Refractory Mantle Source Research Articles

The mafic–ultramafic roots of a Mesoarchean microblock in southern India: Insights from petrochemistry and isotope geochronology of the Coorg Block

The Coorg Block in southern India is an archive of Paleo-Mesoarchean arc magmatism and continental building in the early Earth. Here we investigate a suite of mafic and ultramafic rocks and associated lithologies to characterize the roots of this microcontinent. We present petrologic, geochemical, as well as U-Pb and Lu-Hf data on zircon and U-Pb data on monazite from these rocks which provide insights into the petrogenesis of the rocks as well as the timings of magmatism and subsequent metamorphism. The geochemical features of the mafic granulites indicate that the rock suite was derived from the fractionation of a sub-alkaline tholeiite magma. Most of the rocks correspond to arc setting in a subduction-related tectonic regime. The rocks exhibit relative enrichment in LILE, Pb, and LREE with depletion in HFSE such as Nb and Ta suggesting partial melting of a metasomatized mantle wedge. Their high LILE/HFSE and LREE/HFSE ratios indicate slab dehydration and mantle wedge melting in typical island arc settings. The overall trace element and REE patterns of the rocks indicate that the source magma of the ultramafic and mafic rocks might have been derived from a refractory mantle source followed by the metasomatic enrichment of lithospheric mantle wedge by incompatible elements through the influx of subduction-derived fluids/melts. We present comprehensive zircon U-Pb data and Lu-Hf data on a suite of mafic granulite, garnet-bearing granulite, tremolite actinolite schist, charnockite, and anorthositic gabbro as well as monazite U-Pb data from a charnockite sample. Most zircon grains show cores with magmatic crystallization features and many grains are mantled by metamorphic rims. The age data show a prominent peak at 3.1 Ga for most of the rocks suggesting that the major crustal building in the Coorg Block occurred during the Mesoarchean. Rocks on the margins of the block were affected by the younger (Neoarchean) tectonothermal event in the surrounding blocks. The Lu-Hf isotopic data on zircon grains with ca. 3.1 Ga ages show εHf(t) values ranging from −4.4 to + 3.7 (average + 0.3). In the εHf(t) versus 207Pb/206Pb age diagram, the plots are distributed close to the CHUR line suggesting Paleo-Eoarchean juvenile magma sources. The voluminous mafic lower crust at the root of the Coorg Block is consistent with addition of mafic magmas through slab melting induced by high mantle potential temperatures in the Archean, as well as the interaction of fluids/melts with the mantle wedge.

Chemostratigraphy of the extrusive sequence of a Late Cretaceous Neotethyan ophiolite in southern Iran and its significance for the mode and tempo of subduction initiation magmatism and melt evolution in forearc tectonic settings

Chemostratigraphy of lavas in extrusive sequences of modern and ancient forearc environments provides significant information on oceanic crust formation through progressive stages of melt evolution from subduction initiation magmatism (SIM) to arc infancy, and arc maturation-related magmatism. We present here new trace element and radiogenic Sr–Nd–Pb isotopic data from a Late Cretaceous ophiolite in the Outer Zagros Belt of southern Iran and discuss its magmatic development through SIM in a Neotethyan forearc setting. Initial volcanism produced the stratigraphically oldest boninitic (BON) lavas in the Haji-Abad ophiolite whose trace element ratios as well as Pb isotopic signatures indicate a refractory mantle source, which was contaminated by subducting slab-derived fluids. The BON lavas change structurally upwards into island-arc tholeiitic (IAT) lavas and their fractionated felsic derivatives that display isotopic evidence for the contribution of sediment-derived melts in their magmatic source(s). This melt evolution pattern of the Haji-Abad ophiolite marks a major difference from the progressive melt evolution trends reported from the Izu–Bonin–Mariana (IBM) forearc lava sequence, which starts at the bottom with forearc basalts (FAB) phasing up-section into BON and IAT affinity lavas. IAT lavas in the IBM are in turn overlain by calc-alkaline (CAL) lavas. Our geochemical modelling points to a probable existence of a less depleted, pre-subduction mantle whose partial melting probably generated primary magmas before the eruption of boninitic lavas, although the record of such magmas is missing in the Haji-Abad ophiolite. Our comparison of the chemostratigraphy of the Outer Zagros ophiolites with the documented record of subduction initiation generated volcanic rocks in the other Neotethyan ophiolites in the region and the IBM forearc setting strongly suggests that there is no single rule or template for SIM. Supplementary material: Details of analytical procedures and supplementary figures and tables are available at https://doi.org/10.6084/m9.figshare.c.6837597 Thematic collection: This article is part of the Ophiolites, melanges and blueschists collection available at: https://www.lyellcollection.org/topic/collections/ophiolites-melanges-and-blueschists

Origin and evolution of Neoproterozoic metaophiolitic mantle rocks from the eastern Desert of Egypt: Implications for tectonic and metamorphic events in the Arabian-Nubian Shield

