Relative Chemical Abundances Research Articles

Evidence of Pop III stars’ chemical signature in neutral gas at z ∼ 6

Aims. This study explores the metal enrichment signatures attributed to the first generation of stars (Pop III) in the Universe, focusing on the E-XQR-30 sample – a collection of 42 high signal-to-noise ratio spectra of quasi-stellar objects (QSOs) with emission redshifts ranging from 5.8 to 6.6. We aim to identify traces of Pop III metal enrichment by analyzing neutral gas in the interstellar medium of primordial galaxies and their satellite clumps, detected in absorption. Methods. To chase the chemical signature of Pop III stars, we studied metal absorption systems in the E-XQR-30 sample, selected through the detection of the neutral oxygen absorption line at 1302 Å. The O I line is a reliable tracer of neutral hydrogen and allowed us to overcome the challenges posed by the Lyman-α forest’s increasing saturation at redshifts above ∼5 to identify damped Lyman-α systems (DLAs). We detected and analyzed 29 O I systems at z ≥ 5.4, differentiating between proximate DLAs (PDLAs) and intervening DLAs. Voigt function fits were applied to obtain ionic column densities, and relative chemical abundances were determined for 28 systems. These were then compared with the predictions of theoretical models. Results. Our findings expand the study of O I systems at z ≥ 5.4 fourfold. No systematic differences were observed in the average chemical abundances between PDLAs and intervening DLAs. The chemical abundances in our sample align with literature systems at z > 4.5, suggesting a similar enrichment pattern for this class of absorption systems. A comparison between these DLA-analogs at 4.5 < z < 6.5 with a sample of very metal-poor DLAs at 2 < z < 4.5 shows in general similar average values for the relative abundances, with the exception of [C/O], [Si/Fe] and [Si/O] which are significantly larger for the high-z sample. Furthermore, the dispersion of the measurements significantly increases in the high-redshift bin. This increase is predicted by the theoretical models and indicates a potential retention of Pop III signatures in the probed gas. Conclusions. This work represents a significant advancement in the study of the chemical properties of highly neutral gas at z ≥ 5.4, shedding light on its potential association with the metal enrichment from Pop III stars. Future advancements in observational capabilities, specifically high-resolution spectrographs, are crucial for refining measurements and addressing current limitations in the study of these distant absorption systems.

Detailed chemical compositions of planet-hosting stars – I. Exploration of possible planet signatures

ABSTRACT We present a line-by-line differential analysis of a sample of 16 planet-hosting stars and 68 comparison stars using high-resolution, high signal-to-noise ratio spectra gathered using Keck. We obtained accurate stellar parameters and high-precision relative chemical abundances with average uncertainties in Teff, log g, [Fe/H], and [X/H] of 15 K, 0.034 cm s−2 , 0.012 dex, and 0.025 dex, respectively. For each planet host, we identify a set of comparison stars and examine the abundance differences (corrected for Galactic chemical evolution effect) as a function of the dust condensation temperature, Tcond, of the individual elements. While we confirm that the Sun exhibits a negative trend between abundance and Tcond, we also confirm that the remaining planet hosts exhibit a variety of abundance–Tcond trends with no clear dependence upon age, metallicity, or Teff. The diversity in the chemical compositions of planet-hosting stars relative to their comparison stars could reflect the range of possible planet-induced effects present in these planet hosts, from the sequestration of rocky material (refractory poor) to the possible ingestion of planets (refractory rich). Other possible explanations include differences in the time-scale, efficiency and degree of planet formation, or inhomogeneous chemical evolution. Although we do not find an unambiguous chemical signature of planet formation among our sample, the high-precision chemical abundances of the host stars are essential for constraining the composition and structure of their exoplanets.

