Reduction Of GO Research Articles

Exploring supercapacitance of solvothermally synthesized N-rGO sheet: role of N-doping and the insight mechanism.

We demonstrate the method of achieving excellent supercapacitance in nitrogen-doped reduced graphene oxide (N-rGO) sheets by controlling the amount of N-content through the use of different ratios of GO and urea during solvothermal synthesis. Here, urea plays a dual role in reducing GO and simultaneously doping nitrogen into the GO flakes forming exfoliated N-rGO sheets. The nitrogen content in N-rGO samples rises with an increase in the amounts of urea and saturates at a value of ∼14% for the GO : urea ratios beyond 1 : 8. The obtained N-rGO sheets with ∼ 5% N-content (obtained for GO : urea ratio of 1 : 3) were demonstrated as excellent supercapacitor materials. Using a 3-electrode setup, the maximum specific capacitance obtained for this sample was 514 F g-1 at a current density of 0.5 A g-1 (mass normalized current). The insights into the origin of this excellent supercapacitive behavior are explained through our results on optimum N-content, the relative amount of different N-environments, defects/disorders, and the degree of reduction of GO. Importantly, a proper stacking of rGO sheets with moderate N-content (∼5-6%) and a moderate amount of defects is the key to achieve high specific-capacitance. Furthermore, our 2-electrode device demonstrates the excellence of our samples with a Csp of 237 F g-1, a power density of 225 W kg-1, and an energy density of 6.7 W h kg-1 at 0.5 A g-1, exhibiting a high cyclic constancy with high capacitive retention of ∼ 82% even after 8000 cycles. Hence, our work provides a way to control the properties of N-rGO in achieving excellent supercapacitive performance.

PREPARATION OF IRON- REDUCED GRAPHENE OXIDE/ EPOXY RESIN COMPOSITE AND ITS FLAME RETARDANCY AND THERMAL STABILITY

In order to reduce flammability, smoke release and enhance thermal stability of epoxy resin (EP), iron powder is mixed with graphene oxide/ epoxy resin (GO/EP) composite by mechanical blending. The combustion performance of composite material is investigated through limiting oxygen index (LOI), Underwriters Laboratory (UL)-94 test, and cone calorimeter test (CCT). Thermogravimetric-Fourier transform infrared spectroscopy (TG-FTIR) and scanning electron microscope (SEM) are also used to explore the mechanism of flame retardancy and smoke suppression. Results show that, with the addition of 0.5% mass fraction of GO and the corresponding iron powder combination (EP3 sample), the LOI value can achieve 32.5% while reaching the UL-94 V0 rating. Compare with EP0, the peaks of heat release rate, smoke production rate, and smoke factor values of EP3 are decreased by 42%, 60%, and 50%, respectively. The char and TG-FTIR data of EP3 reveal that it has a more compact structure, good thermal stability, and produce fewer toxic gases and smoke. Reduction of GO could inhibit the degradation of EP, and iron catalyzes the formation of carbonaceous char on the surface. Thus, the thermal stability and flame retardancy of EP are improved significantly. This study provides a suitable way to prepare graphene/EP composites that contain iron catalyst and can be extended to the industrial manufacture of flame retardant polymer composites. Keywords: iron powder; epoxy resin; graphene oxide; flame retardant; thermal stability

NMP-HSO4 ionic liquid assist preparation of Ag/AgCl decorated rGO for visible light photocatalytic degradation of methylene blue

Using ionic liquids (ILs) to modify the structure and properties of nanomaterials are getting more attention in recent times. N-methyl-2 pyrrolidone hydrogen sulfate ionic liquid is used to prepare the plasmonic photocatalyst made up of Ag and AgCl decorated reduced graphene oxide (rGO). The presence of Ag/AgCl crystals is confirmed through powder XRD pattern and 272 nm absorption in UV–vis spectroscopy is evidenced for the presence of AgCl. The shifting of CO band and new band around 1560 cm−1 in FT-IR spectra are indicating the modification in rGO. Decoration of Ag/AgCl on rGO is observed in FE-SEM images. Decreased ID/IG ratio and increased La value from micro-Raman data indicate the reduction of GO into rGO. From thermogravimetric analysis and an endothermic peak at 956 °C in DSC analysis are evidenced for the composite formation. The photocatalytic activity of the IL-rGO was tested under sunlight by degrading MB dye. Based on the results, the improved catalytic degradation was achieved by effective absorption of sunlight by the catalyst through surface plasmon resonance effect and better charge separation aided by rGO.