The mantle rocks from Kadaboura and Madara areas represent sections of dismembered ophiolitic complexes developed during the Neoproterozoic in the Eastern Desert of Egypt, which is located in the northwestern corner of the Arabian–Nubian Shield. The Kadaboura mantle rocks comprise serpentinites and serpentinized dunites, whereas those of the Madara consist of serpentinites and serpentinized pyroxenites.Despite the serpentinization of the studied mantle rocks, few relicts of primary chromite, olivine and pyroxene are preserved. Chromite is partly altered having unaltered Al-rich chromite cores surrounded by Fe-rich chromite and Cr-rich magnetite rims. The unaltered Al-rich chromite cores show compositions equilibrated at temperatures mostly below ~500-600°C, which is a temperature comparable to that estimated for primary chromite in greenschist up to lower amphibolite facies rocks. The high Cr# [100×Cr/(Cr+Al)= 47-76] of the unaltered chromite cores and the Mg-rich nature of the olivine relicts (Fo91–94) indicate that the studied mantle rocks were produced from a highly depleted mantle that experienced high degrees of melt extraction (mostly ~30-40%). This range of melt extraction resembles that estimated for supra-subduction zone peridotites, but higher than that in abyssal and passive margin peridotites. Furthermore, the clinopyroxene relicts show compositions comparable to those from the Mariana forearc peridotites. Bulk-rock geochemistry also reflects derivation from an extremely depleted and a highly refractory mantle source. Modelling of rare-earth elements suggests that the studied mantle rocks were possibly formed by the interaction of their highly depleted harzburgitic mantle precursors with subduction-related melts/fluids during their evolution in a fore-arc basin of the supra-subduction zone.The proposed geodynamic model suggests that the oceanic lithosphere generated during the seafloor spreading of the Mozambique Ocean was emplaced in the upper plate of the intra-oceanic subduction zone, in which the formely depleted Neoproterozoic mantle of the Arabian-Nubian Shield experienced mature phases of hydrous melting, extreme depletion and enrichment.

Heavy magnesium isotopic compositions of basalts erupted during arc inception: Implications for the mantle source underlying the nascent Izu-Bonin-Mariana arc

Basalts formed during the early development of an arc are usually buried, but they record critical information relating to the mantle source of the overriding plate prior to the addition of subducting slab components. Basalts recovered at Site U1438 of International Ocean Discovery Program (IODP) Expedition 351, in the Amami Sankaku Basin (ASB), formed during the transition from forearc basalt (FAB) and boninite eruptions to stratovolcano developments in the Izu-Bonin-Mariana (IBM) arc. In this study, we present magnesium (Mg) isotopic data (δ26Mg) for the ASB basalt core samples, formed at arc inception in the absence of down-going slab components, and report the implications of these data for the characteristics of the mantle sources underlying the proto-IBM arc. The δ26Mg values of the ASB basalts range from −0.21‰ to +0.08‰, with an average value of −0.13 ± 0.07‰. These values are systematically higher than those of mid-ocean ridge basalts (MORBs) (−0.25 ± 0.06‰). No obvious effects of post-eruptive alteration, fractional crystallization, partial melting, or subduction component addition can be identified in the Mg isotopic compositions either of the ASB basalts or their mantle source, given the absence of correlations between the δ26Mg values and the proxies of these processes (e.g., K/Nb, Nb/Zr, Ba/La, Nb/Y, etc.). We conclude that the high δ26Mg values of the ASB basalts are inherited from their mantle source that was enriched in heavy Mg isotopes. Melting of an ultra-depleted, refractory spinel peridotite source containing talc-bearing serpentinite components can explain the origin of the heavy Mg isotopic compositions in the ASB basalts. The presence of water-rich serpentinite components in the mantle provides a new perspective on how a refractory mantle source can undergo partial melting at temperatures and pressures similar to the formation of MORBs without the influence of subducted materials, which has important implications for the initiation of plate subduction. Furthermore, the Mg isotopic contributions of subducted additions and mantle source materials should be carefully discussed in future studies due to the heterogeneity of Mg isotopes in the mantle.

Geochemistry of mafic-ultramafic rocks of the 3.33 Ga Kromberg type-section, Barberton greenstone belt, South Africa: Implications for early Earth geodynamic processes

In conjunction with major, trace and rare earth element data, this study presents the first whole-rock LuHf isotope analyses of mafic-ultramafic rocks of the c. 3.3 Ga Kromberg type-section in the Barberton greenstone belt of South Africa. Three compositionally distinct volcanic rock types are identified namely Group 1 metabasalts, Group 2 metabasalts and komatiitic metabasalts. Group 1 metabasalts are FeMg tholeiitic with compositions that plot close to the Primitive Mantle composition, have isochron intercept εHf(t) value of 0.01 ± 0.4 and Eoarchean Hf model ages. Group 2 metabasalts have very high Al2O3/TiO2 ratios (c. 50), small negative Nb anomalies, LREE-depleted slightly concave up REE patterns, and negative εHf(t) values. The komatiitic basalts variably record small negative Nb anomalies in a primitive mantle normalized plot. Group 1 metabasalts and cumulate peridotites (wehrlites) yield a LuHf isochron age of 3.340 ± 0.190 Ga (95% confidence level). The highly variable major and trace element geochemistry of the rocks in the sequence implies highly dynamic and variable mantle melting environments. The Group 2 metabasalts have geochemical characteristics similar to that of boninites and are interpreted to have formed from a shallow, refractory mantle source. Group 2 metabasalts are argued to have formed in a proto-plate tectonic back-arc basin involving crustal contamination, whereas Group 1 metabasalts likely formed from within a deep mantle plume.

