Ions In Region Research Articles

On the long-term stability of the association between foF2 and EUV solar proxies

Solar extreme ultraviolet (EUV) radiation is the main source of heating and ionization of the Earth's upper atmosphere, forcing most of this system's time variability, which in annual scales corresponds to the solar activity ∼11-year cycle. Due to the difficulties in obtaining solar EUV time series covering extended periods of time or during periods without measurements available, the use of solar EUV proxies became a solution. In the case of the ionosphere, and in particular the F2-layer critical frequency (foF2), in addition to the solar activity cycle variation, it may also exhibit the effect of long-term trend forcings, like the monotonous increasing greenhouse gas concentration since the industrial revolution. To accurately detect and measure this weak trend against the solar activity variability, it is crucial to account for the solar forced variation. Traditionally, it is modeled as a linear association between foF2 and a given solar EUV proxy. However, the stability of this association has become a controversial issue. It would be reasonable to assume, in turn, that if the ionospheric environment is undergoing a trend forced by a non-solar diver, like the greenhouse gas concentration increase, the relationship between foF2 and solar proxies may be affected, ceasing to be stable if this additional driver is not introduced in the modeled association. Using rolling regressions over the period 1960–2023 to analyze this stability, our results suggest that the issue may not only lie in the steady trend expected in foF2 from a non-solar source or the need to include terms in the simple linear regression commonly used, but also in the possible deviation of the different proxies from the 'true' EUV solar flux, which is the ultimate main driver of F2 region ionization, a deviation that has been intensifying over the last two decades. We assert that it is a deviation from the actual EUV behavior because the indices diverge from one another, something that should not occur if they all reflect the same solar EUV.

A plasma-catalytic system with MgO/NiO/Ni cathode for SF6 degradation

In this work, a plasma-catalytic system in DC discharge with MgO/NiO/Ni (MNN) cathode is proposed for the degradation of SF6 greenhouse gas. The discharge power with MNN cathode is significantly increased compared with Ni cathode due to its good electron emission characteristics, and an effective and stable SF6 degradation performance is achieved in this multi-needle plate discharge system. Besides, surface discharge occurs on the MNN cathode in addition to the needle tips, which is believed to be conducive to the catalytic decomposition of SF6 on the MgO surface. Nontoxic products of MgF2 and MgSO4 are detected on the MgO layer after discharge from various characterizations (XRD, XPS, FTIR and Raman, etc.), suggesting that there is a series of catalytic reactions between SF6/intermediates and MgO. The addition of appropriate O2 (O2:SF6 = 1:1) in the background is not only conducive to the defluorination decomposition of SF6 in ionization region, but also O atom generated from O2 discharge promotes the formation of MgF2 and MgSO4, thus resulting in an effective SF6 degradation performance. Then, the possible degradation mechanism of SF6 in gas phase and on the MgO layer is discussed and the possible degradation pathways are proposed. This research first demonstrates the effectiveness of enabling degrading SF6 gases in a plasma-catalytic system with MNN cathode.

Development of an Ion Mobility Spectrometer Based on a Pulsed Photoelectric Effect Ionization Source.

Ion mobility spectrometry (IMS) is a compact and sensitive trace gas analysis instrument that ionizes the sample into ions for detection. Typically, an ion gate is used to cut the continuous ion beam into ion packets for separation and detection. However, commonly used ion gates suffer from complex structures or low ion transmission rates, making the gateless IMS a viable alternative. In this study, an IMS based on a pulsed photoelectric effect ionization source was designed. The photoelectrons were generated by irradiating a photoelectric material with a back-illuminated pulsed xenon lamp. This allows for low-energy photoelectron generation and the production of simple reactant ions (O2-(H2O)n) and thus negative product ions. The photoelectron current generated by this ionization source was analyzed, which can reach an intensity of a few microamperes and can be converted into an ion signal exceeding 10 nA. The introduction of the pulsed photoelectric effect ionization source makes it possible to generate separate ion packets and complete ion injection when a constant electric field is maintained in the ionization region. And with an assisted pulsed electric field in the ionization region, the resolving power of the system can be effectively improved to 1.85 times that of the constant electric field. The IMS developed in this study was used for the detection of common volatile hazardous chemicals, yielding effective results. The detection limit for phenol was below 1 ppb, and the dynamic response range exceeded 1 order of magnitude, which implies the potential applications of this IMS to detect substances with high electron affinity, such as explosives detection in public safety.