Exfoliation of MoS2-RGO Hybrid 2D Sheets by Supercritical Fluid Process

Layered 2D transition metal dichalcogenides (TMD’s) have been considered as an important class of materials in the field of energy and environmental applications. Therefore, it is desirable to fabricate 2D hybrid TMD’s materials in simple solution processing methods. In this study, MoS2-RGO hybrid 2D few layered sheets are produced by supercritical fluid process (SCF) by using ethanol as solvent at 250 ºC in a short duration of 0.5 h. Atomic force microscopy (AFM), transmission electron microscope (TEM) and scanning electron microscope (SEM) images confirmed the formation of 2D hybrid few layered sheets. The electrochemical impedance measurement indicates fivefold increase in conductivity of bulk MoS2. This work presents rapid and one pot exfoliation of MoS2 and simultaneous reduction of GO that can facilitate the production of 2D hybrid materials.

UV-light assisted activation of persulfate by rGO-Cu3BiS3 for the degradation of diclofenac

Reduced graphene oxide (rGO)-Cu3BiS3 composites were synthesized via a solvothermal process. The Cu3BiS3 nanoparticles were successfully distributed on rGO at different weight percentages of 5, 10, 15 and 20%, and were characterized for their physicochemical, morphological, structural and optical properties. Fourier transformed infra-red spectroscopy confirmed the incorporation of Cu3BiS3 on rGO, and also confirmed the reduction of GO during the solvothermal process. X-ray diffraction study confirmed the destruction of the layered structure of GO as a result of the compositing process. Photoluminescence studies of the composites, showed that the quenching ability of rGO on Cu3BiS3 was optimal with the composite containing 15% nanoparticles. The photocatalytic activity of the composite was explored in a UV-assisted persulfate (PS) activation process for the degradation of diclofenac, and the effect of process parameters such as pH, catalyst dosage, and PS dosage were explored. The degradation efficiency of the process reached 85% after 60 min using 30 mg of catalyst, PS concentration of 5 mM and solution pH of 7. Radical scavenging experiments showed that the degradation process proceeded significantly through a non-radiative process and the re-usability study confirmed the stability of the composite after three process cycles. The wide applicability of the process was further studied for the degradation of other organic pollutants such as tetracycline, bisphenol, methyl orange and methylene blue. The UV-light assisted rGO-Cu3BiS3 persulfate activation process could therefore be an important, cost effective and highly efficient process for the degradation of a wide range of water contaminants.

SnO2/reduced graphene oxide nanocomposites for highly efficient photocatalytic degradation of methylene blue

SnO2/reduced graphene oxide (rGO) nanocomposites were prepared by one-step hydrothermal method. The structure, particle size, morphology, and phase composition of SnO2/rGO nanocomposites were studied by X-ray diffraction, field-emission scanning electron microscopy, and Raman scattering spectroscopy measurements. Results showed that SnO2 nanoparticles had a rutile crystal structure and average crystallite sizes of 4.60, 5.24, and 5.60 nm for SnO2, SnO2/rGO-1%, and SnO2/rGO-2% samples, respectively. Raman scattering spectra showed the coexistence of two SnO2 and rGO phases in nanocomposites, and the reduction of GO to rGO increased when the GO concentration increased from 1% to 2%. The absorption properties and the Eg band gap value were studied through UV–vis absorption spectra. The absorption spectra showed a characteristic absorption peak of SnO2 at 296 nm, and the visible region absorption increased with rGO doping. In addition, the band gap of SnO2/rGO nanocomposites decreased with rGO doping. The photocatalytic properties of SnO2/rGO nanocomposites were studied using the decomposition of methylene blue (MB) under visible light. Results showed that SnO2/rGO nanocomposites decomposed MB by more than 90%, while SnO2 decomposed MB by only approximately 30%, proving that rGO has the effect of enhancing the photocatalytic degradation of SnO2/rGO nanocomposite.

