Reduction Potential Research Articles

Potential of Progressive and Disruptive Innovation-Driven Cost Reductions of Green Hydrogen Production

Potential of Progressive and Disruptive Innovation-Driven Cost Reductions of Green Hydrogen Production

A critical review of biochar as an environmental functional material in soil ecosystems for migration and transformation mechanisms and ecological risk assessment.

At present, biochar has a large application potential in soil amelioration, pollution remediation, carbon sequestration and emission reduction, and research on the effect of biochar on soil ecology and environment has made positive progress. However, under natural and anthropogenic perturbations, biochar may undergo a series of environmental behaviors such as migratory transformation, mineralization and decomposition, and synergistic transport, thus posing certain potential risks. This paper outlines the multi-interfacial migration pathway of biochar in "air-soil-plant-animal-water", and analyzes the migration process and mechanism at different interfaces during the preparation, transportation and application of biochar. The two stages of the biochar mineralization process (mineralization of easily degradable aliphatic carbon components in the early stage and mineralization of relatively stable aromatic carbon components in the later stage) were described, the self-influencing factors and external environmental factors of biochar mineralization were analyzed, and the mineral stabilization mechanism and positive/negative excitation effects of biochar into the soil were elucidated. The proximity between field natural and artificially simulated aging of biochar were analyzed, and the change of its properties showed a trend of biological aging>chemical aging>physical aging>natural aging, and in order to improve the simulation and prediction, the artificially simulated aging party needs to be changed from a qualitative method to a quantitative method. The technical advantages, application scope and potential drawbacks of different biochar modification methods were compared, and biological modification can create new materials with enhanced environmental application. The stability performance of modified biochar was compared, indicating that raw materials, pyrolysis temperature and modification method were the key factors affecting the stability of biochar. The potential risks to the soil environment from different pollutants carried by biochar were summarized, the levels of pollutants released from biochar in the soil environment were highlighted, and a comprehensive selection of ecological risk assessment methods was suggested in terms of evaluation requirements, data acquisition and operation difficulty. Dynamic tracing of migration decomposition behavior, long-term assessment of pollution remediation effects, and directional design of modified composite biochar materials were proposed as scientific issues worthy of focused attention. The results can provide a certain reference basis for the theoretical research and technological development of biochar.

Development of soft magnetic composites for magnetized pavement to improve the efficiency of electric vehicle’s wireless power transfer

Integrating the wireless power transfer (WPT) system into the pavement is an effective way to solve the inconvenience of electric vehicles (EVs)’ charging, accelerating the growth of ownership of EVs to achieve net carbon zero in transportation. However, the existence of a cement paving layer between coils was a negative impact factor. Here, two types of ferrite powders were separately mixed into the cement to prepare soft magnetic composite (SMC) material to enhance the coupling degree of coils. The magnetic and mechanical performance of the composite were tested by a vibrating sample magnetometer and compressive and flexural strength tester. Furthermore, to explore the optimal layout of the magnetized pavement structure, nine pavement layouts were designed based on the distribution of magnetic flux. Finally, the effect of SMC material on improving the charging performance was verified by WPT system test platform. Results showed that the Ni-Zn ferrite powder exhibited superior magnetic permeability due to its stronger magnetic moments and lower magnetic domain wall energy compared to Mn-Zn ferrite powder. The peak relative permeability of SMC materials reached 14.370 with an equal mass ratio of Ni-Zn ferrite powder to cement. Conversely, optimal strength was attained with a Mn-Zn ferrite to cement ratio of 0.2, resulting in a compressive strength of 36 MPa and a flexural strength of 4.0 MPa. Strategically placing SMC within the pavement, both in the core's interior and exterior to the coil, enhanced the coupling coefficient of coils, thereby improving the transmission efficiency of the WPT system. The incorporation of Ni-Zn ferrite powder in a 1:1 mass ratio to cement materialized the highest efficiency. Nonetheless, considering the mechanical performance, the SMC material with a 0.6 mass ratio of Mn-Zn ferrite powder to cement was recommended for magnetized pavements. The WPT system test results showed a transmission efficiency of 89.78% when utilizing magnetized pavement, surpassing the efficiency with the whole pavement material by 1.36%, which indicated great value and potential in energy conservation and carbon reduction of employing magnetized pavement in WPT technology.