Interference mechanism of plasma self-organization in transparent dielectrics under the intense femtosecond laser pulse exposure

A new mechanism of plasma self-organization in transparent dielectrics with wide bandgap exposed to the intense tightly focused laser radiation was revealed, which causes the generation of 3D periodic ring structures with subwavelength period both along the laser pulse propagation and in the radial direction. The mechanism involves formation of dense plasma burst in the pre-focal region that provides efficient scattering of the incident wave. The interference of a plane incident laser wave in the focal region and a divergent reflected one will form the standing wave pattern with local minima and maxima of laser field both in the direction of the incident wave propagation and perpendicular to it producing the ring patterns of effective ionization regions in the dielectric volume. Analytical and numerical simulations of the process of laser wave scattering on a near-spherical plasma object with dimensions both smaller and larger than the laser radiation wavelength are performed to verify the proposed model.

Aerodynamic thermal breakup droplet ionization combined with a β-irradiation source for mass-spectrometric analysis of samples in a nonpolar solvent

A method is proposed for increasing the number of ions during mass-spectrometric analysis of samples in a nonpolar solvent (benzene). For this purpose, aerodynamic thermal breakup droplet ionization (ATBDI) with the impact of β-radiation on the aerosol droplets used in ATBDI was evaluated. This modification of the method, which we named β-ATBDI, allows to shift a nonvolatile analyte (trinitrotoluene in the negative ionization region and cocaine in the positive ionization region, as an example) into a gas phase as an aerosol at room temperature (in contrast to atmospheric pressure chemical ionization). In addition, β-ATBDI enables a researcher to distinguish mass spectrometric peaks of the compounds located in an aerosol droplet from compounds located outside the droplet, i.e., to identify background peaks. Also briefly discussed the ionization of two antibiotics—azithromycin in methylene chloride and sulfadiazine in salt water with β-ATBDI, ATBDI and electrospray ionization source.

Ionospheric Virtual Height (h′F2) Response and its Vertical Ion Drifts Characteristics at an Equatorial Station

The Ionospheric virtual heights (h’F2) obtained from the DPS-4.2 Version of the GIRO’s site, as a computing parameter for vertical E × B ion drifts in this present study using the international quiet days (IQDs) is engaged. Vertical ion drifts () computed from virtual heights was studied over Ilorin (lat. 8.31°N, long. 4.34°E, dip lat. 2.95o) during a solar minimum (SM), a station situated at the equatorial dip. The hourly averages of vertical ion drifts, were computed from 10-international quiet days (IQDs) hourly h’F2 averages for the four seasonal months adopted. Seasonally, was having same behavourial patterns of pre-noon and post-noon peaks, but in h’F2, it had noontime, post-sunset and pre-sunrise peaks occurred in all seasons. The pre-noon peaks magnitudes are 6.8, 14.4 and 15.0 m/s in June Solsticial, Equinoctial and December Solsticial respectively; and its post-noon peaks magnitudes are 0.8, 7.4 and 7.9 m/s in December and June Solsticials, and Equinoctial seasons respectively. The h’F2 noontime peaks magnitudes are (321–410) km, post-sunset peaks magnitudes are (253–329) km and pre-sunrise peaks magnitudes are (228–318) km in all seasons. Also, depicted pre-reversal enhancement (PRE) night peaks in all seasons. The PRE peaks magnitudes are [(-4.0)–(-13.4)] m/s at 2000 LT, [(-4.9)–(-9.3)] m/s between 2200 LT and 2300 LT in all seasons. Similar phenomenal observations occurred in the h’F2 and annual patterns plots. In general, the h’F2 and magnitudes were greatest in Solsticial seasons and least in Equinoctial season. The h’F2 and stable and continual descent indicates generally that the electrons briskly drifting away from the equator triggered by solar ionization in the equatorial region. As well, seasonal peaks occurred in general are assumed to be controlled by the enhanced vertical E × B ion drifts upsurge, which adapts with former aftermaths at some stations in the West African sector during closely related solar activity

