Resonant Reflection Research Articles

Bragg reflection of linear shallow-water waves by an array of widely spaced trapezoidal bars on a fringing reef flat

A closed-form solution to the linear shallow-water wave equation for wave reflection by a finite periodic array of widely spaced trapezoidal bars on a fringing reef flat is presented. It is shown that, when the total number, height, or top width of the trapezoidal bars increases, the strength of the Bragg resonance increases but the downward shift of the resonance phase becomes more pronounced. When the width of the reef face increases or when the reef face changes from a concave profile to a convex profile, the strength of the Bragg resonance decreases and the downward shift of the resonance phase also becomes more pronounced. Especially, it is found that the location of trapezoidal bars plays an important role in the strength and occurrence condition of the Bragg resonant reflection. Finally, the optimal collocation of the location and width of trapezoidal bars is investigated. Considering both construction cost and reflecting capacity, the relative width is recommended to be within 0.4≤wb/d≤0.6 and the distance from the reef edge to trapezoidal bars is suggested to be equal to the spacing of trapezoidal bars.

Resonances in a single-lead reflection from a disordered medium: [formula omitted]-model approach

Using the framework of supersymmetric non-linear σ-model we develop a general non-perturbative characterization of universal features of the density ρ(Γ) of the imaginary parts (“width”) for S-matrix poles (“resonances”) describing waves incident and reflected from a disordered medium via M-channel waveguide/lead. Explicit expressions for ρ(Γ) are derived for several instances of systems with broken time-reversal invariance, in particular for quasi-1D and 3D media. In the case of perfectly coupled lead with a few channels (M∼1) the most salient features are tails ρ(Γ)∼Γ−1 for narrow resonances reflecting exponential localization and ρ(Γ)∼Γ−2 for broad resonances reflecting states located in the vicinity of the attached wire. For multimode quasi 1D wires with M≫1, an intermediate asymptotics ρ(Γ)∼Γ−3/2 is shown to emerge reflecting diffusive nature of decay into wide enough contacts.

Controlling Electron Delocalization in Vanadium‐Based Hybrid Bronzes through Molecular Templation

AbstractWe show that the conductivity of hybrid vanadium bronzes—mixed‐valence organic–inorganic vanadium oxides—can be tuned over six orders of magnitude through judicious choice of molecular component. By systematically varying the steric profile, charge density, and propensity to hydrogen bond across a series of eight diammonium‐based molecules, we engender multiple distinct motifs of V−O connectivity within the two‐dimensional vanadium oxide layers of a family of bulk crystalline hybrid materials. A combination of single‐crystal and powder X‐ray diffraction analysis, variable‐temperature electrical transport measurements, and a range of spectroscopic methods, including UV/Visible diffuse reflectance, X‐ray photoelectron, and electron paramagnetic resonance are employed to probe how vanadium oxide layer topology correlates with electron localization. Specifically, alkylammonium molecules yield hybrids featuring more corrugated layers that contain V−O tetrahedra as well as a higher ratio of corner‐sharing to edge‐sharing polyhedra and that exhibit highly localized electronic behavior, while alkyl bipyridinium molecules yield more regular layers with polyhedral edge‐sharing that show substantially delocalized electronic behavior. This work allows for the development of design principles based on structure–property relationships and brings the charge transport capabilities of hybrid vanadium bronzes to more technologically relevant levels.

Controlling Electron Delocalization in Vanadium-Based Hybrid Bronzes through Molecular Templation.

We show that the conductivity of hybrid vanadium bronzes-mixed-valence organic-inorganic vanadium oxides-can be tuned over six orders of magnitude through judicious choice of molecular component. By systematically varying the steric profile, charge density, and propensity to hydrogen bond across a series of eight diammonium-based molecules, we engender multiple distinct motifs of V-O connectivity within the two-dimensional vanadium oxide layers of a family of bulk crystalline hybrid materials. A combination of single-crystal and powder X-ray diffraction analysis, variable-temperature electrical transport measurements, and a range of spectroscopic methods, including UV/Visible diffuse reflectance, X-ray photoelectron, and electron paramagnetic resonance are employed to probe how vanadium oxide layer topology correlates with electron localization. Specifically, alkylammonium molecules yield hybrids featuring more corrugated layers that contain V-O tetrahedra as well as a higher ratio of corner-sharing to edge-sharing polyhedra and that exhibit highly localized electronic behavior, while alkyl bipyridinium molecules yield more regular layers with polyhedral edge-sharing that show substantially delocalized electronic behavior. This work allows for the development of design principles based on structure-property relationships and brings the charge transport capabilities of hybrid vanadium bronzes to more technologically relevant levels.

