Metal heat pipe evacuated collector tube (ECT) suffer from cracks in the joint between the glass outer layer and the metal heat pipe due to the large difference in thermal expansion coefficients of glass and metal, resulting in non-industrialization. In this paper, the metal heat pipe is replaced with a glass heat pipe to form an all-glass heat pipe ECT to address the air-tight sealing problem, and a reflective film was added to the lower part of the outer tube to improve energy. According to these results, the thermal stress of 0.279 MPa is well below the bearing range of 40–120 MPa, and the maximum thermal strain of 0.175 mm/mm is also far less than the affordable value of 120 mm/mm, inducting the all-glass structure fully copes with the transient local heating changes. The optical efficiency is increased by 0.17 % by the addition of the reflective film, and yielding an energy output of 87 W and a maximum volume fraction of 4.8 % for liquid–water in the quasi-thermal equilibrium state. At the same time, the evaporation operating speed of the vapor can be increased by improving the solar radiation flux density and reducing thermal losses, and optimizing the multi-level and cross-scale vapor vortices can also improve the convective heat transfer rate, so they are future directions for development. However, there are the limitations of decreasing the thermal conductivity and increases the resistance due to the heat pipe conversion from metal to glass.