For the nonequilibrium flowfield and high-temperature gas radiation spectral characteristics of the hypersonic reentry capsule, a spectral prediction method based on quasi-steady-state assumption and line-by-line method is introduced. Meanwhile, the characteristics of the spectrum are studied to investigate the influence of viewing angles and trajectory points during reentry based on this method. We use Fire II flight test data to verify the accuracy of the gas radiation model and update the prediction values of the cumulative radiation intensity in the wavelength range of 2.2–4.1 eV by previous methods. The results show that the radiation signal is most significant at the stagnation line and gradually decreases with the deviation of the line of sight from the stagnation line. The cumulative radiation intensity of the various trajectory points exhibits a profile that increases and then decreases during reentry; it rises to its peak at 50 km. The emission spectrum of gas radiation is mainly distributed in the ultraviolet and near-infrared bands. The transition processes of atoms N and O contribute more than 90% of the total radiation intensity, and the contribution of the first negative series in the molecular spectrum is relatively considerable compared to other molecular components.