Study on the effects of medium-low pressure and oxygen concentration on positive streamer based on a two-dimensional fluid model

We studied positive streamers with a 5 mm gap under 20–101 kPa pressure and 1%–31% O2 concentrations conditions using a 2D axisymmetric fluid model based on local field approximation. As the pressure decreases from 101 kPa to 20 kPa, the axial reduced electric field, the mean electron energy and the electron diffusion coefficient increase, which leads to the acceleration of the streamer propagation velocity and the increase of the streamer channel radius. The opposite change of ionization cross section and gas molecular density caused by the decrease of pressure leads to the non-monotonic change of the peak of net ionization rate. At medium-low pressure, there is a wider ionization region at the streamer head. As the O2 concentration decreases from 31% to 1% in N2/O2, the streamer propagation velocity decreases. When the O2 concentration drops to 1%, the streamer velocity decreases with a descent gradient of nearly 4 times, compared to 11% O2. Based on the space charge effect and chemical reaction rate, a possible mechanism is proposed to explain the abrupt change in the streamer velocity.

Enhancing the Performance of Tyndall-Powell Gate Ion Mobility Spectrometry by Combining Ion Enrichment, Discrimination Reduction, and Temporal Compression into a Single Gating Process.

The broad applications of ion mobility spectrometry (IMS) demand good sensitivity and resolving power for ion species with different reduced mobilities (K0). In this work, a new Tyndall-Powell gate (TPG) gating method for combining ion enrichment, mobility discrimination reduction, and temporal compression into a single gating process is proposed to improve IMS analysis performance. The two-parallel-grid structure and well-confined gate region of the TPG make it convenient to spatiotemporally vary the electric fields within and around the gate region. Under the new gating method, a potential wave is applied on TPG grid 1 to enrich ions within the ionization region adjacent to the TPG during the gate-closed state; meanwhile, a potential wave is applied on TPG grid 2 to enhance mobility discrimination reduction and temporal compression simultaneously during the gate-open state. For triethyl phosphate (TEP) and dimethyl methylphosphonate mixtures, product ion peaks within K0 of 1.9 to 1.1 cm2/V·s exhibit a 19-fold increase in ion current compared to the traditional TPG gating method, while maintaining a resolving power of 85. The estimated limit of detection for the TEP dimer is lowered from 8 ppb to 135 ppt. The new gating method can be applied to other TPG-based IMS systems to enhance their performance in analyzing complex samples.

High power impulse magnetron sputtering of a zirconium target

High power impulse magnetron sputtering (HiPIMS) discharges with a zirconium target are studied experimentally and by applying the ionization region model (IRM). The measured ionized flux fraction lies in the range between 25% and 59% and increases with increased peak discharge current density ranging from 0.5 to 2 A/cm2 at a working gas pressure of 1 Pa. At the same time, the sputter rate-normalized deposition rate determined by the IRM decreases in accordance with the HiPIMS compromise. For a given discharge current and voltage waveform, using the measured ionized flux fraction to lock the model, the IRM provides the temporal variation of the various species and the average electron energy within the ionization region, as well as internal discharge parameters such as the ionization probability and the back-attraction probability of the sputtered species. The ionization probability is found to be in the range 73%–91%, and the back-attraction probability is in the range 67%–77%. Significant working gas rarefaction is observed in these discharges. The degree of working gas rarefaction is in the range 45%–85%, higher for low pressure and higher peak discharge current density. We find electron impact ionization to be the main contributor to working gas rarefaction, with over 80% contribution, while kick-out by zirconium atoms and argon atoms from the target has a smaller contribution. The dominating contribution of electron impact ionization to working gas rarefaction is very similar to other low sputter yield materials.