Моделирование режимов генерации двух гиротронов с общим резонансным отражателем

The generation regimes of two gyrotrons with a common narrow-band resonant reflector were studied using numerical simulation in the approximation of a fixed field structure. The dependences of the output power and generation efficiency, frequency and phase of oscillations of each gyrotron on system parameters, such as the driving magnetic field, mutual detuning of the gyrotrons’ eigen frequencies and the phase delay of the reflected wave, have been calculated. Using the example of gyrotrons at a frequency of 28 GHz with an output power of up to 10 kW, the possibility of stabilizing the radiation frequency of two gyrotrons when part of their power is reflected from an external high-Q resonator was demonstrated. It is shown that even if the eigen frequencies of the gyrotron resonators and the delay phases of the reflected wave do not coincide, it is possible to obtain frequency-stable states in which the phase difference of the gyrotrons does not depend on time and on the initial conditions, while the radiation power of each gyrotron exceeds the power of autonomous generation.

Monolithic VECSEL for stable kHz linewidth.

Vertical-external-cavity surface-emitting semiconductor lasers (VECSELs) are of increasing interest for applications requiring ultra-coherence and/or low noise at novel wavelengths; performance that is currently achieved via high-Q, air-spaced resonators to achieve long intra-cavity photon lifetimes (for the so-called class-A low noise regime), power scaling and high beam quality. Here, we report on the development of a compact, electronically tunable, monolithic-cavity, class-A VECSEL (monolithic VECSEL) for ultra-narrow free-running linewidths. A multi-quantum-well, resonant periodic gain structure with integrated distributed Bragg reflector (DBR) was optically-bonded to an air-gap-free laser resonator created inside a right-angle fused-silica prism to suppress the influence of environmental noise on the external laser oscillation, thus achieving high stability. Mode-hop-free wavelength tuning is performed via the stabilized temperature; or electronically, and with low latency, via a shear piezo-electric transducer mounted on the top of the prism. The free-running linewidth, estimated via the frequency power spectral density (PSD), is sub-kHz over ms timescales and <1.9 kHz for time sampling as long as 1s, demonstrating at least two orders-of-magnitude improvement in noise performance compared to previously reported single frequency VECSELs. The stable, total internal reflection resonator concept is akin to the prevalent monolithic non-planar ring oscillator (NPRO), however the monolithic VECSEL has several important advantages: tailored emission wavelength (via semiconductor bandgap engineering), no relaxation oscillations, no applied magnetic field, and low requirements on the pump beam quality. This approach is power-scalable in principle and could be applied to VECSELs at any of the wavelengths from the visible to the mid-infrared at which they are already available, to create a range of robust, ultra-coherent laser systems with reduced bulkiness and complexity. This is of particular interest for remote metrology and the translation of quantum technologies, such as optical clocks, from research laboratories into real world applications.

Study on Thermal Behavior Characteristics and Microstructure Evolution Mechanism of Residual Coal Combustion Process in Deep High Initial Temperature Environment