Valorizing inherent resources from waste streams for in-situ CO2 capture and sequestration in the steel industry

The imperative need for decarbonization within the energy-intensive steel industry, a pivotal sector for meeting global warming mitigation targets, underscores the significance of deploying cost-effective CO2 capture and sequestration (CCS) measures. The substantial external costs and resource consumption associated with traditional CCS methods present practical challenges. Here, we proposed a pragmatic strategy to integrate CCS into the steel industry through recycling inherent resources from steelmaking waste streams for in-situ CCS (ICCS). The composites prepared from blast furnace slag (BFS) and steel slag (SS) demonstrated the capacity to capture a maximum of 2.77 mol/kg of CO2 from the simulated flowing flue gas at 75 °C, and the energy required could be sourced from steelmaking waste heat. Comprehensive characterizations revealed the evolution of phase compositions and pore structures in different BFS/SS-incorporated composites, providing insights into accelerating the carbonation by elevating temperatures and SS dosages. Notably, ICCS strategy was validated to offer significant potential in CO2 emission reduction (up to −570.0 kg CO2e/t) normalized by compressive strength of the conventional construction materials. Overall, ICCS strategy can minimize the external resource consumption and additional units for implementing collaborative waste recycling in the steel industry with significant environmental benefits.

Is a 15-Minute City Within Reach? Measuring Multimodal Accessibility and Carbon Footprint in 12 Major American Cities

Enhanced efforts in the transportation sector should be implemented to mitigate the adverse effects of CO2 emissions resulting from zoning-based planning paradigms. The concept of a 15-minute city, emphasizing proximity-based planning, holds promise in reducing unnecessary travel and progressing towards carbon neutrality. However, a critical research question remains inadequately explored: to what extent is the 15-minute city concept feasible for American cities? This paper presents a comprehensive framework to evaluate the 15-minute city concept using SafeGraph Point of Interest (POI) check-in data across 12 major American cities. Our findings suggest a prevailing reliance on cars among residents due to the spatial distribution of essential activities beyond convenient walking, cycling, and public transit distances. Nevertheless, there exists significant promise for realizing the 15-minute city vision, given that most residents' daily activities can be accommodated within a 15-minute radius by low-emission modes transportation modes. When comparing cities, it appears that achieving a 15-minute walking city is more feasible for metropolises like New York City, San Francisco, Boston, and Chicago, while proving to be challenging for cities such as Atlanta, Dallas, Houston, and Phoenix. In examing inter-group comparisons, neighborhoods with higher proportion of White residents and higher median incomes tend to have more accessible POIs, with a substantial percentage of activities concentrated within a 15-minute radius. This demographic also shows a greater propensity to fulfill daily activities through walking, cycling, or public transit trips within a 15-minute travel time, thus presenting a greater potential in CO2 reduction compared to African Americans. This study can offer policymakers insight into how far American cities are away from the 15-minute city concept. It also highlights the potential CO2 emissions reductions that could be achieved through successful implementation.

Exploring the Volatile Composition and Antibacterial Activity of Edible Flower Hydrosols with Insights into Their Spontaneous Emissions and Essential Oil Chemistry.

In the circular economy framework, hydrosols, by-products of the essential oil industry, are gaining attention for their potential in waste reduction and resource reuse. This study analyzed hydrosols from six edible flowers, investigating their chemical composition (VOC-Hyd) and antibacterial properties alongside volatile organic compounds of fresh flowers (VOC-Fs) and essential oils (EOs). Antirrhinum majus exhibited ketones as major VOC-Fs (62.6%) and VOC-Hyd (41.4%), while apocarotenoids dominated its EOs (68.0%). Begonia cucullata showed alkanes (33.7%) and aldehydes (25.7%) as primary VOC-Fs, while alkanes were prevalent in both extracts (65.6% and 91.7% in VOC-Hyd and in EOs, respectively). Calandula officinalis had monoterpenoids in VOC-Fs and VOC-Hyd (89.3% and 49.7%, respectively), while its EOs were rich in sesquiterpenoids (59.7%). Dahlia hortensis displayed monoterpenoid richness in both VOC-Fs and extracts. Monocots species' VOC-Fs (Polianthes tuberosa, Tulbaghia cominsii) were esters-rich, replaced by monoterpenoids in VOC-Hyd. P. tuberosa EO maintained ester richness, while T. cominsii EOs contained a significant percentage of sulfur compounds (38.1%). Antibacterial assays indicated comparable minimum inhibitory concentration profiles across VOC-Hyd: B. calcullata and P. tuberosa against Staphylococcus aureus and Salmonella enterica ser. typhimurium, T. cominsii against Escherichia coli and S. enterica, A. majus and C. officinalis against S. aureus, and D. hortensis against S. enterica.