Production of High-Power Nitrogen Sputtering Plasma for TiN Film Preparation

High-density nitrogen plasma was produced using a high-power pulsed power modulator to sputter titanium targets for the preparation of titanium nitride film. The high-power pulsed sputtering discharge unit consisted of two targets facing each other with the same electrical potential. The titanium target plates were used as target materials with dimensions of 60 mm length, 20 mm height, and 5 mm thickness. The gap length was set to be 10 mm. The magnetic field was created with a permanent magnet array behind the targets. The magnetic field strength at the gap between the target plates was 70 mT. The electrons were trapped by the magnetic and electric fields to enhance the ionization in the gap. The nitrogen and argon gases were injected into the chamber with 4 Pa gas pressure. The applied voltage to the target plates had an amplitude from −600 V to −1000 V with 600 μs in pulse width. The target current was approximately 10 A with the consumed power of 13 kW. The discharge sustaining voltage was almost constant and independent of the applied voltage, in the same manner as the conventional normal glow discharge. The ion density and electron temperature at the surface of the ionization region were obtained as 1.7 × 1019 m−3 and 3.4 eV, respectively, by the double probe measurements. The vertical distribution of ion density and electron temperature ranged from 1.1 × 1017 m−3 (at 6 cm from the target edge) to 1.7 × 1019 m−3 and from 2.4 eV (at 6 cm from the target edge) to 3.4 eV, respectively. From the emission spectra, the intensities of titanium atoms (Ti I), titanium ions (Ti II), and nitrogen ions (N2+) increased with increasing input power. However, the intensities ratio of Ti II to Ti I was not affected by the intensities from N2+.

Photoabsorption cross section measurements of acetylene in the nonionizing region using the double-ion chamber method

The double-ion chamber (DIC) method has been used to measure photoabsorption cross sections in the ionization region of the sample gas. In this study, we introduce a method to extend the wavelength region of the DIC measurements beyond the ionization threshold wavelength by using the photoion currents from the impurities in the sample gas. To verify this method, the photoabsorption cross sections of C2H2 (ionization threshold wavelength λth = 108.8 nm) have been measured from 105 to 137 nm. The natural impurity, acetone (λth = 127.8 nm), contained 1% in high-purity grade acetylene (C2H2) sample gas, allowing for measurements in the non-ionizing region of C2H2 up to 127.7 nm. By adding 1% benzene (λth = 134.6 nm) in the sample gas, measurements were possible even further, to 134.5 nm. This new method enables the measurement of the photoabsorption cross section by photoions that are produced from the impurities in the sample gas in a substantial amount. The current measurement methodology aligns well with the previous measurements of Suto and Lee [Suto and Lee, J. Chem. Phys. 80, 4824 (1984)].

On working gas rarefaction in high power impulse magnetron sputtering

The ionization region model (IRM) is applied to explore working gas rarefaction in high power impulse magnetron sputtering discharges operated with graphite, aluminum, copper, titanium, zirconium, and tungsten targets. For all cases the working gas rarefaction is found to be significant, the degree of working gas rarefaction reaches values of up to 83%. The various contributions to working gas rarefaction, including electron impact ionization, kick-out by the sputtered species or hot argon atoms, and diffusion, are evaluated and compared for the different target materials, and over a range of discharge current densities. The relative importance of the various processes varies between different target materials. In the case of a graphite target with argon as the working gas at 1 Pa, electron impact ionization (by both primary and secondary electrons) is the dominating contributor to working gas rarefaction, with over 90% contribution, while the contribution of sputter wind kick-out is small <10 %. In the case of copper and tungsten targets, the kick-out dominates, with up to ∼60% contribution at 1 Pa. For metallic targets the kick-out is mainly due to metal atoms sputtered from the target, while for the graphite target the small kick-out contribution is mainly due to kick-out by hot argon atoms and to a smaller extent by carbon atoms. The main factors determining the relative contribution of the kick-out by the sputtered species to working gas rarefaction appear to be the sputter yield and the working gas pressure.

Optimization of magnetic field design for Hall thrusters based on a genetic algorithm

Magnetic field design is essential for the operation of Hall thrusters. This study focuses on utilizing a genetic algorithm to optimize the magnetic field configuration of SPT70. A 2D hybrid PIC-DSMC and channel-wall erosion model are employed to analyze the plume divergence angle and wall erosion rate, while a Farady probe measurement and laser profilometry system are set up to verify the simulation results. The results demonstrate that the genetic algorithm contributes to reducing the divergence angle of the thruster plumes and alleviating the impact of high-energy particles on the discharge channel wall, reducing the erosion by 5.5% and 2.7%, respectively. Further analysis indicates that the change from a divergent magnetic field to a convergent magnetic field, combined with the upstream shift of the ionization region, contributes to the improving the operation of the Hall thruster.

