Reformulated Gasoline Research Articles

Customizing reformulated gasoline using biofuel-additives to replace aromatics

Understanding the thermophysical and dynamic characteristics of hydrocarbon blends is crucial for optimizing engine performance and emissions control. By investigating the properties of blends with diverse biomass-derived oxygenates (BDO) as green fuel additives, we aim to mitigate toxic aromatic compounds in both conventional and reformulated gasoline. Experimental verification of prior molecular dynamics (MD) simulation results on gasoline+alkyl levulinate blends establishes the validity of our gasoline model, establishing MD simulations as a powerful tool for investigating blend properties. Subsequent MD simulations estimate the density, viscosity, and compressibility of three gasoline formulations blended with four BDOs (butanol, dimethyl ether, methyl ethyl ketone, and methyl pentanoate). At the molecular level, these BDOs exhibit similar solvation environments in blends, except for butanol, which influences their dynamic properties. Methyl pentanoate and butanol emerge as potent candidates for green fuel integration in conventional gasoline, albeit with limited effectiveness in low-aromatic content fuel corresponding to aromatic mole fraction of 0-0.16. Introducing butyl levulinate significantly enhances valid compositions from 18% in binary blends to 70% in ternary blends, with 100% success in one of the reformulated gasoline formulations.

Production, fuel properties and combustion testing of an iso-olefins blendstock for modern vehicles

With the increasing pressure to decarbonize the transportation sector, exploring strategies that can reduce emissions from light-duty vehicles (LDV) has become critical. Bioblendstocks that allow for higher engine efficiency and fuel economy could complement vehicle electrification and help reach carbon neutrality by 2050. In this context, the potential of a mixture of iso-olefins as a bioblendstock was investigated for multimode boosted spark-ignition (SI)/advanced compression ignition (ACI) engine operation designed to achieve higher overall vehicle fuel economy. By establishing the relationship between the molecular structure of iso-olefins and research octane number (RON), octane sensitivity (S) (i.e., the difference between RON and motor octane number [MON]), and phi-sensitivity (i.e., the sensitivity of autoignition to the fuel-air equivalence ratio) a dimethyl-hexenes rich olefins mixture (DMHROM) was identified as a preferred blendstock for SI/ACI combustion engines. A pathway for DMHROM production from biomass-derived ethanol was developed and scaled up. More than 1 gallon of DMHROM blendstock was produced for fuel properties assessment including engine testing. Measurements in a Cooperative Fuel Research Engine showed that the DMHROM blendstock possesses a RON of 94 and S of 13.5, and blends synergistically. Rapid compression machine tests coupled with single-cylinder gasoline direct injection engine measurements demonstrated the 20 vol% DMHROM blend has higher phi-sensitivity than an olefin-free gasoline base fuel and a typical California Reformulated Gasoline Blendstock for Oxygenate Blending (CARBOB) gasoline fuel. These results demonstrate the potential of DMHROM for improving gasoline fuel performance and quality for operation under ACI conditions. The effectiveness of the aftertreatment system in mitigating emissions was verified and showed that the pure DMHROM blendstock and 20 vol% blend would not increase non-methane organic gases, NOx, or carbon monoxide (CO) emissions. The DMHROM blendstock was found to slightly decrease sooting tendency when added to a gasoline-base fuel (i.e., ∼6% reduction at 20 vol% blending level). Oxidation stability and lubricant compatibility were both confirmed for the 20 vol% blend. Overall, these results demonstrate that dimethyl-hexenes have potential for improving engine efficiency and fuel economy while meeting emissions regulations and ASTM specifications for gasoline fuel.