Enhanced performance of attapulgite-supported g-C3N4 for photocatalytic CO2 reduction

As a new type of non-metallic semiconductor photocatalyst, g-C3N4 has great potential in photocatalytic CO2 reduction. However, due to the low catalytic activity, it is still far from industrial reality for such applications. Herein, this work introduces attapulgite (ATP) into the photocatalyst system of g-C3N4. Additionally, ATP/Au-CN was obtained through the photodeposition method. The photocatalytic reduction ability of the photocatalyst for CO2 is enhanced. The photoelectric tests show that loading of ATP can promote the separation and migration of photocarriers. Through BET testing, it was found that the alkaline pore structure on the surface of ATP not only captures CO2, but also increases the specific surface area of the composite. According to the experimental results, the possible photocatalytic mechanism was verified by in-situ diffuse reflection infrared Fourier transform (DRIFT) spectral analysis and DFT calculation. This work provides new guidance for the construction of high efficient photocatalyst systems using abundant ATP as a support.

Heated tobacco products: Potentials of harm reduction, improvement of indoor air quality and the need for further studies

Air pollution is a major concern in the Philippines, with indoor and outdoor air pollution among the highest causes of mortality in the country. However, the latest regulations deal only with ambient outdoor air pollution. Indoor air pollution is seldom monitored or studied. Most of the official government monitoring data also deal with outdoor air pollution even if Filipinos spend more than 80% of their time indoors. Smoking indoors can be a cause of excess air pollutants in the indoor setting. Heated Tobacco products, newly introduced in the country, have been reported to reduce the harm of exposure to users to air pollutants. We investigated this through the review of 282 studies, research papers, books, and narratives about HTP use and their effects. These studies show reduced release of harmful and potentially harmful compounds (HPHC) in the aerosol and lower concentrations of HPHCs in the indoor environment when using HTPs as compared to tobacco smoke. Short term pre-clinical studies also show a reduction in the biomarkers for potential exposure to these HPHCs and risk calculations have shown a reduction in cancer potencies across populations. While long-term epidemiological studies are still required to determine with finality the risks that HTP use may have, there is already wide agreement in the initial results that the complete switch to HTP use from cigarette smoking presents less risks of harm. The review, however, shows that much has to be studied about the manner by which HTPs can affect indoor air quality in tropical countries such as the Philippines.

Investigating the Mixture Quality in Multi-Injector Burner Systems, Part II: Model Application

Abstract Multi-injector burner systems offer a high spatial-temporal mixture homogeneity due to their small size and thus have a high NOx emission reduction potential at increasing flame temperatures. This potential is reduced due to the sensitivity of the mixing quality to inflow distortions caused by the flow path in the burner head. A deep understanding of the link between the inflow conditions and the mixture quality helps to optimize the flow field upstream of the injectors within the spatial and pressure loss constraints of gas turbine combustors to obtain minimal NOx emissions. This paper presents a new model approach for determining the mixture quality in multi-injector burners with output-based proper orthogonal decomposition (O-POD). The sensitivity to the inflow distortion is considered with the so-called observable vector, which describes the injector inflow conditions and is given as model input. The target quantity is the probability mass function (PMF) of the equivalence ratio at the injector outlet. This model allows a fast estimation of the mixing PMF for arbitrary inflow conditions, which is otherwise only accessible with complex time-resolved experimental or numerical approaches. The performance of the model was demonstrated with 21 reference datasets, for which a good agreement between the experimental results and the model output was obtained.

