Abstract This study investigates the spatiotemporal variations of the summer frequency of daytime–nighttime compound extreme high-temperature events (FCEHEs) in the mid–high latitudes of Asia (MHA) from 1979 to 2014. Results show that FCEHE has shown an upward trend with fluctuations, especially in Mongolia–Baikal. The descending anomaly caused by the anomalous high pressure over Mongolia–Baikal results in reduced cloud cover, which increases solar radiation reaching the ground, favoring the higher FCEHE. This process is consistent during the daytime and nighttime periods, with relatively limited nighttime solar radiation, potentially compensated by the increased downward longwave radiation to sustain the extreme high temperatures. This benefit process is closely connected with two main factors: the increased sea ice in the Barents Sea during spring and the anomalously warm sea surface temperature (SST) in the Northwest Pacific during summer. The increased sea ice can affect the Eurasia (EU) teleconnection, while the warm SST affects the Pacific-Japan/East Asia–Pacific pattern (PJ/EAP). Subsequently, these factors further modulate the circulation anomalies and then FCEHE. Significance Statement This study provides valuable insights into the spatiotemporal variations and the possible underlying mechanisms for change in the frequency of daytime–nighttime compound extreme high-temperature events (FCEHEs) in the mid–high latitudes of Asia. The spring sea ice anomalies over the Barents Sea and summer sea surface temperature anomalies in the Northwest Pacific affect the local anticyclonic circulation in Mongolia–Baikal through Eurasia (EU) and Pacific-Japan/East Asia–Pacific (PJ/EAP) patterns, respectively. The resulting descending anomaly and reduced cloud cover contribute to interannual variations of FCEHE, which is highly similar during the daytime and nighttime periods. During the nighttime, when the solar radiation is relatively limited, the increased downward longwave radiation may compensate to sustain extreme high temperatures.