Reconstructing the Crustal Section of the Intra‐Oceanic Caribbean Island Arc: Constraints From the Cumulate Layered Gabbronorites and Pyroxenites of the Rio Boba Plutonic Sequence, Northern Dominican Republic

AbstractLocated in northern Dominican Republic, the Early Cretaceous Rio Boba mafic‐ultramafic plutonic sequence constitutes a lower crust section of the Caribbean island arc, made up by gabbroic rocks and subordinate pyroxenite. Modal compositions, mineral chemistry, whole‐rock compositions and thermobarometric calculations indicate that pyroxenites and gabbronorites represent a cumulate sequence formed by fractionation of tholeiitic magmas with initially very low H2O content in the lower crust of the arc (0.6–0.8 GPa). Melts evolved along a simplified crystallization sequence of olivine → pyroxenes → plagioclase → Fe‐Ti oxides. The magmatic evolution of the Rio Boba sequence and associated supra‐crustal Puerca Gorda metavolcanic rocks is multi‐stage and involves the generation of magmas from melting of different sources in a supra‐subduction zone setting. The first stage included the formation of a highly depleted substrate as result of decompressional melting of a refractory mantle source, represented by a cumulate sequence of LREE‐depleted island arc tholeiitic (IAT) and boninitic gabbronorites and pyroxenites. The second stage involved volumetrically subordinate cumulate troctolites and gabbros, which are not penetratively deformed. The mantle source was refractory and enriched by a LILE‐rich hydrous fluid derived from a subducting slab and/or overlying sediments, and possibly by a LREE‐rich melt. The third stage is recorded in the upper crust of the arc by the Puerca Gorda “normal” IAT protoliths, which are derived from an N‐MORB mantle source enriched with a strong subduction component. This magmatic evolution has implications for unraveling the processes responsible for subduction initiation and subsequent building of the Caribbean island arc.

The Central-Sudetic ophiolites – Remnants of the SSZ-type Devonian oceanic lithosphere in the European part of the Variscan Orogen

The Variscan Central-Sudetic Ophiolites (CSO) are located in the Sudetes,the NE segment of the Bohemian Massif. The Devonian CSO display highly depleted, harzburgite mantle sections containing gabbroic dykes and local occurrences of mostly isotropic, large gabbroic bodies as well as volcanic rocks. The ultramafic rocks locally show melt percolation-derived clinopyroxene-olivine aggregates and chromitites. The low REE composition and depletion in LREE relative to HREE of the clinopyroxene as well as the chromite Cr# and Mg# values are typical for phases formed from refractory melts occurring in the supra-subduction zone environment. The gabbroic bodies consist of differently evolved, mostly cumulate rocks, while the volcanic rocks form a relatively monotonous basalt sequence. The trace element compositions of both the plutonic and volcanic rocks display depleted N-MORB affinities, their derivation from a refractory mantle source is further reflected by previously published depleted mantle-like Sr-Nd isotopic compositions. The ultramafic and mafic members of the CSO show greenschist- to lower amphibolite-facies metamorphic overprints.The occurrence ofdepleted harzburgites and isotropic gabbros forming the mantle and the crustal sections of the CSO, respectively, indicate intermediate- to slow-spreading conditions and aheterogeneous structureof the oceanic lithosphere, untypical for layered ophiolites. The geochemical characteristics of the melt-percolation phases of the ultramafic rocks, the bulk-rock compositions of the mafic rocks and the homogeneous volcanic sequences suggest a formation of the CSO in a mature back-arc basin setting, lacking subduction-derived contamination. Spreading rate conditions and geochemical affinities of the CSO are similar to those of other Devonian ophiolites localized along the Variscan Belt, for instance the Upper Ophiolitic Units in the NW Iberian Massif (Spain), thereby confirming the general absence of N-MORB type lithosphere in the European Variscan Orogen.

Copper recycling and redox evolution through progressive stages of oceanic subduction: Insights from the Izu-Bonin-Mariana forearc

Addition of subducted materials from the slab to the mantle wedge is often thought to elevate the oxygen fugacity of arc magmas and also to fertilize the mantle wedge in metals for subduction-related Cu-Au deposits. However, it remains controversial if slab-driven metal addition is effective and whether it occurs at all stages of subduction. The Izu-Bonin-Mariana (IBM) forearc preserves a full record of arc development from the initiation of subduction of the Pacific plate to mature arc volcanism. Here, we study the ore-forming and redox-sensitive metal Cu and its isotopes (δ65Cu) in the type-locality forearc basalts (FABs), boninites and high-Mg andesites from the IBM forearc, as well as MORBs from the East Pacific rise. Overall, the FABs display variably high Cu contents and MORB-like δ65Cu, consistent with limited Cu isotopic fractionation during partial melting of typical MORB mantle sources. Beginning with the boninites, the magma products from the IBM record strong slab signals, high water contents and high fO2 (ΔFMQ > +1). However, the oxidized, hydrous boninites and subsequent high-Mg andesites display low Cu contents, and mantle-like Cu/Sc ratios and δ65Cu, with no clear indication of the addition of Cu from the slab. The boninites show noticeably lower TiO2, Yb and Cu contents than the FABs, consistent with refractory mantle sources. Combined with available data from boninites and arc basalts worldwide, our results lead to a general conclusion that subducted oceanic slabs from initial to mature subduction contribute little Cu to the mantle wedge. This is further supported by the compiled Cu contents of arc peridotites. Adding Cu-poor, water-rich slab melts to the mantle wedge at any stage of Pacific oceanic subduction causes limited release of Cu, which remains trapped predominantly by reduced sulfides in the subducting slab. This likely reflects the overall reducing nature of slab materials added to the mantle wedge. However, we propose that the subsequent reaction of such reducing, hydrous slab melts with peridotites and flux melting produce oxidized primitive arc magmas deep in the mantle wedge. The reactive process promotes sulfide dissolution and metal release from the mantle wedge itself to oxidized arc magmas with high sulfur solubility, which explains the inheritance of mantle-like δ65Cu and the sulfide-undersaturated early-stage evolution in boninites and arc basalts. This study elucidates the role of subducted oceanic slabs in metal transfer and redox evolution and implies no significant Cu enrichment in the metasomatized mantle sources of magmatic arcs.