Investigation on spectral standardization among multi-channel of an on-line near-infrared spectrometer

To tackle the issue that the multivariate calibration model cannot be shared among channels due to the inter-channel spectral differences in the on-line multi-channel spectrometer, taking the determination of octane number (RON) and aromatic hydrocarbon content (AC) of multiple reformulated gasoline by on-line Fourier transform near-infrared (FT-NIR) spectrometer combined with partial least squares (PLS) as an example, a novel approach for spectral standardization by piecewise cosine spectra (cosSSM) is proposed in this paper. A total of 42 reformulated gasoline samples were collected and their RON and AC were determined using standard methods with their NIR absorption spectra being measured using the three channels of an on-line NIR spectrometer, respectively. To prove the effectiveness of cosSSM, the spectra of each channel were standardized using cosSSM, and the PLS models of RON and AC were established using the cosine spectra in one channel, then the predictions of the cosine spectra in the other channels were made. The results suggested that cosSSM effectively eliminated the adverse effect of inter-channel spectral variation on the applicability of the channel-specific PLS model, and the performance was comparable to that of the well-established piecewise direct standardization (PDS) method. Besides, cosSSM is relatively simple and easy-to-implement in practical application.

OPEC news and predictability of energy futures returns and volatility: evidence from a conditional quantile regression

Purpose This paper aims to provide an important perspective to the predictive capacity of Organization of the Petroleum Exporting Countries (OPEC) meeting dates and production announcements for energy futures (crude oil West Texas Intermediate (WTI), gasoline reformulated gasoline blendstock for oxygen blending (RBOB), Brent oil, London gas oil, natural gas and heating oil) market returns and volatilities. Design/methodology/approach To examine the impact of OPEC news on energy futures market returns and volatilities, the authors use a conditional quantile regression methodology during the period from April 01, 2013 to June 30, 2017. Findings From the empirical findings, the authors show a conditional dependence between energy futures returns and OPEC-based predictors; hence, the authors can find clear the significance of relationship in the process of financialization of the OPEC announcements and energy futures in the case of this paper. From the quantile-causality test, the authors find that the effect of OPEC news is important to energy futures. Specifically, OPEC announcements dates predict the quantiles of the conditional distribution of energy futures market returns. Originality/value The authors confirm the presence of unidirectional nexus between OPEC news and energy commodities futures in the long term.

Autoignition behavior of a full boiling-range gasoline: Observations in RCM and GCI engine environments

The understanding of, and capability to modulate fuel autoignition behavior are important aspects towards the development of advanced, low temperature combustion (LTC) engine concepts, which have potential to significantly increase engine efficiency while at the same time addressing emissions concerns. Proper combustion phasing and control of heat release rates via, for instance, multiple injections and exhaust gas recirculation, are significant challenges that can vary with fuel composition. Overall reactivity, which is a strong function of the in-cylinder temperature and pressure, is a prime driver for regulating combustion timing, while preliminary exothermicity, in the form of low- and intermediate-temperature heat release (LTHR, ITHR) can inhibit, or facilitate operational success, e.g., control combustion phasing. There are still gaps in understanding these features and how they interact with needs of advanced combustion engines, and how practical fuels can be rated for the new challenges of LTC engines.This work utilizes a rapid compression machine (RCM) and gasoline compression ignition (GCI) engine to probe the autoignition behavior of a California Reformulated Gasoline Blendstock for Oxygenate Blending (CARBOB) (RON = 86, MON = 81.4) under quasi- homogeneous charge compression ignition (qHCCI) operation. A wide range of thermodynamic conditions is explored (Tc = 700–1000 K, Pc = 15–90 bar) where ignition delay times and LTHR/ITHR are quantified. Both stoichiometric, dilute (11% O2) and lean (equivalence ratio (ϕ) = 0.23) fuel loading conditions are considered. The GCI engine is operated under fuel-lean conditions (ϕ = 0.23) using no external exhaust gas recirculation over a range of intake temperature (Tin = 30–70 °C), with the intake pressure adjusted (Pin = 1.2–1.3 bar) to achieve constant combustion phasing (CA50 = −4 °aTDC). Preliminary exothermicity is also quantified under these conditions.The stoichiometric, dilute RCM measurements reveal negative temperature coefficient (NTC) behavior for this fuel and indicate that rates and extents of LTHR and ITHR are both affected by the compressed conditions, with temperature imposing an inverse dependence, while increased pressure causes LTHR to increases, but ITHR to decrease. These are the first experimental quantifications of ITHR trends for a practical fuel under well-controlled, static conditions. When the lean RCM measurements are mapped to the in-cylinder conditions of the engine, it is found that under a constant combustion phasing scenario (as used in the engine), the fuel has little overall temperature sensitivity, while the starts of high temperature heat release (soHTHR) and top dead center (TDC) points seen along the engine compression trajectories correspond to isopleths of ignition delay times τRCM = 6 and 3 ms, respectively. In addition, the points of peak LTHR rate in the engine correspond to an isopleth of first-stage ignition τ1,RCM = 0.50–0.75 ms. Correlating the magnitudes of LTHR and ITHR measured in the RCM to the engine requires quantification of the preliminary exothermicity at the thermodynamic conditions of peat LTHR rate and soHTHR, respectively. The current measurements demonstrate how fundamental data from an RCM can be used to project expected trends in overall fuel reactivity to a qHCCI engine environment, and thus provide a possible avenue for characterizing fuels for LTC engines.

