Reflectance Spectra Research Articles

N-doped nano-casted carbon monolith for Pb (II) removal and photocatalytic degradation of thiamethoxam from aqueous solution.

Single rock-like N-doped carbon monolith (ND-PFCM) was successfully constructed via nanocasting method. Phenol formaldehyde resin was taken as carbon source and nitrogen was incorporated in monoliths through NaNH2 activation. The synthesized monoliths were used for the removal of Pb (II) from aqueous solution. Various characterization techniques, namely Brunauer-Emmett-Teller (BET), Raman spectroscopy, UV-visible diffuse reflectance spectra (DRS) UV-DRS, zeta potential, scanning electron microscopy (SEM), TEM (transmission electron microscopy), TGA (thermogravimetric analysis), and XPS (X-ray photoelectron spectroscopy), were utilized to characterize synthesized monolithic samples. The different parameters such as pH, adsorbent dosage, and time were enquired on the removal efficiency of monoliths toward Pb(II). ND-PFCM exhibited the highest adsorption capacity of 330.03mgg-1 in 180min at pH 6. This is attributed to the fact that the better texture properties and presence of nitrogen functional groups enhance the uptake of Pb (II) ions on the monolith surface. In the kinetic studies, pseudo-second-order model fitted best with the experimental data. Furthermore, the removal of thiamethoxam (TM) from aqueous solution was done by using different weight ratios of ND-PFCM under the visible light. The maximum removal efficiency of 97.35% with rate constant of 0.02085min-1was obtained in 160min. Moreover, monoliths exhibited good reusability for five consecutive cycles. The findings suggest that the synthesized monoliths exhibit characteristics suitable and eco-friendly for sustainable use in water treatment applications.

High photocatalytic activity of g-C3N4/CdZnS/MoS2 heterojunction for hydrogen production

In an effort to improve the light absorption efficiency of the photocatalyst, g-C3N4 nanosheets with visible light response have been prepared by roasting method, and the g-C3N4/CdZnS composite catalyst with 2D/0D architecture has been prepared by hydrothermal method after ultrasonic thinning. The g-C3N4/CdZnS/MoS2 composite catalyst with 2D/0D architecture has been synthesized by secondary hydrothermal method. TEM analysis proves that a close heterogeneous interface has been formed between g-C3N4 and CdZnS, and between CdZnS and MoS2. The ultraviolet diffuse reflectance spectrum shows that MoS2 has a wide light absorption range, which effectively enhances the light utilization ratio of the composite catalyst. The energy band structure diagram and photoelectrochemical test results show that a continuous stepped type II ternary heterojunction is formed among g-C3N4, CdZnS and MoS2, which promotes its separation of photogenerated charges. When the loading mass fraction of g-C3N4 and MoS2 is 4%, the hydrogen evolution rate of g-C3N4/CdZnS/MoS2 composite catalyst is 57.02 mmol g−1 h−1 under visible light, which is exceeding 20% that of g-C3N4/CdZnS and 4.79 times and 44.9 times higher than that of CdZnS and g-C3N4, respectively. The two-dimensional structure of g-C3N4 and MoS2 significantly improves the stability of the composite catalyst. This work offers feasible ways for ternary heterogeneous photocatalyst construction.

Stretchable terahertz metasurface based on laser induced graphene for contactless deformation sensing

In this paper, a 1D stretchable terahertz (THz) metasurface based on laser-induced graphene (LIG) for deformation sensing is developed with low cost, good sensitivity and robustness. After the LIG metasurface is fabricated by laser-direct writing on a polyimide film, it is divided into columns and bonded to a medical polyurethane (PU) tape, thus endowed with high elasticity due to the excellent flexibility of PU. Because LIG supports surface plasmon polaritons in the THz band, a plasmonic resonance is introduced in the reflection spectrum and red shifts with lateral stretching. Experimental results show that the device can realize a resonant frequency shift of 336 GHz at a deformation of 0-14 mm, and the linearity reaches 0.988, achieving a sensitivity of 24 GHz/mm and excellent robustness (>1000 repetitions). The LIG-based stretchable THz sensor has great application potential for contactless deformation sensing in aerospace, industrial manufacturing, and related fields.

