Conditions Of Reduced Salinity Research Articles

Effect of wettability and phase distribution on critical salt concentration for fines migration initiation in sandstone reservoirs

Fines migration in sandstone oil reservoirs during different field operations is influenced by the salinity of injected brine. When salinity drops below a critical salt concentration (CSC), fines migration is initiated, leading to pore throat blockage and formation damage. Factors such as rock wettability, fluid type, fines size and concentration, and flow rate contribute to the severity of this issue. However, the impact of phase distribution and rock wettability on the CSC remains unexplored. Most results are reported for water-wet systems, but in many cases, assuming a strong water-wet state is not accurate. The current research fills that gap and provides new insights by investigating the relationship between the CSC, phase distribution, and rock wettability.Upper Berea sandstone cores were used in this study, and the CSC was experimentally determined. Brine was injected into strong water-wet and weak water-wet core samples. The injection brine salinity was gradually reduced to identify the salinity at which fines migration initiated within the core. The analysis of pressure drops and effluent analysis was applied to estimate CSC at different wettability states.The step-by-step reduction in salinity led to CSCs of 0.12 M and 0.09 M NaCl for the weak water-wet core and strong water-wet core in the presence of oil, respectively. A weak water-wet system results in a higher CSC value compared to a strong water-wet system because fine particles are contained within a thin water film, and weak water wettability facilitates their easy migration under low reduced salinity conditions. The CSC corresponded to the point of maximum pressure difference and the highest concentrations of produced fines. The findings of this research provide valuable insights into the significant influence of rock wettability and phase distribution on the initiation of fines migration. These parameters must be carefully determined and considered during the design phase of production and enhanced oil recovery in sandstone reservoirs to ensure efficient operations.

Distinguishing Coastal Habitats of Caribbean Panama with Benthic Foraminifera

Abstract Benthic foraminifera were collected from reef coral, seagrass and mangrove sediments of Almirante Bay, Caribbean Panama, to associate species and assemblages with habitats and environmental conditions related to degraded water quality. The three habitats occur in different adjacent areas within an embayed, patch-reef setting. We analyzed the relative abundance, diversity and community structure of benthic foraminiferal species > 63 µm in 17 sediment samples from < 2 m mean water depth. Results from hierarchical cluster analysis, analysis of similarity, similarity percentages, non-metric multidimensional scaling and Fisher's alpha diversity were compared from seagrass, mangrove and coral habitats and also between two areas with contrasting water quality as previously defined by hydrography and general water quality. Among the three neighboring habitats, assemblages are fairly similar but differ in species proportions. Overall, Ammonia parkinsoniana, indicative of relatively low and variable salinities, is a dominant taxon. Foraminiferal assemblages from mangroves had the lowest mean diversity, a common trend under reduced salinity conditions, and diversity appears to be regionally controlled by freshwater input. Planorbulina acervalis was dominant in seagrass beds. Low-diversity, stress-tolerant foraminiferal assemblages are present in samples from all three habitats, reflecting the bay's highly variable patch-reef structure, freshwater input, and possible hypoxia. Diversity is generally lower near the mainland than in the eastern bay off the island of Isla Colón. Environmental associations of the benthic foraminifera of Almirante Bay are baseline ecologic data for comparisons to coastal habitats formed before human occupation and have the potential to be used in the sedimentary record to assess the impact of anthropogenic disturbance.

NEW GEOCHEMICAL INSIGHTS INTO CENOZOIC SOURCE ROCKS IN AZERBAIJAN: IMPLICATIONS FOR PETROLEUM SYSTEMS IN THE SOUTH CASPIAN REGION