Bead milling liberates the antioxidant properties of nanosized tubers of Vernonia guineensis Benth (Asteraceae)

Vernonia guineensis Benth. (Asteraceae), locally known as ‘African ginseng’, is an herbaceous plant with various therapeutic properties, sold by herbalists, and used in several traditional African preparations. Nanosizing has the capability to potentiate those preparations in their pharmacological properties. Premilling and extensive grinding using a planetary ball mill were used to reduce the size of V. guineensis tubers towards antioxidant studies. Water was used as an environmental friendly, cost effective solvent and dispersant to generate a nanocolloidal suspension of V. guineensis tubers. Size and size distribution were determined via photon correlation spectroscopy at room temperature which allows discussion on stability by Zeta potential and polydispersity index. Phytochemical screening shows presence of alkaloids, coumarins, polyphenol, saponins, tanins, terpenes, and anthraquinones. The distribution curve in water shows a polydispersed system with large hydrodynamic particles of size close to 1000 nm and a Z-average of 484.5 nm. The preparation separate in two phases with polydispersity index 0.217 for the supernatant and 0.543 for the suspension. In the supernatant and suspension, the particles zeta potential were -12.3 mV and -13.7mV respectively. The Mastersizer analysis indicates that there are smaller particles in volume in the supernatant than in the suspension. The 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging capacity shows an increase in antioxidant activity, compared to that of ascorbic acid, in the nanoformulated state. These findings allow us to conclude on the potential of size reduction when compared to solvent extraction in pharmacologic preparations.

Multi-objective optimization of the performance for a marine methanol-diesel dual-fuel engine

Marine methanol-diesel compound combustion (DMCC) engines have received extensive attention in the shipping industry. This work aims to further improve the performance and evaluate the carbon reduction potential of the marine DMCC engine. First, the computational fluid dynamic model of the dual-fuel engine was built. Then, an intelligent regression method based on the grey wolf optimizer (GWO) algorithm optimized support vector machine regression (SVR) was proposed. The methanol substitution rate (MSR), excess air ratio (EAR), and diesel injection timing (DIT) were adopted as the decision variables to establish the regression models for NOx, CO, and CO2 emissions and indicated specific fuel consumption (ISFC). Subsequently, a multi-objective grey wolf optimizer (MOGWO) and entropy weight TOPSIS were employed to obtain the optimal case for achieving low NOx and CO emissions and ISFC. Finally, the maximum MSR was explored to achieve greater carbon reduction benefits while balancing the NOx emission and ISFC. The results showed that after GWO optimization, the coefficients of determination of the SVR regression models are all greater than 0.95, with mean square errors consistently below 0.015. It indicates that the regression models have excellent consistency and applicability. The optimal case calculated by MOGWO and entropy-weighted TOPSIS enables co-optimization of the NOx emission and ISFC while maintaining the CO emission below 600 ppm. Compared to the original case, the optimal case achieves reductions of 26.22 % for NOx and 13.39 % for ISFC. The exploration of the maximum MSR reveals that in the Pareto optimal set, the maximum MSR reaches 56.16 %, at which point the NOx and CO2 emissions reduce by 75.85 % and 59.32 % respectively, while the ISFC increases by 21.67 % compared to the original case.

Effect of Biochar Types and Rates on SOC and Its Active Fractions in Tropical Farmlands of China

To date, most studies have shown that biochar has great potential in carbon sequestration and reduction, as well as soil quality improvement. However, there is limited knowledge of its effect on soil organic carbon (SOC) fractions in tropical farmland. This study aimed to determine the impact of different types and rates of biochar applied in tropical farmlands on so SOC and its active fractions. The SOC, microbial biomass carbon (MBC), dissolved organic carbon (DOC), and soil mineralizable carbon (SMC) in the 0–30 cm soil layers under rice hull (R) and peanut shell (P) biochar treatments were measured. The results showed that the application of R and P biochar increased the contents, stocks, and cumulative stocks of SOC, MBC, and DOC in the 0–10 cm, 10–20 cm, and 20–30 cm soil layers. The contents, stocks, and cumulative stocks increased with increasing biochar application rates. Compared with CK, the ranges of the increased SOC, MBC, and DOC cumulative stocks were 10.76–46.36%, 30.04–195.65%, and 0.02–17.03%, respectively. However, the R60 and P60 had the lowest cumulative stocks of SMC, decreasing by 14.69% and 8.05%, respectively. The biochar treatment of more than 20 t ha−1 reduced the ratio of SMC:SOC and active fractions:SOC. Therefore, it can be inferred that the application of biochar improved the levels of SOC, MBC, and DOC, and the application of more than 20 t ha−1 biochar could decrease soil carbon mineralization, thus improving the stability of SOC in tropical farmlands.