One-step electrodeposition of ZnO/graphene composite film as photoanode for dye-sensitised solar cells

Zinc oxide (ZnO) nanostructures are commonly used as semiconductor films for the photoanodes of dye-sensitized solar cells (DSSCs). However, the photoelectric conversion efficiency (PCE) of DSSCs with ZnO photoanode was compromised by the instability of the physical and chemical properties of ZnO. In this paper, ZnO-reduced graphene oxide (rGO) composite photoanodes were obtained by a one-step electrodeposition method, and the photoelectric performance of the assembled DSSCs were measured. By comparing the PCE and other photoelectric parameters of the DSSCs constructed by the ZnO-rGO photoanodes deposited under different deposition potentials and times, the DSSCs achieved the best performance with the photoelectric conversion efficiency (PCE), open circuit voltage (Voc), short-circuit current density (Jsc), and fill factor (FF) of 1.07%, 386.15 mV, 4.65 mA cm −2 , and 0.59, respectively. • We report a one-step electrodeposition method for preparing ZnO-rGO composite. • The photoelectric properties of ZnO-rGO composite photoanodes are higher than ZnO. • The electrodeposition of ZnO was carried out simultaneously with reduction of GO.

Photo-induced Janus effect of graphene oxide films

The effect of UV irradiation on the wettability of GO films, as well as the possibility of making a film with different properties of its surface, the Janus film, has been studied. The O/C ratio changes from 0.32 to 0.26 after 6 ​h of UV irradiation. The contact angle of water droplet wetting on an unirradiated surface is θ ​≈ ​35°. The contact angle reaches more than 95° on the irradiated surface, which means that a hydrophobic surface on a film can be obtained. The origin of amphiphilic properties of the GO film are associated with the photochemical reduction of GO.

Simultaneous electrochemical deposition of nickel cobalt oxide-reduced graphene oxide composites for high performance asymmetric supercapacitors

In this work, a one-step electrodeposition approach was applied for nanosheets fabrication of binder free nickel cobalt oxide (NCO) and NCO-reduced graphene oxide (NCO-rGO) composites on the nickel-foam substrate by repetitive cyclic voltammetry (rCV). The NCO-rGO hybrids were firstly fabricated on Ni foam surface with the reduction of GO and electrodeposition of NCO simultaneously. Interaction of NCO particles with rGO sheets increased the conductivity of the composite and consequently facilitated the electron transfer rate. Electrochemical measurements proved that specific capacitance and cyclic performance of as-prepared materials were improved with the synergistic effect of rGO in the hybrid structure. The optimized NCO-rGO electrode exhibited a specific capacitance of 1916.5 F g−1 at 1 A g−1 with superior stability of 95.6% at a high current density of 10 A g−1 even after 3000 cycles. To explore its practical applications, an asymmetric supercapacitor (ASC) based on NCO-rGO as a positive electrode and rGO as a negative electrode was constructed, which exhibited a prominent specific energy of 45.22 Wh kg−1 at 400 W kg−1. As a result, NCO-rGO hybrid structure as the functional electrode material for the supercapacitors with remarkable electrochemical performance were obtained, thanks to the increased conductivity and decreased mass by removing binders.

Influence of integrated nitrogen functionalities in nitrogen doped graphene modified WO3 functional visible photocatalyst

Nitrogen doped graphene modified WO3 nanocomposites were synthesized through an effective methodology. The prepared photocatalysts were employed as active candidates for degradation of highly toxic organics i.e., 2, 4 dichloro phenol (2, 4-DCP) and methyl orange (MO). XRD profile of N-graphene showed complete reduction of GO into N-graphene. All diffraction peaks of WO3 along with N-graphene indicated monoclinic phase of WO3. SEM and TEM images of 3.0% N-graphene/WO3 have demonstrated the mixed morphology of irregular massive rod like blocks and round shaped particles of WO3 distributed on cracked sheets of N-graphene. Nitrogen defects in graphene altered zero band gap semi-metallic graphene to semiconducting material and increased the absorption edge of N-graphene/WO3 nanocomposites towards visible region as studied in DRS analysis. FTIR and Raman studies showed the strong connection between N-graphene and WO3 by making W−O−C surface linkage. The noticeable reduction in PL emission peaks of 3.0% N-graphene/WO3 indicated obvious separation of photo induced charge carriers. The study of radical scavengers suggested that holes (h+) and •OH are the main elements for the decontamination of both MO and 2, 4-DCP. XPS analysis shows all possible C−N bonding configurations in 3.0% N-graphene/WO3. 3.0% N-graphene/WO3 composite showed the maximum photo degradation of MO (~94.0%) and 2, 4-DCP (~81.0%). The synergism between N-graphene and WO3 results into more sporty sites on catalyst and restoring of sp2 structural defects in N-graphene lattice improve the transportation of charge carriers during photocatalysis. This work provides innovative strategies for designing the N-graphene/semiconductor nanosystems with enhanced photocatalytic phenomena in the environmental cleanup remedies.