The Maikop Group and the Diatom Formation constitute the two main source rocks in the South Caspian Basin and onshore Azerbaijan where large‐scale oil production began more than 150 years ago. However, the stratigraphic distribution of the source rocks and the vertical variation of source‐rock parameters are still poorly understood. The aim of the present paper is therefore to investigate in high resolution the source‐rock distribution in the Perekishkyul and Islamdag outcrop sections, located 25 km NW of Baku, which provide nearly complete middle Eocene and lower Oligocene to upper Miocene successions. Bulk geochemical parameters of 376 samples together with maceral, biomarker and isotope data were analysed. In addition, new Re/Os data provide independent age dating for the base of the Upper Maikop Formation (30.0 ± 1.0 Ma) and the paper shale within the Diatom Formation (7.2 ± 2.6 Ma). The presence of steradienes in high concentrations demonstrates the thermal immaturity of the studied successions, limiting the application of some biomarker ratios.Intervals with high TOC contents and containing kerogen Type II occur near the top of the middle Eocene succession. However, because of the low net thickness, these sediments are not considered to constitute significant hydrocarbon (HC) source rocks. The Maikop Group in the Islamdag section is 364 m thick and represents lower Oligocene (upper Solenovian) to middle Miocene (Kozakhurian) levels. Samples are characterized by moderately high TOC contents (∼1.8 wt.%) but low hydrogen index (HI) values (average ∼120 mgHC/gTOC) despite a dominance of aquatic organic matter (diatoms, methanotrophic archaea and sulphate‐reducing bacteria). Rhenium‐osmium chronology suggests low sedimentation rates (∼25 m/Ma), which may have had a negative impact on organic matter preservation. Terrigenous organic matter occurs in variable but typically low amounts. If mature, the Maikop Group sediments at Islamdag could generate about 2.5 tHC/m2.The Diatom Formation includes a 60 m thick paper shale interval with high TOC contents (average 4.35 wt.%) of kerogen Type II‐I (HI up to 770 mgHC/gTOC). The source potential is higher (∼3 tHC/m2) than that of the Maikop Group. The organic matter is dominated by algal material including diatoms. High TOC/S ratios suggest deposition under reduced salinity conditions. Strictly anoxic conditions are indicated by the presence of biomarkers for archaea involved in methane cycling.For oil‐source correlations and a better understanding of the petroleum system, it will be necessary to distinguish oil generated by the Maikop Group from that generated by the Diatom Formation. This study shows that these oils can be distinguished based on the distribution of specific biomarkers e.g. C30 steranes, C25 highly branched isoprenoids (HBIs), and the C25 isoprenoid pentamethylicosane (PMI).

Ichnological signatures from wave- and fluvial-dominated deltas: The La Anita Formation, Upper Cretaceous, Austral-Magallanes Basin, Patagonia

Depositional processes operating in deltaic shorelines create a variety of physico-chemical stressful conditions that impact directly on benthic fauna. The ichnological signatures of deltaic successions reflect these physico-chemical stresses, such as rapid sediment influx, elevated water turbidity, periodically reduced oxygenation, salinity fluctuations, and wave- and tidal-energy. In the Campanian La Anita Formation of the Austral-Magallanes Basin, two examples of deltaic successions, each showing different relative dominance of wave and fluvial processes, are described in detail, allowing the recognition of contrasting stresses that acted differentially in a wave-dominated, fluvial-influenced delta and a fluvial-dominated delta. Variations in the burrowing intensity and ichnodiversity allowed us to discriminate the different physico-chemical stresses. In the wave-dominated, fluvial-influenced deltaic deposits, the alternation between fair-weather waves and storm events acted as the main controlling factor on benthic fauna in the facies of the prodelta and distal delta front, displaying facies-crossing and horizontal elements attributable to the Skolithos and Cruziana Ichnofacies, such as Arenicolites isp., Chondrites isp., Cylindrichnus isp., Diplocraterion isp., Gyrochorte isp., Ophiomorpha isp., Palaeophycus isp., Planolites isp., Rhizocorallium isp., Rossellia isp., Schaubcylindrichnus isp. and Skolithos isp. Water turbidity and periodically reduced bottom water oxygenation conditions also played an important but subordinate role. The proximal delta front, and distributary and terminal distributary channel deposits show low burrowing intensities and ichnodiversities with structures attributable to the depauperate Skolithos Ichnofacies with few Diplocraterion isp., Gordia isp., Lockeia isp., Macaronichnus isp., Ophiomorpha isp., Schaubcylindrichnus coronus and Siphonichnus isp., showing stress conditions associated with rapid sediment influx, high energy and reduced salinity conditions related to fluvial discharges as the most important controlling factors. Periodically, fluctuations in salinity conditions due to river discharges and channel avulsion may have also played important roles. The fluvial-dominated deltaic deposits show that the controlling factors were associated with fluvial discharge and river-sediment influx with no clear influence of wave or tidal action. The facies of the distal delta front were controlled by episodic sedimentation, elevated water turbidity, periodically reduced oxygenation and salinity fluctuations, the associated trace fossil suite consists of a monospecific assemblage of Ophiomorpha isp. and sparse Palaeophycus isp. The proximal delta front and the distributary channel deposits are mostly unburrowed, locally displaying a few Arenicolites isp., Lockeia isp., Ophiomorpha isp., Psilonichnus isp. and Teredolites isp. The development of these suites was controlled mainly by heightened sedimentation rates influx triggered by high fluvial discharges, elevated water turbidity due to heightened suspended load and buoyant plumes, periodic fluctuations in salinity conditions caused by river discharges and channel avulsion. Interdistributary areas are characterized by facies preserving evidence that reduced oxygenation was the most important controlling factor in this subenvironment. Fluvial processes generate the most extreme stressful conditions for benthic colonization by tracemakers. Wave processes tend to buffer the stresses produced by river discharge. The effect of waves on fluvial stress is reflected in the higher bioturbation intensities and ichnodiversities that the wave-dominated deltaic deposits of the La Anita Formation delta show in relation to the fluvial-dominated ones.