A Metal-poor Damped Lyα System at Redshift 6.4

Abstract We identify a strong Lyα damping wing profile in the spectrum of the quasar P183+05 at z = 6.4386. Given the detection of several narrow metal absorption lines at z = 6.40392, the most likely explanation for the absorption profile is that it is due to a damped Lyα system. However, in order to match the data a contribution of an intergalactic medium 5%–38% neutral or additional weaker absorbers near the quasar is also required. The absorption system presented here is the most distant damped Lyα system currently known. We estimate an H i column density of 1020.68±0.25 cm−2, metallicity [O/H] = −2.92 ± 0.32, and relative chemical abundances of a system consistent with a low-mass galaxy during the first Gyr of the universe. This object is among the most metal-poor damped Lyα systems known and, even though it is observed only ∼850 Myr after the big bang, its relative abundances do not show signatures of chemical enrichment by Population III stars.

Solar UV and X-ray spectral diagnostics

X-ray and ultraviolet (UV) observations of the outer solar atmosphere have been used for many decades to measure the fundamental parameters of the solar plasma. This review focuses on the optically thin emission from the solar atmosphere, mostly found at UV and X-ray (XUV) wavelengths, and discusses some of the diagnostic methods that have been used to measure electron densities, electron temperatures, differential emission measure (DEM), and relative chemical abundances. We mainly focus on methods and results obtained from high-resolution spectroscopy, rather than broad-band imaging. However, we note that the best results are often obtained by combining imaging and spectroscopic observations. We also mainly focus the review on measurements of electron densities and temperatures obtained from single ion diagnostics, to avoid issues related to the ionisation state of the plasma. We start the review with a short historical introduction on the main XUV high-resolution spectrometers, then review the basics of optically thin emission and the main processes that affect the formation of a spectral line. We mainly discuss plasma in equilibrium, but briefly mention non-equilibrium ionisation and non-thermal electron distributions. We also summarise the status of atomic data, which are an essential part of the diagnostic process. We then review the methods used to measure electron densities, electron temperatures, the DEM, and relative chemical abundances, and the results obtained for the lower solar atmosphere (within a fraction of the solar radii), for coronal holes, the quiet Sun, active regions and flares.

The chemistry and kinematics of two molecular clouds near Sagittarius A*

We have analysed the chemical and kinematic properties of the 20 and 50 km s−1 molecular clouds in the Central Molecular Zone of the Milky Way Galaxy, as well as those of the molecular ridge bridging these two clouds. Our work has utilized 37 molecular transitions in the 0.65, 3 and 7-mm wavebands, from the Mopra and NANTEN2 telescopes. The 0.65-mm NANTEN2 data highlights a dense condensation of emission within the western part of the 20 km s−1 cloud, visible in only four other transitions, which are 3-mm H13CN (1–0), H13CO+ (1–0), HNC (1–0) and N2H+ (1–0), suggesting that the condensation is moderately optically thick and cold. We find that while the relative chemical abundances between both clouds are alike in many transitions, suggesting little variation in the chemistry between both clouds; the 20 km s−1, cold cloud is brighter than the 50 km s−1 cloud in shock and high density tracers. The spatial distribution of enhanced emission is widespread in the 20 km s−1 cloud, as shown via line ratio maps. The position velocity diagrams across both clouds indicate that the gas is well mixed. We show that the molecular ridge is most likely part of the 20 km s−1 cloud and that both of them may possibly extend to include the 50 km s−1 cloud, as part of one larger cloud. Furthermore, we expect that the 20 km s−1 cloud is being tidally sheared as a result of the gravitational potential from Sgr A*

First high-precision differential abundance analysis of extremely metal-poor stars