The effect of fuel composition and additive packages on deposit properties and homogeneous charge compression ignition combustion

Homogeneous charge compression ignition combustion is highly dependent on in-cylinder thermal conditions that are favorable to auto-ignition, and the presence of deposits can dramatically impact the in-cylinder environment. Because fuels available at the pump can differ considerably in composition, and fuel composition and the included additive package directly affect how deposits accumulate in a homogeneous charge compression ignition engine, strategies intended to bring homogeneous charge compression ignition to market must account for this fuel and additive variability. In order to investigate this impact, two oxygenated refinery stream test fuels with two different additives were run in a single cylinder homogeneous charge compression ignition engine. The two fuels had varying chemical composition; one represents a “dirty” fuel with high aromatic content that was intended to simulate a worst-case scenario for deposit growth, while the other represents a California Reformulated Gasoline Blendstock for Oxygenate Blending fuel, which is the primary constituent of pump gasoline at fueling stations across the state of California. The additive packages are typical of technologies that are commercially available to treat engine deposits. Both fuels were run in an experimental, single-cylinder homogeneous charge compression ignition engine in a passive conditioning study, during which the engine was run at steady state over a period of time in order to track changes in the homogeneous charge compression ignition combustion event as deposits accumulated in-cylinder. Both the composition and the additive influenced the structure of the combustion chamber deposit layer, but more importantly, both the rate at which the layer developed and the equilibrium thickness it achieved. The overall thickness of the combustion chamber deposit layer was found to have a significant impact on homogeneous charge compression ignition combustion phasing.

Diminishing Benefits of Federal Reformulated Gasoline (RFG) Compared to Conventional Gasoline (CG)

Diminishing Benefits of Federal Reformulated Gasoline (RFG) Compared to Conventional Gasoline (CG)

Application of first order kinetics to characterize MTBE natural attenuation in groundwater

Methyl tertiary butyl ether (MTBE) was a gasoline oxygenate that became widely used in reformulated gasoline as a means to reduce air pollution in the 1990s. Unfortunately, many of the underground storage tanks containing reformulated gasoline experienced subsurface releases which soon became a health concern given the increase in public and private water supplies containing MTBE. Many states responded to this by banning the use of MTBE as an additive, including Connecticut. Although MTBE dissipates by natural attenuation, it continues to be prevalent in groundwater long after the Connecticut ban in 2004. This study estimated the rate of the natural attenuation in groundwater following the Connecticut ban by evaluating the MTBE concentration two years prior to and two years after the MTBE ban at eighty-three monitoring wells from twenty-two retail gasoline stations where MTBE contamination was observed. Sites chosen for this study had not undergone active remediation ensuring no artificial influence to the natural attenuation processes that controls the migration and dissipation of MTBE. Results indicate that MTBE has dissipated in the natural environment, at more than 80% of the sites and at approximately 82% of the individual monitoring wells. In general, dissipation approximated first order kinetics. Dissipation half-lives, calculated using concentration data from the two year period after the ban, ranged from approximately three weeks to just over seven years with an average half-life of 7.3months with little variability in estimates for different site characteristics. The accuracy of first order estimates to predict further MTBE dissipation were tested by comparing predicted concentrations with those observed after the two year post-ban period; the predicted concentrations closely match the observed concentrations which supports the use of first order kinetics for predictions of this nature.