Second Harmonic Generation from exciton-polaritons: Strong coupling between monolayer WS[formula omitted] and multilayer WSe[formula omitted] metasurfaces Quasibound states in the continuum

The second harmonic generation (SHG) from exciton-polaritons, produced by the strong coupling between quantum emitters and cavity photons, can provide a unique insight for controlling nonlinear responses on the nanoscale. Achieving SHG generally depends on phase matching, limited by nonlinear materials and nanostructure fabrication. Here, we demonstrate a novel way to obtain tunable SHG from van der Waals metasurfaces composed of nanostructured multilayer WSe2 strong coupling with monolayer WS2. By breaking symmetry via varying the metasurface unit tilted angle and period, quasibound state in the continuum (q-BIC) mode resonances energy is tuned across the monolayer WS2 exciton resonance energy, enabling anticrossing behavior of strong coupling in both reflection spectrum and SHG spectrum, which means that SHG was successfully observed by strong coupling. Furthermore, the SHG spectrum can be tuned by changing the armchair direction of the monolayer WS2 and pump polarization direction. Moreover, the mechanism of exciton-polaritonic SHG is investigated by a coupled nonlinear oscillator model, which reveals the SHG origin from exciton-polaritons, providing a new rule for fine-tuning the SHG. Our work provides a new strategy and additional freedom in the nonlinear light-matter interaction and coherent control of the SHG in integrated photonic devices.

Using synthetic disk-integrated reflectance spectra to constrain direct imaging sensitivity requirements for a Mars-like exoplanet

The 2020 Decadal Survey on Astronomy and Astrophysics 11https://doi.org/10.17226/26141. recommended the prioritization of a space-based telescope capable of directly characterizing Earth-like exoplanets in reflected light. The planned suite of instruments onboard such a mission are expected to provide disk-integrated spectra with moderate spectral resolution and signal-to-noise (SNR). Although the detection and characterization of Earth-like exoplanets remains the primary focus of such a mission, land planets with limited available water, such as Mars, may be much more common. Mars-like exoplanets, therefore, are an equally significant set of targets when investigating the diverse climatologies and potential habitability of other worlds, especially if our own Solar System is any indication of planetary diversity. In this study, we constrain the direct imaging sensitivity requirements for observing and characterizing Mars-like exoplanets with the goal of informing future telescope design and mission planning. Employing an instrument noise model simulating a coronagraph-equipped, space-based telescope, spatially- and spectrally-resolved synthetic observations of Mars are produced. We evaluate the direct imaging sensitivity requirements across a range of wavelengths, from the ultraviolet (UV) to near-infrared (near-IR), to enable the spectral characterization of key atmospheric and surface features from disk-integrated reflectance spectra. Detectability at a given SNR is assessed through optical wavelength integration times for a range of phase angles, host star spectral types, and levels of atmospheric dustiness. Our results indicate that a Decadal-recommended space telescope featuring an aperture of 6-m is likely only proficient in detecting Mars-like exoplanets around K-type stars located within a 10 parsec (pc) radius from Earth. Furthermore, we demonstrate that when integrating over visible and near-IR wavelengths, required exposure times to detect such a planet are reasonable, especially near full phase angles. In the context of upcoming and proposed observatories, such as the Habitable Exoplanet Observatory (HabEx) and Large UV/Optical/IR Surveyor (LUVOIR), our findings provide valuable insights into the direct imaging capabilities and optimal observational strategies needed for detecting and studying Mars-like exoplanets.

