns of Avocado (Persea americana Hass.) Seed and Peel Biomass as a Retainer for Contaminating Metals

This study evaluated the adsorbent capacity of the Ecuadorian avocado (Persea americana Hass.) seed and peel wastes as an alternative method for cadmium (Cd), mercury (Hg), lead (Pb), and nickel (Ni) ion removal from aqueous solutions. The laboratory microscale process was performed using fixed-bed columns containing 1 g of 600 μm particles of biomaterial pretreated with ethanol and ethylene glycol. Subsequently, metal solutions of different concentrations were eluted and measured by flame atomic absorption spectroscopy. Results showed that fixed-bed columns allow efficient adsorption of Pb (2.6 mg/g) with ethanol pretreatment. Lower adsorption capacity was achieved for Cd, Hg, and Ni ions. Favorable adsorption with high retention capacity was found for Pb+2 for the ethanol pretreated bio-adsorbent at higher concentrations (120 mg/L). Lower removal percentages were found for Cd+2, Hg+2, and Ni+2; Ni showed the lowest adsorption capacities and negative RL values, suggesting inefficient adsorbent development. Regeneration of Cd, Hg, and Pb ions from avocado peel and seed showed the highest recovery when 1 mol/L HCl solution was used. Regarding the adsorption isotherms, the Langmuir model was the one that best fit our data, demonstrating that adsorption takes place in a uniform monolayer and that each contaminant ion occupies a single site.

Mn3O4-MnOOH nanocomposites for the adsorption-based removal of nickel ions from wastewater.

The removal of nickel from wastewater is a significant environmental concern because of its potential hazards to environment. Adsorption is known as an efficient water treatment strategy and there is a growing interest in the development of new adsorbent materials providing rapid adsorption kinetics, cost-effectiveness, and high adsorption capacity. In this study, the feasibility of Mn3O4-MnOOH nanocomposites was evaluated as the adsorbent material for the removal of nickel ions from wastewater. The nanocomposites were prepared using a modified sonochemical method and characterized by XRD analysis and SEM images. Batch adsorption experiments were carried out under different experimental conditions obtained by varying solution pH, adsorbent amount, and contact period. Under the optimum adsorption conditions, the %RE value was recorded around 80% for 10mg/L Ni(II) ions. The adsorption characteristics were investigated with respect to adsorption isotherms and kinetics. Langmuir and Freundlich isotherm models were used to fit the adsorption data and the results indicated that adsorption of nickel ions onto nanocomposite could be complex and obey both monolayer adsorption and heterogeneous surface. Accordingly, maximum adsorption capacity of nanocomposites were calculated as 12.387mg/g. Research works comparing the kinetic models of pseudo-first-order, pseudo-second-order, and Elovich revealed that chemical sorption plays an important role as the rate-limiting step in the adsorption of nickel ions.

Tactfully introducing amphoteric group into electroactive membrane motivates highly efficient H2O splitting for reversible removal and recovery of nickel(II)

Membrane-based electro-deposition (MED) is an original process promising for reversible removal and recovery of toxic heavy metal ions from wastewater. The removal efficiency of heavy metal ions, however, was limited by the poor membrane surface H2O splitting in the conventional ion exchange membrane (IEM). Inspired by the amphoteric interface-triggered ion exchange resin regeneration phenomenon in electro-deionization, herein we subtly introduced the amphoteric group into IEM as a proof of concept to solve the above bottleneck. By virtue of the “electronic porter” role of the amphoteric -3OS-R-N(CH3)3+, the electron extraction from adsorbed H2O could be accelerated, extending the H2O splitting from the conventional membrane surface to the bulk membrane interior. Such an H2O splitting extension favorably produced an intensified and well-modeled OH- production region at the anodic side of IEM, enhancing the Ni2+ basic deposition accordingly. This special characteristic allowed our MED to realize a super-eminent metal ion removal rate (10.5 mol·h−1·m−2) along with an ultra-low specific energy consumption (0.1 kWh·mol−1) for Ni2+ removal, which considerably surpassed those of state-of-the-art heavy metal ion removal processes reported yet. Further, the deposited Ni2+ could be in situ recovered in conjunction with the facile polarity reversal method. The amphoteric electroactive membrane with high H2O splitting activity is expected to pave the path to engineering MED for efficient heavy metal ion removal and recovery.