Un análisis de la estructura tecnológica de refinerías y licuadoras: cálculo de la función de costo de Leontief multiproducto y reserva de precios

<p align="justify">La función de costos flexibles multiproducto de Leontief pretende una aproximación a la tecnología utilizada por las refinerías y batidoras. En general, esta función de costos satisface las restricciones de comportamiento racionales impuestas por la teoría económica. Los costos marginales estimados se incorporan en un modelo de competencia monopolística, para calcular los precios virtuales de los demás productos ofrecidos por las refinerías y batidoras en la situación hipotética en la que la gasolina esté ausente en los mercados de combustibles. Se ha encontrado que la gasolina convencional y otros precios de productos son mayores que en el caso hipotético mencionado. Este resultado refleja el hecho de que los consumidores están asumiendo la sobrecarga de precios altos, con el fin de tener un combustible disponible que se ajuste a las regulaciones de la Agencia de Protección Ambiental (EPA). Por último, cuando todos los productos se convierten en sustitutos perfectos, es decir, los consumidores no están interesados en la calidad de los combustibles, las diferencias de precios tienden a ser insignificantes.</p>

Responses of the steroidogenic pathway from exposure to methyl-tert-butyl ether and tert-butanol

Methyl tertiary-butyl ether (MTBE) is a solvent and fuel additive included in reformulated gasoline to increase combustion efficiency. While widespread use in motor fuels in the U.S. was discontinued after MTBE was detected in surface and ground waters due to concerns about environmental persistence and water quality, it is still manufactured in the U.S. for export. Questions concerning the etiology of rat Leydig cell and mouse liver tumors identified in extremely high dose cancer studies have led to an interest in evaluating potential hormonal imbalances and endocrine system involvement. To address the possibility that MTBE or its metabolite, tert-butanol (TBA), are interacting with components of the endocrine system that are involved in steroidogenesis a number of targeted experiments were performed focusing mostly on the primary gonadal steroids, estradiol and testosterone. The goal of the experiments was to gain a better understanding of potential interactions with the steroidogenic pathway, including effects specifically on aromatase, the P450 enzyme that converts testosterone to estradiol. In three GLP-compliant in vitro guideline studies, MTBE and TBA were classified as non-binders to the androgen receptor, were classified negative for effects on testosterone and estradiol in the steroidogenesis assay, and were classified as non-inhibitors of aromatase activity. In three 14-day in vivo experiments involving gavaging of male Sprague-Dawley rats with doses of MTBE ranging from 400 to 1500mg/kg bw/day, the lack of definitive and consistent supporting statistically significant findings in steroid hormone measurements and aromatase activity and mRNA measured in liver and testis microsomes further suggested that it is unlikely that MTBE is interacting with the endocrine system directly. Evidence of other underlying systemic effects were also seen, including reduced body weight gain, increased adrenal weights, and elevated corticosterone suggestive of a more general stress response. Taken together, the results from these studies suggest that MTBE and TBA do not directly impact the steroidogenic pathways involved in estrogen and androgen production.

A ban on one is a boon for the other: Strict gasoline content rules and implicit ethanol blending mandates

Ethanol and methyl-tertiary butyl ether (MTBE) were close substitutes in the gasoline additives market until MTBE was banned due to the concerns about groundwater contamination, leading to a sudden and dramatic substitution toward ethanol as an alternative oxygenate and octane-booster. We use variation in the timing of MTBE bans across states to identify their effects on gasoline prices. We find that state bans increased reformulated gasoline prices by 3–6 cents in non-Midwestern states for which the bans were binding, with larger impacts during times of high ethanol prices relative to MTBE and crude oil. We find qualitatively similar, yet smaller effects for conventional gasoline. We argue on the basis of a simple conceptual model and supporting empirical evidence that these bans functioned as implicit ethanol blending mandates in areas that were previously using MTBE to comply with strict environmental constraints. Overall, our results are consistent with the theoretical prediction that mandating a minimum market share for a more costly alternative fuel—either directly, or implicitly through a ban on the preferred conventional fuel—will inevitably increase fuel prices in a competitive market.

