Batik industrial waste contains some hazardous substance, such as Remazol Black B, Remazol Red AB, Remazol golden yellow RNL, naphthol, benzene and other azo dyes class. Batik dye also contains high Pb, COD and TDS which electrochemical degradation is needed. Preparation and application of carbon-PVC (95% w/w: 5%) electrode using the batch system for batik waste degradation with electrolysis method were performed in this study. Variations of voltage and electrolysis time used are 6, 7, 8, and 9 V and 60, 90, 120, and 150 minutes, respectively. Electrolysis was done by the addition of 1.5 g NaCl and the flow of external DC circuit Sanfix SP-303E. The optimum results were obtained from electrolysis with the voltage of 9 V in 150 minutes with 97.68% of waste degraded, and percent reduce TDS until 91.16%, total Pb metal content of 0.636 mg/L and COD figures amounted to 95.76%. This study concludes that electrolysis method using carbon-PVC electrode was used to degrade the batik waste is effective and can be reduce the value of COD, total Pb, and TDS.