Properties of the ionization region in a magnetron plasma at gas-aggregation-source-relevant pressure regime explored using a global model

A global (volume averaged) model is developed for the ionization region (IR) of a gas aggregation source (GAS) plasma. The case of using argon gas and a copper target is considered. The model describes the densities of thermal and hot electrons, argon and copper ions, copper atoms and argon atoms in different excited states, the temperature of thermal electrons, the kinetic energies of the ions with which they bombard the target, the sheath width near the target cathode and the energy fluxes by different plasma species to a planar probe in the IR. Also, the fraction of input power is estimated which is dissipated to energize the thermal electrons in the IR. The gas discharge properties are analyzed for different pressures and discharge currents under conditions corresponding to the experimental conditions (Gauter et al 2018 J. Appl. Phys. 124 073301). The calculated pressure- and current-dependences for the GAS properties are used to explain the measured dependences for the deposition rate and the energy flux. It is found that the deposition rate increases with increasing discharge current because of the growth of currents of copper atoms and ions. With increasing pressure, the rate decreases due to drop of the densities of copper atoms and ions because of decreasing the kinetic energies of the ions with which they bombard the target. The model indicates that in the gas-aggregation-source relevant pressure regime, the energy flux by ions dominates over the energy fluxes of other plasma species.

Argon admixture-driven enhanced ionization and performance of a 5 kW Hall thruster on krypton

Utilizing alternative propellants has been recognized as a strategy to reduce the total cost of propellants in electric propulsion-based missions. The aim of this study is to quantify the Hall effect thruster (HET) performance and operating characteristics using a Kr–Ar mixture to enable mission designers to evaluate the impact on mission and spacecraft design. We present the performance and plume plasma properties of the P5 5 kW-class HET operated with a Kr–Ar mixture with Ar volumetric flow rate fractions from 0 to 100%. The thruster is characterized at discharge power levels of 2.6 kW and 4.1 kW at constant discharge current and voltage over the range of Ar fractions. Despite higher ionization energy and lower mass of Ar, the thruster exhibited a similar level of thrust within 2% when comparing the pure Kr and 26%-Ar mixture cases. The derived ion energy distribution functions and analytical modeling suggest that the characteristic length for the ionization region is extended as the Ar fraction increases. The increased residence time of Kr at the extended ionization region and background energetic electrons from the ionized Ar neutrals are considered to cause this enhanced ionization of the injected Kr neutrals. This leads to a 6% higher Kr ion density at the 26%-Ar case even at the 16% less injected Kr neutral density than in the pure Kr case. The enhanced Kr ionization and generated Ar ions in the 26%-Ar case consequently led to a comparable thrust with that of the pure Kr case. The study indicates that mixing Ar with approximately 26% volumetrically with Kr can provide a similar or even higher thrust performance at the same discharge power. This will be particularly advantageous for various space missions that require high impulses by reducing the total cost of the propellant.

Scale-invariant breathing oscillations and transition of the electron energization mechanism in magnetized discharges

Scale-invariant breathing oscillations are observed in similar magnetized discharges at different spatiotemporal scales via fully kinetic particle-in-cell simulations. With an increase in the similarity invariant B/p, i.e., the ratio of magnetic field to pressure, breathing oscillations are triggered, leading to an appreciable time-averaged potential fall outside the sheath. With the onset and development of breathing oscillations, the electron energization mechanism shifts from sheath energization to direct Ohmic heating in the ionization region due to the change in the potential fall inside and outside the cathode sheath. Based on the scale invariance of the Boltzmann equation and its collision term, the characteristics of breathing oscillations and the transition of the electron energization mechanism are confirmed to be scale-invariant under similar discharge conditions.