The Ca isotope composition of mare basalts as a probe into the heterogeneous lunar mantle

The Ca isotope compositions of mare basalts offer a novel insight into the heterogeneous nature of the lunar mantle. We present new high-precision Ca isotope data for a suite of low-Ti and high-Ti mare basalts obtained using our collision cell MC-ICP-MS/MS instrument, Proteus. Mare basalts were found to have a Ca isotope composition resembling terrestrial basalts (δ44/40CaSRM 915a =0.78–0.89‰) even though they are derived from a differentiated, refractory cumulate mantle source. Modelling of Ca isotope fractionation during crystallisation of a lunar magma ocean (LMO) indicates that the dominantly harzburgitic cumulates of the lunar interior should be isotopically heavier than Earth's mantle (δ44/40CaSRM 915a =1.1–1.2‰ versus 0.93‰, respectively). These are balanced by an isotopically light lunar anorthosite crust, consistent with data for lunar anorthosite and feldspathic breccia meteorites.We investigate the major element and Ca isotope composition of partial melts of various cumulate reservoirs by combining pMELTS models with equilibrium isotope fractionation mass balance calculations. The principal finding is that harzburgite cumulates alone are too refractory a source to produce low-Ti magmas. Partial melts of harzburgite cumulates have too low CaO contents, too high Al2O3/CaO and too high δ44/40CaSRM 915a to resemble low-Ti magmas. From Ca isotope constraints, we find that the addition of 10–15% of late-stage, clinopyroxenite cumulates crystallising at 95% LMO solidification is required to produce a suitable source that can generate low-Ti basalt compositions. Despite the addition of such late-stage cumulates pMELTS finds that these hybrid sources are undersaturated in clinopyroxene and are thus consistent with experimental constraints that the mantle sources of the lunar magmas are clinopyroxene-free. High-Ti basalts have slightly lower δ44/40CaSRM 915a (0.80–0.86‰) than low-Ti magmas (0.85–0.89‰) and clearly elevated TiO2/CaO. No suitable hybrid source involving ilmenite-bearing cumulates (IBC) was found that could reproduce melts with appropriate δ44/40Ca and major element systematics. Instead, we suggest that metasomatism of low-Ti mantle sources by IBC melts is the most plausible way to generate high-Ti magma sources and the rich diversity in TiO2 contents of lunar basalts and pyroclastic glasses.

Basalt derived from highly refractory mantle sources during early Izu-Bonin-Mariana arc development

The magmatic character of early subduction zone and arc development is unlike mature systems. Low-Ti-K tholeiitic basalts and boninites dominate the early Izu-Bonin-Mariana (IBM) system. Basalts recovered from the Amami Sankaku Basin (ASB), underlying and located west of the IBM’s oldest remnant arc, erupted at ~49 Ma. This was 3 million years after subduction inception (51-52 Ma) represented by forearc basalt (FAB), at the tipping point between FAB-boninite and typical arc magmatism. We show ASB basalts are low-Ti-K, aluminous spinel-bearing tholeiites, distinct compared to mid-ocean ridge (MOR), backarc basin, island arc or ocean island basalts. Their upper mantle source was hot, reduced, refractory peridotite, indicating prior melt extraction. ASB basalts transferred rapidly from pressures (~0.7-2 GPa) at the plagioclase-spinel peridotite facies boundary to the surface. Vestiges of a polybaric-polythermal mineralogy are preserved in this basalt, and were not obliterated during persistent recharge-mix-tap-fractionate regimes typical of MOR or mature arcs.

