The spark gap switch is a crucial component in the primary energy drive system for large pulse power devices. The switch electrodes are composed of high-density artificial graphite, possessing excellent erosion resistance. However, insufficient mechanical strength in the graphite electrodes makes them especially susceptible to mechanical damage under the enormous impact force caused by the increasing arc current, which seriously affects the reliability and service life of the switch. The distribution of the shock wave overpressure on the graphite electrode surface is deduced and calculated, and the refraction and reflection process of the shock wave from the air to the graphite interface is analyzed based on the Huygens–Fresnel principle. Furthermore, the doubling of refracted shock wave intensity into the graphite electrode is a preliminary characterization. The propagation process of stress wave after the shock wave enters the electrode is investigated by establishing two conventional graphite electrode structure models, namely T-shape and reverse T-shape, which reveal that severe stress concentration occurs in both structures. Drawing inspiration from the physiological structure of the woodpecker’s head, renowned for its exceptional impact resistance, the macroscopic geometry of the graphite electrode and the assembly structure of the switch have been bionically designed. The simulation results demonstrate that, in comparison to the conventional electrode structure, the bionic electrode structure eliminates stress concentration at the bolt end and electrode corner, while significantly reducing maximum equivalent stress and the degree of the stress concentration on the bottom surface of the electrode. These features contribute to the enhancement of the current capacity and reliability of the spark gap switch.