Two-dimensional nonlinear spectroscopy in the extreme ultraviolet to study dynamics of atomic and molecular gases

We present a two-dimensional (2D) nonlinear four-wave mixing scheme in the extreme ultraviolet (XUV) to investigate ultrafast electronic wave-packets dynamics of multi-electron states in the above-threshold ionization region, using atomic argon and molecular nitrogen as examples. Coherent light sources in the range between 24 and 45 eV is generated by phase-matched cascaded four-wave mixing processes with a collinear configuration of laser fields 800 nm and 1400 nm. Motion of the electrons involving the excited states 3s3p6np (1P10) of argon gas, theF2Σg+ state and the predissociation state C2Σu+ of molecular nitrogen ion N2+ are unravelled through the ‘on-axis’ and ‘off-axis’ features of the two-dimensional spectra. Interpretation of the experimental data is supported by a theoretical dipole control model. Hence, results of this study may be promising for studies of dynamics of electrons in more complex systems.

Spatial structures of different particles in helicon plasma

The spatial density structures of different particles (high-energy electron excited ionic and low-energy electron excited neutral particles) in both discharge and plume plasmas of a helicon source were characterized by an optical emission spectroscope (OES) and a Langmuir probe. Filters of 480 nm band pass and 600 nm high pass were used to distinguish the ionic and the excited neutral particles, respectively. The ion energy distributions at the outlet of the discharge tube with different magnetic field were obtained by a four-grid retarding field energy analyzer (RFEA). Results show that as RF input power increased, the helicon discharge modes change from a capacitive (E mode) to an inductive (H mode) to a wave coupling or a helicon discharge (W mode). After reaching the W mode, neutral particles are basically saturated, but ions will experience another growth as the power increases. Moreover, the reversed applied magnetic field can change the axial distribution of ion density (ionization region). The IEDF test results show that the maximum (most probable) ion energy increases with increasing input power. Meanwhile, the reversed magnetic field (+ 50 A) can increase the maximum ion energy by about 15 eV, which is believed to be the ionization/acceleration zone is close to the ion energy test point. Therefore, the directed ion energy is more correlated with the ion density distribution excited by high-energy electrons.

Effective mass function of radio meteoroids as a modulating factor in determining atmospheric scale height

Abstract A long-standing problem in meteor science has been the persistent presence of bias in the measured value of atmospheric scale heights obtained from radio meteor echoes. A common practice of fitting a linear function for bias correction follows the assumption that the systematic bias is devoid of seasonal asymmetry. This would be true if the mass and the velocity distribution of meteoroids remain invariant, both spatially and temporally. But so far no such convincing evidence has been published. On the contrary, fundamental arguments suggest that an universal mass function of radio meteoroids is counter-intuitive. This parameter cannot remain invariant due to the intrinsic variability in the meteor response function resulting from the Earth’s motion on the plane of ecliptic. In this paper, we show that an inverse relation exists between the width of meteor height distribution, expressed in unit of atmospheric scale height, and the exponent of the mass function. The overall mean of this exponent for the Sodankylä radar is 1.91 ± 0.02, modulated by a seasonal variation from the mean of the order of ∼±0.1. The stated inverse relation is applied to correct for the effect of mass distribution on the height distribution. Allowing for variable mass correction effectively removes the nonlinear bias in the measured scale heights in the meteor ionisation region.

Characteristics of a pre-combustion plasma jet igniter

Plasma ignition technology has delivered good performance in the aerospace industry. In this study, a pre-combustion plasma jet igniter was designed, and its characteristics were examined from three aspects: the morphology, temperature, and discharge characteristics and process of ignition. Images of the OH distribution were obtained by using an OH Planar Laser⁃Induced Fluorescence (OH-PLIF) experimental system. Results have shown that the proposed plasma jet had a higher OH concentration, longer length, and larger area than those of a traditional igniter. The stability of discharge of the igniter was improved as the equivalence ratio φ was increased, and reducing gas flow reduced the pulsation of the plasma jet. When the input current was increased from 15 A to 35 A, the highest average temperature increased from 5127 K to 7987 K. An increase in the equivalence ratio reduced the region of arc ionization, but expanded the regions of the core combustion reaction and the outer flame. Herein, this study has obtained a deep understanding of the jet and ignition law and developed a new idea for the application of plasma in the ignition field. A pre-combustion plasma jet igniter can significantly improve the efficiency of ignition and shorten the ignition process compared with a traditional igniter.