Enhancing the accuracy of paddy rice mapping is crucial for bolstering global food security. Prior research incorporating Sentinel imagery with phenological characteristics has identified paddy rice fields effectively. However, challenges such as reliance on a single index, cloud cover interference, and a lack of sufficient training samples continue to complicate the mapping of paddy rice. This study introduces a comprehensive paddy rice mapping framework that incorporates annual phenological features throughout the entire growth phase. This was achieved by expanding the sample size through the extraction of phenological features, and the visually verified samples were then integrated with distinct phenological phases and relevant indices, utilizing hybrid Sentinel-1/2 imagery to map paddy rice distribution. The accuracy of the generated rice map was validated against trusted samples, corroborative agricultural statistics, and another high-resolution 10 m mapping product. Compared with ground-truth samples, the algorithm has achieved an overall accuracy of approximately 92% in most rice production regions with a confusion matrix. Additionally, the estimated rice area in Anhui and several other rice-producing regions shows less than 10% error when compared with governmental statistical records from the yearbook. When compared with another recent paddy rice map at the same spatial resolution (10 m), our approach provided cleaner details and more effectively reduced omission errors. It received values of R2 = 0.991 and slope = 1.08 in a prefecture-level statistical comparison with a counterpart. Our proposed approach is proven to be valid and is expected to offer significant benefits to agricultural sustainability and technological applications in farming.