Context: Studies of extremely metal-poor stars indicate that chemical abundance ratios [X/Fe] have an rms scatter as low as 0.05 dex (12 \%). It remains unclear whether this reflects observational uncertainties or intrinsic astrophysical scatter arising from physical conditions in the ISM at early times. Aims: Measure differential chemical abundance ratios in extremely metal-poor stars to investigate the limits of precision and to understand whether cosmic scatter or observational errors are dominant. Methods: We used high resolution (R $\sim 95,000$) and high S/N (S/N $= 700$ at 5000$\AA$) HIRES/Keck spectra, to determine high precision differential abundances between two extremely metal-poor stars through a line-by-line differential approach. We determined stellar parameters for the star G64-37 with respect to the standard star G64-12. We performed EW measurements for the two stars for the lines recognized in both stars and performed spectral synthesis to study the carbon abundances. Results: The differential approach allowed us to obtain errors of $\sigma$(T$_{eff}$ ) $=$ 27 K, $\sigma$(log $g$) $=$ 0.06 dex, $\sigma$([Fe/H]) $=$ 0.02 dex and $\sigma$(v$_{t}$ ) $=$ 0.06 kms$^{-1}$. We estimated relative chemical abundances with a precision as low as $\sigma$([X/Fe]) $\approx$ 0.01 dex. The small uncertainties demonstrate that there are genuine abundance differences larger than the measurement errors. The observed Li difference can not be explained by the difference in mass, because the less massive star has more Li. Conclusions: It is possible to achieve an abundance precision around $\approx$ 0.01-0.05 dex for extremely metal-poor stars, opening new windows on the study of the early chemical evolution of the Galaxy.

VLT X-Shooter spectroscopy of the nearest brown dwarf binary

The aim of the project is to characterise both components of the nearest brown dwarf sytem to the Sun, WISE J104915.57-531906.1 (=Luhman16AB) at optical and near-infrared wavelengths. We obtained high signal-to-noise intermediate-resolution (R~6000-11000) optical (600-1000 nm) and near-infrared (1000-2480nm) spectra of each component of Luhman16AB, the closest brown dwarf binary to the Sun, with the X-Shooter instrument on the Very Large Telescope. We classify the primary and secondary of the Luhman16 system as L6-L7.5 and T0+/-1, respectively, in agreement with previous measurements published in the literature. We present measurements of the lithium pseudo-equivalent widths, which appears of similar strength on both components (8.2+/-1.0 Angstroms and 8.4+/-1.5 Angstroms for the L and T components, respectively). The presence of lithium (Lithium 7) in both components imply masses below 0.06 Msun while comparison with models suggests lower limits of 0.04 Msun. The detection of lithium in the T component is the first of its kind. Similarly, we assess the strength of other alkali lines (e.g. pseudo-equivalent widths of 6-7 Angstroms for RbI and 4-7 Angstroms for CsI) present in the optical and near-infrared regions and compare with estimates for L and T dwarfs. We also derive effective temperatures and luminosities of each component of the binary: -4.66+/-0.08 dex and 1305(+180)(-135) for the L dwarf and -4.68+/-0.13 dex and 1320(+185)(-135) for the T dwarf, respectively. Using our radial velocity determinations, the binary does not appear to belong to any of the well-known moving group. Our preliminary theoretical analysis of the optical and J-band spectra indicates that the L- and T-type spectra can be reproduced with a single temperature and gravity but different relative chemical abundances which impact strongly the spectral energy distribution of L/T transition objects.

Solar system chemical abundances corrected for systematics

Abstract The relative chemical abundances between CI meteorites and the solar photosphere exhibit a significant trend with condensation temperature. A trend with condensation temperature is also seen when the solar photospheric abundances are compared to those of nearby solar twins. We use both these trends to determine the alteration of the elemental abundances of the meteorites and the photosphere by fractionation and calculate a new set of primordial Solar system abundances.

