A large number of construction practice projects have found that there are many joints and microcracks in rock, concrete, and other structures, which cause the complexity of rock mechanical properties and are the main cause of geological or engineering disasters such as earthquakes, landslides, and rock bursts. To establish a rock fracture toughness evaluation method and understand the distribution range of fracture toughness of Longmaxi Formation shale, this study prepared three-point bending semi-circular disk shale samples of Longmaxi Formation with different crack inclination angles. The dimensionless fracture parameters of the samples, including the dimensionless stress intensity factors of type I, type II, and T-stress, were calibrated using the finite element method. Then, the peak load of the samples was tested using quasi-static loading, and the load–displacement curve characteristics of Longmaxi Formation shale and the variation in fracture toughness with crack inclination angle were analyzed. The study concluded that the specimens exhibited significant brittle failure characteristics and that the stress intensity factor is not the sole parameter controlling crack propagation in rock materials. With an increase in crack inclination angle, the prefabricated crack propagation gradually transitions from being dominated by type I fracture to type II fracture, and the T-stress changes from negative to positive, gradually increasing its influence on the fracture. An excessively large relative crack length increases the error in fracture toughness test results. Therefore, this paper suggests that the relative crack length a/R should be between 0.2 and 0.6. The fracture load distribution range of shale samples with different crack angles is 3.27 kN to 10.92 kN. As the crack inclination angle increases, the maximum load that the semi-circular disk shale samples can bear gradually increases. The pure type I fracture toughness of Longmaxi Formation shale is 1.13–1.38 MPa·m1/2, the pure type II fracture toughness is 0.55–0.62 MPa·m1/2, and the T-stress variation range of shale samples with different inclination angles is −0.49–9.48 MPa.
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