The effect of different GO reduction strategies on the lower level electrochemical determination of Epinephrine and Serotonin in quaternary mixtures

The effect of different reduction techniques on the structure and electrochemical sensing properties of reduced graphene oxide (RGO) was systematically studied. The comparison of the electrochemical properties of three RGOs formed by chemical reduction using sodium borohydride, hydrazine monohydrate and hydrothermal reduction was investigated. The electrodes modified with RGOs showed an excellent electrocatalytic effect by enhancing the anodic current and decreasing the electrode potential on the oxidation of epinephrine (EPN), and serotonin (SER). The effect of scan rate, pH, stability and reproducibility of the sensor was thoroughly investigated. Although all the RGOs obtained from different reduction strategies had very similar characteristics, NaBH4 reduced sample had better current response. The anodic peak current showed a linear relation with the EPN and SER concentration in a wide range of 70 nM-0.5 mM, 100 nM-2 mM respectively. The detection limit (LOD) of 0.33 nM and 3.99 nM were obtained for EPN and SER respectively. The modified electrode sensor was very effective for simultaneous determination of EPN, SER, Uric acid (UA) and Acetaminophen (AC) with well separated peaks at −0.069, 0.091, 0.269 and 0.395 V. The peak to peak separation values (ΔEpa) of EPN-AA, SER-EPN, AC-SER and AA-AC were 0.16, 0.178, 0.126, and 0.464 V. This work demonstrates the practical utility of the single component modified electrodes for measurements of EPN, SER in human blood serum and urine.

Ultrathin freestanding PDA-Doped rGO/MWCNT composite paper for electromagnetic interference shielding applications

The scalable and controllable preparation of carbon nanomaterial-based scaffolds with superior electromagnetic interference (EMI) shielding properties in addition to being ultrathin, robust, lightweight, flexible, and foldable is a challenging task. However, commonly used techniques such as integrating conducting moieties and high-temperature annealing cannot simultaneously meet the demands of high specific shielding effectiveness (SSE), robustness, and flexibility. Here, we adopted a novel PDA reduction technique to integrate various functionalities, including a nitrogen doping source, extended reduction of GO, and a large accessible area to accommodate multiwall carbon nanotubes (MWCNTs). The prepared ultrathin PDA-rGO/CNT composite sheet exhibited a low density (0.26 g/cm3), high flexibility, and superior shielding effectiveness (SE) under a wide range of microwave frequencies (i.e., the X band and Ku band). The total shielding effectiveness (SET) reached 47.6 dB and 48.7 dB in the X band and Ku band, respectively, at a thickness of 82 µm and a high SSE; in particular, the SE/density reached a maximum value of 183.3 and 187.3 dB cm3/g, respectively, which are superior to those of previously reported studies. This comprehensive study revealed the synergistic effect of PDA doping and MWCNTs, resulting in excellent shielding properties. Hence, this superior SSE and flexibility makes ultrathin lightweight PDA-rGO/CNT composite sheets a suitable candidate for replacing metallic counterparts for foldable and wearable electronic components.

Dual-functional single stranded deoxyribonucleic acid for graphene oxide reduction and charge storage enhancement

This study reports a one-step process to produce single-stranded deoxyribonucleic acid (ssDNA) functionalized reduced graphene oxide (ssDNA/rGO). The ssDNA acts as a reducing agent for the reduction of GO into rGO and simultaneously performs functionalization onto rGO, which is confirmed by spectroscopic and microscopic analyses. Such reduction capability is not being observed in double-stranded DNA (dsDNA). The high charge density of ssDNA on rGO is investigated for its application in electrochemical supercapacitor, and it is revealed that the ssDNA/rGO exhibits a specific capacitance of 129 F g−1 with high stability (92%) up to 10,000 cycles. The findings open the gateway to develop a biomolecule-based energy storage system.