New Caledonia Ophiolite, Marginal Rifting to Fore‐arc Evolution

AbstractThe New Caledonia Ophiolite (Peridotite Nappe), represents about one third of the island's surface (i.e. 5 500 km2). The ophiolite is composed of harzburgites, dunites, lherzolites, minor mafic‐ultramafic cumulates, and various dykes and sills. The mantle section underwent a polyphase evolution, which involved prominent depletion and re‐fertilization.The oldest events are probably recorded by abyssal‐type lherzolites of the northern massifs, which bear traces of moderate partial melting. Plagioclase lherzolites were formed by shallow entrapment of highly depleted MORB melt in residual spinel lherzolites. Nd isotope compositions are consistent with derivation from an asthenospheric mantle source that experienced a recent MORB‐producing depletion. This evolution was most likely accomplished during the late Cretaceous breakup of the eastern Australian margin.The harzburgite‐dunite association, which forms the bulk of Peridotite Nappe was probably formed through a multistage magma‐producing process. Harzburgites composition may have be obtained by a first phase of ∼15% dry fractional melting, followed by 15%–18% hydrous melting in a supra‐subduction zone setting. Variable ∊Nd negatively correlate with 87Sr/86Sr, while Pb isotopes cover a wide range, trending from depleted mantle towards enriched, sediment‐like, compositions. Such signatures likely reflect the evolution of a highly depleted fore‐arc mantle wedge variably modified by different fluid and melt inputs during Eocene subduction.The harzburgite‐dunite set is overlain by a dunite transition zone ∼300m thick, in turn discontinuously covered by cumulate lenses consisting of layered pyroxenites, dunites, and wherlites at the base and gabbronorites/websterites on top. The mafic cumulates crystallized from primitive, ultra‐depleted melts in the nascent lower fore‐arc crust. In particular, FME enrichments and Nd‐Pb isotopes support an origin from a refractory mantle source modified by slab fluids for the gabbronorite‐forming melts.The Peridotite Nappe has been extensively serpentinized (40% to 100%) with extremely scarce occurrences of unserpentinized rocks. Lizardite, brucite, magnetite and minor chrysotile developed from joints and intra‐granular cooling cracks in a near‐static environment. Serpentine‐coated joints and peridotite foliation have been thereafter reopened and injected by various felsic, mafic and ultramafic supra‐subduction melts emplaced within a narrow time interval (55–50 Ma), immediately after subduction inception at 56 Ma, i.e. the age of granulite‐facies metamorphic sole. The youngest magmatic event is represented by island‐arc tholeiite dykes dated at 50 Ma.A widespread set of antigorite and tremolite‐bearing veins crosscut all previous structures in a progressively cooling fore‐arc environment. The former are synkinematic crack seals, which display highly radiogenic, sediment‐like 87Sr/86Sr ratios suggesting direct derivation of fluids from the subduction zone, while the latter bear mantle‐like isotopic signatures and probably originated from the interaction of wall rocks with Ca‐rich fluids released by Eocene dykes or fluids that leached them.Finally, continental subduction and obduction occurred during the 44–34 Ma interval and were accompanied by the development of the HP‐LT metamorphic belt of northern New Caledonia, which constrains the polarity of subduction.

Geochemistry of Early Paleozoic boninites from the Central Qilian block, Northwest China: Constraints on petrogenesis and back-arc basin development

Early Paleozoic boninites occur in the Central Qilian orogenic belt, Northwest China. Their petrogenesis provides insights into lithosphere process and tectonic evolution of the Qilian block. In this paper, we carry out a study of geochronological, geochemical and Sr-Nd isotopic compositions for the Early Paleozoic boninites in the Lajishan area of the Central Qilian block. The Lajishan boninites (∼483 Ma) have high Al2O3/TiO2 (36.7–64.7) and CaO/TiO2 (31.1–49.6) ratios, and high MgO (7.86–10.47 wt%), Cr (439–599 ppm) and Ni (104–130 ppm) contents, indicating that the boninites result from a refractory mantle source. They are depleted in high field-strength elements (HFSE) and enriched in large ion lithophile elements (LILE), coupled with slightly high initial 87Sr/86Sr values of 0.7059–0.7074 and low εNd(t) values of −1.05 to +2.66, indicating that the mantle source was metasomatized by subducted slab-derived components. We found that an assemblage of low-Ca group and high-Ca group boninites occurred in the Lajishan belt. The high-Ca group boninites were derived from relatively fertile mantle with slightly higher melting degree, whereas the low-Ca group boninites were generated by partial melting of more refractory mantle wedge peridotites with slightly lower melting degree. The assemblage of low-Ca group and high-Ca group boninites reveals that the low-Ca group boninites were generated by the further melting of the more refractory mantle source after the segregation of the high-Ca group boninitic magmas in response to the back-arc basin opening. In the light of reported boninites worldwide, a diagram of Zr/Y vs. CaO/Al2O3 is used to identify boninites in fore-arc and back-arc regions. We suggest that the Lajishan boninites represent the products of back-arc basin development in response to the northward subduction of the Qaidam-West Qinling ocean slab.

Incipient boninitic arc crust built on denudated mantle: the Khantaishir ophiolite (western Mongolia)

The ~ 570 Ma old Khantaishir ophiolite is built by up to 4 km harzburgitic mantle with abundant pyroxenites and dunites followed by ~ 2 km of hornblende-gabbros and gabbronorites and by a ~ 2.5 km thick volcanic unit composed of a dyke + sill complex capped by pillow lavas and some volcanoclastics. The volcanics are mainly basaltic andesites and andesites (or boninites) with an average of 58.2 ± 1.0 wt% SiO2, X Mg = 0.61 ± 0.03 (X Mg = molar MgO/(MgO + FeOtot), TiO2 = 0.4 ± 0.1 wt% and CaO = 7.5 ± 0.6 wt% (errors as 2σ). Normalized trace element patterns show positive anomalies for Pb and Sr, a negative Nb-anomaly, large ion lithophile elements (LILE) concentrations between N- and E-MORB and distinctly depleted HREE. These characteristics indicate that the Khantaishir volcanics were derived from a refractory mantle source modified by a moderate slab-component, similar to boninites erupted along the Izu-Bonin-Mariana subduction system and to the Troodos and Betts Cove ophiolites. Most strikingly and despite almost complete outcrops over 260 km2, there is no remnant of any pre-existing MORB crust, suggesting that the magmatic suite of this ophiolite formed on completely denudated mantle, most likely upon subduction initiation. The architecture of this 4–5 km thick early arc crust resembles oceanic crust formed at mid ocean ridges, but lacks a sheeted dyke complex; volcanic edifices are not observed. Nevertheless, low melting pressures combined with moderate H2O-contents resulted in high-Si primitive melts, in abundant hornblende-gabbros and in a fast enrichment in bulk SiO2. Fractional crystallization modeling starting from the observed primitive melts (56.6 wt% SiO2) suggests that 25 wt% pyroxene + plagioclase fractionation is sufficient to form the average Khantaishir volcanic crust. Most of the fractionation happened in the mantle, the observed pyroxenite lenses and layers in and at the top of the harzburgites account for the required cumulate volumes. Finally, the multiply documented occurrence of highly depleted boninites during subduction initiation suggests a causal relationship of subduction initiation and highly depleted mantle. Possibly, a discontinuity between dense fertile and buoyant depleted mantle contributes to the sinking of the future dense subducting plate, while the buoyant depleted mantle of the future overriding plate forms the infant mantle wedge.