The Geminid meteoroid stream as a potential meteorite dropper: a case study

A Geminid fireball with an absolute magnitude of -13 was observed over the south of Spain on Dec. 15, 2009. This extraordinarily bright event (the brightest Geminid ever recorded by our team) was imaged from two meteor observing stations operated by the SPanish Meteor Network (SPMN). The bolide exhibited fast and quasi-periodic variations in brightness, a behaviour typically associated to the rotation of the parent meteoroid. The inferred tensile strength of this particle was found to be significantly higher that the typical values obtained for Geminid meteoroids. The fireball penetrated in the atmosphere till a final height of about 25 km above the ground level and a non-zero terminal mass was calculated at the ending point of the luminous trajectory. In this way, the observational evidence points to the existence of a population of meteoroids in the higher end of the Geminid mass distribution capable of producing meteorites. From the relative chemical abundances inferred from the emission spectrum of this bolide we conclude that the Geminid-forming materials are similar to some primitive carbonaceous chondrite groups. Then, we conclude that in meteorite collections from cold deserts, capable to preserve meteorites of few tens of grams, some rare groups of carbonaceous chondrites could be coming from the Geminid parent body: (3200) Phaeton.

EASY-GOING deconvolution: Combining accurate simulation and evolutionary algorithms for fast deconvolution of solid-state quadrupolar NMR spectra

A fast and accurate fit program is presented for deconvolution of one-dimensional solid-state quadrupolar NMR spectra of powdered materials. Computational costs of the synthesis of theoretical spectra are reduced by the use of libraries containing simulated time/frequency domain data. These libraries are calculated once and with the use of second-party simulation software readily available in the NMR community, to ensure a maximum flexibility and accuracy with respect to experimental conditions. EASY-GOING deconvolution ( EGdeconv) is equipped with evolutionary algorithms that provide robust many-parameter fitting and offers efficient parallellised computing. The program supports quantification of relative chemical site abundances and (dis)order in the solid-state by incorporation of (extended) Czjzek and order parameter models. To illustrate EGdeconv’s current capabilities, we provide three case studies. Given the program’s simple concept it allows a straightforward extension to include other NMR interactions. The program is available as is for 64-bit Linux operating systems.

On the sodium overabundance in cometary meteoroids

Relative chemical abundances and physical properties of cometary meteoroids can be deduced from meteor spectroscopy. The study of moderately volatile elements like Na can provide clues on the structure of cometary particles and processes suffered by these particles. Recent studies of spectra of photographic fireballs (produced by cm-sized meteoroids) suggest that Na is enhanced in a 1.5 factor relative to the chondritic value. The observed features in the ablation of Perseid and Leonid meteoroids suggest that the particle fragmentation behavior of an important part of the large meteoroids fits well with a dustball model where Na would be associated with an interstitial material joining mineral grains. We suggest that aqueous alteration in the parent bodies of these meteoroids can promote chemical redistribution of Na as has been widely observed in carbonaceous chondrites. Then, this element is mobilised towards interstitial fine-grain materials that are joining large mineral grains. These more friable materials (rich in Na) can be ablated preferentially in the first stages of ablation. Finally, we discuss briefly the interest in the development of meteor spectroscopy in UV and IR in order to improve our knowledge of the ablation of volatile and moderately volatile phases of meteoroids.

Diffuse Interstellar Bands Toward HD 62542

Diffuse interstellar bands (DIBs) have been detected for the first time along the peculiar translucent line of sight toward HD 62542, which passes through a diffuse cloud core. Although only a small fraction (18 out of more than 300) of generally weak DIB features have been shown to correlate with and C_3 (the C_2 DIBs), it is predominantly these DIBs that are observed toward HD 62542. The typically strong DIBs λλ5780 and 5797 are detected but are significantly weaker than toward other lines of sight with similar reddening. Other commonly observed DIBs (such as λλ4430, 6270, and 6284) remain noticeably absent. These observations further support the suggestion that the line of sight toward HD 62542 crosses only the core of a diffuse cloud and show that the correlation between the DIBs and small carbon chains is maintained in environments with very large fractions of molecular hydrogen, f_(H_2) > 0.8. A comparison of CH, CN, C_2, and C_3 column densities and DIB strengths toward HD 62542, HD 204827, and HD 172028 suggests that the line of sight toward HD 204827 passes through a diffuse cloud core similar to that seen toward HD 62542, as well as what might be referred to as a diffuse cloud envelope. This indicates that the bare core toward HD 62542 may not have significantly different relative chemical abundances from other diffuse cloud cores and that the DIBs may serve as a diagnostic of such cores.