Stray Light in 3D Porous Nanostructures of Single‐Crystalline Copper Film

In the design of optical devices and components, geometric structures and optical properties of materials, such as absorption, refraction, reflection, diffraction, scattering, and trapping, have been utilized. Finding the ideal material with certain optical and geometric characteristics is essential for a customized application. Herein, unoxidizable achromatic copper films (ACFs) are fabricated on Al2O3 substrates utilizing an atomic sputtering epitaxy apparatus. ACFs are made up of two regions vertically: a comparatively flat layer region and a 3D porous nanostructured region on top of the flat region. The measured specular reflectance displays low‐pass filter behavior with a sharp cutoff frequency in the infrared spectrum. Furthermore, the measured diffusive reflectance spectra show light‐trapping behavior in the spectral region above the cutoff frequency, where there are no known absorption mechanisms, such as phonons and interband transitions. A focused ion beam scanning electron microscope is utilized to study the thin film's nanostructured region through 3D tomographic analysis in order to comprehend the phenomena that are observed. This work will shed fresh light on the design and optimization of optical filters and light‐trapping employing porous nanostructured metallic thin films.

Reflectance Spectroscopy of 27 Fine-particulate Mineral Samples from Far-ultraviolet through Mid-infrared (0.12–20 μm)

This paper presents far-ultraviolet through mid-infrared (0.12–20 μm) reflectance spectra of 27 fine-particulate (<10 μm) terrestrial mineral samples, providing continuous spectra that cover an unusually broad spectral range and are of unusually fine particle size relative to most existing spectral libraries. These spectra of common geologic materials are useful for future applications that study the dust on various planetary bodies. Reflectance spectra were acquired of the samples at multiple laboratories at multiple wavelengths. All of the spectra were compared to one another to observe the general, common spectral characteristics (e.g., slope, band shape, and band depth), and the best segments of the spectra representing the mineral reflectance were scaled and spliced together to form a “Frankenspectrum” for each mineral that best represents the full wavelength range of far-ultraviolet, visible, near-infrared, and middle-infrared wavelengths. These scaled and spliced Frankenspectra, as well as the entire set of individual “original” reflectance spectra from each laboratory, are available in the Planetary Data System Geosciences Node.

Spectral properties of bright deposits in permanently shadowed craters on Ceres

Context. Bright deposits in permanently shadowed craters on Ceres are thought to harbor water ice. However, the evidence for water ice presented thus far is indirect. Aims. We aim to directly detect the spectral characteristics of water ice in bright deposits present in permanently shadowed regions (PSRs) in polar craters on Ceres. Methods. We analyzed narrowband images of four of the largest shadowed bright deposits acquired by the Dawn Framing Camera to reconstruct their reflectance spectra, carefully considering issues such as in-field stray light correction and image compression artifacts. Results. The sunlit portion of a polar deposit known to harbor water ice has a negative (blue) spectral slope of −58 ± 12% µm−1 relative to the background in the visible wavelength range. We find that the PSR bright deposits have similarly blue spectral slopes, consistent with a water ice composition. Based on the brightness and spectral properties, we argue that the ice is likely present as particles of high purity. Other components such as phyllosilicates may be mixed in with the ice. Salts are an unlikely brightening agent given their association with cryovolcanic processes, of which we find no trace. Conclusions. Our spectral analysis strengthens the case for the presence of water ice in permanently shadowed craters on Ceres.

Excited States of Excitons in MoSe2 and WSe2 Monolayers

Excitons in MoSe2 and WSe2 monolayers encapsulated with hexagonal boron nitride have been studied using optical reflectance spectroscopy. The ground and excited states of A- and B-excitons have been studied at temperatures from liquid helium to room temperature. The lines of excitons A:\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$1s$$\\end{document}, B:\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$1s$$\\end{document} and their excited states А:\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$2s$$\\end{document}, А:\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$3s$$\\end{document}, and В:\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$2s$$\\end{document} are clearly observed in the reflectance spectrum. The observed line shapes of the reflection spectrum of transition metal dichalcogenide monolayers depend on the thickness of the hexagonal boron nitride layers used in the structure and are in good agreement with the numerical simulation using the transfer matrix method. For the first time, the values of the reduced masses of B-excitons have been obtained from experimental data and the performed calculations of the exciton binding energy.