ABSTRACT The shallow coal seam resources are gradually reduced, the depth of coal seam mining is increased, and the underground temperature is increased, which makes the risk of residual coal fire increase year by year. In order to explore the transformation path of functional groups during oxidation and the caloric release characteristics of residual coal in deep coal mine, the microcosmic changes of coal oxidation process in deep mine were analyzed by in situ diffuse reflectance (In situ FTIR) and electron spin resonance (EPR) experiments, and macroscopic characteristics such as characteristic temperature of residual coal were tested by synchronous thermal analysis experiment. In FTIR results, it is observed that hydroxyl groups, active aliphatic hydrocarbon structures, and active oxygen-containing groups are key chemical structures involved in the oxidation process of residual coal, displaying a strong correlation transformation phenomenon. This can be described as follows: oxygen absorption led to a negative correlation between aliphatic hydrocarbon structures and hydroxyl groups, while the conversion of aliphatic hydrocarbon structures into carboxyl and aldehyde groups resulted in a negative correlation between aliphatic hydrocarbons, carboxyl groups, and aldehyde groups. Active oxygen-containing functional groups showed a positive correlation. With the increased of free radical concentration, the type of free radicals increased and the linewidth (ΔH) increased. The high-temperature environment intensified thermal behavior tendencies, increased the number of active structures, and raised the risk of spontaneous combustion. The research results provided a theoretical basis for understanding the process of coal spontaneous combustion, and had important reference value for ensuring the safe mining of deep coal seams and implementing effective disaster prevention measures.

Enhancement of electrical conductivity associated with non-bridged oxygen defects in molybdenum phosphate oxide glass via doping of SrO

Based on the attractive properties of phosphate glass, improved molybdenum phosphate glasses of composition 40P2O5, 20MoO3, 15MgO, (25-x)Li2O, xSrO, [x = 0, 5, 10, 15 and 20 mol %] were prepared via the melt-quench technique. They were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV–visible reflectance and Electron spin resonance (ESR). FTIR confirmed the existence of several structural phosphate groups other than MoO4 and MoO6 units. Optical analysis revealed the active species of molybdenum ions. SrO addition decreases the bandgap energy, converting the glass insulator features into semiconductor properties. The measured AC electrical conductivity (σac) increased within the temperature range of 298–473(K) and decreased in the frequency range of 0.042 kHz–1 MHz. The estimated DC electrical conductivity increased with temperature, suggesting the semiconducting behavior. The highest electrical conductivity was found in base and 5% SrO samples. Therefore, it appears that the prepared glasses are viable candidates for opto-electronic applications.

Mechanically Induced Anisotropic Fragments in Sn-Doped In2O3 Nanoparticle Films for Flexible Strain Sensing Based on Surface Plasmons.

Recently, mechanical strain sensors have been extensively developed to quantify large mechanical deformations for stretchable and wearable applications. In this study, we propose a plasmonic strain sensor based on the mechanical control of optical properties using an assembled film comprising In2O3: Sn nanoparticles (ITO NP film). The resonant reflectance in the infrared range could effectively be tuned by applying strain to the ITO NP film deposited on an elastomeric polydimethylsiloxane (PDMS) sheet. The change in reflectance was caused by the mechanical deformation of the PDMS sheet. The operating mechanism of the proposed plasmonic strain sensor was related to anisotropic fragments induced by cracks formed perpendicular to the direction of the applied strain. These anisotropic fragments were functionalized as optical modulators to change the reflectance depending on the applied strain. The sensing performance of the proposed plasmonic strain sensor was evaluated by using a PDMS sheet with a circular hole that produced nonuniform stress distributions. Finally, to evaluate the flexible and wearable performance of the proposed sensor, the optical detection of human motion was performed by detecting joint-related movements. The optical detection of human motion could be achieved because a change in motion (e.g., bending and stretching of the index finger) was reversibly associated with reflectance changes. Therefore, this study provides new insights into plasmon-based strain sensing for various applications in flexible instruments and human motion detection.

Light-Induced Intramolecular Electron Transfer in a 1D [CuFe] Coordination Polymer Containing the [Fe(C2O4)3]3- Core.

A one-dimensional (1D) ladder-like coordination polymer {NH4[{Cu(bpy)}2(C2O4)Fe(C2O4)3]·H2O}n (1; bpy = 2,2'-bipyridine) containing [Cu(bpy)(μ-C2O4)Cu(bpy)]2+ cationic units linked by oxalate groups of [Fe(C2O4)3]3- building blocks was investigated as a new type of photoactive solid-state system. It exhibits a photocoloration effect when exposed to direct sunlight or UV/vis irradiation. The photochromic properties and mechanism were studied by powder and single-crystal X-ray diffraction, UV/vis diffuse reflectance, IR and electron paramagnetic resonance spectroscopy, magnetization and impedance measurements, and density functional theory calculations. The process of photochromism involves simultaneous intramolecular electron transfers from the oxalate ligand to Fe(III) and to [CuII(bpy)(μ-C2O4)CuII(bpy)]2+, leading to the reduction of the metal centers to the electronic states Fe(II) and Cu(I), accompanied by the release of gaseous CO2.