SPECTROSCOPY OF A GEMINID FIREBALL: ITS SIMILARITY TO COMETARY METEOROIDS AND THE NATURE OF ITS PARENT BODY

A detailed analysis of a photographic spectrum of a Geminid fireball obtained in December 14, 1961 at the Ondrejov Observatory is presented. We have computed a synthetic spectrum for the fireball and compared it with the observed spectrum assuming chemical equilibrium in the meteor head. In this way we have determined relative chemical abundances in meteor vapors. Comparing the relative chemical abundances of this Geminid meteoroid with those obtained from meteoroids associated with comets 55P/Tempel-Tuttle and 109P/Swift-Tuttle we found no significant chemical differences in main rock-forming elements. Despite of this similarity, the deepest penetration of the Geminid meteoroids and their ability to reach high rotation rates in space without fragmentation suggest that thermal processing is affecting their physical properties. We suggest that as consequence of space weathering a high-strength envelope is produced around these particles. In this picture, heating processes of the mineral phases could result in the peculiar properties observed during atmospheric entry of the Geminid meteoroids, especially their strength, which is evidenced by its resistance to ablation. Finally, although one meteoroid cannot be obviously considered as representative of the composition of its parent body, we conclude that 3200 Phaethon is able to produce millimetre-size debris nearly chondritic in composition, but the measured slight overabundance of Na would support a cometary origin for this body.

Chemical abundances determined from meteor spectra: I. Ratios of the main chemical elements

Abstract— Relative chemical abundances of 13 meteoroids were determined by averaging the composition of the radiating gas along the fireball path that originated during their penetration into the Earth's atmosphere. Mg, Fe, Ni, Cr, Mn, and Co abundances, relative to Si, are similar to those reported for CI and CM carbonaceous chondrites and interplanetary dust particles. In contrast, relative abundances of Ca and Ti in meteor spectra indicate that these elements suffer incomplete evaporation processes. The chemical composition of all meteoroids studied in this work differs from that of 1P/Halley dust.

Is Hale-Bopp a juvenile comet - study of the energy balance to explain the vapor flux of volatiles from the surface

Sublimation of minor gases from ices inside of a porous comet nucleus strongly depends on the effective energy input. Our model meant to describe the gas flux inside and out of the porous nucleus has been used to study the influence of physical and structural parameters on the effective energy input. We solve the conservation equations for H2O and CO as the most abundant minor component of higher volatility under appropriate boundary conditions. From the calculations we obtain the gas flux from volatile, icy components inside the porous nucleus, temperature profiles, changes in relative chemical abundances, and the gas flux into the coma for each of the volatiles. We will show results from our calculations for a model comet in the orbit of Hale-Bopp (C/1995 O1). In this paper we focus on the energy balance at the surface. We will also relate measurements of molecule fluxes to available energies and try to provide hints about the evolutionary status of the comet.

Optimum Chemical Sites and Techniques for Searches for Negatively Charged Rare Particles

Supersymmetric particle theories have predicted the existence of massive, negatively charged, nonstrongly interacting particles, denoted as X - particles. If stable X - particles existed at the onset of primordial nucleosynthesis, they would have been bound initially to the primordial nuclides. However, subsequent stellar processing, as part of the chemical evolution of the galaxy, is shown to have produced considerable rearrangement of the relative chemical abundances of X - particles subsequent to their binding to primordial nuclei. Optimal chemical environments in which to search for X - particles are found to be boron and fluorine. A mass-independent search for X - particles bound to heavy nuclei that utilizes laser spectroscopy of rotational bands in diatomic molecules is estimated to have an unusually high relative sensitivity to possible X - particles.