On obtaining the coupled-mode theory using a model of coupled plane waves for symmetric resonant diffraction gratings

We consider two analytical models describing resonant scattering of light by resonant diffraction gratings possessing a horizontal symmetry plane. For the case of oblique incidence, a multiple interference model is formulated, on the basis of which, a new approach for deriving the coupled-mode theory for the considered structures is proposed. Both considered models describe resonances in the reflectance and transmittance spectra of the studied diffraction gratings arising due to the excitation of quasiguided modes and Fabry–Pérot modes. Interaction of these modes leads to the appearance of bound states in the continuum, which are also described by the proposed models.

Adsorption mechanisms, kinetics and photoactivities of green synthesized hydroxyapatite supported ZnO and La–ZnO catalysts

In this study, hydroxyapatite (HAP) is synthesized by a co-precipitation method from the waste eggshell, utilized as a support for ZnO (ZnO-HAP) and La–ZnO (La–ZnO-HAP) and employed to degrade methyl orange (MO) and methylene blue (MB) dyes under UV irradiation. Water vapor adsorption as relative humidity (84 % RH) on the HAP structure and the as-prepared catalysts are also examined. The characteristic ZnO and HAP reflections are detected in X-ray diffraction (XRD) analysis of ZnO-HAP, La–ZnO-HAP and humidified samples. ZnO and La–ZnO existence is also verified by scanning electron microscopy-energy dispersive X-ray (SEM-EDX) analysis, UV–Vis diffuse reflectance (UV–Vis DRS) spectra and X-ray photoelectron spectra (XPS). ZnO and La–ZnO loading on the HAP induce the formation of mesoporous structures with high surface areas. Dark adsorption capacities and photoactivities of the as-prepared samples are explored regarding electrostatic interactions, Lewis acid-base interactions and hydrogen bonding for both MO and MB. In particular, La–ZnO-HAP 500 °C and La–ZnO-HAP 500 °C (RH) exhibit improved adsorption abilities and photoactivities. The pseudo-second order model describes the kinetic behavior of all samples under dark conditions. Unhumidified samples follow Langmuir isotherm while Freundlich isotherm better fits humidified ones. Under irradiation, the Langmuir-Hinshelwood kinetic model describes the photoactivities of all samples. The four recycling tests confirm the stabilities of HAP 100 °C, HAP 500 °C, ZnO-HAP 500 °C and La–ZnO-HAP 500 °C. This study suggests that the ZnO or La–ZnO loaded HAP catalysts prepared in the presence and absence of humid conditions are considered promising materials for environmental remediation.

A novel fluoroapatite-type phosphor Ca2Y8(BO4)2(SiO4)4F2:Eu3+ with high quantum efficiency and good thermal stability for multimodal applications☆

A novel Eu3+ doped fluorapatite red phosphor Ca2Y8(BO4)2(SiO4)4F2:Eu3+ with pure phase was synthesized in this study. Density functional theory (DFT) calculation and diffuse reflection spectrum analysis reveal its potential as a matrix for phosphors excited by ultraviolet light. Eu3+ has a 7F0→5L6 transition at 394 nm, and the prepared phosphor exhibits a high emission intensity at 614 nm, which may be attributed to the 5D0-7F2 energy transition at the lower symmetry site of Eu3+. The optimal doping concentration of the phosphor is determined to be 11 mol%, with concentration quenching attributed to the exchange interaction mechanism. The overall color purity of the phosphor is up to 99.88%, with an internal quantum efficiency as high as 91.15%. Notably, Ca2Y8(BO4)2(SiO4)4F2:11 mol%Eu3+ (CYBSF:11 mol%Eu3+) phosphors exhibit good thermal stability, with a thermal quenching temperature (T1/2) of 552 K and the intensity of emission at 423 K still at 88.89% of that at 298 K. The activation energy of the phosphor is up to 0.30287 eV. Its comprehensive luminescence performance surpasses that of commercial red phosphor, making it suitable for near ultraviolet excited warm white light emitting diode (NUV-WLED) with a high color rendering index (Ra = 82) and a correlation color temperature (CCT) of 4339 K. Moreover, the phosphor achieves latent fingerprint visualization and anti-counterfeiting ink on different material surfaces: glass, aluminum foil, plastic and paper. Overall, the fluorapatite CYBSF:11 mol%Eu3+ phosphor holds great potential for multimodal applications due to its high quantum efficiency and good thermal stability.