Geochemistry and geochronology of the Mesozoic Lanong ophiolitic mélange, northern Tibet: Implications for petrogenesis and tectonic evolution

The Lanong ophiolitic mélange is a typical ophiolitic mélange in the middle section of the Bangong–Nujiang suture zone in northern Tibet. It mainly consists of ultramafic and mafic rocks, and its tectonic setting and formation age remain poorly constrained. In this paper, new geochemical and LA–ICP–MS (laser ablation–inductively coupled plasma mass spectrometer) zircon U–Pb age data obtained from gabbro, gabbro–dolerite, dolerite and basalt of the Lanong ophiolitic mélange are provided. The pillow basalts exhibit N-MORB (normal mid-ocean ridge basalt)-like geochemical features with a zircon U–Pb age of 147.6±2.3Ma. They were generated by ~20–30% partial melting of a depleted mantle source composed of spinel lherzolite. The gabbro, massive basalt and gabbro–dolerite samples are characterised by more depleted and “V”-shaped REE (rare earth element) patterns, and they exhibit variable degrees of boninite-like geochemical characteristics, with a zircon U–Pb age of 149.1±1.2Ma (gabbro-dolerite). They were derived from the remelting of a significantly refractory mantle source following one or more episodes of previous basaltic melt extraction. Geochemical data of these mafic rocks indicate that they were developed in a continental fore-arc setting, and magmas were derived from depleted mantle sources modified by subducted slab-derived fluids and melts with minor crustal contamination. On the other hand, the dolerites show distinct OIB (oceanic island basalt)-like geochemical features, with a zircon U–Pb age of 244.1±3.0Ma. They were formed in a rift setting on a continental shelf-slope and originated from a low degree of partial melting of a depleted asthenospheric magma source mixed with some ancient sub-continental lithospheric mantle materials. The signatures presented here, combined with the results of previous studies, suggest that the Lanong ophiolitic mélange probably developed in a convergent plate margin under the southward subduction of the Bangong–Nujiang Tethys Ocean beneath the Lhasa terrane during the Middle Triassic–Early Cretaceous. Namely, the OIB-like dolerites likely reflect an extensional rift setting featuring thin continental crust in the Middle Triassic, and the gabbros, gabbro–dolerites and basalts represent a later stage of a fore-arc basin during the Late Jurassic–Early Cretaceous.

Using mineral geochemistry to decipher slab, mantle, and crustal input in the generation of high-Mg andesites and basaltic andesites from the northern Cascade Arc

To better understand the role of slab melt in the petrogenesis of North Cascades magmas, this study focuses on petrogenesis of high-Mg lavas from the two northernmost active volcanoes in Washington. High-Mg andesites (HMA) and basaltic andesites (HMBA) in the Cascade Arc have high Mg# [molar Mg/(Mg+Fe 2+ )] relative to their SiO 2 contents, elevated Nd/Yb, and are Ni- and Cr-enriched. The rock units examined here include the Tarn Plateau HMBA (51.8–54.0 wt% SiO 2 , Mg# 68–70) and Glacier Creek HMA (58.3–58.7 wt% SiO 2 , Mg# 63–64) from the Mount Baker Volcanic Field, and the Lightning Creek HMBA (54.8–54.6 SiO 2 , Mg# 69–73) from Glacier Peak. This study combines major and trace element compositions of minerals and whole rocks to test several petrogenetic hypotheses and to determine which, if any, are applicable to North Cascades HMA and HMBA. In the Tarn Plateau HMBA, rare earth element (REE) equilibrium liquids calculated from clinopyroxene compositions have high Nd/Yb that positively correlates with Mg#. This correlation suggests an origin similar to that proposed for Aleutian adakites, where intermediate, high Nd/Yb slab-derived melts interact with the overlying mantle to become Mg-rich, and subsequently mix with low Nd/Yb, mantle-derived mafic magmas with lower Mg#. In the Glacier Creek HMA, elevated whole-rock MgO and SiO 2 contents resulted from accumulation of xenocrystic olivine and differentiation processes, respectively, but the cause of high Nd/Yb is less clear. However, high whole-rock Sr/P (fluid mobile/fluid immobile) values indicate a mantle source that was fluxed by an enriched, hydrous slab component, likely producing the observed high Nd/Yb REE signature. The Lightning Creek HMBA is a hybridized rock unit with at least three identifiable magmatic components, but only one of which has HMA characteristics. Cr and Mg contents in Cr-spinel and olivine pairs in this HMA component suggest that its source is a strongly depleted mantle, and high whole-rock Sr/P values indicate mantle melting that was induced through hydration, likely adding the component responsible for the observed high Nd/Yb REE pattern. The elevated SiO 2 contents (54.6 wt%) of the HMA component resulted from differentiation or high degrees of partial melting of ultramafic material through the addition of H 2 O. Therefore the Lightning Creek HMBA is interpreted to have originated from a refractory mantle source that underwent melting through interaction with an enriched slab component. Our results indicate that in addition to slab-derived fluids, slab-derived melts also have an important role in the production of HMA and HMBA in the north Cascade Arc.