Design of VO2-based spacecraft smart radiator with low solar absorptance

Thermochromic film with the ability to self-adaptively switch emittance is important for spacecraft missions experiencing rapidly increasing demand. Current research on thermochromic films primarily focuses on optimizing emittance tunability, while the solar absorptance of these films remains high, limiting their practical application in spacecraft thermal control. In this work, a VO2-based spacecraft smart radiator with low solar absorptance and high emittance tunability is proposed. The smart radiator is a multilayer structured film composed of a switchable resonator (i.e., a superposed Fabry-Perot cavity) and a solar reflector (i.e., a Distributed Bragg Reflector). The performance of the smart radiator is optimized by combining the Rigorous Coupled Wave Analysis method and Genetic Algorithm, achieving a normal solar absorptance of 0.121 and emittance tunability of 0.825. The solar absorptance and emittance tunability of the smart radiator remain excellent even at large incident angles. The underlying mechanisms involved in the smart radiator are attributed to the combination of superposed Fabry-Perot resonance and multiple solar reflectance. In addition, we provide a numerical example using a geosynchronous orbit satellite to demonstrate that the regulation range of the net heat dissipation flux density can increase from 146.5–463.9 W/m2 by using Optical Solar Reflector to 0–494.6 W/m2 when using the proposed smart radiator within the permissible temperature range (263.15–318.15 K) of spacecraft. This VO2-based spacecraft smart radiator with outstanding properties which outperform the existing thermochromic films reveals the promising potential of thermochromic films for spacecraft intelligent thermal control applications.

Coherent control of the photonic spin Hall effect by Er3+ ion concentration in an Er3+-doped YAG crystal

We theoretically investigate the effect of doped Er3+ ion concentration on the spin Hall effect (SHE) of light reflected from a Kretschmann-Raether (K-R) structure. In such a structure, an Er3+-doped yttrium aluminum garnet (YAG) crystal acts as the substrate. The excitation of surface plasmon resonance(SPR) leads to the enhancement of the spin splitting of the reflected beam in the resonance reflection dip. Due to the variation of electric dipole moment and energy level lifetime induced by Er3+ ion concentration, the spin-dependent transverse shift is sensitively dependent upon Er3+ ion concentration. Furthermore, under different concentrations of Er3+ ion, the intensity and detuning of the control field have different effects on the magnitude, sign and position of the transverse shift. More importantly, the photonic SHE can be significantly enhanced via choosing the suitable values of the control intensity and detuning at 15% Er3+ ion concentration. Therefore, our scheme may provide a basis for selecting suitable Er3+ ion concentration to enhance the SHE of light in future integrated systems.

Direct Experimental Observations of Ion Distributions during Overcharging at the Muscovite-Water Interface by Adsorption of Rb+ and Halides (Cl- , Br- , I- ) at High Salinity.

Classical electric double layer (EDL) models have been widely used to describe ion distributions at charged solid-water interfaces in dilute electrolytes. However, the chemistry of EDLs remains poorly constrained at high ionic strength where ion-ion correlations control non-classical behavior such as overcharging, i. e., the accumulation of counter-ions in amounts exceeding the substrate's surface charge. Here, we provide direct experimental observations of correlated cation and anion distributions adsorbed at the muscovite (001)-aqueous electrolyte interface as a function of dissolved RbBr concentration ([RbBr]=0.01-5.8 M) using resonant anomalous X-ray reflectivity. Our results show alternating cation-anion layers in the EDL when [RbBr]≳100 mM, whose spatial extension (i. e., ~20 Å from the surface) far exceeds the dimension of the classical Stern layer. Comparison to RbCl and RbI electrolytes indicates that these behaviors are sensitive to the choice of co-ion. This new in-depth molecular-scale understanding of the EDL structure during transition from classical to non-classical regimes supports the development of realistic EDL models for technologies operating at high salinity such as water purification applications or modern electrochemical storage.