Crystallographic and Mid‐Infrared Spectroscopic Properties of the CaS‐MgS Solid Solution

AbstractWe synthesized the solid solution between the sulfides CaS (oldhamite) and MgS (niningerite). Electron microprobe and X‐ray diffraction showed homogeneous and pure samples after the synthesis. The calculated lattice parameters fit to earlier literature data. Mid‐infrared spectroscopy of the samples reveal that the produced sulfides were fragile and tend to alternate very fast. However, we were able to provide clean reflectance spectra of all samples. The spectra of un‐altered samples show no peaks or bands but a rather constant spectrum within the analyzed spectral range between 7.0 and 12.5 μm. The altered spectra contain signatures of sulfates and carbonates and probably further compounds. The gathered data help to understand the formation conditions of the studies sulfides as it shows that the solvus exists in the CaS‐MgS system between 1000°C and 1200°C. In addition, the infrared data will help to improve remote sensing in the mid‐infrared of planetary objects that might be covered with sulfide containing material like asteroids or Mercury.

Structural and optical properties of mesoporous akermanite derived from industrial waste for multifunctional applications

The present study focuses on the synthesis of akermanite by chemical free hydrothermal route using two major industrial waste ground granulated blast furnace slag (GGBS) and coal fly ash (FA) as the initial precursors. Further, leaf extract and Cetyltrimethyl ammonium bromide (CTAB) have been used as stabilizing and chelating agent to observe their effect on the structural, optical and morphological properties of the nanoparticles. The synthesized powders were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), ultraviolet visible (UV–visible) spectroscopy, Brunauer-Emmett-Teller (BET) analyser techniques. The detailed structural studies implied that the fabricated powders are akermanite and the average crystallite size was calculated to be in the range 23–27 nm. Field emission scanning electron microscopy analysis showed that the samples synthesized using water and leaf extract adopt rod like morphology while the sample fabricated using CTAB are seed shaped. The calculated bandgap of the developed powders from the UV-Visible reflectance spectra using Kubelka-Munk method lie in the range 3.1–3.26 eV. BET analysis revealed all the samples are mesoporous in nature and their specific surface area were estimated.

Crystal structures, dielectric properties, and lattice vibrational characteristics of Zn1-xCaxWO4 (x = 0–0.25) composite ceramics

In this work, Zn1-xCaxWO4 (x=0–0.25, ZCWO) composite ceramics were prepared by using the conventional solid-state sintering method at 1070 ℃. The impact of Ca2+ substitution on the lattice vibrational characteristics and dielectric responses of the ZCWO composite ceramics was investigated in detail. The formation of composite ceramics was verified by the Rietveld refined X-ray diffraction data of the ZCWO samples. The lattice vibrational characteristics were also identified and analyzed by the Raman and infrared reflection spectra combined with the theoretical simulations. The vibrational modes analysis of the Raman spectra showed that the internal modes of the ZCWO ceramics correspond to the vibrations of the W-O octahedrons. From the Fourier transform infrared reflectance spectra, the existence of three new vibrational modes of Au (315 cm−1), Au (834 cm−1), and Eu (885 cm−1) at x = 0.15–0.25 was observed, which belong to the modes of the CaWO4 ceramic. In addition, the intrinsic dielectric properties fitted by the four-parameter semiquantum model were in direct agreement with the theoretical values obtained from the Clausius-Mossotti & damping equations and the measured values. Besides, the contribution of each lattice vibrational mode to the intrinsic properties of the ZCWO ceramics was thoroughly studied, which shows that external mode 1 contributes the most to the intrinsic properties. The structure-property relationships of the ZCWO ceramics were established using the Raman modes as a media. The optimum dielectric properties of the ZCWO ceramics were obtained when x = 0.25: εr =13.98 (10.48 GHz), Q × f = 32,188 GHz.