Historical trends in greenhouse gas emissions of the Alberta oil sands (1970–2010)

There has been increased scrutiny of the Alberta oil sands due to their high carbon intensity (CI) relative to conventional crude oil. Relying entirely on public and peer-reviewed data sources, we examine historical trends in the CI of oil sands extraction, upgrading, and refining. Monthly data were collected and interpolated from 1970 to 2010 (inclusive) for each oil sands project. Results show a reduction in oil sands CI over time, with industry-average full-fuel cycle (well-to-wheels, WTW) CI declining from 165 gCO2e MJ−1 higher heating value (HHV) of reformulated gasoline (RFG) to 105 (−12, +9) gCO2e MJ−1 HHV RFG. 2010 averages by production pathways are 102 gCO2e MJ−1 for Mining and 111 gCO2e MJ−1 for in situ. The CI of mining-based projects has declined due to upgrader efficiency improvements and a shift away from coke to natural gas as a process fuel. In situ projects have benefitted from substantial reductions in fugitive emissions from bitumen batteries. Both mining and in situ projects have benefitted from improved refining efficiencies. However, despite these improvements, the CI of oil sands production (on a pathway-average basis) ranges from 12 to 24% higher than CI values from conventional oil production. Due to growing output, total emissions from the oil sands continue to increase despite improved efficiency: total upstream emissions were roughly 65 MtCO2e in 2010, or 9% of Canada’s emissions.

Quantification of personal exposure concentrations to gasoline vehicle emissions in high-end exposure microenvironments: Effects of fuel and season

Mobile-source air toxic (MSAT) levels increase in confining microenvironments (MEs) with numerous emission sources of vehicle exhaust or evaporative emissions or during high-load and cold-start conditions. Reformulated fuels are expected to reduce MSAT and ozone precursor emissions. This study, required under the Clean Air Act Section 211b, evaluated high-end exposures in cities using reformulated (methyl tertiary-butyl ether [MTBE] or ethanol [EtOH]) fuels and conventional gasoline blends. The study investigates 13 high-end MEs, sampling under enhanced exposure conditions expected to result in maximal fuel and exhaust component exposures to carbon monoxide (CO), carbon dioxide (CO2), BTEX (benzene, toluene, ethylbenzene, xylenes), MTBE, 1,3-butadiene (1,3-BD), EtOH, formaldehyde (HCHO), and acetaldehyde (CH3CHO). The authors found that day-to-day ME variations in high-end benzene, 1,3-BD, HCHO, and CO concentrations are substantial, but independent of gasoline composition and season, and related to the activity and emission rates of ME sources, which differ from day to day. Implications: Mobile-source air toxic (MSAT) levels increase in confining microenvironments (MEs) in the presence of vehicular exhaust or evaporative emissions. This study, required under the Clean Air Act Section 211b, evaluated high-end exposures in cities using oxygenated (methyl tertiary-butyl ether or ethanol) and conventional gasoline blends. Personal exposure concentrations were quantified in selected MEs representing the upper end of the frequency distribution of potential population exposures. This work presents the first systematic look at high-end/maximal exposures to multiple contaminants, in multiple microenvironments, in multiple cities, over two seasons, for multiple fuels, making it a very complete evaluation of reformulated fuel impacts on MSAT concentrations in confined microenvironments. The study found that day-to-day ME variations of high-end pollutant concentrations are substantial, but independent of gasoline composition and season, and related to the variable daily activity and emission rates of ME sources. The data collected in this study may be used in bounding exposure modeling estimates that account for time spent in similar confining MEs. Supplemental Materials: Supplemental materials are available for this paper. Go to the publisher's online edition of the Journal of the Air & Waste Management Association for information on average, maximum and minimum ME concentrations and summary of reconstructed 1-minute data.

