Band and Park have criticized the von Neumann entropy, S N( ϱ) =− Tr ϱ In ϱ, of a density matrix (ϱ) as an inappropriate indicator of the uncertainty in ϱ. Rather, they proposed using an index based on expanding ϱ over all possible (pure and impure) states (D), not one founded on the terse (entropy- minimizing) spectral expansion of ϱ. However, a natural prior distribution over D is not available, while the uniform distribution over the pure states (P) is invariant under all unitary transformations. The minimum relative (barycentric) entropy, S b(ϱ), with respect to this distribution over P can be determined, using parametrizations of P for spin- 1 2 , spin-1, spin- 3 2 and two-photon systems. The relevance, in this regard, of certain theorems of Rothaus concerning the Laplace transforms of measures is discussed. The relation between S N(ϱ) and S b(ϱ) is established by a duality theorem of convex programming.
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