Co-ZIF-derived dual Co and Co3S4 nanoparticles encapsulated in N-doped carbon matrix for efficient photocatalytic CO2 reduction

In this study, a novel N-doped carbon-coated dual Co and Co3S4 nanoparticles composite (Co-Co3S4@NC) has been developed by pyrolysis of an ideal flower-like Co-ZIF precursor followed via subsequent hydrothermal sulfidation. Under visible-light irradiation, the Co-Co3S4@NC exhibits outstanding performances for CO2 reduction with H2O vapor into CO (23.14 μmol g−1 h−1) and CH4 (0.62 μmol g−1 h−1) in a continuous flow system, significantly outperforming the single Co@NC photocatalyst. The experimental results demonstrate that the energy band structure in Co-Co3S4@NC can provide a more favorable reduction potential for the effective reduction of CO2. Moreover, the presence of Co3S4 is beneficial for the rapid separation and transfer of charges, thereby enhancing the utilization of photogenerated charge carriers. Thanks to its unique composition, Co-Co3S4@NC possesses abundant active sites for chemisorption and activation of CO2, which facilitates CO2 photoreduction. The reaction mechanism is revealed in detail by analyzing the key intermediate species obtained through in situ DRIFTS. The current work offers a facile route for the construction of MOF-derived composites for promising photocatalytic reactions.

Synthesis and Crystallographic Characterization of Heteroleptic Ir(III) Complexes Containing the N-oxide Functional Group and Crystallographic Characterization of Ir(III) N-oxide Precursors

The N-oxide functional group has been exploited for synthetic strategies and drug design, and it has been utilized in imaging agents. Herein, we present rare examples of neutral heteroleptic cyclometallated Ir(III) compounds that contain an uncoordinated N-oxide functional group. These species, along with others described within, were verified by NMR, EA, HRMS, and single-crystal X-ray analysis. N-oxide-containing Ir(III) species were prepared selectively in high yields > 66% from chloro-bridged Ir(III) dimers with Acipimox, a picolinate-type ligand containing the N-oxide functional group. Non-N-oxide analogs were synthesized in a similar fashion (yields > 77%). Electrochemical comparison (cyclic voltammetry) indicates that the presence of an N-oxide functional group anodically shifts the reduction potential, suggesting that the N-oxide is acting as an electron-withdrawing group in these species. Crystallographic studies were pursued to examine the coordination behavior of these N-oxides compared to their non-oxidized congeners. The Ir(III) complexes with Acipimox indeed leave the N-oxide uncoordinated and exposed on the complexes. The uncoordinated N-oxide group is influential in directing the packing structures of these complexes directly through C-H···O and O···π interactions at the N-oxide. The crystallographic characterization of cationic Ir(III) compounds with uncoordinated nitrogen atoms is also presented. The C-H···N interactions between these complexes form a variety of dimers, finite chains, and continuous chains. Future work will focus on functionalizing the cationic Ir(III) species into their corresponding N-oxide derivatives and rigorously characterizing how the N-oxide functional group impacts the optical properties of transition metal compounds in both cationic and neutral complexes.

A Novel Homoconjugated Propellane Triimide: Synthesis, Structural Analyses, and Gas Separation.

Rigid three-dimensional (3D) polycyclic propellanes have garnered interest due to their unique conformational spaces, which display great potential use in selectivity, separation and as models to study through-space electronic interactions. Herein we report the synthesis of a novel rigid propellane, trinaphtho[3.3.3]propellane triimide, which comprises three imide groups embedded on a trinaphtho[3.3.3]propellane. This propellane triimide exhibits large bathochromic shift, amplified molar absorptivity, enhanced fluorescence, and lower reduction potential when compared to the subunits. Computational and experimental studies reveal that the effective through-space π-orbitals interacting (homoconjugation) occurs between the subunits. Single-crystal XRD analysis reveals that the propellane triimide has a highly quasi-D3h symmetric skeleton and readily crystallizes into different superstructures by changing alkyl chains at the imide positions. In particular, the porous 3D superstructure with S-shaped channels is promising for taking up ethane (C2H6) with very good selectivity over ethylene (C2H4), which can purify C2H4 from C2H6/C2H4 in a single separation step. This work showcases a new class of rare 3D polycyclic propellane with intriguing electronic and supramolecular properties.