Resonant optical reflection from a GaN/(Al,Ga)N excitonic Bragg structure

We experimentally demonstrate the formation of a superradiant optical mode in the room-temperature reflection spectra from a resonant Bragg structure composed of 30 equidistant GaN quantum wells separated by (Al,Ga)N barriers. The mode arises when the condition of the Bragg diffraction is fulfilled at the wavelength corresponding to the energy of the quasi-two-dimensional excitons in the quantum wells. It manifests itself as a significant increase in the amplitude and a change in the shape of the resonant optical reflection due to the electromagnetic coupling of the excitons. By modeling of the optical spectra, we evaluate the radiative and non-radiative broadening parameters of the excitonic states in the GaN quantum wells, which appear to be 0.4 ± 0.02 and 40 ± 5 meV, correspondingly, for the resonant exciton energy of 3.605 eV. The resonant Bragg structure based on the periodic sequence of the GaN quantum wells demonstrates an efficient coupling of photons and excitons at room temperature, which makes it promising for device applications.

Non-uniform Gd distribution and magnetization profiles within GdCoFe alloy thin films

Rare earth (RE):transition metal (TM) ferrimagnetic alloys continue to attract significant attention for spintronics. This work focuses on the elemental distribution of RE and TM elements throughout the thickness of nominally uniform films and the resulting spatial variations of the magnetization within these layers. Samples of CoFe alloyed with Gd were studied using secondary ion mass spectroscopy, polarized neutron reflectometry, and x-ray resonant magnetic reflectivity. The samples were grown by magnetron co-sputtering to control the RE:TM alloy ratio of the ferrimagnetic layer, which was combined with W and Pt layers as either under or over-layers to create sample structures such as W/Gdx(Co70Fe30)100−x/Pt, where x = 0, 8, and 23 at. %. Results show that uniformly deposited thin-films have a significant variation in the distribution of the TM and RE through the film thickness, and this leads to a spatial distribution in the net magnetization profile and a non-uniform Gd magnetization profile within the layer. These findings have implications for the application RE:TM alloys in spintronics as they may impact the perpendicular magnetic anisotropy, the ferrimagnetic compensation temperature, and interfacial spin transport.

Modeling the Propagation of Fast Magnetosonic Waves and Their Conversion to Electromagnetic Ion Cyclotron Waves at Low L Shells

AbstractThe propagation of fast magnetosonic (MS) waves from high to extremely low L shells and their conversion into electromagnetic ion cyclotron (EMIC) waves is investigated with a ray tracing model and a full‐wave model. The ray tracing simulations show that MS waves in the vicinity of the local crossover frequency at low L shells have a latitudinal range from to with wave normal angles from to , both of which provide the opportunity for their mode conversion to EMIC waves. Results from ray tracing are fed into the full‐wave model as initial conditions. The full‐wave simulations show that the incoming MS waves with small () and intermediate () wave normal angles may be efficiently converted to right‐handedly polarized band EMIC waves, which may be further converted to right‐handedly polarized band EMIC waves or to guided left‐handedly polarized band EMIC waves through bi‐ion resonance reflection and polarization reversal. With intermediate () or larger wave normal angles, via polarization reversal and left‐handed polarization cut‐off reflection, the incoming MS waves may be efficiently converted to guided left‐handedly polarized band EMIC waves and the optimal wave normal angles corresponding to the maximum conversion efficiencies decrease with magnetic latitudes. Our study verifies the mode conversion mechanism of MS waves to EMIC waves proposed with a previous ray tracing study and examines the dependence of the efficiency of the wave energy transfer on the magnetic latitudes and wave normal angles, which may help to understand the wave properties and distribution of MS and EMIC waves observed at extremely low L shells.