Petrogenesis and Geodynamic Evolution of the Paleoproterozoic (~1878 Ma) Trout Lake Volcanogenic Massive Sulfide Deposit, Flin Flon, Manitoba, Canada

The Trout Lake deposit (1878 ± 1 Ma) is a rhyolite-hosted, bimodal-mafic, volcanogenic massive sulfide (VMS) deposit. It is one of the largest VMS deposits in the Flin Flon mining district, containing 21.8 Mt of Cu-Zn rich ore. The deposit underwent greenschist facies metamorphism and polyphase synvolcanic to postvolcanic hydrothermal alteration. Footwall and hanging-wall lithostratigraphic units of the Trout Lake deposit occur as an upright, steeply NE dipping, homoclinal succession of thrust-repeated volcanic and siliciclastic sedimentary units. The deposit consists of several massive sulfide ore lenses hosted within a felsic volcanic unit that represents a localized felsic eruptive center composed of flows, synvolcanic sills, and volcaniclastic lithofacies with an FIIIb-type tholeiitic to transitional rhyolite composition (Zr = 213–385 ppm; Ybcn = 47–100; La/Ybcn = 0.97–2.33). The felsic unit occurs along strike of an andesitic unit comprising an intercalation of high-MgO andesite (MgO > 5.0 wt %) and Nb-enriched andesite (Nb = 10–13 ppm) flows that are underlain by a footwall basaltic unit composed of flow lithofacies with a low-Ti tholeiitic basaltic composition (TiO2 < 0.48 wt %; Zr = 15–17 ppm; Al2O3/TiO2 = 37–45). Postvolcanic gabbros with back-arc basin basalt composition intrude the volcanic units, which are unconformably covered by a younger argillite unit deposited at ca. <1843 ± 9 Ma. The felsic volcanic and argillite units were repeated and structurally interleaved during west-directed thrusting. The presence of low-Ti tholeiitic basalts indicates high-temperature melting (1,200°–1,500°C) of strongly depleted refractory mantle sources (Nb/Yb 1.45) variably affected by slab-derived hydrous melts. These petrologic characteristics suggest a geochemically heterogeneous mantle wedge that underwent metasomatism by slab-derived components. In addition, zircon saturation thermometry indicates that FIIIb-type rhyolites formed at temperatures >900°C during partial melting of mafic lower crust. Collectively, the occurrence of high-temperature melts indicates that the Trout Lake VMS deposit formed in a hot, intraoceanic, extensional-arc geodynamic setting. Intra-arc rifting, asthenospheric upwelling, and subduction of young and hot oceanic crust are mechanisms that explain the high-temperature magmatism and are features consistent with the formation of the massive sulfide ore lenses. The back-arc basalt geochemical signatures of the postvolcanic gabbros suggest that the tectonic environment of the Trout Lake area evolved from an intra-arc rift, during the deposition of the ore lenses, to an incipient back-arc basin during the intrusion of the gabbros.

Evidence from accreted seamounts for a depleted component in the early Galapagos plume

The existence of an intrinsic depleted component in mantle plumes has previously been proposed for several hotspots in the Pacific, Atlantic, and Indian Oceans. However, formation of these depleted basalts is often associated with unusual tectonomagmatic processes such as plume-ridge interaction or multistage melting at plume initiation, where depleted basalts could reflect entrainment and melting of depleted upper mantle. Late Cretaceous to middle Eocene seamounts that accreted in Costa Rica and are part of the early Galapagos hotspot track provide new insights into the occurrence and nature of intrinsic depleted components. The Paleocene (ca. 62 Ma) seamounts include unusually depleted basalts that erupted on the Farallon plate far from a mid-ocean ridge. These basalts closely resemble Gorgona komatiites in terms of trace element and radiogenic isotope composition, suggesting formation from a similar, refractory mantle source. We suggest that this source may be common to plumes, but is only rarely sampled due to excessive extents of melting required to extract melts from the most refractory parts of a heterogeneous mantle plume.

Strain localization and fluid infiltration in the mantle wedge during subduction initiation: Evidence from the base of the New Caledonia ophiolite