Control of visible-range transmission and reflection haze by varying pattern size, shape and depth in flexible metasurfaces

Cost-effective soft imprint lithography technique is used to prepare flexible thin polymeric surfaces containing a periodic arrangement of nanodimples and nanobumps of sub-micron size. Using a single master mold of self-assembled colloidal crystal, metasurfaces with different depths and heights of patterns with a fixed pitch are possible, which makes the process inexpensive and simple. These metasurfaces are studied for their diffuse and total transmission and reflection spectra in the visible range. The transmission haze and reflection haze are calculated from the measurements. The surface containing nanobumps of lesser pattern height result in higher values of reflection and transmission haze than from surfaces containing nanodimples of much higher depth for the same pitch. The haze is more dependent on the pattern depth or height and less dependent on the pitch of the pattern. Far-field transmission profiles measured in the same wavelength range from the patterned surfaces show that the scattering increases with the increase of the ratio of pattern depth/height to pitch, similar to the haze measurements conducted with a closed integrating sphere. These profiles show that the angular spread of scattered light in transmission is within 10°, explaining the reason for the relatively low transmission haze in all the patterned surfaces. Simulation results confirm that the nanobump pattern gives higher transmission haze compared to nanodimple pattern. By controlling the ratio of pattern depth/height to pitch of the features on these surfaces, both an increase in optical haze and a balance between total reflection intensity and total transmission intensity can be achieved.Graphical

Influence of ZnMn2O4/CuCo2O4 nano-fillers on the optical and electrical properties PVA/CMC/PEG blended polymers

(1-x)ZnMn2O4/xCuCo2O4 samples were synthesized by the co-precipitation method while polyvinyl alcohol/carboxymethyl cellulose/polyethylene glycol (PVA/CMC/PEG) blended polymer were fabricated by the casting method. Rietveld refinement analysis was used to determine the crystallite size and phase percentages for each composition were determined for all samples. The morphology and structure of PVA/CMC/PEG/(1-x)ZnMn2O4/xCuCo2O4 blends were examined using scanning electron microscopy and x-ray diffraction techniques. The reflectance and transmittance spectra were examined for blended polymers using a diffused reflectance spectrophotometer. Using LCR meter, the prepared blend films' dielectric properties were evaluated. When the blend is loaded with 0.9ZnMn2O4/0.1CuCo2O4, the lowest transmittance values (29–47 %) in the visible region are reached. As the CuCo2O4 doping levels became 10 % in the filler, the smallest direct and indirect energy gap values of 5.4 and (4.47, 1.9, 1.65) eV were attained, respectively. The linear and nonlinear optical parameters affected by the amount of CuCo2O4 in the filler samples. The optical conductivity of the doped blend reached its maximum value at x = 0.15. The CIE chromaticity diagrams revealed that the blends have varying degrees of blue color. The addition of (1-x)ZnMn2O4/xCuCo2O4 fillers improves the energy storage capability of the blends without raising the energy dissipation. The highest value of AC conductivity was achieved with the blend containing 0.9ZnMn2O4/0.1CuCo2O4. Nyquist plot revealed that the ionic conductivity increased as a result of doping. The obtained results suggest that the doped PVA/CMC/PEG/(1-x)ZnMn2O4/xCuCo2O4 blends might be used in a variety of industrial applications, including solar cell technology.