Finite Element Analysis of Diffusion Processes in White Dwarfs

The spectral evolution of white dwarfs is governed by diffusion processes which enter into competition with mechanisms such as mass loss, convective mixing, and accretion from the interstellar medium in various phases of the evolution. Until recently, our theoretical understanding of the chemical evolution of these stars has been limited by the very severe numerical difficulties which plague a time-dependent description of the problem. Indeed, diffusion problems in white dwarf interiors and envelopes are particularly demanding from a computational standpoint: they involve relative chemical abundances spanning many orders of magnitude, time integration length of a few billion years, and many physical processes operating with greatly different time constants. We have already introduced in the field a robust numerical technique based on an implicit finite difference scheme designed for nonlinear two-point boundary value problems (Pelletier 1986). This method has been used to investigate a number of problems related to the spectral evolution of white dwarfs (Pelletier 1986; Pelletier et al. 1986; Dupuis et al. 1987). As requirements for further progress in the field become more exacting and in the interest of improving the efficiency, we have sought to develop even more powerful numerical techniques. We briefly introduce here an efficient computational approach to diffusion problems in white dwarfs based on a Galerkin finite element method to solve the convective-diffusion equation in an evolving white dwarf model. As an illustrative example, we discuss some sample results of a detailed investigation of the problem of chemical sedimentation (H, He, and C) in the envelopes of hot white dwarfs and the formation of DA stars.

Petrology and tectonic setting of some Ordovician volcanic rocks from the Southern Uplands of Scotland

Abstract: SUMMARY: Within the Ordovician sequence of the Southern Uplands of Scotland numerous basaltic units occur, forming local basement to sequences of chert, graptolitic mudstone and greywacke. The basalts are fault-bounded at their base. Although they have suffered secondary alteration to varying degrees, the least mobile elements, Ti, Zr, Y and Nb, show a correlation between relative chemical abundances and supposed tectonic level. The most northern tectonic slice contains alkali basalts; the central slice contains 11 examples of what are apparently ocean-floor tholeiites and 4 mildly alkaline basalts; a third slice, found at one locality only, also contains tholeiites whose chemistry is comparable with the most primitive basalts. Samples of Ordovician extrusives from Bail Hill have calc-alkaline to alkaline affinities, while extrusives from Wrae Hill are quartz-keratophyres. The geochemical pattern is consistent with a model of an opening Iapetus Ocean in which rifting pre-dated spreading such that the basement to the Lower Palaeozoic sequence of the Southern Uplands was oceanic.

Relative chemical abundances in different solar regions

Intensities of extreme-ultraviolet emmision lines formed in quiet Sun regions, a coronal hole, an active region, and a prominence are used to derived chemical abundances of carbon, nitrogen, and oxygen relative to silicon in each region. For each element the relative abundance in each region agrees to within the estimated errors in the analysis. This means that the relative abundances are constant over a wide range of electron densities, emission measures, turbulent mass motions, and heights above the limb. Uncertainties in the atomic data appear to be the primary source of scatter in the derived abundances.

The Surprising Constancy of Relative Chemical Abundances in Different Regions of Interstellar Space – Particularly for Formaldehyde

Many of the places in which radio astronomers search for molecules are located in exotic regions lying near the galactic center, near H II regions or other continuum sources, or in high density regions. Such regions have wide variations in their physical environment. Here we wish to compare two types of region whose environments are thought to be well-understood. One of these is dust clouds; the other is unshielded (from UV) cold clouds in front of bright radio sources. For the sake of interest, we include without comment results for molecular regions near the Galactic center and near Orion A.Comparison of dust clouds and unshielded clouds is of interest because the volume density differs by a factor of 104 or more and the extinction differs by 8 mag. or more. Neither type of cloud lies near H II regions or other sources of intense radiation. Even though their properties differ widely, we will see that the abundances of OH and H2CO relative to hydrogen are approximately the same in the two. Although this is understandable for OH, no current theory would predict this situation for H2CO.