Assessing the Efficiency of Chemically Modified Biochars in Removing Nickel From Aqueous Solutions

Background: Modification methods can significantly alter the adsorption properties of biochar by changing its structure. This study aimed to optimize the removal of Ni2+from aqueous solutions using unmodified pristine biochar (PB) and acid-modified biochar (ACB) and alkali-modified biochar (ALB) treatments. Methods: After producing unmodified and modified biochars, their efficacy (PB, ACB, ALB) in optimizing nickel (Ni) removal from aqueous solutions, affected by various factors including initial Ni concentration, solution pH, adsorbent dose and contact time was evaluated using the response surface methodology (RSM: Box-Behnken design). Results: Comparative analysis employing Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) confirmed that ACB and ALB biochars exhibited an improved aromatic structure and smoother surfaces compared to PB. However, the modification process resulted in a decline in specific surface area (SSA) for ACB and ALB, consequently reducing their Ni adsorption capacity compared to PB. It was observed that acidic and alkaline treatments caused dissolution and rearrangement of biochar components, leading to a decrease in porosity and SSA. Consequently, the modified biochars demonstrated diminished effectiveness in removing Ni from solutions. Furthermore, the study revealed that pH, contact time, and adsorbent dose directly affected the Ni removal, while the initial Ni concentration exhibited an inverse effect. Conclusions: The current study revealed that the modification of biochar does not invariably enhance its pollutant adsorption properties. Further research is needed to explore the influence of feedstock types and the specific method of biochar modification on its pollutant adsorption efficiency.

Facile Synthesis of Polypyrrole-Decorated RGO-CuS Nanocomposite for Efficient Nickel Removal from Wastewater.

Efficient wastewater treatment, particularly the removal of heavy metal ions, remains a challenging priority in environmental remediation. This study introduces a novel sandwich-structured nanocomposite, RGO-CuS-PPy, composed of reduced graphene oxide (RGO), copper sulfide (CuS), and polypyrrole (PPy), synthesized via a straightforward hydrothermal method. The unique combination of RGO, CuS, and PPy offers enhanced adsorption capacity for Ni(II) ions due to RGO's high surface area and CuS's active binding sites, supported by PPy's structural stability contributions. This study is among the first to explore this specific nanocomposite architecture for Ni(II) removal, achieving an adsorption capacity of 166.67 mg/g and a high removal efficiency of 94.9% within 210 min for 55 mg/L of Ni(II) concentration at pH 6 and adsorbent dose of 3 mg/15 mL. The kinetic analysis shows the best fitted time-dependent experimental data with the pseudo-second-order model, indicating chemisorption. Isotherm studies confirmed the Langmuir model as the best fit, yielding a high monolayer adsorption capacity of 166.67 mg/g. Thermodynamic analysis shows the adsorption process was endothermic (ΔH° = 80.23 kJ/mol) and spontaneous (ΔG° ranging from -6.985 to -14.399 kJ/mol). Additionally, reusability tests using 0.1 M HCl for desorption demonstrated good reusability, emphasizing the RGO-CuS-PPy nanocomposite's potential as a sustainable adsorbent for Ni(II) removal in wastewater treatment applications.

Use of Biochar Obtained from Pyrolysis of Waste Filter Coffee as Adsorbent for Nickel Removal

Use of Biochar Obtained from Pyrolysis of Waste Filter Coffee as Adsorbent for Nickel Removal

Sustainable valorisation of cigarette butts waste through pyrolysis: An insight into the pyrolytic products and subsequent aqueous heavy metals removal by pyrolytic char

In this study, cigarette butts (CB) waste was pyrolyzed over a wide temperature range (400–700 °C) using Pyro/GC–MS and slow pyrolysis experiments. The feedstock and char products were extensively investigated using TGA, elemental analysis, surface area and porosity analysis, SEM-EDS, XRD, and FT-IR, and subsequently tested for their ability to remove Ni (II) and Cu (II) from aqueous solutions. The Pyro/GC–MS analysis revealed the presence of several useful compounds including acids, esters and hydrocarbons. Char yields ranged from 26.6 to 20.1 wt%, and carbon contents varied from 65.3 to 60.8 wt%. The chars produced at medium temperatures (500-600 °C) were highly porous, with a specific surface area of 272.9–270.8 m2/g. The heavy metal adsorption studies revealed that CB 500 °C had the highest adsorption capacity of 13.8 mg/g with 53.4 % nickel removal, while CB 600 °C had the highest adsorption capacity of 23.4 mg/g with 94.7 % copper removal.