Anatomy of a late Cenomanian transgressive shelf system: The influence of high-frequency eustasy and crustal flexure on stratigraphy and paleogeography, basal Kaskapau Formation, Western Canada Foreland Basin

AbstractThe late Cenomanian Kaskapau Formation records transgression of the Greenhorn Sea over deltaic strata of the Dunvegan Formation. However, stratigraphic and paleogeographic details of the initial stages of this profound reorganization of basin geography have not previously been determined. The basal Kaskapau strata above the Dunvegan Formation are assigned to the informal allostratigraphic ‘A-X unit’. Subsurface and outcrop correlation shows that five regionally-mappable allomembers, bounded by marine flooding surfaces, can be mapped within the A-X unit which, as a whole, forms a wedge that thickens south-westward from <5 to 60 m over approximately 300 km. Within each allomember, three main depositional environments can be distinguished. Sandy heterolithic facies in the north and west form few-metre scale, upward-shoaling successions that contain abundant brackish-water molluscs and are capped by paleosols and dinosaur-trampled surfaces. These rocks represent river-dominated deltas that prograded into a low-energy embayment, about 200 x 200 km, and open to the SE. The central part of the embayment accumulated mud-dominated heterolithic successions with a restricted fauna of lingulid brachiopods and inoceramids, suggestive of turbid, low-energy and reduced salinity conditions. The muddy facies enclose isolated units of well-sorted fine- to very fine-grained sandstone that form NE-SW elongate bodies up to 170 km long, 50 km wide and 11 m thick. Each sandstone body is interpreted to represent the shoreface of one or more strandplains and/or wave-dominated deltas that developed across the mouth of the embayment at sea-level lowstand. Isopach mapping shows that the A-X unit, as a whole, forms a prismatic wedge, thickest adjacent to the fold and thrust belt in the SW. This geometry indicates that accommodation was created by spatially uniform flexural subsidence in response to a linear tectonic load striking NW-SE. Isopach maps of individual allomembers, however, show that subsidence took place in a more complex pattern, with localized depocentres of approximately 100 km radius that suggest brief periods of subsidence before being superseded by a new depocentre along-strike. This pattern may reflect temporally and spatially discontinuous deformation in the adjacent orogenic wedge. During each relative sea-level cycle, the shoreline oscillated by about 150–200 km in a NW-SE direction. Shoreline movement was perpendicular to the direction that would be expected (i.e. SW-NE), if flexural subsidence had been the dominant control on relative sea-level change. This geometric relationship suggests that allomembers were generated by high-frequency, high rate eustatic changes that were superimposed on a lower rate of flexural subsidence. Isopach maps spanning Dunvegan allomembers C, A+B, and the Kaskapau A-X unit show a near 90° anticlockwise rotation of isopleths. This abrupt re-orientation of the axis of flexure marks a new phase of subsidence linked to the onset of NE-directed thrusting that was driven by dextral transpression across a restraining bend in the Northern Rocky Mountain Trench fault. This new stress regime was in turn linked to a change in the convergence direction between the North American and Farallon plates.