Spectroscopic Phenological Characterization of Mangrove Communities

Spaceborne spectroscopic imaging offers the potential to improve our understanding of biodiversity and ecosystem services, particularly for challenging and rich environments like mangroves. Understanding the signals present in large volumes of high-dimensional spectroscopic observations of vegetation communities requires the characterization of seasonal phenology and response to environmental conditions. This analysis leverages both spectroscopic and phenological information to characterize vegetation communities in the Sundarban riverine mangrove forest of the Ganges–Brahmaputra delta. Parallel analyses of surface reflectance spectra from NASA’s EMIT imaging spectrometer and MODIS vegetation abundance time series (2000–2022) reveal the spectroscopic and phenological diversity of the Sundarban mangrove communities. A comparison of spectral and temporal feature spaces rendered with low-order principal components and 3D embeddings from Uniform Manifold Approximation and Projection (UMAP) reveals similar structures with multiple spectral and temporal endmembers and multiple internal amplitude continua for both EMIT reflectance and MODIS Enhanced Vegetation Index (EVI) phenology. The spectral and temporal feature spaces of the Sundarban represent independent observations sharing a common structure that is driven by the physical processes controlling tree canopy spectral properties and their temporal evolution. Spectral and phenological endmembers reside at the peripheries of the mangrove forest with multiple outward gradients in amplitude of reflectance and phenology within the forest. Longitudinal gradients of both phenology and reflectance amplitude coincide with LiDAR-derived gradients in tree canopy height and sub-canopy ground elevation, suggesting the influence of surface hydrology and sediment deposition. RGB composite maps of both linear (PC) and nonlinear (UMAP) 3D feature spaces reveal a strong contrast between the phenological and spectroscopic diversity of the eastern Sundarban and the less diverse western Sundarban.

Noncentrosymmetric Crystal [C10H8NO2]2SiF6·H2O with Large Birefringence.

Crystals with noncentrosymmetric structures are applied in many fields, but reported compounds have a high probability of forming a centrosymmetric structure. Here, by hydrogen-bonding the π-conjugated [C10H8NO2]+ cation with the separated [SiF6]2- octahedron, a noncentrosymmetric isoquinoline hexafluorosilicate monohydrate optical crystal of [C10H8NO2]2SiF6·H2O was formed under the regulatory influence of hydrogen bonding. It not only possesses a moderate second harmonic generation response (1.0 × KDP) but also has a large birefringence (0.282 at 550 nm), which is greater than those of most commercial birefringent crystals. In addition, the UV-vis-NIR diffuse reflectance spectrum and thermal stability analysis are also reported. Our finding gives insight into how to design noncentrosymmetric structural compounds in the organic-inorganic system.

Study on the Luminescence Performance and Anti-Counterfeiting Application of Eu2+, Nd3+ Co-Doped SrAl2O4 Phosphor.

This manuscript describes the synthesis of green long afterglow nanophosphors SrAl2O4:Eu2+, Nd3+ using the combustion process. The study encompassed the photoluminescence behavior, elemental composition, chemical valence, morphology, and phase purity of SrAl2O4:Eu2+, Nd3+ nanoparticles. The results demonstrate that after introducing Eu2+ into the matrix lattice, it exhibits an emission band centered at 508 nm when excited by 365 nm ultraviolet light, which is induced by the 4f65d1→4f7 transition of Eu2+ ions. The optimal doping concentrations of Eu2+ and Nd3+ were determined to be 2% and 1%, respectively. Based on X-ray diffraction (XRD) analysis, we have found that the physical phase was not altered by the doping of Eu2+ and Nd3+. Then, we analyzed and compared the quantum yield, fluorescence lifetime, and afterglow decay time of the samples; the co-doped ion Nd3+ itself does not emit light, but it can serve as an electron trap center to collect a portion of the electrons produced by the excitation of Eu2+, which gradually returns to the ground state after the excitation stops, generating an afterglow luminescence of about 15 s. The quantum yields of SrAl2O4:Eu2+ and SrAl2O4:Eu2+, Nd3+ phosphors were 41.59% and 10.10% and the fluorescence lifetimes were 404 ns and 76 ns, respectively. In addition, the Eg value of 4.98 eV was determined based on the diffuse reflectance spectra of the material, which closely matches the calculated bandgap value of SrAl2O4. The material can be combined with polyacrylic acid to create optical anti-counterfeiting ink, and the butterfly and ladybug patterns were effectively printed through screen printing; this demonstrates the potential use of phosphor in the realm of anti-counterfeiting printing.