Modulation of reduced graphene oxide membrane for low-fouling wastewater filtration: Membrane structure, wastewater property, and DFT calculation

Membrane fouling is a major hurdle impeding real-world application of membranes for advanced wastewater treatment. In this study, a GO membrane and a reduced GO (rGO) membrane were examined in parallel for their anti-fouling propensities and ability to remove pharmaceutical compounds from realistic wastewater effluents. The effects of membrane properties and wastewater characteristics on the two aspects were also assessed by experiments and DFT simulation. The results showed that the transmembrane pressure (TMP) of the rGO membrane increased by 0–3.5 kPa after filtering a secondary wastewater effluent from an activated sludge system (SW), as compared to 201.6–292.1 kPa for the GO membrane. Meanwhile, slightly greater TMP increases were observed for both membranes after filtering a secondary wastewater effluent from a partial nitrification and denitrification system (PND), but the fouling remained low for the rGO membrane. Overall, chemical reduction of GO to rGO led to larger SSA and reduced negative charge, which promoted adsorptive filtration of pharmaceutical compounds. Also, the diminishing of functional groups possessed by the GO membrane mitigated attractive interlayer polar interaction and expanded membrane pore dimension, thus enhancing the permeability and anti-fouling propensity of GO membranes.

Factors Influencing the Electrocatalytic Properties of Graphene Oxide – Gold Nanoparticles Hybrid System

AbstractGraphene oxide (GO) – gold nanoparticles (AuNPs) nanocomposites are promising materials for H2O2 electrochemical sensors. Surface composition of GO is an important factor influencing the sensitivity. In this study GO has been mildly reduced by ammonia (GO‐NH3) or sodium hydroxide solution (GO‐NaOH). Such mild reduction opens up the epoxide groups on the GO surface but not the other oxygen functionalities. The electrochemical reduction of GO has been carried out too. It is found that the structure of the electrochemically reduced graphene oxide (ERGO) depends on the concentration of GO used to prepare the layer. For concentrated GO (10 mg/ml) the electro‐reduction leaves OH surface groups while for lower concentrations all surface groups can be removed. All GO materials listed above were combined with AuNPs and examined as possible amperometric H2O2 sensors. The two types of layers were examined: AuNPs deposited on the top of the GO material or AuNPs deposited under the GO material layer. Among studied composites ERGO obtained from 5 mg/ml GO on the AuNPs layer showed the highest sensitivity (155.6 μA cm−2 mM−1 at −0.4 V vs Ag/AgCl).

Incorporation of polyaniline on graphene-related materials for wearable thermoelectric applications

Polyaniline (PANi)/graphene composite on the cotton fabric is blended via a fusion of in-situ polymerization and solution process. PANi is initially grafted to graphene oxide via solution process where an associated reduction of GO transpired due to the hydrothermal condition and acquaintance of GO to KOH. The structural, morphological, elemental, thermal and electrical characteristics of these fabrics are studied by various physio-chemical techniques. The study is aimed to comprehend the participation of PANi as well as improved composite thereof under investigation. UV shielding ability of Nanostructured PANi/ graphene composite fabric is found to be enhanced to the value of 447 along with the thermal stability till 280 °C. It is also detected that the electrical conductivity of the PANi/graphene composite fabrics has improved. The thermo power value of the PANi/graphene composite fabric reaches 0.045 µVK−1. Hence, these materials are expected to be prominent for wearable thermoelectric devices.

Performances of Reduced Graphene Oxide/Iron (III) Oxide/Silica Dioxide (rGO/Fe3O4/SiO2) as a Potential Oxygen Reduction Electrocatalyst in Fuel Cell

Synthesis of the nanocomposite comprises reduced graphene oxide, iron (III) oxide and silica dioxide nanocomposites which were denoted as rGO/Fe3O4/SiO2. The acquired nanocomposite was determined to be a substitute for platinum electrode in oxygen reduction reaction (ORR) to catalyze reaction, as usage of platinum causes disadvantages in production. The nanocomposite was analyzed physically and electrochemically to ensure the quality of the synthesized compound. Fourier transform-infrared spectroscopy (FTIR) shows the presences of functional groups such as O-H hydroxyl group, C=C, C=O and existence of silica peak in the spectra of rGO/Fe3O4/SiO2, where the data is also supported by SEM-EDS. Raman Spectrophotometer shows the structural change of three different graphene related materials as modification took place and X-Ray Diffraction (XRD) analysis confirms the reduction of GO into rGO, where the crystalline structure decreased significantly approximately about 10 nm. This data supported with Brunauer-Emmett-Teller (BET) analysis through surface area examination. The compound of rGO/Fe3O4/SiO2 was drop-casted onto glassy carbon electrode (GCE) for modification into rGO/Fe3O4/SiO2/GCE to carry out electrochemical analysis where Cyclic Voltammetry (CV) shows current response by modified electrode is greater than bare GCE while Electron Impedance Spectroscopy (EIS) of same modified electrode affirms the sample underwent reversible process with stable and rapid electron transfers with minimal resistance charge transfer (RCT). The study of ORR was carried out and observed a good electrochemical response of the nanocomposite when purged with oxygen gas.