Mitigating Health Risks Through Biosorption: Effective Removal of Nickel (II) and Chromium (VI) from Water with Acid-Treated Potato Peels

Introduction: Nickel (Ni(II)) and chromium (Cr(VI)) are associated with serious health risks, including respiratory problems, kidney damage, and cancer, along with potential threats to ecosystems. Given their persistence and significant toxicity, effective removal from contaminated water is essential to mitigate these health risks. This study explores the efficacy of acid-treated potato peels (ATPP) as an economical and readily accessible biosorbent for the removal of Ni(II) and Cr(VI) from water solutions. Methods: The study explored two biosorbents: raw potato peels (RPP) and ATPP. Fourier Transform Infrared (FTIR) spectroscopy was utilized to analyze changes in surface functional groups. Batch biosorption experiments were performed using distinct contact times (30-180min), pH (3–11), and biosorbent dosages (0.1–0.5 g). The Mann-Whitney U test was applied for the statistical analysis. Results and Discussion: The FTIR analysis indicated an enhancement in carboxyl groups on the ATPP surface after acid treatment, with stronger transmittance peak at 1645 cm⁻¹. ATPP showed significant improvements in biosorption capacity compared to RPP, removing 18.23% of 10 mg/L Ni(II) at pH 5 in 120minutes using 0.5 g of ATPP. For Cr(VI), 52.28% removal was achieved at pH 7 with 0.2 g of ATPP within the same time frame. Statistical analysis confirmed the superior performance of ATPP in removing Ni(II) (p = 0.024) and Cr(VI) (p = 0.004). Conclusion: ATPP offers significantly higher biosorption capabilities than RPP attributed to the increased presence of carboxyl groups on the modified surface, indicating potential for eco-friendly effective material in mitigating the heavy metal pollution's health risks.

Investigation of the biological removal of nickel and copper ions from aqueous solutions using mixed microalgae

AbstractThe use of mixed microalgae offers an effective solution for the management of contamination risks in cultivation while enhancing economic viability. In this study, mixed microalgae were used for the first time for the removal of copper (Cu) and nickel (Ni) from aqueous solutions. The characteristics of the adsorbents were examined thoroughly, and the adsorption process was assessed using isotherms, kinetics, and thermodynamics. Particle size, concentration, contact time, temperature, and pH were among the variables assessed. The findings demonstrated that, at an initial concentration of 100 mg L–1 and a pH of 6, the maximum adsorption of Cu with a particle size of 1 mm (90.20%) took place in 60 min. The highest adsorption rate (78.25%) was found for Ni. Microalgae performed best over 180 min at room temperature and at pH values that promoted metal dissolution. The removal percentages of wet and dried microalgae were comparable, and the wet adsorbent was more economical. It was feasible to remove both metals at the same time. Up to three cycles of adsorbent reuse were possible, with sodium hydroxide treatment offering superior removal to hydrochloric acid. Thermodynamic analysis demonstrated that this process, which results in a disordered state, is exothermic and spontaneous.

Optimization and Efficiency of Novel Magnetic-Resin-Based Approaches for Enhanced Nickel Removal from Water

Nickel contamination in water is a critical issue due to its toxicity and persistence. This study presents a novel magnetic resin, developed by modifying Lewatit® MonoPlus TP 207 with magnetite nanoparticles, to enhance adsorption capacity and facilitate efficient separation. A Definitive Screening Design (DSD) was employed to identify and optimize key parameters affecting nickel adsorption, including pH, resin dosage, initial nickel concentration, and the presence of competing ions (calcium and magnesium). The DSD analysis revealed that pH and magnesium concentration were the most significant factors influencing nickel removal. Optimal conditions were determined as pH 7, 270 min contact time, resin dosage of 0.5 mL/L, initial nickel concentration of 110 µg/L, calcium concentration of 275 mg/L, and magnesium concentration of 52.5 mg/L, achieving a maximum removal efficiency of 99.21%. The magnetic resin exhibited enhanced adsorption capacity and faster kinetics compared to the unmodified resin, leading to more efficient nickel removal. Moreover, its magnetic properties facilitated rapid separation from treated water, offering practical advantages for real-world applications. This study demonstrates the effective use of DSD in optimizing adsorption parameters and underscores the potential of magnetic resin as a sustainable and efficient adsorbent for water treatment.

Optimizing the Cementation Process of Leach Solution of Cold Purification Cake: Maximum Removal of Cadmium and Minimum Removal of Nickel

Optimizing the Cementation Process of Leach Solution of Cold Purification Cake: Maximum Removal of Cadmium and Minimum Removal of Nickel