A Novel Homoconjugated Propellane Triimide: Synthesis, Structural Analyses, and Gas Separation

AbstractRigid three‐dimensional (3D) polycyclic propellanes have garnered interest due to their unique conformational spaces, which display great potential use in selectivity, separation and as models to study through‐space electronic interactions. Herein we report the synthesis of a novel rigid propellane, trinaphtho[3.3.3]propellane triimide, which comprises three imide groups embedded on a trinaphtho[3.3.3]propellane. This propellane triimide exhibits large bathochromic shift, amplified molar absorptivity, enhanced fluorescence, and lower reduction potential when compared to the subunits. Computational and experimental studies reveal that the effective through‐space π‐orbitals interacting (homoconjugation) occurs between the subunits. Single‐crystal XRD analysis reveals that the propellane triimide has a highly quasi‐D3h symmetric skeleton and readily crystallizes into different superstructures by changing alkyl chains at the imide positions. In particular, the porous 3D superstructure with S‐shaped channels is promising for taking up ethane (C2H6) with very good selectivity over ethylene (C2H4), which can purify C2H4 from C2H6/C2H4 in a single separation step. This work showcases a new class of rare 3D polycyclic propellane with intriguing electronic and supramolecular properties.

In Situ Growth of Interfacially Nanoengineered 2D-2D WS2/Ti3C2Tx MXene for the Enhanced Performance of Hydrogen Evolution Reactions.

In line with current research goals involving water splitting for hydrogen production, this work aims to develop a noble-metal-free electrocatalyst for a superior hydrogen evolution reaction (HER). A single-step interfacial activation of Ti3C2Tx MXene layers was employed by uniformly growing embedded WS2 two-dimensional (2D) nanopetal-like sheets through a facile solvothermal method. We exploited the interactions between WS2 nanopetals and Ti3C2Tx nanolayers to enhance HER performance. A much safer method was adopted to synthesize the base material, Ti3C2Tx MXene, by etching its MAX phase through mild in situ HF formation. Consequently, WS2 nanopetals were grown between the MXene layers and on edges in a one-step solvothermal method, resulting in a 2D-2D nanocomposite with enhanced interactions between WS2 and Ti3C2Tx MXene. The resulting 2D-2D nanocomposite was thoroughly characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman, Fourier transform infrared (FTIR), and X-ray photoelectron spectroscopy (XPS) analyses before being utilized as working electrodes for HER application. Among various loadings of WS2 into MXene, the 5% WS2-Ti3C2Tx MXene sample exhibited the best activity toward HER, with a low overpotential value of 66.0 mV at a current density of -10 mA cm-2 in a 1 M KOH electrolyte and a remarkable Tafel slope of 46.7 mV·dec-1. The intercalation of 2D WS2 nanopetals enhances active sites for hydrogen adsorption, promotes charge transfer, and helps attain an electrochemical stability of 50 h, boosting HER reduction potential. Furthermore, theoretical calculations confirmed that 2D-2D interactions between 1T/2H-WS2 and Ti3C2Tx MXene realign the active centers for HER, thereby reducing the overpotential barrier.