Fingerprint identification of volatile organic compounds in gasoline contaminated groundwater using gas chromatography differential ion mobility spectrometry

Groundwater can be contaminated when e.g. gasoline tanks leak. Due to sampling and lab analysis, groundwater monitoring is time consuming and expensive. The technologies developed for rapid on-site analysis of gasoline contaminated groundwater face the technical limitation to distinguish the gasoline from complex matrices. In the present study the fingerprint identification of volatile organic components (VOCs) in gasoline contaminated groundwater using gas chromatography (GC) differential ion mobility spectrometry (DMS) is investigated. Groundwater was spiked with five sorts of gasoline (one reformulated gasoline, gasoline without additives and three different brand gasoline collected on petrol stations) and analyzed by GC-DMS. Seven VOCs (benzene, toluene, ethyl benzene, m-xylene, p-xylene, o-xylene, 1,2,4-trimethylbenzene) were identified by GC mass spectrometry (GC-MS) as well as by GC-DMS and selected as markers. The semi-quantitative determination of the selected compounds was achieved. The limits of detection of the GC-DMS are 46.42 ng for benzene, 1.13 ng for toluene, 1.80 ng for ethylbenzene, 0.22 ng for m-xylene, 1.13 ng for p-xylene, 0.61 ng for o-xylene and 0.37 ng for 1,2,4-trimethylbenzene, respectively. These results reveal the feasibility of GC-DMS for on-site monitoring of contaminated groundwater.

Effects of Subchronic Inhalation Exposure to Ethyl Tertiary Butyl Ether on Splenocytes in Mice

Ethyl tertiary-butyl ether (ETBE) is a motor fuel oxygenate used in reformulated gasoline. The current use of ETBE in gasoline or petrol is modest but increasing. To investigate the effects of ETBE on splenocytes, mice were exposed to 0 (control), 500 ppm, 1750 ppm, or 5000 ppm of ETBE by inhalation for 6 h/day for 5 days/wk over a 6- or 13-week period. Splenocytes were harvested from the control and exposed mice, and the following cell phenotypes were quantified by flow cytometry: (1) B cells (PerCP-Cy5.5-CD45R/B220), (2) T cells (PerCP-Cy5-CD3e), (3) T cell subsets (FITC-CD4 and PE-CD8a), (4) natural killer (NK) cells (PE-NK1.1), and (5) macrophages (FITC-CD11b). Body weight and the weight of the spleen were also examined. ETBE-exposure did not affect the weight of the spleen or body weight, while it transiently increased the number of RBC and the Hb concentration. The numbers of splenic CD3+, CD4+, and CD8+ T cells, the percentage of CD4+ T cells and the CD4+/CD8+ T cell ratio in the ETBE-exposed groups were significantly decreased in a dose-dependent manner. However, ETBE exposure did not affect the numbers of splenic NK cells, B cells, or macrophages or the total number of splenocytes. The above findings indicate that ETBE selectively affects the number of splenic T cells in mice.

The higher price of cleaner fuels: Market power in the rail transport of fuel ethanol

This paper provides evidence of market power in the transportation of ethanol used in reformulated gasoline and alternative transportation fuels. I estimate a reduced form model for railroad route-level prices. My identification strategy instruments for railroad entry, controls for selection and explicitly models capacity constraints. A detailed understanding of this industry is important because U.S. environmental policies seek to substantially expand ethanol use. Evidence of market power may alter the types of policies pursued by lawmakers. I find that ethanol shipment prices are lower for more competitive routes. I also find evidence that railroads price discriminate based on environmental regulation at route destinations. Monopolist prices for shipments to carbon monoxide non-attainment areas are 3% higher than shipments to other destinations. This price premium falls sharply with increased competition. This suggests a perverse result where environmental regulation increases the price of a clean input.

The Higher Price of Cleaner Fuels: Market Power in the Rail Transport of Fuel Ethanol

This paper provides evidence of market power in the transportation of ethanol used in reformulated gasoline and alternative transportation fuels. I estimate a reduced form model for railroad route-level prices. My identification strategy instruments for railroad entry, controls for selection and explicitly models capacity constraints. A detailed understanding of this industry is important because U.S. environmental policies seek to substantially expand ethanol use. Evidence of market power may alter the types of policies pursued by lawmakers. I find that ethanol shipment prices are lower for more competitive routes. I also find evidence that railroads price discriminate based on environmental regulation at route destinations. Monopolist prices for shipments to carbon monoxide non-attainment areas are 3% higher than shipments to other destinations. This price premium falls sharply with increased competition. This suggests a perverse result where environmental regulation increases the price of a clean input.

