Free-form surfaces have been widely used in aerospace, automotive and other fields. Due to its complex geometry, free-form surface inspection is generally conducted by touch-trigger or measuring probe-based Coordinate Measurement Machines or On-machine Measurement. Sampling strategy plays a decisive role in improving both measurement accuracy and efficiency, which is determined by sample size and distribution of sample points. However, it is difficult to simultaneously take the surface curvature, sampling density and approximation error into account, considering the complexity of surface geometry. In this paper, triangle mesh simplification is innovatively adopted in sampling planning to achieve multi-geometric constraints. As triangle mesh has outstanding advantages in representing the surface features, strong stability and is easy to modify its structure, free-form surface is converted to a dense triangle mesh. Triangle mesh simplification is implemented by iteratively contracting triangle edges. An improved quadric error metric is established to decide contraction order and optimal target vertices under discrete curvature constraint. Sampling density is controlled by limiting the triangle edge length. Detailed adaptive sampling algorithm under multi-geometric constraints is then developed. Both simulation and experiment are conducted to validate feasibility and robustness of the proposed method. The results are compared with uniform sampling and existing adaptive sampling strategy to show that the proposed method can prominently reduce sampling error when sample size is small.