Plots of dispersion versus absorption (DISPA) in NMR have previously been shown to provide an extremely sensitive test for deviations from Lorentzian lineshape. In this paper, the experimental absorption derivative EPR spectrum of peroxylamine disulfonate (PADS) is digitized during field-sweep detection and numerically integrated to give an absorption spectrum, which is then numerically Hilbert transformed to yield a dispersion spectrum, and in turn a DISPA plot. The effect of field modulation is demonstrated both theoretically and experimentally to produce an EPR DISPA curve whose displacement outside its reference circle is directly related to the strength of the modulating field. The modulating field strength can thus be determined without external calibration, using a single DISPA plot. In addition, DISPA detection of small lineshape distortions resulting from field sweep at rates faster than are appropriate to the time constant of the phase-sensitive detector is demonstrated experimentally. Finally, the circular DISPA plot for PADS at high concentration readily illustrates the homogeneous nature of the line broadening, again from a single EPR spectrum. These results show that the DISPA technique can be used, even when only the absorption spectrum is experimentally available.
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