Despite decades of petrological and geochemical studies, the nature and setting of obducted ophiolites remain controversial: the influence of supra-subduction zone environments on pre-existing oceanic lithosphere is yet to assess, and the processes leading to subduction/obduction initiation are still poorly constrained. Our study documents successive influx of slab-derived fluids and progressive strain localization within the upper mantle in a supra-subduction environment during the first few My of the subduction history. We focus on strongly sheared mafic amphibolites intruding peridotites near the mantle–crust transition of the New Caledonia obducted ophiolite and ~50 to 100m above the basal thrust contact of the ophiolite. These m- to hm-long and several m-thick shear bands are interpreted as inherited small-scale intrusions of mafic melts, probably dikes or sills, which were derived from a moderately refractory mantle source refertilized by supra-subduction zone fluids. 40Ar/39Ar age constraints on pargasite at ca. 90Ma suggest that they could be inherited from the former Pacific west-dipping subduction.Secondary deformation of these mafic intrusions is intimately associated to three major stages of fluid infiltration: (1) the first stage of deformation and metasomatism is marked by syn-kinematic growth of Ca-amphibole (at 700–800°C and 3–5kbar) with a distinctive supra-subduction zone signature, and controlled later channelization of aqueous fluids. 40Ar/39Ar dating on magnesio-hornblende indicates that this deformation episode occurred at ca. 55Ma, coincident with east-dipping subduction initiation; (2) the main metasomatic stage, characterized by the development of a phlogopite-rich matrix wrapping peridotites and amphibolite boudins, points to the percolation of alkali-rich aqueous fluids at still high temperature (650–750°C); (3) the last, low temperature (<600°C) metasomatic stage results in the formation of deformed veinlets containing talc, chlorite and serpentine.

Boninitic metavolcanic rocks and island arc tholeiites from the Older Metamorphic Group (OMG) of Singhbhum Craton, eastern India: Geochemical evidence for Archean subduction processes

The metavolcanic rocks of the Paleo-Mesoarchean Older Metamorphic Group (OMG) from Jagannathpur area of the Singhbhum Craton occur as enclaves within the Singhbhum granites (SBG). The primary mineralogical composition of these rocks has been overprinted by plagioclase–chlorite–tremolite–actinolite assemblage reflecting lower to medium greenschist facies metamorphism. Disseminated sulphides and minor amount of chromite are present as opaque phases. Clinopyroxene compositions correspond to augite. Major, trace and rare earth element compositions of these rocks are characterized by high Mg# (80–82), MgO (30.6–32.9wt.%), Ni (490–1262ppm) and Cr (2404–4385ppm) contents, high Al2O3/TiO2 (49–67), Zr/Hf (10–100) ratios with low TiO2 (0.1–0.2wt.%), Zr (1.0–3.1ppm) contents, (La/Sm)N >1 and (Gd/Yb)N <1. These geochemical features in conjunction with distinct negative Nb, Ta, Zr, Hf and Ti anomalies on N-MORB normalized multi-element diagram, relative enrichment in LILE and La collectively attest to boninitic signatures and magma generation in an intraoceanic subduction zone setting. These boninites are associated with low Ti island arc tholeiites (IAT) that have geochemical characteristics inherited from subduction zone processs. Relative MREE depletion in the OMG boninites compared to LREE and HREE is reflected by their high ((La/Sm)N=0.7–6.7) and low (Gd/Yb)N=0.4–0.6) ratios. These REE signatures corroborate a multi-stage petrogenetic process involving a refractory mantle source that was previously depleted by melt extraction episodes and subsequently enriched by subduction-related slab-dehydration process. The LILE and LREE replenishment of the refractory mantle wedge is attributed to influx of slab-derived hydrous fluids that lowered the solidus temperature and triggered partial melting of mantle wedge at shallow level under hydrous conditions. A mantle domain of spinel peridotite composition has been inferred for partial melting and generation of magmas parental to OMG boninites and IAT. The PGE chemistry of the studied boninites and IAT, marked by higher Pd and Pd/Ir over lower Pt and Pt/Pd and S-undersaturated nature attest to fluid-fluxed metasomatism of mantle wedge and sulphide retention in the residual mantle due to high fluid pressure and high degree of mantle melting at shallow depth.

Petrogenesis of Mesoproterozoic lamproite dykes from the Garledinne (Banganapalle) cluster, south-western Cuddapah Basin, southern India

We report mineral chemistry and whole-rock major and trace-element geochemistry for a recent find of Mesoproterozoic (~1.4 Ga) lamproites from the Garledinne (Banganapalle) cluster, south-western part of the Paleo-Mesoproterozoic Cuddapah Basin, southern India. The Garledinne lamproites occur as WNW–ESE-trending dykes that have undergone varying degree of pervasive silicification and carbonate alteration. Nevertheless, their overall texture and relict mineralogy remain intact and provide important insights into the nature of their magmas. The lamproite dykes have porphyritic to weakly porphyritic textures comprising pseudomorphed olivine macrocrysts and microphenocrysts, titanian phlogopite microphenocrysts, spinel having a compositional range from chromite to rarely magnesiochromite, Sr-rich apatite and niobian rutile. The Garledinne and other Cuddapah Basin lamproites (Chelima and Zangamarajupalle) collectively lack sanidine, clinopyroxene, potassic richterite, and titanite and are thus mineralogically distinct from the nearby Mesoproterozoic lamproites (Krishna and Ramadugu) in the Eastern Dharwar Craton, southern India. The strong correlation between various major and trace elements coupled with high abundances of incompatible and compatible trace elements imply that alteration and crustal contamination have had a limited effect on the whole-rock geochemistry (apart from K2O and CaO) of the Garledinne lamproites and that olivine fractionation played an important role in their evolution. The Garledinne lamproites represent small-degree partial melts derived from a refractory (previously melt extracted) peridotitic mantle source that was subsequently metasomatised (enriched) by carbonate–rich fluids/melts within the garnet stability field. The involvement of multiple reservoirs (sub-continental lithospheric mantle and asthenosphere) has been inferred in their genesis. The emplacement of the Garledinne lamproites is linked to extensional events, across the various Indian cratons, related to the break-up of the Proterozoic supercontinent of Columbia.