3D Architectural MXene‐based Composite Films for Stealth Terahertz Electromagnetic Interference Shielding Performance

AbstractThe terahertz frequency range is gaining popularity in security, stealth technology, and the future 6G network communication. For the control of severe terahertz electromagnetic interference (EMI) pollution, frequency‐selective stealth‐capable shielding materials are being explored to mask terahertz signals. For the realization of masking terahertz signals, the robustness, lightweight, and shape‐conformable materials with excellent terahertz EMI shielding/absorption are crucial. Here, the study reports the fabrication of 3D symmetric pyramidal architectural MXene composite films with frequency‐selective stealth performance characteristics via the facile drop casting method. With the high absorption capability of 2D MXene layers, the MXene composite films exhibit substantial terahertz stealth performance. 3D pyramidal microstructure design leads to frequency selective surface‐assisted reflection resonance in the frequency range of 0.6–1.1 THz. The MXene composite film demonstrates an outstanding maximum terahertz shielding effectiveness (SE) of up to 70.4 dB and a specific SE of 0.55 dB µm−1. These terahertz SE values exceed all of those for MX‐based shielding material designs reported in the literature. The investigation will open a new direction toward developing terahertz EMI shielding thin films with easy integration into any surface for stealth capabilities.

Integrated microcavity optomechanics with a suspended photonic crystal mirror above a distributed Bragg reflector.

Increasing the interaction between light and mechanical resonators is an ongoing endeavor in the field of cavity optomechanics. Optical microcavities allow for boosting the interaction strength through their strong spatial confinement of the optical field. In this work, we follow this approach by realizing a sub-wavelength-long, free-space optomechanical microcavity on-chip fabricated from an (Al,Ga)As heterostructure. A suspended GaAs photonic crystal mirror is acting as a highly reflective mechanical resonator, which together with a distributed Bragg (DBR) reflector forms an optomechanical microcavity. We demonstrate precise control over the microcavity resonance by change of the photonic crystal parameters. We find that the microcavity mode can strongly couple to the transmissive modes of the DBR. The interplay between the microcavity mode and a guided resonance of the photonic crystal modifies the cavity response and results in a stronger dynamical backaction on the mechanical resonator compared to conventional optomechanical dynamics.

Glucose Concentration Monitoring Using Microstrip Spurline Sensor

Abstract This article reports a microstrip spurline sensor for glucose concentration monitoring. The microstrip spurline sensor is a low-cost and easy-to-fabricate device that uses printed circuit board (PCB) technology. It consists of a combination of four spurlines and transmission lines. The four spurlines are used to reject unwanted frequencies, while the transmission lines allow the desired frequencies to pass through. The resonance frequency (Fr) and reflection coefficient (S11) were recorded through meticulous simulations and experiments over a frequency range from 1.5 GHz to 4 GHz. In addition, the sensor was used to detect changes in glucose concentration, ranging from 0 mg/dL to 150 mg/dL. The findings of this study show that the antenna-based sensor proposed in this research can effectively measure glucose levels across the diabetes range, from hypoglycemia to normoglycemia to hyperglycemia, with a high degree of sensitivity of 7.82 x 10−3 dB/(mg/dL) and 233.33 kHz/(mg/dL).

Mechanically Driven Solidly Mounted Resonator‐Based Nanoelectromechanical Systems Magnetoelectric Antennas

The miniaturization of antennas has been a significant challenge in the field of electronics and telecommunications. In recent years, mechanically driven thin‐film bulk acoustic resonator (FBAR) magnetoelectric (ME) antennas have emerged as a promising solution, demonstrating superior miniaturization capabilities compared to conventional state‐of‐the‐art compact antennas. While nanoelectromechanical systems (NEMS) FBAR ME antennas exhibit high miniaturization potential, their suspended thin‐film heterostructures render them fragile and exhibit low power handling capabilities. The findings demonstrate that solidly mounted resonator (SMR) NEMS ME antennas on a Bragg acoustic resonant reflector offer a compelling solution. With a circular resonating disk of 200 μm diameter operating at 1.75 GHz, these SMR‐based antennas display a high antenna gain of −18.8 dBi and a 1 dB compression point (P1dB) of 30.4 dBm. Compared to same‐size FBAR ME antennas with a free‐standing membrane, SMR‐based antennas exhibit significantly higher structural stability and 23.3 dB stronger power handling capability, in addition to easier fabrication processes. The compatibility of the simple fabrication processes with complementary metal–oxide–semiconductor technology, along with the dramatic miniaturization, high power handling, robust mechanical properties, and much higher antenna radiation gain, make these SMR‐based ME antennas a promising candidate for future antenna systems.