Enhancing Light Absorption and Prolonging Charge Separation in Carbon Quantum Dots via Cl-Doping for Visible-Light-Driven Photocharge-Transfer Reactions.

Limited light absorption beyond the UV region and rapid photocarrier recombination are critical impediments for the improved photocatalytic performance of carbon quantum dots (CQDs) under visible-light irradiation. Herein, we demonstrate single-step microwave-assisted syntheses of O-CQDs (typical CQDs terminated by carboxylic and hydroxyl functional groups) from a sucrose precursor and Cl-doped CQDs (Cl-CQDs) from a sucralose precursor in short reaction times and without using obligatory strong acids for Cl doping. The doping of Cl into the CQDs is observed to widen the absorption range and facilitate an enhanced separation of photoexcited charge carriers, which is confirmed by the results of optical absorption, photothermal response, and pump-probe ultrafast transient absorption spectroscopy measurements of the O-CQDs and Cl-CQDs. The photoexcited charge carriers with their longer lifetimes in Cl-CQDs enabled the quick degradation of methylene blue dye, rapid conversion of Ag+ ions to metallic Ag nanoparticles on the CQD surfaces, and reduction of GO to a well-dispersed rGO through the photoelectron transfer reactions under visible-light irradiation. The facile Cl doping strategy, hybridization of Ag nanoparticles or rGO to CQDs, and the elevated charge separation mechanism would open up new avenues in designing CQD-based materials for futuristic applications.

A porous rGO with high specific surface area and high content of doped-N modifying the separator for high performance Li-S battery

HSN-rGO with high specific surface area and high content of N is prepared via GO reduction and N-doping of DMF, corrosion oxidation pore-forming of H2O2 as well as further reduction and N-doping of N2H4•H2O under the solvothermal condition. The porous HSN-rGO has a high BET specific surface area of 464.3 m2 g−1. The N content in HSN-rGO is 5.27 at.%. The HSN-rGO shows a strong adsorption capability for the soluble lithium polysulfides (LiPSs) and more importantly it presents an excellent catalytic capability for the redox conversion of LiPSs. The HSN-rGO modified separator can inhibit the shuttle effect of LiPSs in Li-S battery. Besides, the HSN-rGO based separator has a good electrolyte wettability. The catalytic activity of HSN-rGO and Li+ diffusion property in Li-S battery are well studied quantitatively. The Li-S battery with HSN-rGO-PP separator exhibits a high initial discharge capacity of 1372.8 mAh g−1 at 0.1 C and 681.5 mAh g−1 at 2 C, and a low-capacity decay rate of 0.055% per cycle for 1000 cycles at 1 C. This study proves the strategy that the HSN-rGO modified separator can effectively inhibit the shuttle effect of LiPSs and accelerate the redox reaction kinetics for high-performance Li-S battery.

Nano-scale P, Zn-codoped reduced-graphene oxide incorporated epoxy composite; synthesis, electronic-level DFT-D modeling, and anti-corrosion properties

The great potential of the advanced nano-materials like graphene oxide as smart containers for the controlled desorption of the inhibitors and their effectiveness as dual active/passive anti-corrosive agents in the polymeric composites has been noticed in recent researches. In this work, aminotrimethylene phosphonic acid (AMP) was used with two primary purposes: a non-toxic reductant of GO and a potent chelating agent. Zinc cations were chelated with AMP on the reduced graphene oxide, forming a nanocontainer with active protection potency. The successful reduction of GO and AMP-zinc chelation were confirmed by FT-IR, Raman, TGA, and UV–visible analysis. The interactions between GO, AMP, and zinc cations were investigated by density-functional theory (DFT)-D computational modeling. The electrochemical analyses have proved the inhibitory potency of the P, Zn-codoped reduced-graphene oxide (GAZ) nanoparticle. The incorporation of the anti-corrosive nanocontainers into the epoxy coating covered the defects of the matrix significantly. It resulted in great protection of the coating after 10 weeks of coatings evaluation in the NaCl media. It was also found that a dense and protective complex of AMP and zinc cations was formed in the scratched zone of the polymeric matrix. This protective complex demonstrated the self-healing anti-corrosion potency of the fabricated nanoparticles.