Cyclic paleo-salinity changes inferred from benthic foraminiferal assemblages in the Upper Burdigalian (Lower Miocene) Korneuburg Basin, Austria

The late Burdigalian (Karpatian) Korneuburg Basin gives an excellent insight into the continuous modification of its paleo-environments and paleo-ecology and therefore into its dynamics over geological time scales. The investigated outcrops provided a unique opportunity to study the change of foraminiferal assemblages in an Early Miocene estuarine-marine system as a response to climate (precipitation) oscillations. To this end, we studied foraminiferal assemblages. Ostracods provided additional information. Paleo-salinities were estimated by applying a transfer equation using modern frequency distributions of indicative foraminiferal taxa. This technique is used here for the first time to reconstruct salinity in the past, and may facilitate further studies in shallow water paleo-environments elsewhere. On the basis of the recorded benthic foraminiferal assemblages, their modern distribution, and several diversity indices (Fisher α, Shannon, Dominance, Evenness), we were able to discriminate between five paleo-environments. Paleo-salinity was the most important environmental factor that governed the distribution of taxa in the Korneuburg Basin. Low diverse brackish environments yielded Ammonia and Aubignyna. Slightly reduced salinity conditions are dominated by Ammonia with additional taxa and are more diverse. Normal marine salinities are indicated by the dominance of Heterolepa, Gyroidinoides, or Bulimina and go along with a more balanced assemblage composition. Hypersaline conditions are characterized by Cycloforina and Ammonia and an intermediate diversity distribution. Freshwater samples are free of benthic foraminifera. Environmental changes and consequent ecological stress resulted in an overall low-diverse paleo-ecosystem. Salinity variations are interpreted as being caused by freshwater influx into the system. Seventeen combined increases and decreases of paleo-salinity indicate a coupling with obliquity cycles and a linkage to regional climate changes. The estuarine system of the Korneuburg Basin, that lasted over 700,000years shows distinct effects of the regional climate regimes on the local micro-fauna.

Reduced salinity increases susceptibility of zooxanthellate jellyfish to herbicide toxicity during a simulated rainfall event

Accurately predicting how marine biota are likely to respond to changing ocean conditions requires accurate simulation of interacting stressors, exposure regimes and recovery periods. Jellyfish populations have increased in some parts of the world and, despite few direct empirical tests, are hypothesised to be increasing because they are robust to a range of environmental stressors. Here, we investigated the effects of contaminated runoff on a zooxanthellate jellyfish by exposing juvenile Cassiopea sp. medusae to a photosystem II (PSII) herbicide, atrazine and reduced salinity conditions that occur following rainfall. Four levels of atrazine (0ngL−1, 10ngL−1, 2μgL−1, 20μgL−1) and three levels of salinity (35 ppt, 25 ppt, 17 ppt) were varied, mimicking the timeline of light, moderate and heavy rainfall events. Normal conditions were then slowly re-established over four days to mimic the recovery of the ecosystem post-rain and the experiment continued for a further 7 days to observe potential recovery of the medusae. Pulse-amplitude modulated (PAM) chlorophyll fluorescence, growth and bell contraction rates of medusae were measured. Medusae exposed to the combination of high atrazine and lowest salinity died. After 3 days of exposure, bell contraction rates were reduced by 88% and medusae were 16% smaller in the lowest salinity treatments. By Day 5 of the experiment, all medusae that survived the initial pulse event began to recover quickly. Although atrazine decreased YII under normal salinity conditions, YII was further reduced when medusae were exposed to both low salinity and atrazine simultaneously. Atrazine breakdown products were more concentrated in jellyfish tissues than atrazine at the end of the experiment, suggesting that although bioaccumulation occurred, atrazine was metabolised. Our results suggest that reduced salinity may increase the susceptibility of medusae to herbicide exposure during heavy rainfall events.

A fluctuating salinity regime mitigates the negative effects of reduced salinity on the estuarine macroalga, Enteromorpha intestinalis (L.) link.

We tested the response of Enteromorpha intestinalis to fluctuating reduced salinity regimes which may occur in coastal estuaries due to both natural and anthropogenic influences. In a fully crossed two factor experiment, we subjected E. intestinalis to 0, 5, 15 and 25 psu water enriched with nutrients for 1-, 5-, 11- and 23-day periods. Each period was followed by 24 h of exposure to 25 psu (ambient) water that was not nutrient enriched. Following 24 h in ambient salinity water, algae were returned to reduced salinity conditions for the appropriate period and the cycle continued over the 24 days for which all treatments were maintained. Exposure to 0 psu for 5 days or longer resulted in loss of pigmentation, decreased wet and dry biomass, increased wet wt:dry wt ratios, decreased removal of nitrogen (N) and phosphorus (P) from the water column and an accumulation of NH(4) in the water column. More frequent exposure to ambient salinity in the 1-day treatment mitigated these effects. Across all salinity levels tested, biomass increased as frequency of exposure to ambient salinity increased. At all durations of exposure to low salinity tested, biomass increased as salinity level increased. We conclude that growth of E. intestinalis is decreased by reduced salinity. E. intestinalis is able to withstand exposure to 0 psu but there is a temporal limit to this tolerance that is somewhere between 1 and 5 days. Populations of E. intestinalis in coastal estuaries may suffer from freshwater inputs if salinity conditions are persistently reduced.