Ethyl t‐butyl ether: review of reproductive and developmental toxicity

Ethyl t-butyl ether (ETBE) is a motor fuel oxygenate used in reformulated gasoline. Knowledge of developmental and reproductive toxicity potential of ETBE is critical for making informed decisions about acceptance and regulations. This review discusses toxicology studies providing information about effects on reproduction and the conceptus. Seven GLP-compliant studies following widely accepted protocols have focused specifically on developmental and reproductive toxicity (DART) in rats and rabbits exposed to ETBE by gavage with doses up to 1,000 mg/kg body weight/day, the limit specified in standardized test guidelines. Other repeat-dose general toxicology studies have administered ETBE to rodents for up to 180 days, and included reproductive organ weights, histology, or other indications of reproductive system structure or function. DART potential of the main ETBE metabolite t-butyl alcohol and class-related MTBE has also been studied. More GLP-compliant studies exist for evaluating ETBE using well-established, currently recommended protocols than are available for many other chemicals used today. The database for determining ETBE DART potential is adequate, although not all study details are currently easily accessible for peer-review. ETBE does not appear to be selectively toxic to reproduction or embryofetal development in the absence of other manifestations of general toxicity. Studies using recommended methods for sample preservation and analysis have shown no targeted effect on the reproductive system. No embryofetal effects were observed in rabbits. Early postnatal rat pup deaths show no clear dose-response and have largely been attributed to total litter losses with accompanying evidence of maternal neglect or frank maternal morbidity.

Mathematical modeling and global optimization of large-scale extended pooling problems with the (EPA) complex emissions constraints

Environmental Protection Agency (EPA) Title 40 Code of Federal Regulations Part 80.45: Complex Emissions Model [40CFR80.45, 2007] codifies a mathematical model of gasoline emissions for reformulated gasoline (RFG) as a function of eleven fuel properties. In this paper we propose an extended pooling problem to maximize the profit of blending reformulated gasoline on a predetermined network structure of feed stocks, intermediate storage tanks, and gasoline products subject to applicable environmental standards. A mixed-integer nonlinear programming (MINLP) model is introduced which is nonconvex due to the presence of bilinear, polynomial, and fractional power terms. A mixed-integer linear programming (MILP) relaxation of the extended pooling problem is proposed and we introduce several test cases from small to medium to large scale and solve them to global optimality. The large-scale test case involves 14 feed stocks, 5 pools, and 10 products and consists of 1104 continuous variables, 150 binary variables, and 640 nonlinear terms. The nonconvexities in the large-scale case study include 410 bilinear terms, 40 polynomial terms, and 10 terms raised to a fractional power.

Converting Oil Shale to Liquid Fuels with the Alberta Taciuk Processor: Energy Inputs and Greenhouse Gas Emissions

We calculate the greenhouse gas (GHG) emissions from producing liquid fuels from Green River oil shale with the Alberta Taciuk Processor (ATP). Kerogen contained in oil shale can be retorted to produce liquid and gaseous hydrocarbons. The ATP is an above-ground oil shale retort that combusts the coke or “char” deposited on the shale during retorting to fuel the retorting process. Using life cycle assessment (LCA), we calculate the energy inputs and outputs of each process stage. We then calculate the resulting full-fuel-cycle GHG emissions from producing reformulated gasoline using the ATP. Full-fuel-cycle GHG emissions are conservatively calculated at ≈130−150 g CO2 equiv/MJ of gasoline produced. These emissions are 1.5 to 1.75 times larger than emissions from conventionally produced gasoline. The results depend most sensitively on the grade of shale used and the rate of carbonate mineral decomposition, which causes inorganic carbon dioxide (CO2) release.