Sodium Citrate Electrolyte Additive to Improve Zinc Anode Behavior in Aqueous Zinc-Ion Batteries

Despite features of cost-effectiveness, high safety, and superior capacity, aqueous zinc-ion batteries (ZIBs) have issues of uncontrolled dendritic cell failure and poor Zn utilization, resulting in inferior cycling reversibility. Herein, the environmentally friendly and naturally abundant sodium citrate (SC) was adopted as a dual-functional additive for ZnSO4-based (ZSO) electrolytes. Owing to the abundant hydrogen-bond donors and hydrogen-bond acceptors of SC, the Zn2+-solvation shell is interrupted to facilitate Zn desolvation, resulting in inhibited corrosion reactions. Additionally, sodium ions (Na+) from the SC additive with a lower effective reduction potential than that of zinc ions (Zn2+) form an electrostatic shield inhibiting the formation of initial surface protuberances and subsequent Zn dendrite growth. This assists in the Zn three-dimensional (3D) diffusion and deposition, thereby effectively enhancing cycling stability. Specifically, a long cycling lifespan (more than 760 h) of the Zn//Zn symmetric cell is achieved with a 2 M ZSO-1.0 SC electrolyte at a current density of 1 mA cm−2. When coupled with the NaV3O8·1.5 H2O (NVO) cathode, the full battery containing SC additive exhibited a capacity retention rate (40.0%) and a cycling life of 400 cycles at a current density of 1 A g−1 compared with that of pure ZnSO4 electrolyte (23.8%). This work provides a protocol for selecting an environmentally friendly and naturally abundant dual-functional electrolyte additive to achieve solvation shell regulation and Zn anode protection for the practical large-scale application of ZIBs.

Hybrid PET/MRI of large vessel vasculitis : Radiation dose compared to PET/CT with view on cumulative effective dose.

The diagnosis of large vessel vasculitis (LVV) is often challenging due to the various clinical appearances and the low prevalence. Hybrid imaging by positron emission tomography and computed tomography (PET/CT) is ahighly relevant imaging modality for diagnostics and disease surveillance but may be associated with asignificant amount of radiation dose especially in patients with complications. The aim of this retrospective analysis was to compare the image quality and impact of hybrid imaging methods PET/CT and PET/MRI on the potential for dose reduction. This retrospective single-center study included acohort of 32patients who were referred to PET/MRI for the evaluation of LVV, including graft infections and fever of unknown origin. This cohort was compared to asimilar cohort of 37patients who were examined with PET/CT in the same period. Mean radiation dose as well as image quality to establish adiagnosis were compared between the groups. The mean radiation dose applied in PET/MRI was significantly lower when compared to PET/CT (mean 6.6 mSV vs. 31.7 mSV; p < 0.001). This effect was based on the partially multiphasic CT protocols. At the same time, diagnostic image quality using a4-point scale showed similar results for both imaging modalities in the work-up of LVV. With PET/MRI, the radiation exposure can be significantly reduced with similar image quality and diagnostic impact. Patients with LVV have ahigher risk of receiving aclinically relevant cumulative effective dose (CED) and PET/MRI should be made available to them.

Assessment of CO2 Co-benefits of Air Pollution Control Policies in Taiyuan's 14th Five-Year Plan

To quantitatively evaluate the co-benefits of air pollution reduction and carbon dioxide reduction of Taiyuan's 14th Five-Year Plan air pollution prevention and control policies, this study used the Beijing-Tianjin-Hebei Greenhouse Gas-Air Pollution Interaction and Synergy Model (GAINS-JJJ) to simulate and evaluate the emission reduction potential and CO2 co-benefit of 13 air pollution control measures. The emission reductions of PM2.5, PM10, SO2, NOx, VOCs, and NH3 in 2025 were 1.8 (5%, compared with that in the baseline scenario), 2.5 (2%), 3.7 (16%), 20.0 (27%), 13.6 (15%), and 0.0 kt (0%), respectively. The reduction in CO2 emissions was 9.0 Mt (13%), whereas CH4 emissions increased by 203.3 kt (25% increase relative to that in the baseline scenario). SO2, NOx, and VOCs emission reductions derived from the power, industrial combustion, and solvent use sectors. CO2 reduction occurred mainly in the industrial combustion sector, and CH4 emission increased mainly due to the increase in coal mining activity. The highest synergistic CO2 reductions were achieved by restricting energy consumption in the high energy-consuming and high-emitting sectors; prohibiting new capacity in the steel, coke, cement, and flat glass industries; and replacing coal-fired power generation with renewable energy. Furthermore, the CO2 reduction co-benefit was highest for VOCs. In addition, this study suggests that promoting the policy of terminal electrification and simultaneously increasing the share of clean energy and the ability to consume renewable energy generation in the power sector are the keys to decreasing the emissions in Taiyuan.