The Use of Aquatic Macrophyte Ecotoxicological Assays in Monitoring Coastal Effluent Discharges in Southern Australia

Germination inhibition of zoospores of the aquatic, brown algal macrophyte Ecklonia radiata was employed to assess the toxicity of sewage effluents under short to long term exposure and under modified salinity conditions. The rate of germination inhibition was determined for exposure times between 2 and 48 h in salinity modified and unmodified regimes and under reduced salinity conditions alone. The results indicated that rate of germination inhibition increased with duration of exposure to sewage effluents and to salinity reduction alone, and that response to the effluents may be enhanced under conditions of reduced salinity. Whilst the effect of primary treated effluent was primarily that of toxicity, secondary treated effluent effects appeared to be primarily that of reduced salinity although at a greater rate than would be expected for salinity reduction alone. The assay is suggested to provide a mechanism for monitoring sewage effluent quality and to monitor potential impacts of sewage effluent discharge on kelp communities in southern Australia.

Foraminifera from the Irish Sea glacigenic deposits at Aberdaron, western Lleyn, North Wales: Palaeoenvironmental implications

AbstractIn a sequence of glacigenic sediments at Aberdaron, Foraminifera were obtained from samples located specifically in order to differentiate between opposing models of depositional environment. All the diamict samples yielded remarkably uniform assemblages, with similar numbers of benthic specimens and benthic species per unit weight of sediment, similar planktic : benthic ratios, and similar ratios of clearly allochthonous to possibly autochthonous elements. This is precisely as predicted by the terrestrial model of sedimentation, where all of the sediments are interpreted as being derived from the melting of glacier ice rich in marine debris entrained during passage along the Irish Sea Basin. The results lend no support to a glacial marine model, since no faunal responses to increasingly distal sedimentary environments are observed. However, the fauna is dominated by the Foraminifera Elphidium excavatum (Terquem) forma clavata Cushman, which is commonly assumed to indicate glacial marine conditions. The modern distribution of similar assemblages suggests that it is just as likely to represent the cold, reduced salinity conditions that would have prevailed in the northern Irish Sea Basin for much of the Quaternary.

Osteoclasts can be induced in fish having an acellular bony skeleton

Kelp bass (Paralabrax clathratus) and leopard sharks (Triakis semifasciata) are characterized by an acellular (anosteocytic) bony skeleton and a focally calcified cartilaginous endoskeleton, respectively. These skeletal forms are not considered to function as mineral reservoirs. Previous studies showed that implanted bone particles are resorbed in rats by large multinucleated cells with ultrastructural features (ruffled borders) characteristic of osteoclasts. We tested the ability of fish to resorb bone matrix and to adapt to reduced salinity conditions. Bone particles were implanted in sharks and bass maintained in seawater (34 ppt, 40.5 mg of calcium per dl) or in diluted seawater (26 ppt, 28.5 mg of calcium per dl). Sera and elicited tissues were harvested 4 weeks later. In sharks, bone particles were not resorbed, and multinucleated cells were not evident under either normal or hyposalinity conditions. Shark sera were isoosmolar with the seawater or diluted seawater, with serum chemistries of the hyposalinity group reflecting the 23% reduction in environmental minerals and electrolytes, compared to sharks in normal seawater. In marked contrast, bass adapted to diluted seawater resorbed bone particles and maintained normal serum chemistries. Electron microcopy showed that the bone particles were surrounded by large, foamy multinucleated cells, many with membrane specializations typical of osteoclasts from higher vertebrates, i.e., extensive clear zones apposed to intact bone matrix and active ruffled borders overlying areas of matrix undergoing dissolution. Although osteoclasts had not been described in these fish, this study shows that bass have stem cells that can be stimulated to differentiate into bone-resorbing osteoclasts.